• Title/Summary/Keyword: process synthesis

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GTL 합성유 제조용 파일럿 플랜트 최적 운전 변수 도출을 위한 합성가스 공정 시뮬레이션 연구 (A simulation study on synthesis gas process optimization for GTL (Gas-to-Liquid) pilot plant)

  • 김용헌;배지한;박명호
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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    • pp.74.2-74.2
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    • 2011
  • A simulation study on synthesis gas process in GTL process was carried out in order to find optimum operation conditions for GTL (gas-to-liquid) pilot plant design. Optimum operating conditions for synthesis gas process were determined by changing reaction variables such as feed temperature and pressure. During the simulation, overall synthesis process was assumed to proceed under steady-state conditions. It was also assumed that physical properties of reaction medium were governed by RKS (Redlich-Kwong-Soave) equation. The effect of temperature and pressure on synthesis gas process $H_2$/CO ratio were mainly examined. Simulation results were also compared to experimental results to confirm the reliability of simulation model. Simulation results were reasonably well matched with experimental results.

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FT(Fischer-Tropsh) 합성유 제조를 위한 합성가스 공정 최적화 연구 (A simulation study on synthesis gas process optimization for FT(Fischer-Tropsh) synthesis)

  • 김용헌;이원수;이흥연;구기영;송인규
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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    • pp.888-888
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    • 2009
  • A simulation study on SCR (Steam Carbon dioxide Reforming) process in gas-to-liquid (natural gas to Fischer-Tropsch synthetic fuel) process was carried out in order to find optimum reaction conditions for GTL (gas-to-liquid) process reaction. Optimum SCR operating conditions for synthesis gas to FT (Fischer-Tropsch) process were determined by changing reaction variables such as feed temperature and pressure. During the simulation, overall synthesis process was assumed to proceed under steady-state conditions. It was also assumed that physical properties of reaction medium were governed by RKS (Redlich-Kwong-Soave) equation. SCR process was considered as reaction models for synthesis gas in GTL proess. The effect of temperature and pressure on SCR process $H_2$/CO ratio and the effect of reaction pressure on SCR reaction were mainly examined. Simulation results were also compared to experimental results to confirm the reliability of simulation model. Simulation results were reasonably well matched with experimental results.

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방사성의약품 합성 프로세스 검증을 위한 네트워크 모델링 (Development of A Validation System For Automatic Radiopharmaceutical Synthesis Process Using Network Modeling)

  • 이철수;허은영;김종민;김동수
    • 산업공학
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    • 제24권3호
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    • pp.187-195
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    • 2011
  • The automatic radiopharmaceutical module consists of several 2-way valves, couple of syringes, gas supply unit, heating(cooling) unit and sensors to control the chemical reagents as well as to help the chemical reaction. In order to control the actuators of radiopharmaceutical module, the process is tabulated using spread sheet as like excel. Unlike the common program, a trivial error is too critical to allowed in the process because the error can lead to leak the radioactive reagent and to cause the synthesis equipment failure during synthesizing. Hence, the synthesis process has been validated using graphic simulation while the operator checks the whole process visually and undergoes trial and error. The verification of the synthesis process takes a long time and has a difficulty in finding the error. This study presents a methodology to verify the process algebraically while the radiopharmaceutical module is converted to the network model. The proposed method is validated using actual synthesis process.

연소합성법을 이용한 Ni 분말 합성에서 첨가 연료의 영향 (Effect of Fuel on Synthesis of Nanocrystalline Ni particles by a Combustion Synthesis Process)

  • 정충환;신형철;이희균;홍계원;윤순길
    • 한국분말재료학회지
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    • 제8권1호
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    • pp.13-19
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    • 2001
  • Ni and NiO particles were made by a combustion synthesis process. The characteristics of synthesized powders were investigated with various kinds and amounts of fuels such as urea, citric acid and glycine. Ni phase particles without NiO phase were obtained through combustion synthesis process in air atmosphere with-out further calcinations process, when the content of glycine was 2.44 times of the stoichiometric ratio in the precursor solution. Primary particle sizes of synthesized Ni and NiO particles were about 20∼30 nm.

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폐기물 열분해과정에서 발생된 합성가스의 연소 특성 (Combustion Characteristics of Synthesis Gas Generated in Waste Pyrolysis Process)

  • 안용수;황상순;이성호;이협희
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 제26회 KOSCO SYMPOSIUM 논문집
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    • pp.143-150
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    • 2003
  • The synthesis gas generated in waste pyrolysis melting process which consists of pyrolysis of waste and melting process of ash is known to be an alternative fuel. Since the compositopn of synthesis gas is much different from other synthesis gases, the fundamental combustion characteristics are analyzed in this study. The radiation heat heat flux is used to estimate the heat flux from flames made by many combinations of fuel and oxidant supply. The results show that the synthesis gas needs much more amount of oxidant for equivalent heat flux to methane flame and the inverse diffusion flame type for synthesis gas burner is suitable for better radiation heat transfer.

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암모니아 식각 가스 도입에 의한 고순도 탄소나노튜브의 합성 (Carbon Nanotube Synthesis with High Purity by Introducing of NH3 Etching Gas)

  • 이선우;이붕주
    • 전기학회논문지
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    • 제62권6호
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    • pp.782-785
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    • 2013
  • Multi-walled carbon nanotubes were synthesized on Ni catalyst using thermal chemical vapor deposition. By introducing ammonia gas during the CNT synthesis process, clean and vertically aligned CNTs without impurities could be prepared. As the ammonia gas increased a partial pressure of hydrogen in the mixed gas during the CNT synthesis process, we could control the CNT synthesis rate appropriately. As the ammonia gas has an etching ability, amorphous carbon species covering the catalyst particles were effectively removed. Therefore catalyst particles could maintain their catalytic state actively during the synthesis process. Finally, we could obtain clean and vertically aligned CNTs by introducing $NH_3$ gas during the CNT synthesis process.

파일럿 플랜트 최적운전을 위한 SCR공정 동적 모사 (A dynamic simulation study on SCR (Stream Carbon dioxide Reforming) process for pilot plant operation)

  • 김용헌;배지한;박명호
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
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    • pp.136.2-136.2
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    • 2011
  • A dynamic simulation study on SCR process in GTL process was carried out in order to find optimum operation conditions for pilot plant operation. Optimum operating conditions for SCR synthesis gas process were determined by changing operation variables such as feed temperature and pressure. It was also assumed that physical properties of reaction medium were governed by RKS (Redlich-Kwong-Soave) equation. The effect of temperature and pressure on synthesis gas process $H_2$/CO ratio were mainly examined. Dynamic simulation results were fed back to feed operation condition for optimizing productivity, especially for appropriate condition to FT (Fischer-Tropsch) synthesis unit.

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직류 열플라즈마를 이용한 질화알루미늄 초미세분말의 합성 (Synthesis of Ultrafine Powders for Aluminum Nitride by DC Thermal Plasma)

  • 안현;허민;홍상희
    • 한국표면공학회지
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    • 제29권1호
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    • pp.45-59
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    • 1996
  • Ultrafine powders(UFPs) of aluminum nitride(AlN) have been synthesized by chemical reactions in the nitrogen atmosphere and the gaseous aluminum evaporated from Al powders in thermal plasmas produced by a DC plasma torch. A synthesis system consisting of a plasma torch, a finely-controllable powder feeder, a reaction chamber, and a quenching-collection chamber have been designed and manufactured, and a filter for gathering AlN UFPs produced by the quenching process subsequent to the synthesis is set up. The synthesis process is interpreted by numerical analyses of the plasma-particle interaction and the chemical equilibrium state, respectively, and a fully-saturated fractional factorial test is used to find the optimum process conditions. The degrees and ultrafineness of synthesis are evaluated by means of SEM, TEM, XRD, and ESCA analyses. AlN UFPs synthesized in the optimum process conditions have polygonal shapes of the size of 5-100 nm, and their purities differ depending on collecting positions and filter types, and the maximum purity obtained is 72 wt% at the filter.

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단백질 합성 과정 종이 모형 개발과 고등학교 생물 수업에서의 활용 (Development and Application of the Paper Model of Protein Synthesis Process in High School Biology)

  • 변선영;심규철
    • 과학교육연구지
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    • 제34권2호
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    • pp.268-278
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    • 2010
  • 본 연구에서는 단백질 합성 과정을 효과적으로 학습하기 위한 단백질 합성 과정 종이 모형을 개발하여 고등학교 생물 수업에서 그 교육적 효과를 알아보고자 하였다. 교육적 효과를 알아보기 위해 대전에 위치한 고등학교 2학년 117명을 대상으로 적용하였다. 실험 집단(59명)은 본 연구에서 개발한 단백질 합성 과정 종이 모형을 활용한 수업을 적용하였으며 통제 집단(58명)은 전통적 설명식 수업을 적용하였다. 그 결과 단백질 합성 과정 종이 모형을 적용 수업의 학생들의 학업성취도 향상 효과가 있었으며 학습 흥미 또한 향상된 것으로 나타났다. 단백질 합성 과정과 같이 추상적이거나 비가시적이어서 이해하기 어려운 학습 내용의 경우 종이 모형과 같은 구체적 경험을 활용한 수업을 활용하는 것이 효과적인 것을 알 수 있었다. 또한 이러한 학습 내용에 적절하면서도 흥미를 유발할 수 있는 새로운 모형 개발과 더불어 학교 현장에서 이를 적극 활용할 수 있도록 하기 위한 방안이 필요하다.

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Stoffenmanager nano 컨트롤 밴딩 도구 이해와 나노물질 합성 및 포장 공정 적용 연구 (Understanding and Application of Stoffenmanager Nano Tool into Synthesis and Packing Process of Nanomaterials)

  • 이나루;안정호
    • 한국산업보건학회지
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    • 제25권1호
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    • pp.95-103
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    • 2015
  • Objectives: This study was conducted in order to better understand the conceptual model and Stoffenmanager nano module and apply it to the synthesis and packing processes of nanomaterials. Methods: Site visits were conducted to five nanomaterial production processes. Product and exposure variables were investigated in these workplaces. Hazard banding and exposure classification of the synthesis and packing processes of nanomaterials were conducted using documents and the website of Stoffenmanager Nano. Results: The five sites featured different products, packing tasks, ventilation and local exhaust, and others. The hazards for nano-nickel and copper were classified as E. The hazards for both fumed silica and indium tin oxide were classified as D. The hazard for spherical silica was classified as C. The exposure classes in the synthesis process of nanomaterials ranged from 2 through 4. The exposure classes in the packing process of nanomaterials ranged from 1 through 4. Conclusions: Application of Stoffenmanager nano to the synthesis and packing processes of nanomaterials helped to better understand the control level of the work environment and to suggest appropriate actions. The comparison of each process showed the effect of the production process and handling of solids and ventilation on exposure class.