• Title/Summary/Keyword: preferential flow

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COMPARISON OF FLUX AND RESIDENT CONCENTRATION BREAKTHROUGH CURVES (BTCs) IN STRUCTURED SOIL COLUMNS

  • Kim, Dong-Ju
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1997.05a
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    • pp.25-29
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    • 1997
  • In many solute transport studies, either flux or resident concentration has been used. Choice of the concentration mode was dependent on the monitoring device in solute displacement experiments. It would be questionable, however. to accept the equivalency in the solute transport parameters between flux and resident concentrations in structured soils exhibiting preferential movement of solute. In this study, we investigate how they differ in the monitored breakthrough curves (BTCs) and transport parameters for a given boundary and flow condition by performing solute displacement experiments on a number of undisturbed soil columns. Both flux and resident concentrations have been simultaneously obtained by monitoring the effluent and resistance of the Horizontally-positioned TDR probes. The study reveals that soil columns having relatively high flux densities exhibited great differences in the degree of peak concentration and travel time of peak between flux and resident concentrations. The peak concentration in flux mode was several times higher than that in resident one. This was mainly due to the bypassing of solute through soil macropores.

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Electrokinetic Ions Injection into Kaolinite and Sand for Bioremediation (카올리나이트와 모레에서의 Bioremediation을 위한 Electrokinetic 이온 주입 특성)

  • 이호창;한상재;김수삼;오재일
    • Proceedings of the Korean Geotechical Society Conference
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    • 2001.03a
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    • pp.405-410
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    • 2001
  • Bioremediation is a degradation process of existing organic contaminants in soils and groundwater by indigenous or inoculated microorganisms. This process can provide economical solution as well as safe and effective alternative in remediation technologies. However, it has been suggested that the rate of bioremediation process of organic contaminants by microorganisms can be limited by the concentration of nutrients and TEAs(Terminal Electron Accepters). In in-situ bioremediation, conventional pumping techniques have been used for supplying these additives. However, the injection of these additives is difficult in low permeable soils, and also hindered by preferential flow paths resulting from heterogeneities in high permeable ground. Therefore, the Injection of chemical additives is the most significant concern in in-situ bioremediation. Most recently, electrokinetic technique has been applied into the bioremediation and the injection characteristics under electrokinetics have not been examined in various soil types. Therefore, in this study, electrokinetic injection method is investigated in kaolinite and sand, and the concentration of ammonium(nutrients) and sulfate(TEAs) in soil is presented.

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Effects of Hydrostatic Pressure on Solidification Phenomena of Al-Si binary alloys(I);Metallurgical Study (Al-Si이원계 합금의 응고현상에 미치는 정수압의 영향(I);금속 조직적 연구)

  • Han, Y.S.;Kim, D.H.;Lee, H.I.
    • Journal of Korea Foundry Society
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    • v.6 no.2
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    • pp.116-121
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    • 1986
  • The effects of pressure during solidification on macro-and micro-structures have been studied in pure aluminium and Al-Si alloys. The application of pressure during solidifcation accelerated both equiaxed and columnar dendritic-growth due to stimulating of equiaxed survival and faster preferential growth of primary dendrites against the parallel direction of heat flow. Burden-Hunt model was modified to express the significant changes of CET behaviours under pressure. A further point to be noted was that greatly fine eutectic silicon flakes ($0.5\;{\times}\;13{\mu}m$) with the decrease of halo layers ($7{\mu}m$) of aluminium riched phases in the periphery of primary silicon particles were observed when pressure was applied during solidification.

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Infinite Selectivity Etching Process of Silicon Nitride to ArF PR Using Dual-frequency $CH_2F_2/H_2/Ar$ Capacitively Coupled Plasmas (Dual-frequency $CH_2F_2/H_2/Ar$ capacitively coupled plasma를 이용한 실리콘질화물과 ArF PR의 무한 선택비 식각 공정)

  • Park, Chang-Ki;Lee, Chun-Hee;Kim, Hui-Tae;Lee, Nae-Eung
    • Journal of the Korean institute of surface engineering
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    • v.39 no.3
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    • pp.137-141
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    • 2006
  • Process window for infinite etch selectivity of silicon nitride $(Si_3N_4)$ layers to ArF photoresist (PR) was investigated in dual frequency superimposed capacitive coupled plasma (DFS-CCP) by varying the process parameters such as low frequency power $(P_{LF})$, $CH_2F_2$ and $H_2$ flow rate in $CH_2F_2/H_2/Ar$ plasma. It was found that infinite etch selectivities of $Si_3N_4$ layers to the ArF PR on both blanket and patterned wafers can be obtained for certain gas flow conditions. The etch selectivity was increased to the infinite values as the $CH_2F_2$ flow rate increases, while it was decreased from the infinite etch selectivity as the $H_2$ flow rate increased. The preferential chemical reaction of the hydrogen with the carbon in the polymer film and the nitrogen on the $Si_3N_4$ surface leading to the formation of HCN etch by-products results in a thinner steady-state polymer and, in turn, to continuous $Si_3N_4$ etching, due to enhanced $SiF_4$ formation, while the polymer was deposited on the ArF photoresist surface.

Role of $N_2$ flow rate on etch characteristics and variation of line edge roughness during etching of silicon nitride with extreme ultra-violet resist pattern in dual-frequency $CH_2F_2/N_2$/Ar capacitively coupled plasmas

  • Gwon, Bong-Su;Jeong, Chang-Ryong;Lee, Nae-Eung;Lee, Seong-Gwon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.458-458
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    • 2010
  • The process window for the etch selectivity of silicon nitride ($Si_3N_4$) layers to extreme ultra-violet (EUV) resist and variation of line edge roughness (LER) of EUV resist were investigated durin getching of $Si_3N_4$/EUV resist structure in a dual-frequency superimposed capacitive coupled plasma (DFS-CCP) etcher by varying the process parameters, such as the $CH_2F_2$ and $N_2$ gas flow rate in $CH_2F_2/N_2$/Ar plasma. The $CH_2F_2$ and $N_2$ flow rate was found to play a critical role in determining the process window for infinite etch selectivity of $Si_3N_4$/EUV resist, due to disproportionate changes in the degree of polymerization on $Si_3N_4$ and EUV resist surfaces. The preferential chemical reaction between hydrogen and carbon in the hydrofluorocarbon ($CH_xF_y$) polymer layer and the nitrogen and oxygen on the $Si_3N_4$, presumably leading to the formation of HCN, CO, and $CO_2$ etch by-products, results in a smaller steady-state hydrofluorocarbon thickness on $Si_3N_4$ and, in turn, in continuous $Si_3N_4$ etching due to enhanced $SiF_4$ formation, while the $CH_xF_y$ layer is deposited on the EUV resist surface. Also critical dimension (and line edge roughness) tend to decrease with increasing $N_2$ flow rate due to decreased degree of polymerization.

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Establishment and Operation of a Soil Moisture Monitoring System Considering Temporal and Spatial Features of Representation (시공간 대표성을 고려한 토양수분 모니터링 System의 구축 및 운영)

  • Kim, Ki-Hoon;Kim, Sang-Hyun;Kim, Hyung-Sub;Kim, Won
    • Journal of Korea Water Resources Association
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    • v.38 no.1
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    • pp.73-82
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    • 2005
  • A soil moisture measuring method of a hillslope for Korean watershed is developed to configure spatial-temporal distribution of soil moisture. Intensive surveying of topography had been performed to make a digital elevation model(DEM). Flow distribution algorithms were applied and a distribution pattern of the measurement sensors was determined to maximize representative features of spatial variation of soil moisture. Inverse surveying provides appropriate information to install the waveguides in the field. Measurements were performed at the right side hillslope of Bumrunsa located at the Sulmachun watershed. A multiplex monitoring system has been established and spatial-temporal variation of soil moisture data has been measured for a rainfall-runoff event. Acquired soil moisture data show that physical hydrologic interpretations as well as the effectiveness of monitoring system. Lack of connectivity in vertical distribution of soil moisture suggests that preferential flow and macropore flux are important components in the hillslope hydrology.

Fabrication of IZO thin films for flexible organic light emitting diodes by RF magnetron sputtering

  • Jun, D.G.;Cho, H.H.;Jo, D.B.;Lee, K.M.
    • Journal of Ceramic Processing Research
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    • v.13 no.spc2
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    • pp.260-264
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    • 2012
  • We have investigated the effect of ambient gases on the structural, electrical, and optical characteristics of IZO thin films intended for use as anode contacts in the organic light emitting diodes (OLED) devices. These IZO thin films were deposited on the PES film by radio frequency (RF) magnetron sputtering under different ambient gases (Ar, Ar + O2, and Ar + H2) at room temperature. In order to investigate the influences of the ambient gases, the flow rate of oxygen and hydrogen in argon has been changed from 0.1 sccm to 0.5 sccm, respectively. All the IZO thin film has an (222) preferential orientation regardless of ambient gases. The electrical resistivity of the IZO film increased with increasing O2 flow rate, whereas the electrical resistivity decreased sharply under an Ar + H2 atmosphere and was nearly similar regardless of the H2 flow rate. The change of electrical resistivity with changes in the ambient gas composition was mainly interpreted in terms of the charge carrier concentration rather than the charge carrier mobility. All the films showed the average transmittance over 85% in the visible range. The OLED device was fabricated with different IZO substrates made with the configuration of IZO/α-NPD/DPVB/Alq3/LiF/Al in order to elucidate the performance of the IZO substrate. The current density and the luminance of OLED devices with IZO thin films deposited in 0.5 sccm H2 ambient gas are the highest amongst all other films.

Development of Numerical Model for Simulating Remediation Efficiency Using Surfactant in a NAPL Contaminated Area (계면활성제에 의한 NAPL 오염의 정화효율 수치 모의를 위한 모델 개발)

  • Suk, Heejun;Son, Bongho;Park, Sungmin;Jeon, Byonghun
    • Clean Technology
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    • v.25 no.3
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    • pp.206-222
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    • 2019
  • Recently, various multiphase flows have been developed, and among them some models have been commercialized. However, most of them have been developed based on a pressure-based approach; therefore, various numerical difficulties were involved inherently. Accordingly, in order to overcome these numerical difficulties, a multiphase flow model, MultiPhaSe flow (MPS), following a fractional-flow based approach was developed. In this study, by combining a contaminant transport module describing an enhanced dissolution effect of a surfactant with MPS, a MultiPhaSe flow and TranSport (MPSTS) model was developed. The developed model was verified using the analytical solution of Clement. The MPSTS model can simulate the process of surfactant enhanced aquifer remediation including interphase mass transfer and contaminant transport in multiphase flow by using the coupled particle tracking method and Lagrangian-Eulerian method. In this study, a surfactant was used in a non aqueous phase liquid (NAPL) contaminated area, and the effect of hydro-geological heterogeneity in the layered media on remediation efficiency was studied using the developed model. According to the numerical simulation, when hydraulic conductivity in a lower layer is 10 times, 20 times, and 50 times larger than that in an upper layer, the concentration of dissolved diesel in the lower layer is much higher than that in the upper layer because the surfactant moves faster along the lower layer owing to preferential flow; thus, the surfactant enhances dissolution of residual non aqueous phase liquid in the lower layer.

Usage of T Cell Receptor Repertoire is Restricted in Synovial Lymphocytes in Rheumatoid Arthritis (류마티스양 관절염 환자 활막 T 세포의 T 세포수용체 β쇄 분석)

  • Kwon, Dae-ho;Lee, Soo-Kon;Kim, Se-Jong;Choi, In-Hong
    • IMMUNE NETWORK
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    • v.1 no.1
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    • pp.70-76
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    • 2001
  • Background: Rheumatoid arthritis is an autoimmune disease characterized by a chronic inflammatory process, primarily involving the synovial membrane of peripheral j oints, where T cell activation is found. To address the superantigen stimulation in rheumatoid arthritis, T cell clonality and the expression of activation markers were analyzed. Methods: To detect TCRB V usage, inverse PCR and sequencing were done. Monoclonal antibodies were used for flow cytometric analysis of TCRBV8 or TCRBV5. As results, a restricted usage of TCRBV3 gene was detected in synovial lymphocytes from one rheumatoid arthritis patient. However, preferential usage for TCRB V8, which may be one indicator for stimulation by staphylococcal superantigen, was not obvious although general activation of T cells was found as high DR+ percentage in synovial T cells. These data show specific antigen rather than superantigen might involve the pathogenesis of rheumatoid arthritis.

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A Numerical Study on Nonlinear Dynamic Behavior of Diffusive-Thermal Instability in Diluted CH4/O2 Conterflow Diffusion Flames (희석된 메탄/산소 대향류 확산화염에서 확산-열 불안정으로 인한 화염의 비선형 동적 거동에 관한 수치해석)

  • Sohn, Chae-Hoon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.6
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    • pp.688-696
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    • 2004
  • Nonlinear dynamic behavior of diffusive-thermal instability in diluted CH$_4$/O$_2$ diffusion flames is numerically investigated by adopting detailed chemistry and transport. Counterflow diffusion flame is adopted as a model flamelet. Particular attention is focused on the pulsating-instability regime, which arises for Lewis numbers greater than unity, and the instability occurs at high strain rate near extinction condition in this flame configuration. Once a steady flame structure is obtained for a prescribed value of initial strain rate, transient solution of the flame is calculated after a finite amount of strain-rate perturbation is imposed on the steady flame. Transient evolution of the flame depends on the initial strain rate and the amount of perturbed strain rate. Basically, the dynamic behaviors can be classified into two types, namely non-oscillatory decaying solution and diverging solution leading to extinction. The peculiar oscillatory solution, which has been found in the previous study adopting one-step chemistry and constant Lewis numbers, is net observed in this study, which is attributed to both convective flow and preferential diffusion effects.