• Title/Summary/Keyword: pressure evolution

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Thermal Decomposition Characteristics of Azo compounds (아조(Azo)화합물 열분해특성)

  • Kim, Kwan-Eung
    • Journal of the Korean Society of Safety
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    • v.17 no.2
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    • pp.39-44
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    • 2002
  • This study was investigated the thermal decomposition characteristics of azo type sponge blowing agent azodicarbonamide(ADCA) using differential scanning calorimeter(DSC). The experimental results showed that the exothermic onset $temperatures(T_{o})$ for ADCA were about $201{\sim}206^{\circ}C$ and evolution heats(Q) were about $144{\sim}150cal/g$. The exothermic onset $temperatures(T_{o})$, exothermic maximum $temperature(T_{m})$ and exothermic final $temperature(T_{f})$ were decreased by decreasing particle size of ADCA and evolution heats(Q) were increased with it. $T_{o}$ and Q for $6.1{\sim}7.2{\mu}m$ ADCA were increased by increasing heating rate at constant sample weight and activation energy was about 37.29kcal/mol. A positive gas pressure was employed in the elucidation of the decomposition behavior of ADCA because it sublimes during linear heating at atmospheric pressure. $T_{o}$ and Q of ADCA tended to increase with a pressure in air or nitrogen. In the case of azo dye, experimental results showed that $T_{o}$ were about $280{\sim}420^{\circ}C$ and Q were about $2{\sim}30cal/g$.

MULTISCALE MODELING OF RADIATION EFFECTS ON MATERIALS: PRESSURE VESSEL EMBRITTLEMENT

  • Kwon, Jun-Hyun;Lee, Gyeong-Geun;Shin, Chan-Sun
    • Nuclear Engineering and Technology
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    • v.41 no.1
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    • pp.11-20
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    • 2009
  • Radiation effects on materials are inherently multiscale phenomena in view of the fact that various processes spanning a broad range of time and length scales are involved. A multiscale modeling approach to embrittlement of pressure vessel steels is presented here. The approach includes an investigation of the mechanisms of defect accumulation, microstructure evolution and the corresponding effects on mechanical properties. An understanding of these phenomena is required to predict the behavior of structural materials under irradiation. We used molecular dynamics (MD) simulations at an atomic scale to study the evolution of high-energy displacement cascade reactions. The MD simulations yield quantitative information on primary damage. Using a database of displacement cascades generated by the MD simulations, we can estimate the accumulation of defects over diffusional length and time scales by applying kinetic Monte Carlo simulations. The evolution of the local microstructure under irradiation is responsible for changes in the physical and mechanical properties of materials. Mechanical property changes in irradiated materials are modeled by dislocation dynamics simulations, which simulate a collective motion of dislocations that interact with the defects. In this paper, we present a multi scale modeling methodology that describes reactor pressure vessel embrittlement in a light water reactor environment.

A Unified Analysis of Low-Power and High-Power Density Laser Welding Processes with Evolution of Free Surface (자유표면변형을 고려한 저에너지밀도 및 고에너지밀도 레이저 용접공정 통합 해석)

  • Ha Eung-Ji;Kim Woo-Seung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.10 s.241
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    • pp.1111-1118
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    • 2005
  • In this study, a unified numerical investigation has been performed on the evolution of weld pool and key-hole geometry during low-power and high-power density laser welding. Unsteady phase-change heat transfer and fluid flow with the surface tension are examined. The one-dimensional vaporization model is introduced to model the overheated surface temperature and recoil pressure during high-power density laser welding. It is shown that Marangoni convection in the weld pool is dominant at low-power density laser welding, and the keyhole with thin liquid layer and the hump are visible at high-power density laser welding. It is also shown that the transition from conduction welding to penetration welding fur iron plate exists when the laser power density is about $10^6W/Cm^2$.

Thermal stability of nitric acid solutions of reducing agents used in spent nuclear fuel reprocessing

  • Obedkov, A.S.;Kalistratova, V.V.;Skvortsov, I.V.;Belova, E.V.
    • Nuclear Engineering and Technology
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    • v.54 no.9
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    • pp.3580-3585
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    • 2022
  • The thermal stability of carbohydrazide, hydrazine nitrate, acetohydroxamic acid in nitric acid solutions has been studied at atmospheric pressure and above atmospheric pressure. The volumes of gaseous products of thermolysis and the maximum rate of gas evolution have been determined at atmospheric pressure. It has been shown that, despite the high rate of gas evolution and large volumes of evolved gases, the conditions for the development of autocatalytic oxidation are not created. Exothermic processes are observed in a closed vessel in the temperature range of 50-250 ℃. With an increase in the concentration of nitric acid, the temperatures of the onset of exothermic effects for all mixtures decrease, and the values of the total thermal effects of reactions increase, to the greatest extent for solutions with carbohydrazide.

A Comparative Study on Eigen-Wear Analysis and Numerical Analysis using Algorithm for Adaptive Meshing (마모해석을 위한 고유치해석과 Adaptive Meshing 알고리듬을 이용한 수치해석 비교)

  • Jang, Ilkwang;Jang, Yong Hoon
    • Tribology and Lubricants
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    • v.36 no.5
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    • pp.262-266
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    • 2020
  • Herein, we present a numerical investigation of wear analysis of sliding systems with a constant speed subjected to Archard's wear law. For this investigation, we compared two methods: eigen-wear analysis and adaptive meshing technique. The eigen-wear analysis is advantageous to predict the evolution of contact pressure due to wear using the initial contact pressure and contact stiffness. The adaptive meshing technique in finite element analysis is employed to obtain transient wear behavior, which needs significant computational resources. From the eigen-wear analysis, we can determine the appropriate element size required for finite element analysis and the time increment required for wear evolution by a dimensionless variable above a certain value. Since the prediction of wear depends on the maximum contact pressure, the finite element model should have a reasonable representation of the maximum contact pressure. The maximum contact pressure and wear amount according to this dimensionless variable shows that the number of fine meshes in the contact area contributes more to the accuracy of the wear analysis, and the time increment is less sensitive when the number of contact nodes is significantly larger. The results derived from a two-dimensional wear model can be applied to a three-dimensional wear model.

Experimental Investigations on Upper Part Load Vortex Rope Pressure Fluctuations in Francis Turbine Draft Tube

  • Nicolet, Christophe;Zobeiri, Amirreza;Maruzewski, Pierre;Avellan, Francois
    • International Journal of Fluid Machinery and Systems
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    • v.4 no.1
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    • pp.179-190
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    • 2011
  • The swirling flow developing in Francis turbine draft tube under part load operation leads to pressure fluctuations usually in the range of 0.2 to 0.4 times the runner rotational frequency resulting from the so-called vortex breakdown. For low cavitation number, the flow features a cavitation vortex rope animated with precession motion. Under given conditions, these pressure fluctuations may lead to undesirable pressure fluctuations in the entire hydraulic system and also produce active power oscillations. For the upper part load range, between 0.7 and 0.85 times the best efficiency discharge, pressure fluctuations may appear in a higher frequency range of 2 to 4 times the runner rotational speed and feature modulations with vortex rope precession. It has been pointed out that for this particular operating point, the vortex rope features elliptical cross section and is animated of a self-rotation. This paper presents an experimental investigation focusing on this peculiar phenomenon, defined as the upper part load vortex rope. The experimental investigation is carried out on a high specific speed Francis turbine scale model installed on a test rig of the EPFL Laboratory for Hydraulic Machines. The selected operating point corresponds to a discharge of 0.83 times the best efficiency discharge. Observations of the cavitation vortex carried out with high speed camera have been recorded and synchronized with pressure fluctuations measurements at the draft tube cone. First, the vortex rope self rotation frequency is evidenced and the related frequency is deduced. Then, the influence of the sigma cavitation number on vortex rope shape and pressure fluctuations is presented. The waterfall diagram of the pressure fluctuations evidences resonance effects with the hydraulic circuit. The influence of outlet bubble cavitation and air injection is also investigated for low cavitation number. The time evolution of the vortex rope volume is compared with pressure fluctuations time evolution using image processing. Finally, the influence of the Froude number on the vortex rope shape and the associated pressure fluctuations is analyzed by varying the rotational speed.

A Study on the storage of Fresh Fruits and Vegetables (Part II) Effects of Intercellular atmosphere and Ethylene evolution by control of external pressure and gas composition in Apple Fruits. (청과물 저장에 관한 연구(제 2보) -사과 저장에 있어서 환경압력 및 기체조성이 사과조직내 기체조성과 Ethylene 생성에 미치는 영향-)

  • 손태화;최종욱;서온수
    • Microbiology and Biotechnology Letters
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    • v.1 no.1
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    • pp.25-30
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    • 1973
  • Experiments were carried out to clarify changes of intercellular gas composition, respiration and ethylene evolution by controlled external atmospheric pressure and external gas composition on apples. Jonathan apples, harvested 25, in September and Rolls apples, harvested 25, in October, 1971 and 1972 were used. Results obtained were as follows: 1. Intercellular gas volumes were proportionally changed by the given pressure, and the given pressure remarkably affected internal gas composition and volume of apples. As intercellular gas volumes were reached in their equilibrium within 5 min. after treatment, the internal atmospheric conditions became constant rapidly. 2. The increase of internal $CO_2$ production was co-related with an amount of internal $O_2$ consumption, therefore, the decreasing period of internal $O_2$ consumption was equalled to the period of climacteric rise in respiration. 3. The increasing of $CO_2$ production followed evolution of $C_2$H$_4$ and this phenomenon on SAP part. was subsequent to NAP part 4. In sub-atmospheric storage, CA effect was also obtained by control of low $O_2$ and high $CO_2$ concentration.

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The impact of ram pressure on the multi-phase ISM probed by the TIGRESS simulation

  • Choi, Woorak;Kim, Chang-Goo;Chung, Aeree
    • The Bulletin of The Korean Astronomical Society
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    • v.43 no.1
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    • pp.62.1-62.1
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    • 2018
  • Galaxies in the cluster environment interact with the intracluster medium (ICM), losing the interstellar medium (ISM) and alternating their evolution. Observational evidences of the extraplanar ISM stripped by the ICM's ram pressure are prevalent in HI imaging studies of cluster galaxies. However, current theoretical understanding of the ram pressure stripping (or ICM-ISM interaction in general) is still limited mainly due to the lack of numerical resolution at ISM scales in large-scale simulations. Especially, self-consistent modeling of the turbulent, multiphase ISM is critical to understand star formation in galaxies interacting with the ICM. To achieve this goal, we utilize the TIGRESS simulation suite, simulating a local patch of galactic disks with high resolution to resolve key physical processes in the ISM, including cooling/heating, self-gravity, MHD, star formation, and supernova feedback. We then expose the ISM disk to ICM flows and investigate the evolution of star formation rate and the properties of the ISM. By exploring ICM parameter space, we discuss an implication of the simple ram pressure stripping condition (so called the Gunn-Gott condition) to the realistic ISM.

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Thermoelastic Instability of the Layer Sliding between Two Non-conducting Half-planes (비전도 반평판 사이에서 미끄럼 운동하는 평판 층의 열탄성 불안정성)

  • 하태원;조용구;김흥섭;이정윤;오재응
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2003.05a
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    • pp.483-488
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    • 2003
  • Frictional heating in brakes causes thermoelastic distortion of the contacting bodies and hence affects the contact pressure distribution. The resulting thermo-mechanical coupling can cause thermoelastic instability (TEI) if the sliding speed is sufficiently high, leading to non-uniform heating called hot spots and low frequency vibration known as hot judder. The vibration of brakes to the known phenomenon of frictionally-excited thermoelastic instability is estimated studying the interface temperature and pressure evolution with time. A simple model has been considered where a layer with half-thickness ${\alpha}$ slides with speed V between two half-planes which are rigid and non-conducting. The advantage of this properly simple model permits us to deduce analytically the critical conditions for the onset of instability, which is the relation between the critical speed and the growth rate of the interface temperature and pressure. Symmetrical component of pressure and temperature distribution at the layer interfaces can be more unstable than antisymmetrical component. As the thickness ${\alpha}$ reduces, the system becomes more apt to thermoelastic instability. Moreover, the evolution of the system beyond the critical conditions has shown that even if low frequency perturbations are associated with low critical speed, it might be less critical than high frequency perturbations if the working sliding speed is much larger than the actual critical speed of the system.

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Evolution of bone structure under axial and transverse loads

  • Qu, Chuanyong;Qin, Qing-Hua
    • Structural Engineering and Mechanics
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    • v.24 no.1
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    • pp.19-29
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    • 2006
  • The evolution process of an initially homogeneous bone structure under axial and transverse loads is investigated in this paper. The external loads include axial and external lateral pressure, electric, magnetic and thermal loads. The theoretical predictions of evolution processes are made based on the adaptive elasticity formulation and coupled thermo-magneto-electro-elastic theory. The adaptive elastic body, which is a model for living bone diaphysis, is assumed to be homogeneous in its anisotropic properties and its density. The principal result of this paper is determination of the evolution process of the initially homogeneous body to a transversely inhomogeneous body under the influence of the inhomogeneous stress state.