• Title/Summary/Keyword: potential gradient

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Electrokinetic-Fenton Process for Removal of Phenanthrene (동전기-펜턴 공정을 이용한 phenanthrene 오염토양의 정화)

  • 양지원;박지연;김상준;이유진;기대정
    • Journal of Soil and Groundwater Environment
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    • v.9 no.1
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    • pp.47-53
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    • 2004
  • Feasibility of electrokinetic process combined with Fenton-like reaction was investigated for the removal of phenanthrene from contaminated soil. Transport of hydrogen peroxide by electroosmosis and decomposition of phenanthrene by Fenton-like reaction were observed in a model system. Electrical potential gradient and electroosmotic flow (EOF) at 10 mA were higher than those at 5 mA. High accumulated EOF resulted in high removal efficiency of phenanthrene because the large amount of hydrogen peroxide was transfered through the soil. Removal efficiency of phenanthrene by water washing was 8.5% for 7 days. The highest removal efficiency including phenanthrene decomposition was 95.6% for 14 days. After the operation, soil samples with removal efficiency of 95.6% showed low concentrations of phenanthrene and its intermediates. From this result, it was presumed that phenanthrene was decomposed to small molecules or mineralized to water and carbon dioxide due to continuous supply of hydrogen peroxide by electroosmotic flow.

A Study on Propulsion Performance of Underwater Ram-Jet with Optimized Nozzle Configuration (최적 노즐형상을 갖는 수중램제트의 추진성능에 관한 연구)

  • Kang, H.K.;Kim, Y.T.;Lee, Y.H.
    • Journal of the Society of Naval Architects of Korea
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    • v.34 no.4
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    • pp.42-52
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    • 1997
  • The basic principle of underwater ram-jet as a unique marine propulsion concept showing vary high cruise speed range(e. g. 80-100 knots) is the thrust production by the transfer of the potential energy of compressed gas to the operating liquid through kinetic mixing process. This paper is aimed to investigate the propulsive efficiency of the nozzle flow in underwater ram-jet at the speed of 80 knots for the buried type vessel. The basic assumption of the theoretical analysis is that mixture of water and air can be treated as incompressible gas. For an optimized nozzle configuration obtained from the performance analysis, preliminary data for performance evaluation are obtained and effects of nozzle inner wall friction, ambient temperature, ambient pressure, water density, gas velocity, bubble radius, flow velocity, diffuser area ratio, mass flow ratio and water velocity gradient are investigated.

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Quantitative Analysis of Luteolin 5-glucoside in Ajuga spectabilis and Their Neuroprotective Effects (자란초에서 분리된 Luteolin 5-glucoside의 함량분석과 신경세포 보호 활성)

  • Woo, Kyeong Wan;Sim, Mi Ok;Kim, A Hyun;Kang, Byoung Man;Jung, Ho Kyung;An, Byeongkwan;Cho, Jung Hee;Cho, Hyun Woo
    • Korean Journal of Pharmacognosy
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    • v.47 no.3
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    • pp.211-216
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    • 2016
  • In the course of our continuing search for biologically active components from Korean medicinal plants, we isolated the main compound, luteolin 5-glucoside from aqueous fraction of Ajuga spectabilis. The structure was elucidated by the basis of $^1H$ and $^{13}C$ NMR and TOF ESI-MS data. Quantitative analysis of luteolin 5-glucoside was carried out on a XBridge C18 column ($S-5{\mu}m$, $4.6{\times}250mm$) with gradient elution composed of acetonitrile:water. The results exhibit that the average content of main compound in A. spectabilis were 0.048%. Oxidative stress plays a major role Alzheimer's disease (AD) and other neurodogenerative disease. AD is major health problem and there is currently no clinically accepted treatment to cure or stop its progression. Pretreatment with luteolin 5-glucoside markedly attenuated $H_2O_2$-induced cell viability loss in a dose-dependent manner. Luteolin 5-glucoside also inhibited the formation of intracellular reactive oxygen species in SH-SY5Y. The results suggest that luteolin 5-glucoside from A. spectabilis has protective effects against oxidative stress-induced cytotoxicity, which might be a potential therapeutic compound for treating and/or preventing neurodegenerative disease implicated with oxidative stress.

A Case Study of Heavy Snowfall with Thunder and Lightning in Youngdong Area (뇌전을 동반한 영동지역 대설 사례연구)

  • Kim, Hae-Min;Jung, Sueng-Pill;In, So-Ra;Choi, Byoung-Choel
    • Atmosphere
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    • v.28 no.2
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    • pp.187-200
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    • 2018
  • The heavy snowfall phenomenon with thunder and lightning occurred in Yeongdong coastal region on 20 January 2017. Amount of snow on that day was a maximum of 47 cm and was concentrated in a short time (2 hours) at the Yeongdong coastal area. The mechanism of thundersnow was investigated to describe in detail using observational data and numerical simulation (Weather Research and Forecast, WRF) applied lightning option. The results show that a convective cloud occurred at the Yeongdong coastal area. The east wind flow was generated and the pressure gradient force was maximized by the rapidly developed cyclone. The cold and dry air in the upper atmosphere has descended (so called tropopause folding) atmospheric lower layer at precipitation peak time (1200 LST). In addition, latent heat in the lower atmosphere layer and warm sea surface temperature caused thermal instability. The convective cloud caused by the strong thermal instability was developed up to 6 km at that time. And the backdoor cold front was determined by the change characteristics of meteorological elements and shear line in the east sea. Instability indexes such as Total totals Index (TT) and Lightning Potential Index (LPI) are also confirmed as one of good predictability indicates for the explosive precipitation of convective rainfall.

Spatial and Temporal Variability of Water Quality in Korean Dam Reservoirs

  • Lim, Go-Woon;Lee, Sang-Jae;An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.42 no.4
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    • pp.452-464
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    • 2009
  • The objectives of this study were to evaluate spatial and temporal variability of water quality in 10 reservoirs and identify the key nutrients (N, P) influencing chlorophyll-a (CHL) along with analysis of empirical models and zonal patterns of total phosphorus (TP) and CHL. We analyzed total nitrogen (TN), TP, CHL, water clarity (Secchi depth, SD), and evaluated potential limiting nutrient using ambient N:P ratios and previous criteria of ambient nutrients. Water clarity and CHL varied largely depending on the seasonal monsoon and type of reservoir, but trophic state was diagnosed as eutrophy, base on mean CHL in most reservoirs. The peak of TP did not match the contents of CHL due to rapid flushing during the high run-off period. In the reservoir of DR, regression coefficient in the $P_r$ was 0.510 but was 0.159 in the $M_o$, while the TP-CHL relation in the YR increased during the monsoon compared to the premonsoon. The regression coefficient in the $P_r$ was not statistically significant but the value of $M_o$ was 0.250. TP showed similar longitudinal zonal gradients among the reservoirs of DR, YR and JR. Empirical models of TP-CHL, based on overall data, showed that CHL was determined by phosphorus($R^2=0.244$, p=0.0019). Regression analysis of CHL-SD showed a stronger linear fit ($R^2=0.638$, p<0.001) than the TP-CHL model.

A Study on Calculation of Readjustment Height of Urban Region by Geo-spatial Information System - Focused on the Region of YOUNGDO-GU, PUSAN- (지형공간정보체계를 이용한 도시지역의 정지표고 산정에 관한 연구 -부산시 영도구 지역을 중심으로-)

  • 박운용;차성렬;신상철
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.12 no.1
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    • pp.119-129
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    • 1994
  • Geo-spatial information system covers a wide range of applications and technologies and is of great potential interest to many users in government, industry and science. In many civil engineering problems it is necessary to model a landform in order to be able to removed or to be brought in to make the site ready for the proposed developed. The earthwork volume, could be calculated by the trapezoidal formula, Simpson's 1/3 and 3/8 rules. And slope is defined by a plane tangent to the surface as modelled by the digital terrain model at any given point and comprises two components namely, gradient, the maximum rate of change altitude, and aspect, the compass direction of this maximum rate of change. The thesis is the earthwork volume could be counted, readjustment height, slope and aspect analysis of various derived products can be obtained form geo-spatial informations.

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The development of high-performance PRO module and effects of operating condition on the performance of PRO module (고성능 PRO 모듈 개발 및 운전조건이 모듈 성능에 미치는 영향)

  • Han, Man Jae;Sim, Yeonju;Lee, Jong Hwa
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.4
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    • pp.303-310
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    • 2017
  • Pressure retarded osmosis(PRO) has attracted much attention as potential technology to reduce the overall energy consumption for reverse osmosis(RO) desalination. The RO/PRO hybrid process is considered as the most logical next step for future desalination. The PRO process aims to harness the osmotic energy difference of two aqueous solutions separated by a semipermeable membrane. By using the concentrated water(RO brine) discharged from existing RO plants, the PRO process can effectively exploit a greater salinity gradient to reduce the energy cost of processing concentrated water. However, in order to use RO brine as the draw solution, PRO membrane must have high water flux and enough mechanical strength to withstand the high operational pressure. This study investigates the development of a thin film composite PRO membrane and spiral wound module for high power density. Also, the influence of membrane backing layer on the overall power density was studied using the characteristic factors of PRO membranes. Finally, the performance test of an 8-inch spiral wound module was carried out under various operating conditions(i.e. hydraulic pressure, flow rate, temperature). As the flow rate and temperature increased under the same hydraulic pressure, the PRO performance increased due to the growth of water permeability coefficient and osmotic pressure. For a high performance PRO system, in order to optimize the operating conditions, it is highly recommended that the flow pressure be minimized while the flow rate is maintained at a high level.

Effects of Microbial Iron Reduction and Oxidation on the Immobilization and Mobilization of Copper in Synthesized Fe(III) Minerals and Fe-Rich Soils

  • Hu, Chaohua;Zhang, Youchi;Zhang, Lei;Luo, Wensui
    • Journal of Microbiology and Biotechnology
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    • v.24 no.4
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    • pp.534-544
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    • 2014
  • The effects of microbial iron reduction and oxidation on the immobilization and mobilization of copper were investigated in a high concentration of sulfate with synthesized Fe(III) minerals and red earth soils rich in amorphous Fe (hydr)oxides. Batch microcosm experiments showed that red earth soil inoculated with subsurface sediments had a faster Fe(III) bioreduction rate than pure amorphous Fe(III) minerals and resulted in quicker immobilization of Cu in the aqueous fraction. Coinciding with the decrease of aqueous Cu, $SO_4{^{2-}}$ in the inoculated red earth soil decreased acutely after incubation. The shift in the microbial community composite in the inoculated soil was analyzed through denaturing gradient gel electrophoresis. Results revealed the potential cooperative effect of microbial Fe(III) reduction and sulfate reduction on copper immobilization. After exposure to air for 144 h, more than 50% of the immobilized Cu was remobilized from the anaerobic matrices; aqueous sulfate increased significantly. Sequential extraction analysis demonstrated that the organic matter/sulfide-bound Cu increased by 52% after anaerobic incubation relative to the abiotic treatment but decreased by 32% after oxidation, indicating the generation and oxidation of Cu-sulfide coprecipitates in the inoculated red earth soil. These findings suggest that the immobilization of copper could be enhanced by mediating microbial Fe(III) reduction with sulfate reduction under anaerobic conditions. The findings have an important implication for bioremediation in Cu-contaminated and Fe-rich soils, especially in acid-mine-drainage-affected sites.

Nutrient dynamics study of overlying water affected by peroxide-treated sediment

  • Haque, Niamul;Kwon, Sung-Hyun
    • Journal of Ecology and Environment
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    • v.41 no.9
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    • pp.235-245
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    • 2017
  • Background: Loading of excess nutrient via bioremediation of polluted sediment to overlying water could trigger anoxia and eutrophication in coastal area. The aim of this research was to understand the changes of overlying water features such as dissolved oxygen (DO); pH; oxidation reduction potential (ORP); $chlorophyll-{\alpha}$ ($Chl-{\alpha}$); and nitrogen nutrients ammonia ($N-NH_4{^+}$), nitrate ($N-NO_3{^-}$), and nitrite ($N-NO_2^-$) when the sediment was not treated (control) and treated by calcium peroxide for 5 weeks. Methods: The water samples were analyzed for measuring physical and chemical properties along with the sediment analyzed by polymerase chain reaction (PCR) including denaturing gradient gel electrophoresis (DGGE) for identifying the phylogenetic affiliation of microbial communities. Results: Results showed that due to the addition of calcium peroxide in sediment, the overlying water exposed the rise of dissolve oxygen, pH, and ORP than control. Among the nitrogen nutrients, ammonia inhibition was higher in calcium peroxide treatment than control but in case of nitrate inhibition, it was reversed than control. $Chlorophyll-{\alpha}$ was declined in treatment column water by 30% where it was 20% in control column water. Actibacter and Salegentibacter group were detectable in the calcium-peroxide-treated sediment; in contrary, no detectable community ware found in control sediment. Both phylogenetic groups are closely related to marine microflora. Conclusions: This study emphasizes the importance of calcium peroxide as an oxygen release material. Interaction with peroxide proved to be enhancing the formation of microbial community that are beneficial for biodegradation and spontaneity of nutrient attenuation into overlying water.

A Study on Development Potential of Shallow Geothermal Energy as Space Heating and Cooling Sources in Mongolia (몽골의 천부 지열에너지(냉난방 에너지)개발 가능성에 관한 연구)

  • Hahn, Jeong-Sang;Yoon, Yun-Sang;Yoon, Kern-Sin;Lee, Tae-Yul;Kim, Hyong-Soo
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.8 no.2
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    • pp.36-47
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    • 2012
  • Time-series variation of groundwater temperature in Mongolia shows that maximum temperature is occured from end of October to the first of February(winter time) and minimum temperature is observed from end of April to the first of May(summer time). Therefore ground temperature is s a good source for space heating in winter and cooling in summer. Groundwater temperatures monitored from 3 alluvial wells in Ulaabaatar at depth between 20 and 24 m are $(4.43{\pm}0.8)^{\circ}C$ with average of $4.21^{\circ}C$ but mean annual ground temperature(MAGT) at the depth of 100 m in Ulaanbaatar was about $3.5{\sim}6.0^{\circ}C$. Bore hole length required to extract 1 RT's heat energy from ground in heating time and to reject 1 RT's heat energy to ground in summer time are estimated about 130 m and 98 m respectively. But in case that thermally enhanced backfill and U tube pipe placement along the wall are used, the length can be reduced about 25%. Due to low MAGT of Ulaabaatar such as $6^{\circ}C$, the required length of GHX in summer cooling time is less than the one of winter heating time. Mongolia has enough available property, therefore the most cost effective option for supplying a heating energy in winter will be horizontal GHX which absorbs solar energy during summer time. It can supply 1 RT's ground heat energy by 570 m long horizontally installed GHX.