• Title/Summary/Keyword: process gas flow

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Adhesion Characteristics of Polymer Material Treated by Atmospheric Pressure Plasma (상압 플라즈마 표면처리에 의한 고분자 재질의 접착특성 변화)

  • Seo, Seung-Ho;Chang, Sung-Hwan;Yoo, Yeoung-Een;Chung, Jae-Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.5
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    • pp.445-450
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    • 2011
  • We studied the adhesion characteristics of polymer films (PC, PET, EVA) treated by atmospheric pressure plasma. The process parameters were the frequency, gas flow, and treatment time; we studied the effects of these parameters on the adhesion characteristics of the polymer materials. We used de-ionized water and diiodomethane as the polar and nonpolar solvents, respectively, for measuring the contact angles, and subsequently calculated the surface free energy of each polymer film. The adhesion characteristics were studied by carrying out a $180^{\circ}$ peel-off test. The polymer films treated with plasma developed a hydrophilic surface, which led to increased surface free energy and improved adhesion properties. From the results for contact angle, surface free energy, and adhesion strength, we obtained the optimal plasma-treatment conditions.

Origin of Decreasing the Dielectric Constant and the Effect of Ionic Polarization (유전상수가 낮아지는 원인과 이온 분극의 효과)

  • Oh, Teresa
    • Journal of the Korean Vacuum Society
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    • v.18 no.6
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    • pp.453-458
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    • 2009
  • SiOC film was deposited by the chemical vapor deposition using BTMSM and oxygen mixed precursor. The characteristic of SiOC film varied with increasing of the gas flow rate ratios. The dielectric constant was obtained by C-V measurement using the structure of metal/SiOC film/Si. The space effect due to the steric hindrance between alkyl group at terminal bond of Si-$CH_3$ made the pores, and increased the thickness. However, the SiOC film due to the lowering of the polarization decreased the thickness and then decreased the dielectric constant. After annealing process, the dielectric constant decreased because of the evaporation of the OH or $H_2O$ sites. The thickness was related to the lowering of the dielectric constant by the reduction of the polarization and the thickness decreased with the decrease of the dielectric constant. The refractive index was in inverse proportion to thickness. The trends of the thickness and refractive index did not change after annealing.

Phenol Conversion Properties in Aqueous Solution by Pulsed Corona Discharge (펄스 코로나 방전에 의한 액체상 페놀 전환 특성)

  • Lee, Hyun-Don;Chung, Jae-Woo;Cho, Moo-Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.1
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    • pp.40-46
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    • 2007
  • A laboratory scale experiment on phenol conversion properties by pulsed corona discharge process was carried out. Effects of operating parameters such as applied voltage, input oxygen, and electrode geometry on phenol conversion and solution properties were investigated. Electrical discharges generated in liquid phase increased the liquid temperature by heat transfer from current flow, decreased the pH value by producing various organic acids from phenol degradation, and increased conductivity by generating charge carriers and organic acids. The oxygen supply enhanced the phenol conversion through the ozone generation dissolution and the production of OH radicals. Series type electrode configuration induced more ozone production than reference type configuration because it produced gas phase discharges as well as liquid phase discharges. Therefore, the higher phenol conversion and TOC(total organic carbon) removal efficiency were obtained in series type configuration.

Structural Properties of Ammoniated Thin Cr Films with Oxygen Incorporated During Deposition (산소가 혼입된 Cr 박막의 질화처리에 따른 구조적 특성)

  • Kim, Jun;Byun, Changsob;Kim, Seontai
    • Korean Journal of Materials Research
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    • v.24 no.4
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    • pp.194-200
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    • 2014
  • Metallic Cr film coatings of $1.2{\mu}m$ thickness were prepared by DC magnetron sputter deposition method on c-plane sapphire substrates. The thin Cr films were ammoniated during horizontal furnace thermal annealing for 10-240 min in $NH_3$ gas flow conditions between 400 and $900^{\circ}C$. After annealing, changes in the crystal phase and chemical constituents of the films were characterized using X-ray diffraction (XRD) and energy dispersive X-ray photoelectron spectroscopy (XPS) surface analysis. Nitridation of the metallic Cr films begins at $500^{\circ}C$ and with further increases in annealing temperature not only chromium nitrides ($Cr_2N$ and CrN) but also chromium oxide ($Cr_2O_3$) was detected. The oxygen in the films originated from contamination during the film formation. With further increase of temperature above $800^{\circ}C$, the nitrogen species were sufficiently supplied to the film's surface and transformed to the single-phase of CrN. However, the CrN phase was only available in a very small process window owing to the oxygen contamination during the sputter deposition. From the XPS analysis, the atomic concentration of oxygen in the as-deposited film was about 40 at% and decreased to the value of 15 at% with increase in annealing temperature up to $900^{\circ}C$, while the nitrogen concentration was increased to 42 at%.

Gasification of Coal-Petroleum Coke-Water Slurry in a 1 ton/d Entrained Flow Gasifier (1톤/일 분류층가스화기에서 석탄과 석유코크스 혼합 슬러리의 가스화특성)

  • Yoon, Sang Jun;Choi, Young-Chan;Hong, Jai-Chang;Ra, Ho Won;Lee, Jae Goo
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.561-566
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    • 2008
  • Gasification plant using petroleum coke for refinery and power generation process is increased from considering petroleum coke as a valuable fuel. In this study, gasification of petroleum coke was performed to utilize petroleum coke and to develop essential technology using 1T/D coal gasification system. In case of petroleum coke gasification, because of lower reactivity, consumption of oxygen is higher than coal gasification. The calorific value of syngas from petroleum coke mixed with coal at a mass ratio of 1:1 shows about $6.7{\sim}7.2MJ/Nm^3$. Although carbon conversion could reach more than 92% according to oxygen amount, cold gas efficiency shows lower value than the case of coal. Therefore, it was shown that complemental study in burner design to atomize slurry droplet is required to elevate gasification performance of petroleum coke which has lower reactivity than coal.

The Control of Side Reactions in Bunsen Reaction Section of Sulfur-Iodine Hydrogen Production Process (황-요오드 수소 생산 공정의 분젠 반응 부분에서 부반응 제어)

  • Lee, Kwang-Jin;Hong, Dong-Woo;Kim, Young-Ho;Park, Chu-Sik;Bae, Ki-Kwang
    • Journal of Hydrogen and New Energy
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    • v.19 no.6
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    • pp.490-497
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    • 2008
  • For continuous operation of the sulfur-iodine(SI) thermochemical cycle, which is expected practical method for massive hydrogen production, suggesting operation conditions at steady state is very important. Especially, in the Bunsen reaction section, the Bunsen reaction as well as side reactions is occurring simultaneously. Therefore, we studied on the relation between the variation of compositions in product solution and side reactions. The experiments for Bunsen reaction were carried out in the temperature range, from 268 to 353 K, and in the $I_2/H_2O$ molar ratio of $0.094{\sim}0.297$ under a continuous flow of $SO_2$ gas. As the result, sulfur formed predominantly with increasing temperature and decreasing $I_2/H_2O$ molar ratios. The molar ratios of $H_2O/H_2SO_4$ and $HI/H_2SO_4$ in global system were decreased as the more side reaction occurred. A side reactions did not appear at $I_2/H_2O$ molar ratios, saturated with $I_2$, irrespective of the temperature change. We concluded that it caused by the increasing stability of an $I_{2x}H^+$ complex and a steric hindrance with increasing $I_2/HI$ molar ratios.

Water Vapor Permeability of SiO2 Oxidative Thin Film by CVD (CVD로 제작된 SiO2 산화막의 투습특성)

  • Lee, Boong-Joo;Shin, Hyun-Yong
    • The Journal of the Korea institute of electronic communication sciences
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    • v.5 no.1
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    • pp.81-87
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    • 2010
  • In this paper, we have fabricated $SiO_2$ oxidation thin films by HDP-CVD(high density plasma-chemical vapor deposition) method for passivation layer or barrier layer of OLED(organic light emitting diode). We have control and estimate the deposition rate and relative index characteristics with process parameters and get optimized conditions. They are gas flow rate($SiH_4:O_2$=30:60[sccm]), 70 [mm] distance from source to substrate and no-bias. The WVTR(water vapor transmission rate) is 2.2 [$g/m^2$_day]. Therefore fabricated thin film can not be applied as passivation layer or barrier layer of OLED.

Study on the Application of the Electric Drive System of Fuel Pump for Diesel Engine of Commercial Vehicle using HILS (HILS기반 상용차 디젤엔진용 연료펌프의 전기구동 시스템 적용에 관한 연구)

  • Ko, Youngjin
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.2
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    • pp.166-174
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    • 2014
  • Fuel injection pressure has steadily increased in diesel engines for the purpose of improving fuel efficiency and cleaning exhaust gas, but it has now reached a point, where the cost for higher pressure does not warrant additional gains. Common rail systems on modern diesel engines have fuel pumps that are mechanically driven by crankshaft. The pumps actually house two pumping module inside: a low pressure pump component and a high pressure pump component. Part of the fuel compressed by the low pressure component returns to the tank in the process of maintaining the pressure in the common rail. Since the returning fuel represents pumping loss, fuel economy improves if the returned fuel can be eliminated by using a properly controled electrical fuel pump. As the first step in developing an electrical fuel pump the fuel supply system on a 6 liter diesel engine was modeled with AMESim to analyze the workload and the fuel feed rate of the injection pump, and the results served as basis for selecting a suitable servo motor and a reducer to drive the pump. A motor controller was built using a DSP and a program which controls the common rail pressure using a proportional control method based on the target fuel pressure information from the engine ECU. A test rig to evaluate performance of the fuel pump is implemented and used to show that the newly developed electrically driven fuel pump can satisfy the fuel flow demand of the engine under various operating conditions when the rotational speed of the pump is adequately controlled.

Analysis of Lattice constants change for study of W-C-N Diffusion (W-C-N 확산방지막의 격자상수 변화 분석을 통한 특성 연구)

  • Kim, Soo-In;Lee, Chang-Woo
    • Journal of the Korean Vacuum Society
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    • v.17 no.2
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    • pp.109-112
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    • 2008
  • The miniaturization of device size and submicron process causes serious problems in conventional metallization due to the solubility of silicon and metal at the interface, such as an increasing contact resistance in the contact hole and interdiffusion between metal and silicon. Moreover, the interaction between Cu and Si is so strong and detrimental to the electrical performance of Si even at temperatures below $200^{\circ}C$. Therefore it is necessary to implement a barrier layer between Cu and Si. So we study W-C-N diffusion barrier for prevent Cu diffusion as a function of $N_2$ gas flow and thermal stability. Especially, we also study the W-C-N diffusion barrier for analyzing the change of lattice constants.

A Study of Automation for Examination Analysis of Inservice Inspection for Nuclear Power Plant (I) (원자력발전소(原子力發電所) 가동중(稼動中) 검사(檢査)의 시험분석(試驗分析)을 위한 자동화연구(自動化硏究) (I))

  • Kim, W.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.5 no.1
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    • pp.34-47
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    • 1985
  • The developing country, KOREA where does not possess the natural resources for traditional energy such as oil and gas, so. The nuclear energy is the most single reliable source available for closing the energy gap. For these reason, It is inavoidable to construct the nuclear power plant and to develop technology related nuclear energy. The rate of operation in large nuclear power facilities depends upon the performance of work system through design and construction, and also the applied technology. Especially, it is the most important element that safety and reliability in operation of nuclear power plant. In view of this aspects, Nuclear power plant is performed severe examinations during preservice and inservice inspection. This study provide an automation of analysis for volumetric examination which is required to nuclear power plant components. It is composed as follows: I. Introduction II. Inservice Inspection of Nuclear Power Plant ${\ast}$ General Requirement. ${\ast}$ Principle and Methods of Ultrasonic Test. ${\ast}$ Study of Flaw Evaluation and Design of Classifying Formula for Flaws. III. Design of Automation for Flaw Evaluation. IV. An Example V. Conclusion In this theory, It is classifying the flaws, the formula of classifying flaws and the design of automation that is the main important point. As motioned the above, Owing to such as automatic design, more time could be allocated to practical test than that of evaluation of defects, Protecting against subjective bias tester by himself and miscalculation by dint of various process of computation. For the more, adopting this method would be used to more retaining for many test data and comparative evaluating during successive inspection intervals. Inspite of limitation for testing method and required application to test components, it provide useful application to flow evaluation for volumetric examination. Owing to the characteristics of nuclear power plant that is highly skill intensive industry and has huze system, the more notice should be concentrated as follows. Establishing rational operation plan, developing various technology, and making the newly designed system for undeveloped sector.

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