• 제목/요약/키워드: precursors

검색결과 1,445건 처리시간 0.028초

A Study on the Characteristics of Natural Organic Matter and Disinfection By-Product Formation in the Juam Reservoir

  • Shin, Dae-Yewn;Moon, Ok-Ran;Yoon, Mi-Ran;Kim, Nam-Joung;Kang, Gang-Unn;Seo, Gwang-Yeob
    • 한국환경보건학회:학술대회논문집
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    • 한국환경보건학회 2005년도 국제학술대회
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    • pp.259-262
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    • 2005
  • This study aims to identify the relationship between characteristics of aqueous organic matter and chlorination by-products formation potential according to temporal effect of Juam reservoir in Sun-Choen. The molecular weight distribution and chemical composition of precursors and their relationship with disinfection by-products(DBPs) were investigated. Most of the organic matters was responsible for the major DBP precursors in the raw water are small compounds with a molecular weight less than IKDa, Aromatic contents determined by SUVA correlated well with DBPs, THMs, and HAAs formation. Especially, THMFP/DOC showed better correlation with SUVA than HAAFP/DOC and DBPFP/DOC with SUVA in Juam reservoir. Therefore, effective removal of small molecules or hydrophobic organic matter prior to disinfection process will significantly reduce the DBP concentration in the finished water.

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Atomic Layer Deposition of $Sb_2S_3$ Thin Films on Mesoporous $TiO_2$

  • 한규석;정진원;성명모
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.282-282
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    • 2013
  • The antimony sulfide ($Sb_2S_3$) thin films were deposited using the gas phase method which known as atomic layer deposition (ALD) on mesoporous micro-films. Tris (dimethylamido) antimony (III[$(Me_2N)_3Sb$] and hydrogensulfide ($H_2S$) were used as precursors to deposit $Sb_2S_3$. Self-terminating nature of $(Me_2N)_3Sb$ and $H_2S$ reaction were demonstrated by growth rate saturation versus precursors dosing time. Absorption spectra and extinction coefficient were investigated by UV-VIS spectroscopy. Scanning electron microscopic analysis and X-ray photoelectron spectroscopy (XPS) depth profile were employed to determine the conformal deposition.

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Determination of Biosynthetic Pathway of Decursin in Hairy Root Culture of Angelica gigas

  • Ji, Xiuhong;Huh, Bum;Kim, Soo-Un
    • Applied Biological Chemistry
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    • 제51권4호
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    • pp.258-262
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    • 2008
  • To establish the biosynthetic pathway of decursin in Angelica gigas Nakai, feeding experiment with stable isotope-labeled precursors were conducted. Umbelliferone and decursin were labeled with deuterium at C-3. The umbelliferone, the decursin, and other commercially available putative precursors, L-phenylalanine-ring-$d_5$ and trans-cinnamic acid-$d_7$, were fed to the hairy root culture of A. gigas. Each deuterated compound was incorporated into decursinol, decursinol angelate, and decursin as determined by mass spectrometric analysis. These findings confirmed the coumarin biosynthesis pathway sequence is composed of phenylalanine, cinnamic acid, umbelliferone, decursinol, and decursin.

탄화규소 선구물질로서의 폴리(디알킬 또는 모노알킬)실란들의 합성과 세라믹 복합체 응용 (Synthesis of poly(dialkyl or monoalkyl)silanes as silicon carbide precursors for ceramic matrix composites)

  • 이규환
    • 분석과학
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    • 제26권1호
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    • pp.27-33
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    • 2013
  • 유기염화실란을 출발물질로 사용하고 초음파 반응 방법을 이용하여 알칼리 금속과 반응시켜 탈염소축합반응으로 폴리(디알킬)실란과 폴리(모노알킬)실란 등의 폴리알킬실란들을 합성하고 이들의 열적성질을 TGA로 조사하여 각각 10-20%와 40-60%의 잔류물 수득률을 얻었고 상업용 SiC 분말과 함께 펠렛 디스크를 성형하여 열분해 과정과 SEM, XRD 등으로 세라믹 복합체 응용 가능성을 조사하였다.

Investigation of Ionospheric Earthquake Precursors Using US-TEC Data during the Solar Maximum of 2013-2015

  • Park, Jeongchan;Park, Sun Mie
    • Journal of Astronomy and Space Sciences
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    • 제37권1호
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    • pp.61-68
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    • 2020
  • Recent studies have suggested that detectable ionospheric disturbances precede earthquakes. In the present study, variations in the vertical total electron content (TEC) for eight earthquakes with magnitudes of M ≥ 5.5 in the western United States were investigated during the solar maximum of 2013-2015 using United States total electron content (US-TEC) data provided by the National Oceanic and Atmospheric Administration. Analyses of 12 earthquakes with magnitudes of 5.0 ≤ M < 5.5 in the same region were also performed. The TEC variations were examined for 40 days, including the times when the earthquakes occurred. The results indicated a correlation between earthquakes with magnitudes of M ≥ 5.0 and ionospheric TEC anomalies. TEC anomalies occurred before 60% of the earthquakes. Additionally, they were more frequently observed for large earthquakes (75%, M ≥ 5.5) than for small earthquakes (50%, 5.5 > M ≥ 5.0). Anomalous increases in the TEC occurred 2-18 days before the earthquakes as an ionospheric precursor, whereas solar and geomagnetic activities were low or moderate.

KIVA3V와 SWEEP을 이용한 디젤 엔진에서의 soot 총량 및 입자 크기 분포 예측 (Prediction of Soot Emissions and Particle Size distribution by KIVA3V and SWEEP in a diesel engine)

  • 이재서;허강열
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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    • pp.129-132
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    • 2012
  • Computation is performed to predict number density, volume fraction and size distribution of soot particles in typical operating conditions of a diesel engine. KIVA has been integrated with the CMC routine to consider turbulence/chemistry coupling and gas phase kinetics for heat release and soot precursors. The compositions of soot precursors are estimated by tracking Lagrangian particles to consider spatial inhomogeneity and differential diffusion in KIVA. The soot simulator SWEEP is employed as a postprocessing step to calculate conditional and integral quantities of soot particles.

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Oogenesis, Oocyte Degeneration and Sexual Maturation in Female Cyclina sinensis (Gmelin, 1971) (Bivalvia: Veneridae) in Korea

  • Chung, Ee-Yung;Koh, Chul-Hwan;Park, Gab-Man
    • Animal cells and systems
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    • 제11권2호
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    • pp.191-198
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    • 2007
  • The ultrastructure of germ cells and follicle cells during oogenesis, oocyte degeneration, reproductive cycle, and first sexual maturity in female Cyclina sinensis were investigated for clams collected from Simpo, Jeollabuk-do, Korea, by cytological and histological observations. Vitellogenesis occured by way of endogeous autosynthesis and exogenous heterosynthesis: vitellogensis occurred through a process of autosynthesis, which involves a combined activities of the Golgi complex, mitochondria, and rough endoplasmic reticulum. The process of heterosynthesis involved endocytotic incorporation of extraovarian precursors into the basal region of the early vitellogenic oocytes prior to the formation of vitelline envelope. The follicle cells appear to play an integral role in vitellogenesis and oocyte degeneration, functioning in phagocytosis and digestion of products originating from the degenerated oocytes: these functions can permit the transfer of yolk precursors needed for vitellogenesis. Follicle cells might have a lysosomal system for breakdown and might also resorb phagosomes in the cytoplasm for nutrient storage during oocyte degeneration.

Study ink-jet ink for surface electron emission materials applied in flat panel display technology

  • Lin, H.M.;Liou, L.W.;Huang, C.Y.;Zheng, J.Y.;Liu, P.Y.;Wu, C.Y.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.270-273
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    • 2006
  • In this study, ink-jet technology is applied to the emitter fabrication for surface-conduction electron-emitter display (SED). The general emiiter material of SED, palladium oxide (PdO), is prepared by calcination the mixture of solvent and precursors of platinum chlorine and platinum nitrate. With controlling the precursors and solvents, the PdO is formed below $400^{\circ}C$ which is required for SED process.

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Pb(Zn, Mg)_{1/3}Nb_{2/3}O_3$계에서 Columbite Precursors의 화학적 특성이 상생성, 미세화학 및 유전특성에 미치는 영향 (Effects of the Columbite Precursors on Phase-Formation Characteristics, Microchemistry and Dielectric Properties of Pb(Zn, Mg)_{1/3}Nb_{2/3}O_3$ Ceramics)

  • 조성률;이규만;장현명
    • 한국세라믹학회지
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    • 제30권9호
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    • pp.723-730
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    • 1993
  • The mechanism of formation of perovskite phase and the dielectric properties of PZMN[Pb(Zn, Mg)1/3Nb2/3O3] ceramics were examined using two different types of the columbite precursors, (Mg, Zn)Nb2O6 (MZN) and MgNb2O6+ZnNb2O6 (MN+ZN). The formatin of perovskite phase in PbO+MN+ZN system is characterized by an initial rapid formation of Mg-rich perovskite phase, followed by a sluggish formation of Zn-rich perovskite phase. On the other hand, thepyrochlore/perovskite transformation in the PbO+MZN system proceeded uniformly with a spatial homogeneity. The degree of diffuseness of the rhombohedral/cubic phase transitionis higher in the PbO+MN+ZN system than in the PbO+MZN specimen, indicating a broadened compositional distributjion of the B-site catons (Nb+5, Zn+2, Mg+2) in the PbO+MN+ZN system.

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XRD 패턴에 따른 유무기복합 화합물의 특성 (Properites of Inorganic Hybrid Silica Materials according to the XRD patterns)

  • 오데레사;고유신;김경식
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2003년도 하계종합학술대회 논문집 II
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    • pp.995-998
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    • 2003
  • This paper reports the correlation between dielectric constant and degree of amorphism of the hybrid type Si-O-C thin films. Si-O-C thin films were deposited by high density plasma chemical vapor deposition using bistrimethyl- silylmethane(BTMSM, $H_{9}$C$_3$-Si-C $H_2$-Si-C$_3$ $H_{9}$) and oxygen precursors with various flow rate ratio. As-deposited film and annealed films at 40$0^{\circ}C$ were analyzed by XRD. The Si-O-C thin films were amorphous from XRD patterns. For quantitative analysis, the diffraction pattern of the samples was transformed to radial distribution function by Fourier analysis, and then compared with each other. The degree of amorphism of annealed films was higher than that of as-deposited ones. The dielectric constant varied in accordance with flow rate ratio of precursors. The lowest dielectric constant was obtained from the as-deposited film which has the highest degree of amorphism after annealing.

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