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Green synthesis of silver nanoparticles to the microbiological corrosion deterrence of oil and gas pipelines buried in the soil

  • Zhi Zhang;Jingguo Du;Tayebeh Mahmoudi
    • Advances in nano research
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    • v.15 no.4
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    • pp.355-366
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    • 2023
  • Biological corrosion, a crucial aspect of metal degradation, has received limited attention despite its significance. It involves the deterioration of metals due to corrosion processes influenced by living organisms, including bacteria. Soil represents a substantial threat to pipeline corrosion as it contains chemical and microbial factors that cause severe damage to water, oil, and gas transmission projects. To combat fouling and corrosion, corrosion inhibitors are commonly used; however, their production often involves expensive and hazardous chemicals. Consequently, researchers are exploring natural and eco-friendly alternatives, specifically nano-sized products, as potent corrosion inhibitors. This study aims to environmentally synthesize silver nanoparticles using an extract from Lagoecia cuminoides L and evaluate their effectiveness in preventing biological corrosion of buried pipes in soil. The optimal experimental conditions were determined as follows: a volume of 4 ml for the extract, a volume of 4 ml for silver nitrate (AgNO3), pH 9, a duration of 60 minutes, and a temperature of 60 degrees Celsius. Analysis using transmission electron microscopy confirmed the formation of nanoparticles with an average size of approximately 28 nm, while X-ray diffraction patterns exhibited suitable peak intensities. By employing the Scherer equation, the average particle size was estimated to be around 30 nm. Furthermore, antibacterial studies revealed the potent antibacterial activity of the synthesized silver nanoparticles against both aerobic and anaerobic bacteria. This property effectively mitigates the biological corrosion caused by bacteria in steel pipes buried in soil.

Numerical and statistical analysis of Newtonian/non-Newtonian traits of MoS2-C2H6O2 nanofluids with variable fluid properties

  • Manoj C Kumar;Jasmine A Benazir
    • Advances in nano research
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    • v.16 no.4
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    • pp.341-352
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    • 2024
  • This study investigates the heat and mass transfer characteristics of a MoS2 nanoparticle suspension in ethylene glycol over a porous stretching sheet. MoS2 nanoparticles are known for their exceptional thermal and chemical stability which makes it convenient for enhancing the energy and mass transport properties of base fluids. Ethylene glycol, a common coolant in various industrial applications is utilized as the suspending medium due to its superior heat transfer properties. The effects of variable thermal conductivity, variable mass diffusivity, thermal radiation and thermophoresis which are crucial parameters in affecting the transport phenomena of nanofluids are taken into consideration. The governing partial differential equations representing the conservation of momentum, energy, and concentration are reduced to a set of nonlinear ordinary differential equations using appropriate similarity transformations. R software and MATLAB-bvp5c are used to compute the solutions. The impact of key parameters, including the nanoparticle volume fraction, magnetic field, Prandtl number, and thermophoresis parameter on the flow, heat and mass transfer rates is systematically examined. The study reveals that the presence of MoS2 nanoparticles curbs the friction between the fluid and the solid boundary. Moreover, the variable thermal conductivity controls the rate of heat transfer and variable mass diffusivity regulates the rate of mass transfer. The numerical and statistical results computed are mutually justified via tables. The results obtained from this investigation provide valuable insights into the design and optimization of systems involving nanofluid-based heat and mass transfer processes, such as solar collectors, chemical reactors, and heat exchangers. Furthermore, the findings contribute to a deeper understanding of stretching sheet systems, such as in manufacturing processes involving continuous casting or polymer film production. The incorporation of MoS2-C2H6O2 nanofluids can potentially optimize temperature distribution and fluid dynamics.

A comparative experimental study on the mechanical properties of cast-in-place and precast concrete-frozen soil interfaces

  • Guo Zheng;Ke Xue;Jian Hu;Mingli Zhang;Desheng Li;Ping Yang;Jun Xie
    • Geomechanics and Engineering
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    • v.36 no.2
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    • pp.145-156
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    • 2024
  • The mechanical properties of the concrete-frozen soil interface play a significant role in the stability and service performance of construction projects in cold regions. Current research mainly focuses on the precast concrete-frozen soil interface, with limited consideration for the more realistic cast-in-place concrete-frozen soil interface. The two construction methods result in completely different contact surface morphologies and exhibit significant differences in mechanical properties. Therefore, this study selects silty clay as the research object and conducts direct shear tests on the concrete-frozen soil interface under conditions of initial water content ranging from 12% to 24%, normal stress from 50 kPa to 300 kPa, and freezing temperature of -3℃. The results indicate that (1) both interface shear stress-displacement curves can be divided into three stages: rapid growth of shear stress, softening of shear stress after peak, and residual stability; (2) the peak strength of both interfaces increases initially and then decreases with an increase in water content, while residual strength is relatively less affected by water content; (3) peak strength and residual strength are linearly positively correlated with normal stress, and the strength of ice bonding is less affected by normal stress; (4) the mechanical properties of the cast-in-place concrete-frozen soil interface are significantly better than those of the precast concrete-frozen soil interface. However, when the water content is high, the former's mechanical performance deteriorates much more than the latter, leading to severe strength loss. Therefore, in practical engineering, cast-in-place concrete construction is preferred in cases of higher negative temperatures and lower water content, while precast concrete construction is considered in cases of lower negative temperatures and higher water content. This study provides reference for the construction of frozen soil-structure interface in cold regions and basic data support for improving the stability and service performance of cold region engineering.

Seismic behavior of deep-sea pipeline after global buckling under active control

  • Jianshuo Wang;Tinghao Meng;Zechao Zhang;Zhihua Chen;Hongbo Liu
    • Earthquakes and Structures
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    • v.26 no.4
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    • pp.261-267
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    • 2024
  • With the increase in the exploitation depth of offshore oil and gas, it is possible to control the global buckling of deep-sea pipelines by the snake lay method. Previous studies mainly focused on the analysis of critical buckling force and critical temperature of pipelines under the snake-like laying method, and pipelines often suffer structural failure due to seismic disasters during operation. Therefore, seismic action is a necessary factor in the design and analysis of submarine pipelines. In this paper, the seismic action of steel pipes in the operation stage after global buckling has occurred under the active control method is analyzed. Firstly, we have established a simplified finite element model for the entire process cycle and found that this modeling method is accurate and efficient, solving the problem of difficult convergence of seismic wave and soil coupling in previous solid analysis, and improving the efficiency of calculations. Secondly, through parameter analysis, it was found that under seismic action, the pipe diameter mainly affects the stress amplitude of the pipeline. When the pipe wall thickness increases from 0.05 m to 0.09 m, the critical buckling force increases by 150%, and the maximum axial stress decreases by 56%. In the pipe soil interaction, the greater the soil viscosity, the greater the pipe soil interaction force, the greater the soil constraint on the pipeline, and the safer the pipeline. Finally, the pipeline failure determination formula was obtained through dimensionless analysis and verified, and it was found that the formula was accurate.

Effect of physicochemical properties and feed mix ratios on the carbothermic reductions of iron ore with coke

  • S.R.R. Munusamy;S. Manogaran;F. Abdullah;N.A.M. Ya'akob;K. Narayanan
    • Advances in materials Research
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    • v.13 no.3
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    • pp.161-171
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    • 2024
  • This study aimed to investigate the effect of physicochemical properties and mix ratios of iron ore (oxide feed): coke (reductant) on the carbothermic reductions of iron ore. Coke size was fixed at ≤63 ㎛ while iron ore size varied between 150-63 ㎛ and ≤63 ㎛ respectively. Mix ratios were changed from 100:0 (reference) to 80:20 and 60:40 while the temperature, heating rate and soaking duration in muffle furnace were fixed at 1100 ℃, 10 ℃/min and 1 hour. Particle size analyzer, XRF, CHNS and XRD analyses were used for determination of raw feed characteristics. The occurrence of phase transformations from various forms of iron oxides to iron during the carbothermal reductions were identified through XRD profiles and supported with weight loss (%). XRF analysis proved that iron ore is of high grade with 93.4% of Fe2O3 content. Other oxides present in minor amounts are 2% Al2O3 and 1.8% SiO2 with negligible amounts of other compounds such as MnO, K2O and CuO. Composite pellet with finer size iron particles (≤63 ㎛) and higher carbon content of 60:40 exhibited 45.13% weight lost compared to 32.30% and 3.88% respectively for 80:20 and 100:0 ratios. It is evident that reduction reactions can only occur with the presence of coke, the carbon supply. The small weight loss of 3.88% at 100:0 ratio occurs due to the removal of moisture and volatiles and oxidations of iron ore. Higher carbon supply at 60:40 leads into better heat and mass transfer and diffusivity during carbothermic reductions. Overall, finer particle size and higher carbon supply improves reactivity and gas-solid interactions resulting in increased reductions and phase transformations.

Vibroacoustic analysis of stiffened functionally graded panels in thermal environments

  • Ashish K. Singh;Anwesha Pal;Shashi Kumar;Anuja Roy;Atanu Sahu
    • Structural Engineering and Mechanics
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    • v.89 no.5
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    • pp.437-452
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    • 2024
  • Functionally graded materials (FGMs) have gained substantial attention from researchers due to their exceptional strength and thermal resistance. Their utilization in the aviation and automobile industries has significantly improved the efficiency of various structural components. Moreover, stiffened panels find wide applications in aerospace and automobile structures and these panels are frequently exposed to extreme environments. It is from this perspective that our research is focused on analysing the vibroacoustic response of stiffened functionally graded panels subjected to external dynamic excitations in a thermal environment. In the present research work, a finite element model is developed to conduct the dynamic analysis of functionally graded stiffened panels using the first-order shear deformation theory. Subsequently, a boundary element based model is also developed and coupled with the finite element model to investigate the sound radiation behaviour of those panels in a thermal environment. The material properties of FG stiffened panels are considered as temperature dependent, while the thermal environment is assumed to be acting as linearly varying through the panel's thickness. The present investigation aim to compare the vibroacoustic responses of different panels due to stiffener orientations, material compositions, power law indices and plate thicknesses at various temperatures. The research findings highlight the significant impact of addition of stiffeners, its orientation and material compositions on the sound radiation characteristics of these panels under thermal environments. The present numerical model can easily be employed for analysing the sound radiation behaviour of other types of flat or curved stiffened panels having arbitrary geometry and boundary conditions.

Effects of hygro-thermal environment on dynamic responses of variable thickness functionally graded porous microplates

  • Quoc-Hoa Pham;Phu-Cuong Nguyen;Van-Ke Tran
    • Steel and Composite Structures
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    • v.50 no.5
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    • pp.563-581
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    • 2024
  • This paper presents a novel finite element model for the free vibration analysis of variable-thickness functionally graded porous (FGP) microplates resting on Pasternak's medium in the hygro-thermal environment. The governing equations are established according to refined higher-order shear deformation plate theory (RPT) in construction with the modified couple stress theory. For the first time, three-node triangular elements with twelve degrees of freedom for each node are developed based on Hermitian interpolation functions to describe the in-plane displacements and transverse displacements of microplates. Two laws of variable thickness of FGP microplates, including the linear law and the nonlinear law in the x-direction are investigated. Effects of thermal and moisture changes on microplates are assumed to vary continuously from the bottom surface to the top surface and only cause tension loads in the plane, which does not change the material's mechanical properties. The numerical results of this work are compared with those of published data to verify the accuracy and reliability of the proposed method. In addition, the parameter study is conducted to explore the effects of geometrical and material properties such as the changing law of the thickness, length-scale parameter, and the parameters of the porosity, temperature, and humidity on the free vibration response of variable thickness FGP microplates. These results can be applied to design of microelectromechanical structures in practice.

Lifespan assessment of piezoelectric sensors under disposal condition of high-level nuclear waste repository

  • Changhee Park;Hyun-Joong Hwang;Chang-Ho Hong;Jin-Seop Kim;Gye-Chun Cho
    • Geomechanics and Engineering
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    • v.38 no.5
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    • pp.529-539
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    • 2024
  • A high-level nuclear waste (HLW) repository is designed for the long-term disposal of high-level waste. Positioned at depths of 500-1000 meters, it offers an alternative to the insufficient storage space for spent fuels, providing a long-term solution. High-level waste emits heat and radiation, causing structural deterioration, including strength reduction and cracks. Therefore, the use of piezoelectric sensors for structural health monitoring is essential for evaluating the safety of the structure over time. Unlike other structures, the HLW repository restricts human access after the disposal of HLW, rendering sensor replacement impossible. Therefore, it is necessary to assess both the lifespan and suitability of sensors under the disposal conditions in the HLW repository. This study employed an accelerated life test (ALT) to assess the sensor's lifespan under disposal conditions. Failure modes, failure mechanisms, and operational limits were analyzed through accelerated stress test (AST). Additionally, the parameters of the Weibull life probability distribution and the Arrhenius accelerated life model were estimated through statistical methods, including the likelihood ratio test, maximum likelihood estimation, and hypothesis testing. Results confirmed that the sensor's lifespan decreases significantly with the increase in the temperature limit of the HLW repository. The findings of this study can be used for improving sensor lifespan through shielding, development of alternative sensors, or lifespan evaluation of alternative monitoring sensors.

A study for Beating Filter Press Dewatering Technology (열(熱) 필터프레스 기술(技術)을 통한 슬러지 탈수율(脫水率) 향상(向上)을 위한 연구(硏究))

  • Lee, Jung-Eun;Kim, Dong-Su
    • Resources Recycling
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    • v.15 no.3 s.71
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    • pp.38-45
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    • 2006
  • The thermal filter press dewatering(TFPD) technology to improve the dewaterability through increasing the inner vapor pressure, lowering the filtration viscosity and forming the porosity easily within cake as applying the heat at the sludge layer was developed in this study. The hot water with temperature of $95^{\circ}C$ and pressure of $1.2kg_f/cm^2$ was supplied to the heating plate equipped between filter plates with plate size of $470{\times}470mm$ and material of polypropylene. Sludge was dewaterd by supplying pressure of $5kg_f/cm^2$ and then by squeezing pressure of $15kg_f/cm^2$. As a results of estimating the characteristics of thermal dewatering to consider the initial water content and organic content to be influenced by a period of water shortage and rainwater, the dewatered cake water content was about 35 wt% and dewatering velocity was $4DSkg/m^2{\cdot}hr$ under the rainwater period, and the dewatered cake water content was about 50 wt% and dewatering velocity was $1.5DSkg/m^2{\cdot}hr$ in the case of sludge of water shortage season. These results was superior to the mechanical dewatering performance with water content of 70wt% and dewatering velocity of $0.9DSkg/m^2{\cdot}hr$. On the base of the results of TFPD, energy consumpted to deal with DS(Dry Solid) of 1kg was estimated by 300 kJ. It was analyzed that the energy consumption of TFPD was decreased about one third with comparison to the dryer system. Dewatering velocity of this technology was faster than the one of mechanical dewatering equipment and it was easier to product low water content cake. Therefore, this technology was recognized that dewaterability was predominant because of the fast of dewatering velocity and production of low water content cake, and also this known as economical efficiency was excellent because of low energy consumption in comparison with dryer.

Development of Biodegradable Polymeric Membrane for Interventional Procedure: Preliminary Study (인터벤션 시술을 위한 생분해성 고분자막의 개발 : 예비연구)

  • Bang, Jung-Wan;Hyun, Chang-Yong;Kim, Tae-Hyung;So, Woon-Young;Kim, Jin-Tae;Kim, Sang-Sub;Jung, Hee Dong;Heo, Yeong Cheol
    • Journal of radiological science and technology
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    • v.37 no.1
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    • pp.15-20
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    • 2014
  • This study was to evaluate clinical feasibility of biodegradable polymeric membrane for interventional procedure in preliminary study. Bio-degradable polymetric membrane was produced into a solution by mixing hyaluronic acid powder with NaOH solution in a heating mantle. Three different concentrations of contrast media (10, 20, and 30 vol%) were added to the produced soluble powder, and vertical agitation was performed for 12 hours at a speed of 100 to 200 rpm at a room temperature. It was freeze dried for 24 hours at a temperature $80^{\circ}C$. Pressure on the freeze dried sample was exerted by a hydraulic press in order to form the freeze dried sample into a membrane. The membrane produced with varying contrast medium concentration was visually examined by a scanning electron microscope and radiographically inspected. Under the visual examination, the higher the concentration of contrast medium, the rougher the surface. Radiographic transparency was similar under all conditions of fluoroscopic radiography, simple radiography, and serial radiography. In conclusion, this preliminary study verified that bio-degradable membrane produced with hyaluronic acid was a material with clinical usability.