• 제목/요약/키워드: potential evaporation

Search Result 178, Processing Time 0.031 seconds

A Capillary Electrochromatographic Microchip Packed with Self-Assembly Colloidal Carboxylic Silica Beads

  • Jeon, In-Sun;Kim, Shin-Seon;Park, Jong-Man
    • Bulletin of the Korean Chemical Society
    • /
    • v.33 no.4
    • /
    • pp.1135-1140
    • /
    • 2012
  • An electrochromatographic microchip with carboxyl-group-derivatized mono-disperse silica packing was prepared from the corresponding colloidal silica solution by utilizing capillary action and self-assembly behavior. The silica beads in water were primed by the capillary action toward the ends of cross-patterned microchannel on a cyclic olefinic copolymer (COC) substrate. Slow evaporation of water at the front of packing promoted the self-assembled packing of the beads. After thermally binding a cover plate on the chip substrate, reservoirs for sample solutions were fabricated at the ends of the microchannel. The packing at the entrances of the microchannel was silver coated to fix utilizing an electroless silver-plating technique to prevent the erosion of the packed structure caused by the sudden switching of a high voltage DC power source. The electrochromatographic behavior of the microchip was explored and compared to that of the microchip with bare silica packing in basic borate buffer. Electrophoretic migration of Rhodamine B was dominant in the microchip with the carboxyl-derivatized silica packing that resulted in a migration approximated twice as fast, while the reversible adsorption was dominant in the bare silica-packed microchip. Not only the faster migration rates of the negatively charged FITC-derivatives of amino acids but also the different migration due to the charge interaction at the packing surface were observed. The electrochromatographic characteristics were studied in detail and compared with those of the bare silica packed microchip in terms of the packing material, the separation potential, pH of the running buffer, and also the separation channel length.

The influence of preparation conditions on the electrochemical degradation of tungsten oxide thin films prepared by electron beam deposition (제작조건이 전자비임으로 제작된 텅스텐산화물 박막의 전기화학적 퇴화에 미치는 영향)

  • 이길동
    • Journal of the Korean Vacuum Society
    • /
    • v.7 no.4
    • /
    • pp.306-313
    • /
    • 1998
  • The electrochromic $WO_3$thin films were prepared by using the electron-beam evaporatin technique. Flms prepared at a vacuum pressure of $10^{-4}$ mbar were found to be most stable during repeated potential cycles. The chemical stability of the film in aqueous solutions was also affected by the vacuum pressure during evaporation. The redox current and the optical properties of the degraded films were affected by the thickness of the film. The 5,000$\AA$-thick films were found to be most stable, undergoing the least degradation during the repeated coloring and bleaching cycles. The origin of the mechanism dominating the degradation during the repeated coloring and bleaching cycles was the accumulation of lithium in the film, which results in decreasing redox current. Tungsten oxide films with titanium content of about 10-15 mol% was found to be most stable, undergoing the least degradation during the repeated cycles. The origin of the mechanism dominating the least degradation during the repeated cycles was the reduction of lithium ion trapping sites in the films, which results in a increased durability.

  • PDF

pH-Sensitive Release of Indomethacin from Curdlan Acetate Microspheres (Curdlan Acetate Microspheres를 이용한 Indomethacin의 pH 민감성 방출)

  • Lee Chang-Moon;Lee Young-Jin;Kim Hyung-Ju;Park Hee-Jung;Lee Ki-Young
    • KSBB Journal
    • /
    • v.20 no.1 s.90
    • /
    • pp.46-49
    • /
    • 2005
  • Curdlan, a natural $\beta-1,3-glucan,$ has been studied as drug carrier due to its unique properties including its thermal gelling characters. In this study, curdlan was chemically acetylated for pH-sensitive drug delivery. Curdlan acetate microspheres(CAMs) were prepared by the solvent evaporation method. The size of the CAMs was below $200{\mu}m.$ The drug loading efficiency of microspheres was approximately $58.44\%$. In the swelling test, the CAMs showed pH-sensitive behavior. The swelling capacity of microspheres at pH 7.4 was much greater than at pH 1.4. Also, release rate of indomethacin(IND) at pH 7.4 from the CAMs was faster than that at pH 1.4. Therefore the CAMs have potential for the controlled release of IND over an extended period of time.

Comparison of Radical Scavenging Activity of Extracts of Mulberry Juice and Cake Prepared from Mulberry (Morus spp.) Fruit

  • Kwon, Yun-Ju;Rhee, Soon-Jae;Chu, Jae-Won;Choi, Sang-Won
    • Preventive Nutrition and Food Science
    • /
    • v.10 no.2
    • /
    • pp.111-117
    • /
    • 2005
  • Radical scavenging activity of water and methanol extracts of mulberry juice and cake prepared from mulberry fruit (Morus spp.) was evaluated using three in vitro assay systems. Mulberry fruits were homogenized with $0.5\%$ trifluoroacetic acid (TFA) in distilled water, filtered with cheeze-cloth and centrifuged to yield mulberry juice and cake. Mulberry juice was evaporated and solubilized in $0.5\%$ TFA in distilled water or $0.5\%$ TFA in $80\%$ aqueous methanol, followed by filtration and evaporation to obtain water (WMJ) and methanol (MMJ) extracts of mulberry juice. Mulberrry cake also was extracted with the above same solvents, and thereby finally obtaining water (WMC) and methanol (MMC) extracts of mulberry cake. Among four extracts, the MMC showed the most potent radical scavenging activity against DPPH radical $(IC_{50}=167.45\;{\mu}g/mL)$, and superoxide $(IC_{50}=36.18\;{\mu}g/mL)$ and hydroxyl radicals $(IC_{50}=467.08\;{\mu}g/mL)$. The WMC also exhibited stronger radical scavenging activity than those of two other mulberry juice extract, WMJ and MMJ. Meanwhile, the MMJ exerted stronger three radical scavenging activity than the WMJ. Total phenolic content of the water and MeOH extracts from mulberry cake was higher than that of the water and MeOH extracts from mulberry juice. Thus, these results suggest that the extracts of mulberry cake with high dietary phenolics may be useful potential source of natural antioxidant as radical scavenger.

Changes of Soil Water Balance and Growth of Red Pepper as Affected by Growing Conditions in the Plastic House (재배 조건에 따른 고추의 생장과 토양 수분소비의 변화)

  • 태근식;엄정식;황재문
    • Journal of Bio-Environment Control
    • /
    • v.12 no.1
    • /
    • pp.38-44
    • /
    • 2003
  • This work was conducted to estimate amounts of irrigating water during the growing periods of pepper after estimating water consumption in the plastic film house in 1997 and 1998. Evapo-transpiration (ET) under conditions of a black and white PE mulch and sandy or clay loam soil which enhanced the growth and yield of red peppers was greater than that at the bare and sand soil. Average ET of pepper grown in pots accounted for 56.5%∼79.7% of total supplying water in 1997 and 1998. Most of ET was proportioned to the transpiration amount (91∼94%), but there was some difference between amounts of ET and transpiration plus evaporation. Although 57 depended on conditions of the soil texture and plant growth, transpiration for pepper growing periods was amounted to 337.7∼774.3 m in the clay soil,910.6 m in the sandy loam soil, and 253.1 mm in the sandy soil.

Capillarity-Driven Self-Assembly of Silver Nanowires-Coated Fibers for Flexible and Stretchable Conductor

  • Li, Yi;Chen, Jun;Han, Xiao;Li, Yinghui;Zhang, Ziqiang;Ma, Yanwen
    • Nano
    • /
    • v.13 no.12
    • /
    • pp.1850146.1-1850146.9
    • /
    • 2018
  • The rapid development of smart textiles requires the large-scale fabrication of conductive fibers. In this study, we develop a simple, scalable and low-cost capillary-driven self-assembly method to prepare conductive fibers with uniform morphology, high conductivity and good mechanical strength. Fiber-shaped flexible and stretchable conductors are obtained by coating highly conductive and flexible silver nanowires (Ag NWs) on the surfaces of yarn and PDMS fibers through evaporation-induced flow and capillary-driven self-assembly, which is proven by the in situ optical microscopic observation. The density of Ag NWs and linear resistance of the conductive fibers could be regulated by tuning the assembly cycles. A linear resistance of $1.4{\Omega}/cm$ could be achieved for the Ag NWs-coated nylon, which increases only 8% after 200 bending cycle, demonstrating high flexibility and mechanical stability. The flexible and stretchable conductive fibers have great potential for the application in wearable devices.

Comparison of reference evapotranspiration estimation methods with limited data in South Korea

  • Jeon, Min-Gi;Nam, Won-Ho;Hong, Eun-Mi;Hwang, Seonah;Ok, Junghun;Cho, Heerae;Han, Kyung-Hwa;Jung, Kang-Ho;Zhang, Yong-Seon;Hong, Suk-Young
    • Korean Journal of Agricultural Science
    • /
    • v.46 no.1
    • /
    • pp.137-149
    • /
    • 2019
  • Accurate estimation of reference evapotranspiration (RET) is important to quantify crop evapotranspiration for sustainable water resource management in hydrological, agricultural, and environmental fields. It is estimated by different methods from direct measurements with lysimeters, or by many empirical equations suggested by numerous modeling using local climatic variables. The potential to use some such equations depends on the availability of the necessary meteorological parameters for calculating the RET in specific climatic conditions. The objective of this study was to determine the proper RET equations using limited climatic data and to analyze the temporal and spatial trends of the RET in South Korea. We evaluated the FAO-56 Penman-Monteith equation (FAO-56 PM) by comparing several simple RET equations and observed small fan evaporation. In this study, the modified Penman equation, Hargreaves equation, and FAO Penman-Monteith equation with missing solar radiation (PM-Rs) data were tested to estimate the RET. Nine weather stations were considered with limited climatic data across South Korea from 1973 - 2017, and the RET equations were calculated for each weather station as well as the analysis of the mean error (ME), mean absolute error (MAE), and root mean square error (RMSE). The FAO-56 PM recommended by the Food Agriculture Organization (FAO) showed good performance even though missing solar radiation, relative humidity, and wind speed data and could still be adapted to the limited data conditions. As a result, the RET was increased, and the evapotranspiration rate was increased more in coastal areas than inland.

Satellite-based Evaporative Stress Index (ESI) as an Indicator of Agricultural Drought in North Korea (Evaporative Stress Index (ESI)를 활용한 북한의 위성영상기반 농업가뭄 평가)

  • Lee, Hee-Jin;Nam, Won-Ho;Yoon, Dong-Hyun;Hong, Eun-Mi;Kim, Dae-Eui;Svoboda, Mark D.;Tadesse, Tsegaye;Wardlow, Brian D.
    • Journal of The Korean Society of Agricultural Engineers
    • /
    • v.61 no.3
    • /
    • pp.1-14
    • /
    • 2019
  • North Korea has frequently suffered from extreme agricultural crop droughts, which have led to food shortages, according to the Food and Agriculture Organization (FAO). The increasing frequency of extreme droughts, due to global warming and climate change, has increased the importance of enhancing the national capacity for drought management. Historically, a meteorological drought index based on data collected from weather stations has been widely used. But it has limitations in terms of the distribution of weather stations and the spatial pattern of drought impacts. Satellite-based data can be obtained with the same accuracy and at regular intervals, and is useful for long-term change analysis and environmental monitoring and wide area access in time and space. The Evaporative Stress Index (ESI), a satellite-based drought index using the ratio of potential and actual evaporation, is being used to detect drought response as a index of the droughts occurring rapidly over short periods of time. It is more accurate and provides faster analysis of drought conditions compared to the Standardized Precipitation Index (SPI), and the Palmer Drought Severity Index (PDSI). In this study, we analyze drought events during 2015-2017 in North Korea using the ESI satellite-based drought index to determine drought response by comparing with it with the SPI and SPEI drought indices.

Analysis on Vertical Structure of Sea Fog in the West Coast of the Korean Peninsula by Using Drone (드론을 활용한 한반도 서해 연안의 해무 연직구조 분석)

  • Jeon, Hye-Rim;Park, Mi Eun;Lee, Seung Hyeop;Park, Mir;Lee, Yong Hee
    • Atmosphere
    • /
    • v.32 no.4
    • /
    • pp.307-322
    • /
    • 2022
  • A drone has recently got attention as an instrument for weather observation in lower atmosphere because it can produce the high spatiotemporal resolution weather data even though the weather phenomenon is inaccessible. Sea fog is a weather phenomenon occurred in lower atmosphere, and has observational limitations because it occurs on the sea. Therefore, goal of this study is to analyze the vertical structures about inflow, development and dispersion of sea fog using the high-resolution weather data with the meteorological sensor-equipped drone. This study observed sea fogs in the west coast of the Korean peninsula from March to October 2021 and investigated one sea fog inflowed into the coast on June 8th 2021. θe - qv diagrams (θe: equivalent potential temperature, qv: water vapor ratio) and vertical wind structures were analyzed. At inflow of sea fog, moist adiabatically stable layer was formed in 0-300 m and prevailing wind was switched from south-southwesterly to west-southwesterly under 120 m. Both changes are favorable for sea fog on the location. θe and qv plummeted in a layer 0-183 m. The inflowed sea fog developed from 183 m to 327 m by mixing with ambient atmosphere on top of sea fog. Also, strong mechanical turbulence near ground drove a vertical mixing under stable layer. At dispersion of sea fog, as θe on ground gradually increased, air condition was changed to neutral. Evaporation occurred on both bottom and top in sea fog. These results induced dissipation of sea fog.

Energy Harvesting System according to Moisture Absorption of Textile and Efficient Coating Method as a Carbon Black (섬유 고분자의 수분 흡수에 따른 에너지 하베스팅 발전 소자 및 이를 위한 카본 블랙의 효율적인 코팅법)

  • Choi, Seungjin;Chae, Juwon;Lee, Sangoh;Lee, Jaewoong
    • Textile Coloration and Finishing
    • /
    • v.33 no.4
    • /
    • pp.280-287
    • /
    • 2021
  • Generating electricity by using water in many energy harvesting system is due to their simplicity, sustainability and eco-friendliness. Evaporation-driven moist-electric generators (EMEGs) are an emergent technology and show great potential for harvesting clean energy. In this study, we report a transpiration driven electro kinetic power generator (TEPG) that utilize capillary flow of water in an asymmetrically wetted cotton fabric coated with carbon black. When water droplets encounter this textile EMEG, the water flows spontaneously under capillary action without requiring an external power supply. First carbon black sonicated and dispersed well in three different solvent system such as dimethylformamide (DMF), sodiumdedecylbenzenesulfonate (SDBS-anionic surfactant) and cetyltrimethylammoniumbromide (CTAB-cationic surfactant). A knitted cotton/PET fabric was coated with carbon black by conventional pad method. Cotton/PET fabrics were immersed and stuttered well in these three different systems and then transferred to an autoclave at 120 ℃ for 15 minutes. Cotton/PET fabric treated with carbon black dispersed in DMF solvent generated maximum current up to 5 µA on a small piece of sample (2 µL/min of water can induce constant electric output for more than 286 hours). This study is high value for designing of electric generator to harvest clean energy constantly.