• Title/Summary/Keyword: power-law liquid

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Hydrogel microrheology near the liquid-solid transition

  • Larsen, Travis;Schultz, Kelly;Furst, Eric M.
    • Korea-Australia Rheology Journal
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    • v.20 no.3
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    • pp.165-173
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    • 2008
  • Multiple particle tracking microrheology is used to characterize the viscoelastic properties of biomaterial and synthetic polymer gels near the liquid-solid transition. Probe particles are dispersed in the gel precursors, and their dynamics are measured as a function of the extent of reaction during gel formation. We interpret the dynamics using the generalized Stokes-Einstein relationship (GSER), using a form of the GSER that emphasizes the relationship between the probe particle mean-squared displacement and the material creep compliance. We show that long-standing concepts in gel bulk rheology are applicable to microrheological data, including time-cure superposition to identify the gel point and critical scaling exponents, and the power-law behavior of incipient network's viscoelastic response. These experiments provide valuable insight into the rheology, structure, and kinetics of gelling materials, and are especially powerful for studying the weak incipient networks of dilute gelators, as well as scarce materials, due to the small sample size requirements and rapid data acquisition.

Low-Temperature Chemical Sintered TiO2 Photoanodes Based on a Binary Liquid Mixture for Flexible Dye-Sensitized Solar Cells

  • Md. Mahbubur, Rahman;Hyeong Cheol, Kang;Kicheon, Yoo;Jae-Joon, Lee
    • Journal of Electrochemical Science and Technology
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    • v.13 no.4
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    • pp.453-461
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    • 2022
  • A chemically sintered and binder-free paste of TiO2 nanoparticles (NPs) was prepared using a binary-liquid mixture of 1-octanol and CCl4. The 1:1 (v/v) complex of CCl4 and 1-octanol easily interacted chemically with the TiO2 NPs and induced the formation of a highly viscous paste. The as-prepared binary-liquid paste (PBL)-based TiO2 film exhibited the complete removal of the binary-liquid and residuals with the subsequent low-temperature sintering (~150℃) and UV-O3 treatment. This facilitated the fabrication of TiO2 photoanodes for flexible dye-sensitized solar cells (f-DSSCs). For comparison purposes, pure 1-octanol-based TiO2 paste (PO) with moderate viscosity was prepared. The PBL-based TiO2 film exhibited strong adhesion and high mechanical stability with the conducting oxide coated glass and plastic substrates compared to the PO-based film. The corresponding low-temperature sintered PBL-based f-DSSC showed a power conversion efficiency (PCE) of 3.5%, while it was 2.0% for PO-based f-DSSC. The PBL-based low- and high-temperature (500℃) sintered glass-based rigid DSSCs exhibited the PCE of 6.0 and 6.3%, respectively, while this value was 7.1% for a 500℃ sintered rigid DSSC based on a commercial (or conventional) paste.

Thermohydrodynamic Lubrication Analysis of Turbocharger Journal Bearing Involving the Mixture of Water within Engine Oil (엔진오일에 물이 혼합될 때 터보챠져 저어널 베어링의 열유체윤활 해석)

  • Chun, Sang-Myung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.1
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    • pp.131-140
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    • 2012
  • In this study, using the governing equation for thermohydrodyamic lubrication involving the homogeneous mixture of incompressible fluid derived by based on the principle of continuum mechanics, it is discussed the effects of water within engine oil on the performance of high speed journal bearing of a turbocharger. The governing equations are the general equations being able to be applied on the mixture of Newtonian fluid and non- Newtonian fluid. Here, the fluid viscosity index, n of power-law non-Newtonian fluid is supposed to be 1 for the application of the journal bearing in a turbocharger lubricated with the mixture of two Newtonian fluid, for example, water within engine oil. The results related with the bearing performance are shown that the bearing friction is to decrease and the side leakage and bearing load increase as increasing the water content in an engine oil.

Study on Bearing Performance Involving the Mixture of Water within Engine Oil in a Turbocharger Journal Bearing (터보챠저 저어널 베어링에서 물과 윤활유가 혼합될 때 베어링 성능에 관한 연구)

  • Chun, Sang-Myung
    • Tribology and Lubricants
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    • v.27 no.4
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    • pp.183-192
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    • 2011
  • In this study, using the governing equations for thermohydrodyamic lubrication involving the homogeneous mixture of incompressible fluid derived by based on the principle of continuum mechanics, it is discussed the effects of water dispersed within engine oil on the performance of high speed journal bearing of a turbocharger. The governing equations are the general equations being able to be applied on the mixture of Newtonian fluid and non-Newtonian fluid. Here, the fluid viscosity index, n of power-law non-Newtonian fluid is supposed to be 1 for the application of the journal bearing on a turbocharger lubricated with the mixture of two Newtonian fluids, water dispersed within engine oil. The results related with the bearing performance are showed that the friction force and bearing load capacity decrease as increasing the volume percent of water.

A Study on the Law Temperature Plasma Etching using Electron Cyclotron Resonance (전자 공명을 이용한 저온 플라즈마 식각에 관한 연구)

  • Lee, Seok-Hyun;Kim, Jae-Sung;Whang, Ki-Woong;Kim, Won-Kyu
    • Proceedings of the KIEE Conference
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    • 1992.07b
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    • pp.850-853
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    • 1992
  • A cryogenic electron cyclotron resonance plasma etching system has been built to study wafer-temperature in the silicon etching characteristics. The wafer temperature was controlled from -150 to +30 $^{\circ}C$ during etching using the liquid nitrogen cooled helium gas. Although silicon was etched isotropically in $SF_6$ plasma at room temperatures, we found that it is possible to suppress the etch undercut in Si by reducing a substrate temperature without side wall passivation. In addition, the selectivity of silicon to photoresist was improved considerably at a low wafer temperature. Etch rates, anisotropy and selectivity to photo resist are measured as a function of the wafer temperature in the region of -125 $\sim$ 25$^{\circ}C$ and rf bias power of 20W $\sim$ 80W.

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Thermohydrodynamic Lubrication Analysis of Journal Bearing on Steam Turbine Shipping Engine Involving the Mixture of Water within Turbine Oil (터빈오일과 물이 혼합될 때 증기터빈 선박엔진 저어널 베어링의 열유체윤활 해석)

  • Chun, Sang-Myung
    • Tribology and Lubricants
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    • v.27 no.2
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    • pp.77-87
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    • 2011
  • In this study, using the governing equation for thermohydrodyamic lubrication involving the homogeneous mixture of incompressible fluid derived by based on the principle of continuum mechanics, it is discussed the effects of water within turbine oil on the performance of high speed journal bearing of a steam turbine shipping engine. The governing equation is the general equation being able to be applied on the mixture of Newtonian fluid and non-Newtonian fluid. Here, the fluid viscosity index, n of power-law non-Newtonian fluid is supposed to be 1 for the application of the journal bearing in a steam turbine shipping engine lubricated with the mixture of two Newtonian fluid, for example, water within turbine oil. The results related with the bearing performance are showed.

Numerical Simulation on Flow and Heat Transfer in a Gas Atomizer (가스분무장치에서 열유동 특성에 관한 전산해석)

  • 이성연
    • Journal of Powder Materials
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    • v.4 no.1
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    • pp.55-62
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    • 1997
  • Flow and heat transfer characteristics of gas, and trajectories and cooling characteristics of droplets/particles in a gas atomizer were investigated by a numerical simulation using FLUENT code. Among several kinds of solution method, the k-$\varepsilon$ turbulent model, power-law scheme, SIMPLE algorithm is adopted in this study. Momentum and heat exchange between a continuous phase(gas) and a dispersed phase(particle) were taken into account. Particle trajectories are simulated using the Lagrangian method, and Rosin-Rammler formula is used for the particle size distribution. Streamlines, velocities and pressures of gas, and trajectories, velocities and cooling rates of particles have been investigated for the various gas inlet conditions. Small but very intensive recirculation is found just below the melt orifice, and this recirculation seems to cause the liquid metal to spread radially. Particle trajectory depends on the particle size, the location of particle formation and the turbulent motion of gas. Small particle cools down rapidly, while large diameter particles solidify slowly, and this is mainly due to the differences in thermal inertia.

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A Numerical Study on Various Energy and Environmental System (II) (에너지${\cdot}$환경 제반 시스템에 관한 수치해석적 연구(II))

  • Jang D. S.;Park B. S.;Kim B. S.;Lee E. J.;Song W. Y.
    • 한국전산유체공학회:학술대회논문집
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    • 1996.05a
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    • pp.58-67
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    • 1996
  • This paper describes some computational results of various energy and environmental systems using Patankar's SIMPLE method. The specific topics handled in this study are jet bubbling reactor for flue gas desulfurization, cyclone-type afterburner for incineration, 200m tall stack for 500 MW electric power generation, double skin and heat storage systems of building energy saving for the utilization of solar heating, finally turbulent combustion systems with liquid droplet or pulverized coal particle. A control-volume based finite-difference method with the power-law scheme is employed for discretization. The pressure-velocity coupling is resolved by the use of the revised version of SIMPLE, that is, SIMPLEC. Reynolds stresses are closed using the standard $k-{\varepsilon}$ and RNG $k-{\varepsilon}$ models. Two-phase turbulent combustion of liquid drop or pulverized coal particle is modeled using locally-homogeneous, gas-phase, eddy breakup model. However simple approximate models are incorporated for the modeling of the second phase slip and retardation of ignition without consideration of any detailed particle behavior. Some important results are presented and discussed in a brief note. Especially, in order to make uniform exit flow for the jet bubbling reactor, a well-designed structure of distributor is needed. Further, the aspect ratio in the double skin system appears to be one of important factors to give rise to the visible change of the induced air flow rate. The computational tool employed in this study, in general, appears as a viable method for the design of various engineering system of interest.

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Development of a prediction model relating the two-phase pressure drop in a moisture separator using an air/water test facility

  • Kim, Kihwan;Lee, Jae bong;Kim, Woo-Shik;Choi, Hae-seob;Kim, Jong-In
    • Nuclear Engineering and Technology
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    • v.53 no.12
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    • pp.3892-3901
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    • 2021
  • The pressure drop of a moisture separator in a steam generator is the important design parameter to ensure the successful performance of a nuclear power plant. The moisture separators have a wide range of operating conditions based on the arrangement of them. The prediction of the pressure drop in a moisture separator is challenging due to the complexity of the multi-dimensional two-phase vortex flow. In this study, the moisture separator test facility using the air/water two-phase flow was used to predict the pressure drop of a moisture separator in a Korean OPR-1000 reactor. The prototypical steam/water two-phase flow conditions in a steam generator were simulated as air/water two-phase flow conditions by preserving the centrifugal force and vapor quality. A series of experiments were carried out to investigate the effect of hydraulic characteristics such as the quality and liquid mass flux on the two-phase pressure drop. A new prediction model based on the scaling law was suggested and validated experimentally using the full and half scale of separators. The suggested prediction model showed good agreement with the steam/water experimental results, and it can be extended to predict the steam/water two-phase pressure drop for moisture separators.

Verification of SPACE Code with MSGTR-PAFS Accident Experiment (증기발생기 전열관 다중파단-피동보조급수냉각계통 사고 실험 기반 안전해석코드 SPACE 검증)

  • Nam, Kyung Ho;Kim, Tae Woo
    • Journal of the Korean Society of Safety
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    • v.35 no.4
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    • pp.84-91
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    • 2020
  • The Korean nuclear industry developed the SPACE (Safety and Performance Analysis Code for nuclear power plants) code and this code adpots two-phase flows, two-fluid, three-field models which are comprised of gas, continuous liquid and droplet fields and has a capability to simulate three-dimensional model. According to the revised law by the Nuclear Safety and Security Commission (NSSC) in Korea, the multiple failure accidents that must be considered for accident management plan of nuclear power plant was determined based on the lessons learned from the Fukushima accident. Generally, to improve the reliability of the calculation results of a safety analysis code, verification work for separate and integral effect experiments is required. In this reason, the goal of this work is to verify calculation capability of SPACE code for multiple failure accident. For this purpose, it was selected the experiment which was conducted to simulate a Multiple Steam Generator Tube Rupture(MSGTR) accident with Passive Auxiliary Feedwater System(PAFS) operation by Korea Atomic Energy Research Institute (KAERI) and focused that the comparison between the experiment results and code calculation results to verify the performance of the SPACE code. The MSGR accident has a unique feature of the penetration of the barrier between the Reactor Coolant System (RCS) and the secondary system resulting from multiple failure of steam generator U-tubes. The PAFS is one of the advanced safety features with passive cooling system to replace a conventional active auxiliary feedwater system. This system is passively capable of condensing steam generated in steam generator and feeding the condensed water to the steam generator by gravity. As the results of overall system transient response using SPACE code showed similar trends with the experimental results such as the system pressure, mass flow rate, and collapsed water level in component. In conclusion, it could be concluded that the SPACE code has sufficient capability to simulate a MSGTR accident.