• Title/Summary/Keyword: pressure evolution

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Effect of irradiation on the oxidation kinetics of TODGA-based extraction mixtures at atmospheric pressure

  • Skvortsov, I.V.;Belova, E.V.;Yudintsev, S.V.
    • Nuclear Engineering and Technology
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    • v.52 no.9
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    • pp.2034-2040
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    • 2020
  • The gas evolution from mixtures consisting of 0.2 M solution of N,N,N',N'-tetra-n-octyldiglycolamide (TODGA) in n-alcohol (n-decanol or n-nonanol) with Isopar-M diluent was investigated during thermal oxidation. The effect of ionizing radiation on their thermal stability has been studied. It has been determined that the volume of gaseous thermolysis products increases by 260% in the case of n-nonanol and 80% in the case of n-decanol compared to non-irradiated solutions. It has been shown that the gas evolution rate and gas volume increase when the irradiated mixture saturated with nitric acid is heated. However, there are no prerequisites for the development of autocatalytic oxidation.

Environmental effect on the chemical properties of star forming galaxies in the Virgo cluster

  • Chung, Jiwon;Rey, Soo-Chang;Kim, Suk;Lee, Ung
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.46.2-46.2
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    • 2013
  • We utilize Sloan Digital Sky Survey DR7 spectroscopic data of ~380 star forming galaxies in the Virgo cluster to investigate their chemical properties depending on the environments. The chemical evolution of galaxies is linked to their star formation histories as well as to the gas interchange in different environments. We derived star formation rate (SFR) and gaseous metallicity (e.g., oxygen abundance) of star forming galaxies. Combining with GALEX ultraviolet photometry and ALFALFA HI 21 cm data, we examine the relations between SFRs, metallicity, and HI deficiency of galaxies in various regions of the Virgo cluster. We also quantify the degree of ram pressure around galaxy using the ROSAT X-ray surface brightness map. We discuss environmental effects on the chemical properties and evolution of star forming galaxies.

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Analysis of the Pultrusion Process of Thermosetting Composites Containing Volatiles (휘발물질이 존재하는 열경화성수지 복합재료의 Pultrusion 공정 해석)

  • 김대환;이우일;김병선
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.2
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    • pp.527-536
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    • 1995
  • Analysis of pultrusion process for the thermosetting composites containing volatiles was performed. Degree of cure, amount of volatile evolved and pulling force were calculated for the processing variables such as die temperature and pulling speed. Cure kinetics was modeled from the data obtained by DSC(Differential Scanning Calorimeter). The volatile evolution kinetics was modeled from the data by DSC as well as TGA(Thermo Gravimetric Analyzer). The cure kinetics and volatile evolution kinetics models were incorporated into the energy equation. The resulting governing equation was solved using finite element method. Pulling force was calculated through the analysis of pressure developed inside the pultrusion die. Experiments were performed and the data were compared with the calculated results. Good agreements were observed.

Diffusive Shock Acceleration with Self-Consistent Injection

  • KANG HYESUNG
    • Journal of The Korean Astronomical Society
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    • v.34 no.4
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    • pp.293-295
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    • 2001
  • A numerical scheme that incorporates a self-consistent cosmic-ray (CR, hereafter) injection model into the combined gas dynamics and CR diffusion-convection code has been developed. The hydro/CR code can follow in a very cos-effective way the evolution of CR modified shocks by adopting subzone shock-tracking and multi-level Adaptive Mesh Refinement techniques. The injection model is based on interactions of the suprathermal particles with self-generated MHD waves in quasi-parallel shocks. The particle injection is followed numerically by filtering the diffusive flux of suprathermal particles across the shock to upstream region according to a velocity-dependent transparency function, which represents the fraction of leaking suprathermal particles. In the strong shock limit of Mach numbers $\ge$20, significant physical processes such as the injection and acceleration seem to become independent of M, while they are sensitively dependent on M for M < 10. Although some particles injected early in the evolution continue to be accelerated to higher energies, the postshock CR pressure reaches a time asymptotic value due to balance between acceleration and diffusion of the CR particles.

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Probing Tidal Field Strength of Virgo Cluster Galaxies

  • Yoon, Hye-In;Chung, Ae-Ree
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.2
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    • pp.74.2-74.2
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    • 2011
  • We probe the tidal perturbation parameter f of Virgo cluster galaxies. The goal is to measure the strength of tidal fields around individual galaxies to get better understanding gravitational processes that can affect galaxy evolution in the cluster environment. The f-value is defined as a logarithmic ratio between the net internal gravitational force within a galaxy and the external tidal force exerted by a neighboring galaxy. Hence, it provides one way to quantify the tidal field strength of galaxies, in particular, due to galaxy neighbors. In this study, we determine f-values of the VIVA galaxies, samples of the VLA Imaging study of Virgo galaxies in Atomic gas, using the Extended Virgo Cluster Catalog (EVCC) which is the most complete Virgo cluster catalog to date. With diagnostics based on the HI gas and R-band morphologies, we discuss the impact of the tidal fields on the evolution of the VIVA sample. Also, we compare the tidal field strength to the intra cluster medium (ICM) pressure for each sample galaxy to pin down environmental processes at work.

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Evaluation of long term shaft resistance of the reused driven pile in clay

  • Cui, Jifei;Rao, Pingping;Wu, Jian;Yang, Zhenkun
    • Geomechanics and Engineering
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    • v.29 no.2
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    • pp.171-182
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    • 2022
  • Reusing the used pile has not yet been implemented due to the unpredictability of the bearing capacity evolution. This paper presents an analytic approach to estimate the sides shear setup after the dissipation of pore pressure. Long-term evolution of adjacent soil is simulated by viscoelastic-plastic constitutive model. Then, an innovative concept of quasi-overconsolidation is proposed to estimate the strength changes of surrounding soil. Total stress method (α method) is employed to evaluate the long term bearing capacity. Measured data of test piles in Louisiana and semi-logarithmic time function are cited to validate the effectiveness of the presented method. Comparisons illustrate that the presented approach gives a reasonably prediction of the side shear setup. Both the presented method and experiment show the shaft resistance increase by 30%-50%, and this highlight the potential benefit of piles reutilization.

In-situ monitoring of oxidation states of vanadium with ambient pressure XPS

  • Kim, Geonhwa;Yoon, Joonseok;Yang, Hyukjun;Lim, Hojoon;Lee, Hyungcheol;Jeong, Changkil;Yun, Hyungjoong;Jeong, Beomgyun;Ethan, Crumlin;Lee, Juhan;Ju, Honglyoul;Mun, Bongjin Simon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.125.2-125.2
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    • 2015
  • The evolution of oxidation states of vanadium is monitored with ambient pressure X-ray photoemission spectroscopy. As the pressure of oxygen gas and surface temperature change, the formations of various oxidation states of vanadium are observed on the surface. Under 100mTorr of the oxygen gas pressure and 523K of sample temperature, VO2 and V2O5 are formed on the surface. The temperature-dependent resistance measurement on grown sample shows a clear metal-insulator transition near 350K. In addition, the measurement of Raman spectroscopy displays the structural change from monoclinic to rutile structures across the phase transition temperature.

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Quantitative Estimation of Radiation Damage in Reactor Pressure Vessel Steels by Using Multiscale Modeling (멀티스케일 모델링을 이용한 압력용기강의 조사손상 정량예측)

  • Lee, Gyeong-Geun;Kwon, Junhyun
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.10 no.1
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    • pp.113-121
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    • 2014
  • In this work, an integrated model including molecular dynamics and chemical rate theory was implemented to calculate the growth of point defect clusters(PDC) and copper-rich precipitates(CRP) which could change the mechanical properties of reactor pressure vessel(RPV) steels in a nuclear power plant. A number of time-dependent differential equations were established and numerically integrated to estimate the evolution of irradiation defects. The calculation showed that the concentration of the vacancies was higher than that of the self-interstitial atoms. The higher concentration of vacancies induced a formation of the CRPs in the later stage. The size of the CRPs was used to estimate the mechanical property changes in RPV steels, as is the same case with the PDCs. The calculation results were compared with the measured values of yield strength change and Charpy V-notch transition temperature shift, which were obtained from the surveillance test data of Korean light water reactors(LWRs). The estimated values were in fair agreement with the experimental results in spite of the uncertainty of the modeling parameters.

Surface Graphite Formation of the Brown Colored Type I Diamonds During High Pressure Annealing (갈색 Type I 다이아몬드의 고압 열처리에 따른 표면 흑연화 생성 연구)

  • Song, Jeongho;Song, Ohsung
    • Journal of the Korean Ceramic Society
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    • v.49 no.6
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    • pp.614-619
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    • 2012
  • We investigated color and graphite layer formation on the surface of Type I tinted brown diamonds exposed for 5 minutes under a high-pressure high-temperature (HPHT) condition in a stable graphite regime. We executed the HPHT processes of Process I, varying the temperature from $1600^{\circ}C$ to $2300^{\circ}C$ under 5.2 GPa pressure for 5 minutes, and Process II, varying the pressure from 4.2 to 5.7 GPa at $2150^{\circ}C$ for 5 minutes. Optical microscopy and micro-Raman spectroscopy were used to check the microstructure and surface layer phase evolution. For Process I, we observed a color change to vivid yellow and greenish yellow and the growth of a graphite layer as the temperature increased. For Process II, the graphite layer thickness increased as the pressure decreased. We also confirmed by 531 nm micro-Raman spectroscopy that all diamonds showed a $1440cm^{-1}$ characteristic peak, which remained even after HPHT annealing. The results implied that HPHT-treated colored diamonds can be distinguished from natural stones by checking for the existence of the $1440cm^{-1}$ peak with 531 nm micro-Raman spectroscopy.

Three-Dimensional Numerical Analysis for Detonation Propagating in Circular Tube

  • Sugiyama, Yuta;Matsuo, Akiko
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.364-370
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    • 2008
  • Spinning detonations propagating in a circular tube were numerically investigated with a one-step irreversible reaction model governed by Arrhenius kinetics. The time evolution of the simulation results was utilized to reveal the propagation mechanism of single-headed spinning detonation. The track angle of soot record on the tube wall was numerically reproduced with various levels of activation energy, and the simulated unique angle was the same as that of the previous reports. The maximum pressure histories of the shock front on the tube wall showed stable and unstable pitch modes for the lower and higher activation energies, respectively. The shock front shapes and the pressure profiles on the tube wall clarified the mechanisms of two modes. The maximum pressure history in the stable pitch remained nearly constant, and the single Mach leg existing on the shock front rotated at a constant speed. The high and low frequency pressure oscillations appeared in the unstable pitch due to the generation and decay of complex Mach interaction on the shock front shape. The high frequency oscillation was self-induced because the intensity of the transverse wave was changed during propagation in one cycle. The high frequency behavior was not always the same for each cycle, and therefore the low frequency oscillation was also induced in the pressure history.

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