• Proceedings of the Korean Powder Metallurgy Institute Conference
• /
• 2006.09a
• /
• pp.162-162
• /
• 2006

• Journal of Electrochemical Science and Technology
• /
• v.15 no.3
• /
• pp.405-413
• /
• 2024

Several techniques for determining the reverse peak current from a cyclic voltammogram (CV) for a reversible system are described in the literature: CV itself as a baseline with long switching potential (E_λ) that serves as a baseline for other CVs, Nicholson equation that uses CV parameters to calculation reverse peak current and linear extrapolation of the current obtained at the switching potential. All methods either present experimental difficulties or large errors in the peak current determination. The paper demonstrates, both theoretically and experimentally, that trapezoidal cyclic voltammetry (TCV) can be used as a baseline to determine anodic peak current (i_ap) with high accuracy and with a switching potential shorter than that used by CV, as long as E_λ is at least 130 mV away from the cathodic peak. Beyond this value of switching potential the electroactive specie is completely depleted from the electrode surface. Using TCV with E_λ = 0.34 V and a switching time (t_λ) of 240 s as a baseline, the determination of the reverse peak current presents a deviation from the expected value of less than 1% for most of the CVs studied (except cases when E_λ is close to the direct potential peak). This result presents better accuracy than the Nicholson equation and the linear extrapolation of the current measured at the switching potential, in addition to presenting a smaller error than that obtained in the acquisition of the experimental current. Furthermore, determining the reverse peak current by extrapolating the linear fit of i_ap vs. ${\sqrt[1/]{t_{\lambda}}}$ to infinite time gave a reasonable approximation to the expected value. Experiments with aqueous potassium hexacyanoferrate (II) and ferrocene in acetonitrile confirmed the theoretical predictions.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.59 no.5
• /
• pp.860-865
• /
• 2010

When a circuit breaker is opened, a large capacitance around the buses, the circuit breaker and the potential transformer (PT) might cause PT ferroresonance. During PT ferroresonance, the iron core repeats saturation and unsaturation even though the supplied voltage is a rated voltage. This paper describes an analytical analysis of PT ferroresonance in the transient-state. To analyze ferroresonance analytically, the iron core is modelled by a simplified two-segment core model in this paper. Thus, a nonlinear ordinary differential equation (ODE) for the flux linkage is changed into a linear ODE with constant coefficients, which enables an analytical analysis. In this simplified model, each state, which is either saturated or unsaturated state, corresponds to one of the three modes, i.e. overdamping, critical damping and underdamping. The flux linkage and the voltage in each state are obtained analytically by solving the linear ODE with constant coefficients. The proposed transient analysis is effective in the more understanding of ferroresonance and thus can be used to design a ferroresonance prevention or suppression circuit of a PT.

• Asian Journal of Atmospheric Environment
• /
• v.9 no.2
• /
• pp.137-145
• /
• 2015

This study focused on the measurement of the actual charging state of ambient aerosol particles, which is important for understanding the intricate process of adverse health effects caused by particulate matter (PM). The net electrostatic charging state of $PM_{2.5}$ collected on filter media was measured in this study. The Faraday cage method and surface potential measurements were used in this study. The results showed that the polarities of the net charging state measured using these two methods were in agreement for 42 out of 48 samples (87.5%), and 36 samples (75%) were negatively charged. The filters were not significantly charged by friction between the filters and air not containing PM. Charge addition to or leakage from the filters was not observed over a two-month storage period. Net charging state of $PM_{2.5}$ collected on the filters was concluded to be negative in most cases, based on data's support of the assumption that aerosol charging state is not altered by the process of PM collection using filter.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.5
• /
• pp.1422-1432
• /
• 2014

Convergent all-electron multi-reference configuration-interaction (MRCI) calculations are performed for a lithium dimer with Kaufmann's Rydberg basis functions. A comparison of the results of these calculations with those of the effective core potential/core polarization potential (ECP/CPP) method and experimental data reveals the deficiency of the all-electron ab initio method. The deficiency is related to the mere 51.9% attainment of electron correlation for the ground state. The percent attainment of electron correlation for the first excited state is slightly better than that for the ground state, preventing us from obtaining better agreements with experimental data by means of increasing the size of basis sets. The Kaufmann basis functions are then used with the ECP/CPP method to obtain the accurate convergent potential energy curves for the $^1\prod_u$ states correlated to Li(2p) + Li(2p) and Li(2s) + Li(n = 2, 3, 4). Quantum defect curves (QDCs) calculated for both the $X^2\sum_g$ and 1 $^2\prod_u$ states of the $Li{_2}^+$ ion and the Lu-Fano plot reveal a strong series-series interaction between the two $2snp{\pi}$ and $2pnp{\pi}$ Rydberg series. The QDCs are then used to resolve assignment problems in the literature. The reassignments, performed by Jedrzejewski-Szemek et al., of the dissociation product of the D $^1\prod$ state from (2s+3d) to (2s+3p) and that of the 6 $^1\prod_u$ from (2s+4d) to (2s+4p) are found to be incorrect. It may be more natural to assign their $2snp{\pi}$ Rydberg series as a $2snd{\pi}$ series. The state, assigned as 5p $^1\prod_u$ by Ross et al. and 4d $^1\prod$ by Jedrzejewski-Szemek et al., is assigned as the 7 $^1\prod_u$ state, correlated to the Li(2s) + Li(4f) limit.

• Bulletin of the Korean Chemical Society
• /
• v.24 no.6
• /
• pp.763-770
• /
• 2003

The $BH_5$ molecule, which is suggested as an intermediate of the acidolysis of $BH_4^-$, contains a weak two-electron-three-center bond and it requires extremely high-level of theories to calculate the energy and structure correctly. The structures and energies of $BH_5$ and the transition state for the hydrogen scrambling have been studied using recently developed multi-coefficient correlated quantum mechanical methods (MCCMs). The dissociation energies and the barrier heights agree very well with the previous results at the CCSD(T)/ TZ(3d1f1g, 2p1d) level. We have also calculated the potential energy curves for the dissociation of $BH_5$ to $BH_3$ and $H_2$. The lower levels of theory were unable to plot correct potential curves, whereas the MCCM methods give very good potential energy curves and requires much less computing resources than the CCSD(T)/ TZ(3d1f1g,2p1d) level. The potential energy of the $BH_5$ scrambling has been obtained by the multiconfiguration molecular mechanics algorithm (MCMM), and the rates are calculated using the variational transition state theory including multidimensional tunneling approximation. The rate constant at 300 K is 2.1 × $10^9s^{-1}$, and tunneling is very important.

• The Korean Journal of Ceramics
• /
• v.4 no.2
• /
• pp.72-77
• /
• 1998

A defect model for UO$_2$ fuel containing soluble fission products was devised based on the defect structure of pure and doped uranias. Using the equilibrium between fuel solid-solution and fission-products and the material balance within the fuel, a tracing method to get the stoichiometry change of urania fuel with burnup was made. This tracing method was applied to high burnup urania fuel and DUPIC fuel. The oxygen potential of urania fuel turned out to increase slightly with burnup. The stoichiometry change was calculated to be negligible due to the buffering role f Mo. The oxygen potential of DUPIC fuel out to be sensitive to the initial chemical state of Mo in the fuel.

• Journal of the Korean Society of Fisheries and Ocean Technology
• /
• v.55 no.3
• /
• pp.206-216
• /
• 2019

This study is aimed to compare stock assessment models depending on how the models fit to observed data. Process-error model, Observation-error model, and Bayesian state-space model for the Korean Western coast fisheries were applied for comparison. Analytical results show that there is the least error between the estimated CPUE and the observed CPUE with the Bayesian state-space model; consequently, results of the Bayesian state-space model are the most reliable. According to the Bayesian State-space model, potential yield of fishery resources in the West Sea of Korea is estimated to be 231,949 tons per year. However, the results show that the fishery resources of West Sea have been decreasing since 1967. In addition, the amounts of stock in 2013 are assessed to be only 36% of the stock biomass at MSY level. Therefore, policy efforts are needed to recover the fishery resources of West Sea of Korea.

• Journal of the Korean Institute of Intelligent Systems
• /
• v.25 no.3
• /
• pp.254-259
• /
• 2015

In this paper, The wireless robot control system was proposed using Brain-computer interface(BCI) systems based on the steady-state visual evoked potential(SSVEP). Cross Power Spectral Density(CPSD) was used for analysis of electroencephalogram(EEG) and extraction of feature data. And Linear Discriminant Analysis(LDA) and Support Vector Machine(SVM) was used for patterns classification. We obtained the average classification rates of about 70% of each subject. Robot control was implemented using the results of classification of EEG and commanded using bluetooth communication for robot moving.

• Journal of the Korean Electrochemical Society
• /
• v.7 no.4
• /
• pp.179-182
• /
• 2004

The aim of this study is to investigate the initiation and propagation of crevice corrosion for ferritic stainless steel in artificial crevice based on micro capillary tube method. The 430 stainless steel in artificial crevice is potentiostatically polarized in different sodium chloride solutions. Potentiodynamic and potentiostatic polarization data were measured in situ. The potentials in the crevice were measured by depth profile using the 0.04 mm diameter micro capillary tube inserted in the crevice. The potentials in the crevice ranged from -220 mV to -360 mV vs SCE from opening to bottom of crevice, which are lower than the external surface potential, -200 mV vs SCE. Such a potential drop induced the change of the metal surface state from passive to active. The surface of metal is located in passive state in -200 mV but the inner surface keeps active state below -220 mV, Thus these results show that the It drop mechanism in the crevice was more objective for evaluation and the method was easier to reproduce. Therefore the potential drop is one of the reasons for crevice corrosion by measuring the potentials in narrow crevice with a new micro measuring system.