• Title/Summary/Keyword: precipitation process

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Experimental study on Microbially Induced Calcite Precipitation for expansive soil stabilization

  • Zheng Lu;Yu Qiu;Jie Liu;Chengcheng Yu; Hailin Yao
    • Geomechanics and Engineering
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    • v.32 no.1
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    • pp.85-96
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    • 2023
  • Microbially induced carbonate precipitation (MICP) is extensively discussed as a promising topic for ground stabilization. The practical effect of stabilizing the expansive soil is presented in this paper with a logical process from the bacterial activity to the treatment technology. Temperature, pH, shaking frequency, and inoculation amount are discussed to evaluate the bacterial activity. The physic-mechanic properties are also evaluated to discuss the effect of the MICP process on expansive soil. Results indicate that the MICP method achieves the mitigation of expansion. The treated soil has a low proportion of fine particles (< 5 ㎛), the plasticity index significantly decreases, and strength values improve much. MICP process has a significant cementation effect on the soil matrix. Moreover, the infiltration model test presents the coating effect on the topsoil. According to the relation between the CaCO3 content and the treatment effect, the topsoil has better treatment than the deeper soil.

Effect of Precipitation on Operation Range of the CO2 Capture Process using Ammonia Water Absorbent (암모니아수 흡수제를 이용한 이산화탄소 제거 공정에서 침전생성이 조업영역에 미치는 영향)

  • You, Jong Kyun;Park, Ho Seok;Hong, Won Hi;Park, Jongkee;Kim, Jong-Nam
    • Korean Chemical Engineering Research
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    • v.45 no.3
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    • pp.258-263
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    • 2007
  • Ammonia water was investigated as a new absorbent of the chemical absorption process for the removal of $CO_2$ in flue gas. The suitable range of ammonia water concentration and $CO_2$ loading ($mol\;CO_2/mol\;NH_3$) were decided in the point of view of $CO_2$ absorption capacity and $NH_4HCO_3$ precipitation. The absorption capacity of $CO_2$ and the precipitation of $NH_4HCO_3$ in liquid phase were calculated by the Pitzer model for electrolyte solution. The $CO_2$ absorption capacity of the ammonia water over $5\;molNH_3/kgH_2O$ was higher than that of conventional amine absorbent. The $CO_2$ loadings where precipitation occurred were decided at various absorbent concentrations. Theses values were higher than 0.5 in the concentration range of $5-14\;molNH_3/kgH_2O$ at 293, 313 K. The absorber for the removal of $CO_2$ in flue gas could be operated without $NH_4HCO_3$ precipitation by using high concentration of ammonia water below these $CO_2$ loading values. The optimum temperature of the ammonia water absorbent for removal of $CO_2$ in flue gas was 297-312 K depending on the concentration of ammonia water.

Enhancement of Mechanical Properties of 5052 Al Alloy by Cryogenic and Warm rolling (극저온 압연 및 온간 압연 기술을 이용한 5052 알루미늄 합금의 기계적 성질의 향상)

  • Gang, U.G.;Lee, S.H.;Lee, J.C.;Nam, W.J.
    • Transactions of Materials Processing
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    • v.17 no.2
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    • pp.102-106
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    • 2008
  • Cryogenic rolling combined with warm rolling has been found more effective than a single cryogenic rolling process in improving the strength of a 5052 Al alloy. In this study, cryo-rolled 5052 Al alloys were warm-rolled at $175^{\circ}C$. A notable increase of tensile strength was achieved by the precipitation during warm rolling process. Mechanical behavior of this alloy was investigated using hardness and tensile tests. It was found that the cryogenic rolling process combined with warm rolling process was very effective in improving tensile strength.

The Correlation Between the Moving Average of Precipitation and Groundwater Level in Korea (한국의 지하수위와 강우이동평균간의 상관관계)

  • Yang, Jeong-Seok;Kim, Nam-Ki
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.3B
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    • pp.265-276
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    • 2011
  • Precipitation data and groundwater level data were collected for Korean peninsular and Jeju island. The relationship between precipitation and groundwater level and the correlation between the moving average of precipitation and goundwater level were analyzed. Critical infiltration, which is the spatially averaged maximum daily infiltration depth over interested region, is considered when the precipitation data was modified for moving average process and correlation between the moving average of modified precipitation and groundwater level. High correlation regions, which have greater than 0.6 correlation coefficients, were selected after the analysis with ciritical infiltration. Twenty-six regions were selected for high correlation regions. If we divide the regions by administrative district, there are nine regions for Gyungsang-Do, five regions for Chunchung-Do, four regions for Gyunggi-Do and Gangwon-Do, three regions for Jolla-Do, and one region for Jeju island. The groundwater level data for high correlation regions shows obvious response after precipitation event and there are few cases with abrupt change in groundwater level without precipitation-related event.

Preparation of High-purity Zinc Oxalate Powder by the Precipitation Stripping Method (Precipitation Stripping법에 의한 고순도 Oxalate 분말의 제조)

  • 이재천;이강인;유효신
    • Journal of the Korean Ceramic Society
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    • v.29 no.12
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    • pp.963-969
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    • 1992
  • This paper describes the feasibility for a direct production of zinc oxalate powders from zinc-loaded D2EHPA solutions combining the purification and the precipitation in one operation unit. This process has the potential as an alternative to conventional method for the synthesis of zinc oxide precursor particles from the hydrometal-lurgical processes. Zinc was extracted into D2EHPA in kerosene and then zinc-loaded D2EHPA solution was emulsified with oxalic acid-HCl solution to precipitate zinc oxalate powder, which was readily calcined to zinc oxide. The precipitation kinetics and yield were sensitive to experimental conditions. The morphology, size and size distribution of the zinc oxalate powders varied with zinc/oxalate ion riatio, temperature, and the presence of SPAN 60, which affected nucleation, growth, and the emulsion characteristics.

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Debiasing Technique for Numerical Weather Prediction using Artificial Neural Network

  • Kang, Boo-Sik;Ko, Ick-Hwan
    • Proceedings of the Korea Water Resources Association Conference
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    • 2006.05a
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    • pp.51-56
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    • 2006
  • Biases embedded in numerical weather precipitation forecasts by the RDAPS model was determined, quantified and corrected. The ultimate objective is to eventually enhance the reliability of reservoir operation by Korean Water Resources Corporation (KOWACO), which is based on precipitation-driven forecasts of stream flow. Statistical post-processing, so called MOS (Model Output Statistics) was applied to RDAPS to improve their performance. The Artificial Neural Nwetwork (ANN) model was applied for 4 cases of 'Probability of Precipitation (PoP) for wet and dry season' and 'Quantitative Precipitation Forecasts (QPF) for wet and dry season'. The reduction on the large systematic bias was especially remarkable. The performance of both networks may be improved by retraining, probably every month. In addition, it is expected that performance of the networks will improve once atmospheric profile data are incorporated in the analysis. The key to the optimal performance of ANN is to have a large data set relevant to the predictand variable. The more complex the process to be modeled by the ANN, the larger the data set needs to be.

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Assessment of Best Available Technology of Wastewater Treatment Facilities in Leather Tanning and Finishing Industry (가죽, 모피가공 및 제조시설의 폐수처리시설 BAT평가)

  • Kim, Youngnoh;Lim, Byungjin;Kwon, Osang
    • Journal of Korean Society on Water Environment
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    • v.22 no.1
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    • pp.51-58
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    • 2006
  • The effluent limitations for individual industry based on the best available technology economically achievable (BAT) have been required to achieve effective regulation. BAT assessment criteria that are suitable for the circumstances of Korean industry were developed in the previous study. The criteria were applied to determine the BAT for leather tanning and finishing industry. For the evaluation BAT, a subcategorization for the industry considering wastewater characteristics, source equipments, raw material and so on should be suggested. Three subcategories: A) Unharing, Chrome Tan, Retan-Wet Finish, B) Chrome Tan, Retan-Wet Finish, and C) Furskins were proposed in this study. Wastewater discharged from the each category contains high concentration of COD, chrome, nitrogen and sulfide. In particular, the concentration of nitrogen from the subcategory A is significantly greater. Twenty sites were surveyed and wastewater qualities were analyzed. Therefore, six different technologies were applied to the subcategory A for the end-of-pipe treatment technology, and a technology was used in the subcategory B and C, respectively. The technology candidates were evaluated in terms of environmental impacts, economically achievability, treatment performance and economical reasonability. As the result, the technology options for each subcategories: A) primary chemical precipitation + modified Ludzack-Ettinger process (MLE) + secondary chemical precipitation, B) chemical precipitation + typical activated-sludge process + Fenton oxidation, C) chemical precipitation + typical activated-sludge process + batch Fenton oxidation or batch activated carbon treatment were selected as the BAT, respectively.

Effect of Thermomechanical Process on Mechanical Property and Microstructure of 9Cr-1Mo Steel (열간가공이 9Cr-1Mo강의 기계적 성질과 미세조직에 미치는 영향)

  • Kim, Jun-Hwan;Baek, Jong-Hyuk;Han, Chang-Hee;Kim, Sung-Ho;Lee, Chan-Bock;Na, Kwang-Su;Kim, Seong-Ju
    • Korean Journal of Metals and Materials
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    • v.47 no.10
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    • pp.621-628
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    • 2009
  • Thermomechanical processes were carried out to evaluate their effects on the mechanical and the microstructural property of a ferritic-martensitic steel. Modified 9Cr-1Mo steels were hot-rolled at a temperature of either $780^{\circ}C$ or $850^{\circ}C$ after normalizing at $1050^{\circ}C$ and then were air-cooled. Continuous annealing at $850^{\circ}C$ for 2 hours immediately after the hot rolling was also performed and they were compared to the specimens without thermomechanical process. The result showed that there were little differences between the hot rolled specimens in terms of the precipitation density and size. However, V content inside the MX precipitates increased in the case of the specimen rolled at $850^{\circ}C$. The application of the continuous annealing induced coarsening of the Nb-rich MX precipitation as well as an increase in the amount of V-rich MX precipitation, which is expected to enhance high temperature mechanical properties of the ferritic-martensitic steel.

Evaluation of Phosphorus Removal Efficiency at Various Coagulation Conditions Using Polyaluminum Chloride with Different Al Contents (Al 함량이 다른 PAC를 이용한 응집 조건 별 인 제거효율 평가)

  • Jeong-Hak Choi;Geon-Gon Yoon;Chang-Han Lee
    • Journal of Environmental Science International
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    • v.32 no.10
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    • pp.731-739
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    • 2023
  • In this study, lab-scale phosphorus coagulation/precipitation experiments were performed using three types of polyaluminum chloride (PAC) with different Al contents (10%, 12%, and 17%). The PO4-P removal efficiencies at various operating conditions, such as initial PO4-P concentration, initial pH, and Al/P molar ratio, were evaluated, and correlations among the operating factors affecting phosphorus coagulation/precipitation with PAC were derived to optimize the process efficiency. When the initial PO4-P concentration was 0.065 and 0.161 mmol P/L under an initial pH of 8-10, the optimal PAC dose was 0.126-0.378 and 0.189-0.667 mmol Al/L, respectively. Under these conditions, the Al/P molar ratio was 2.16-6.18 and 1.28-4.30, respectively, and the PO4-P removal efficiency was in the range of 40.2-92.5%. When the Al/P molar ratio was 2 or less under an initial pH condition of 6-8, the PO4-P removal efficiency was approximately ≤40% owing to insufficient Al3+ ions. However, when the Al/P molar ratio is 3-5, the PO4-P removal efficiency improved to approximately 80-90%. Thus, the optimal Al/P molar ratio to achieve a PO4-P removal efficiency of over 90% was determined to be approximately 4 in the PO4-P coagulation/precipitation process using PAC.

Preparation and Properties of Spherical BaMgAl10O17:Eu Phosphor by Multi-step Precipitation Method (다단 침전법에 의한 구형 BaMgAl10O17:Eu 형광체의 제조 및 특성)

  • Park, Jumg-Min;Jung, Ha-Kyun;Park, Hee-Dong;Park, Yoon-Chang
    • Korean Journal of Materials Research
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    • v.12 no.11
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    • pp.840-844
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    • 2002
  • A spherical $BaMgAl_{10}$ $O_{17}$ :Eu phosphor has been synthesized by a multi-step precipitation route. In order to successfully synthesize the phosphor with spherical shape, the hydrated-alumina particles should be controlled for spherical shape. In this process, the hydroxypropyl cellulose (HPC) was used as a dispersing reagent. This reagent plays an important role in that the particles were controlled to have the uniform size of sub-micron. The final product prepared by the multi-step precipitation method maintained spherical shape with uniform size of 0.4$\mu\textrm{m}$. It can be seen in X-ray diffraction patterns, formation of the single phase of $BaMgAl_{10}$ $O_{17}$ :Eu phosphor prepared by the multi-step precipitation method at $1350^{\circ}C$. Also, the emission spectra of spherical $BaMgAl_{O}$ $10_{17}$ :Eu phosphor in the present case was compared with those of commercially-available blue phosphor under VUV (Vacuum Ultra Violet) excitation. The luminescence process of the $BaMgAl_{10}$ $O_{17}$ :Eu phosphor is characterized by the $4f^{6}$$5d^1$longrightarrow4f$^{7}$ transition (blue) of the $Eu^{2+}$ ion acting as an activating center and the maximum luminescence intensity was obtained by reduction treatment at 145$0^{\circ}C$.