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Research Trend of Membrane for Water Treatment by Analysis of Patent and Papers Publication (특허 및 논문 게재 분석을 통한 수처리용 분리막의 연구동향)

  • Woo, Chang Hwa
    • Applied Chemistry for Engineering
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    • v.28 no.4
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    • pp.410-419
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    • 2017
  • Since the beginning of the water shortage by disasters such as global warming, environmental pollution, and drought, development of original technology and studies have been undergone to increase availability of water resources. Among them the water treatment separation membrane technology is an environmentally friendly process that does not use chemicals and shows better water quality improvement effect than conventional physicochemical and biological processes. The water treatment membrane can be applied to various fields such as waste water treatment, water purification treatment, seawater desalination, ion exchange process, ultrapure water production, organic solvent separation and water treatment technology, and it tends to expand the range of application. In the core technology of water treatment membrane, researches are being actively carried out to develop a separation membrane of better performance by controlling the pore size to adjust the separation performance. In this review, we summarized the frequency of announcement by country and organization through the technological competitiveness evaluation of patents and papers of the water separation membrane. Also, we evaluated the results from membrane research for waste water treatment, water purification treatment, seawater desalination, ion exchange process and present the future direction of research.

Approaches to Internal Corrosion Control Technologies by Controlling Water Quality in Water Treatment Systems (수질제어를 통한 관 내부 부식방지 기술의 정수처리공정 적용방안)

  • Seo, Dae-Keun;Wang, Chang-Keun
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.4
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    • pp.509-518
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    • 2006
  • Although final water of domestic water treatment plants almost contains highly corrosive characteristics, the countermeasures for eliminating internal corrosion of pipeline system have not been conducted yet by controlling water quality in plants. The technologies of internal corrosion control are to control water quality parameters(pH, Alkalinity, and Calcium Hardness etc.) and to use corrosion inhibitor. Under the conditions of domestic water treatment, first of all, the technologies of adjusting water quality parameters has to be considered. Otherwise, The technology of using corrosion inhibitor is favorably thought to be applied with the technology of adjusting water quality parameters in accordance with the result of availability for water treatment process. Since the technology of adjusting water quality parameter influences on other water treatment processes, the guideline of water quality management to be apt for water quality characteristic is required to be estabilished. While the selection of proper chemicals and technologies is dependent upon the raw water characteristics and water treatment process, typically, the technology of $Ca(OH)_2$ & $CO_2$ additions is considered more effective than other technologies in order to adjust pH and Alkalinity, increase $Ca^{2+}$ and form $CaCO_3$ film

Advanced oxidation technologies for the treatment of nonbiodegradable industrial wastewater (난분해성 산업폐수 처리를 위한 고도산화기술)

  • Kim, Min Sik;Lee, Ki-Myeong;Lee, Changha
    • Journal of Korean Society of Water and Wastewater
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    • v.34 no.6
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    • pp.445-462
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    • 2020
  • Industrial wastewater often contains a number of recalcitrant organic contaminants. These contaminants are hardly degradable by biological wastewater treatment processes, which requires a more powerful treatment method based on chemical oxidation. Advanced oxidation technology (AOT) has been extensively studied for the treatment of nonbiodegradable organics in water and wastewater. Among different AOTs developed up to date, ozonation and the Fenton process are the representative technologies that widely used in the field. Based on the traditional ozonation and the Fenton process, several modified processes have been also developed to accelerate the production of reactive radicals. This article reviews the chemistry of ozonation and the Fenton process as well as the cases of application of these two AOTs to industrial wastewater treatment. In addition, research needs to improve the cost efficiency of ozonation and the Fenton process were discussed.

Influence of Initial Water Content, Specific Surface, Air Drying and Freezing-thawing Action on the Liquid Limit of Soils (초기함수비, 비표면적, 풍건 및 동결.융해작용이 흙의 액성한계에 미치는 영향)

  • 류능환
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.38 no.5
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    • pp.116-124
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    • 1996
  • The purpose of The work described in this paper is to clear up the initial moisture content, specific surface, air drying and freezing-thawing process on liquid limit of clayey soils distributed widely at estuary of three main rivers in the west coast. To this end, a series of tests were conducted on clayey soils samples with natural state and treated state. From the test results, the liquid limit was decreased with decrement of initial moisture content, air drying process, and freezing-thawing cycles and increased with increment of specific surface. The specific surface which influenced on the liquid limit is over $25 m^2$m$^2$/g, and their relationships are well formulated. Air drying process is expected to improve the engineering properties of the soils such the pro-water properties were changed to anti-water proper-ties through lowering of water holding as resulted to incline from A-7-5 to A-5 on the soil classificaction plastic chart. The freezing-thawing process decreased 20% of liquid limit, especially under the first cycle of the behavious, as a result of above mentioned reasons, phase change of soil-water system brought the decrement of specific surface and affected to the liquid limit.

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Mass Prediction of Various Water Cluster Ions for an Accurate Measurement of Aerosol Particle Size Distribution (에어로솔 입자의 정밀입경분포 측정을 위한 물분자 클러스터 이온의 질량예측)

  • Jung, Jong-Hwan;Lee, Hye-Moon;Song, Dong-Keun;Kim, Tae-Oh
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.6
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    • pp.752-759
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    • 2007
  • For an accurate measurement of aerosol particle size distribution using a differential mobility analyser (DMA), a new calculation process, capable of predicting the masses for the various kinds of water cluster ions generated from a bipolar ionizer, was prepared by improving the previous process. The masses for the 5 kinds of positive and negative water cluster ions produced from a SMAC ionizer were predicted by the improved calculation process. The aerosol particle charging ratios calculated by applying the predicted ion masses to particle charging equations were in good accordance with the experimentally measured ones, indicating that the improved calculation process are more reasonable than the previous one in a mass prediction of bipolar water cluster ions.

Influence of the Water Vapor Content on the Hydrogen Reduction Process of Nanocrystalline NiO

  • Jung, Sung-Soo;An, Hyo-Sang;Lee, Jai-Sung
    • Korean Journal of Metals and Materials
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    • v.48 no.4
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    • pp.315-319
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    • 2010
  • In this study, the hydrogen reduction behavior of ball-milled NiO nanopowder was investigated depending on the partial pressure of water vapor. The hydrogen reduction behavior was analyzed by thermogravimetry and hygrometry under heating to 873 K in hydrogen. In order to change the partial pressure of the water vapor, the dew point of hydrogen was controlled in the range of 248 K~293 K by passing high-purity hydrogen through a saturator that contained water. Interestingly, with the increase in the dew point of the hydrogen atmosphere, the first step of the hydrogen reduction process decreased and the second step gradually increased. After the first step, a pore volume analysis revealed that the pore size distribution in the condition with a higher water vapor pressure shifted to a larger size, whereas the opposite appearedat a lower pressure. Thus, it was found that the decrease in the pore volume during the chemical reaction controlled process at a dew point of 248 K caused a reduction in retardation in the diffusion controlled process.

Removal of taste and odor causing compounds in drinking water using Pulse UV System (Pulse UV 장치를 이용한 먹는 물의 이취미 유발물질 제거효과에 관한 연구)

  • Sohn, Jin-Sik;Park, Soon-Ho;Jung, Eui-Taek
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.2
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    • pp.219-228
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    • 2012
  • Problems due to the taste and odor in drinking water are common in treatment facilities around the world. Taste and odor are perceived by the public as the primary indicators of the safely and acceptability of drinking water, and are mainly caused by the presence of two semi-volatile compounds-2-methylisoborneol(2-MIB) and geosmin. Conventional treatment processes in water treatment plants, such as coagulation, sedimentation and chlorination have been found to be ineffective for the removal of 2-MIB and geosmin. Pulse UV system is a new UV irradiation system that is a non-mercury lamp-based alternative to currently used continuous wave systems for water disinfection. This study shows pulse UV system to be effective in treatment of these two compounds. Geosmin removal efficiency of UV process alone achieved approximately 70% at 10sec contact time. 2-MIB removal efficiency of UV only process achieved approximately 60% at 10sec contact time. The addition of $H_{2}O_{2}$ 7mg/L increased geosmin and 2-MIB removal efficiency upto approximately 94% and 91%, respectively.

Removal of low concentration organic matter by reverse osmosis membranes in ultrapure water production process (초순수 제조 공정에서 역삼투 막의 저농도 유기물 제거)

  • Lee, Hongju;Kim, Suhan
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.4
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    • pp.391-396
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    • 2014
  • Ultrapure water (UPW) is water containing nothing but water molecule ($H_2O$). The use of UPW is increasing in many industries such as the thermal and nuclear power plants, petrochemical plants, and semiconductor manufacturers. In order to produce UPW, several unit processes such as ion exchange, reverse osmosis (RO), ultraviolet (UV) oxidation should be efficiently arranged. In particular, RO process should remove not only ions but also low molecular weight (LMW) organic matters in UPW production system. But, the LMW organic matter removal data of RO membranes provided by manufacturers does not seem to be reasonable because they tested the removal in high concentration conditions like 1,000 ppm of isopropyl alcohol (IPA, MW=60.1). In this study, bench-scale experiments were carried out using 4-inches RO modules. IPA was used as a model LMW organic matter with low concentration conditions less than 1 ppm as total organic carbon (TOC). As a result, the IPA removal data by manufacturers turned out to be trustable because the effect of feed concentration on the IPA removal was negligble while the IPA removal efficiency became higher at higher permeate flux.

A Study on the Drinking Water Treatment by Precoat Filtration and Activated Carbon Adsorption Process (규조토여과 및 활성탄흡착 공정을 이용한 용수처리에 관한 연구)

  • Shin Dae-Yewn;Kim Ji-Yeoul;Ji Sung-Nam
    • Journal of Environmental Health Sciences
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    • v.30 no.5 s.81
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    • pp.402-409
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    • 2004
  • I performed the research about the drinking water treatment by precoat filtration and activated carbon adsorption process in the D water treatment plant at Gwangju. D water treatment plant inlet water is supplied from Juam lake in Jeollanamdo. The results are as follows; 1. Element disk used in this experiment are R(pore size $10{\mu}m$), B(pore size $20{\mu}m$). And diatomaceous earth are A(cake pore size $3.5{\mu}m$), B(cake pore size $7{\mu}m$) and C(cake pore size $17{\mu}m$) 2. Filtrate of precoat filter during 30 min are B-C 10.2 > BB 5.7 > R-A 5.4 ($m^3/m^2$). 3. The water quality through B-C+AC and R-A+AC are DOC 1.76 mg/1, 1.288 m/l respectively. 4. total THMs produced by chlorination are $84.2{\mu}g/l$(B-C+AC), $66.11{\mu}g/l$ (R-A+AC), $97{\mu}g/l$ (rapid sand filtration water) respectively. 5. The R-A+AC and B-C+AC process can be substitute of CWTS.

A Study on the Optimal Use of Silent Discharge Type Ozonizer in Purification Plant (정수장의 무성방전형 오존발생기 최적활용방안에 관한 연구)

  • Shin, Hong-Sub;Park, Hyun-Mi;Kwon, Young-Hak;Song, Hyun-Gig;Park, Won-Joo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.29 no.3
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    • pp.54-60
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    • 2015
  • There are 5 purification plants with the adopted advanced water purification treatment process in Korea. Annual operating costs were 8,990 million won including purchase cost of oxygen and power usage charges. We need research to optimize, in the future, when considering the direction of domestic water treatment continues to adopt advanced water treatment process. In this paper, calculate the optimal operating costs by injected the oxygen gas, used power cost. approximately 25% of the operating costs can be reduced when injected the ozone gas is 1.0ppm than 2.0ppm, the necessary amount of oxygen is increased then power is lower. so operating costs are decided according to oxygen costs. On the other hand, high ozone concentration 2.0ppm, the necessary power is increased then amount of oxygen is lower. Therefore, in the case of G purification plant, the controlling factor of the input ozone concentration 2ppm, PID control operation by setting the concentration of over 10Wt% is efficient. The installed capacity is the more little the more better when considering on Ozone injection rate in the process of water treatment.