• Toxicological Research
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• v.31 no.2
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• pp.157-163
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• 2015

Nanotechnology has advanced at an extremely rapid pace over the past several years in numerous fields of research. However, the uptake of nanoparticles (NPs) into the body after administration through various routes may pose a risk to human health. In this study, we investigated the potential ocular toxicity of 20-nm, negatively- charged zinc oxide (ZnO) NPs in rats using micro-computed tomography (micro-CT) and histopathological assessment. Animals were divided into four groups as control group, ZnO NPs treatment group (500 mg/kg/day), control recovery group, and ZnO NPs treatment and recovery group. Ocular samples were prepared from animals treated for 90 days (10 males and 10 females, respectively) and from recovery animals (5 males and 5 females, respectively) sacrificed at 14 days after final treatment and were compared to age-matched control animals. Micro-CT analyses represented the deposition and distribution of foreign materials in the eyes of rats treated with ZnO NPs, whereas control animals showed no such findings. X-ray fluorescence spectrometry and energy dispersive spectrometry showed the intraocular foreign materials as zinc in treated rats, whereas control animals showed no zinc signal. Histopathological examination revealed the retinopathy in the eyes of rats treated with ZnO NPs. Neuronal nuclei expression was decreased in neurons of the ganglion cell layer of animals treated with ZnO NPs compared to the control group. Taken together, treatment with 20-nm, negatively-charged ZnO NPs increased retinopathy, associated with local distribution of them in ocular lesions.

• Clean Technology
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• v.15 no.3
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• pp.154-164
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• 2009

In 2007, 94% of organic wastewater sludge from industries located in Ulsan was disposed of by ocean dump. The ocean dump of organic sludge would be totally prohibited by the year of 2012. However, there is no alternative but incinerating the sludge from the industries located in Ulsan. Securing the technology for sludge treatment and on-land disposal is very important issue among the industries in the Ulsan Petrochemical Industry Complex. In this study, the material aspects of dried and carbonized sludge as a fuel were evaluated for petrochemical and sewage sludge from Ulsan. The dried and carbonized sludges from the factories producing terephthalic acid, BTX, propylene, chemical textile, etc. of which the low heat value exceeded 3,000 kcal/kg had high potential as a fuel according to the results of thermal characteristic analysis. However, the dried sludges with heat values lower than 2,100 kcal/kg and carbonized sludges, lower than 1,100 kcal/kg containing more Inorganic material from the industries producing pulp, paper, methylamine, amide, etc. had a little potential to be used as a fuel. In most cases, drying the sludge showed better results than carbonization in the aspect of thermal characteristics of sludge.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.9
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• pp.589-596
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• 2016

Recently organic flash cycle (OFC) has been proposed which is a vapor power cycle where heat addition occurs with the working fluid remaining in the liquid state. This study proposes a modified OFC with regeneration and carries out thermodynamic performance analysis of the system utilizing low-temperature heat source in the form of sensible energy. Effects of working fluid and flash temperature are systemically investigated on the system performance such as net power production and thermal efficiency. Results show that the net power production has a peak value with respect to the flash temperature but the thermal efficiency increases with the flash temperature. The regenerative system shows higher thermal efficiency compared to the original OFC and improved potential for recovery of low-temperature heat sources.

• Journal of Korean Society on Water Environment
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• v.36 no.2
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• pp.153-163
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• 2020

Magnetic separation technology is an efficient and environmentally friendly technology. Compared with the traditional wastewater treatment technology, the magnetic separation technology has its unique advantages and characteristics, and has been widely applied in the field of wastewater treatment. In particular, the emergence of superconducting magnetic separation technology makes possible for high application potential and value. In this paper, which through consulting with the literatures of Korea, Chinese, United States and other countries, the magnetic separation technology applied to wastewater treatment was mainly divided into direct application of magnetic field, flocculation, adsorption, catalysis and separation coupling technology. Advantages and limitations of the magnetic separation technology in sewage treatment and its future development were also studied. Currently, magnetic separation technology needs to be studied for additional improvement in processing mechanism, design optimization of magnetic carrier and magnetic separator, and overcoming engineering application lag. The selection, optimization and manufacturing of cheap magnetic beads, highly adsorbed and easily desorbed magnetic beads, specific magnetic beads, nanocomposite magnetic beads and the research of magnetic beads recovery technology will be hot application of the magnetic separation technology based on the magnetic carriers in wastewater treatment. In order to further reduce the investment and operation costs and to promote the application of engineering, it is necessary to strengthen the research and development of high field strength using inexpensive and energy-saving magnet materials, specifically through design and development of new high efficiency magnetic separators/filters, magnetic separators and superconducting magnetic separators.

• Food Science and Industry
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• v.53 no.3
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• pp.284-294
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• 2020

High voltage pulsed electric field technology has been attracting attention in the the food industry as an eco-friendly nonthermal process technology using electrical energy. The lack of understanding of the equipment and the burden of equipment cost have not significantly increased the commercial application, but the potential as a technology to replace the heat process has been continuously increased. Sterilization of foods using the PEF process has been applied to liquid foods with low viscosity such as fruit and vegetable juices, but recently, high viscosity smoothies, high concentrate protein drink, mixed juice, and alcoholic beverages. Studies on sterilization of solid foods such as powders, raw meats are also being conducted. Also, the application of extraction and recovery of useful ingredients, activation of active compounds, pretreatment of drying, improvement of meat quality, changes of properties of starch has been studies.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.10
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• pp.4679-4688
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• 2011

This study was performed to the municipal waste generation amounts and characteristics for B city in Gangwon province, predicted the methane gas generation rate emitted from landfill, and analyzed the possibility of energy recovery to RDF(Refuse Derived Fuel) using combustible waste. The study results showed that the average bulk density of municipal waste for B city was 144.0 kg/$m^3$, and the average ratios of combustible waste were 36.0 % of paper, 21.6 % of vinyl, and 19.7 % of food waste. respectively. In the experiment for heating value, high and low heating value(moisture) was measured to 3,471 $kca{\ell}$/kg and 2,941 $kca{\ell}$/kg, respectively. After the prohibition of burying of food waste in landfill, the heating value of municipal waste was dramatically increased due to increase of the ratio of paper, vinyl, and plastic waste. The prediction results of methane gas generation rate emitted from landfill showed that the gas generation rate is increasing to 2,505.7 CH4 ton/year in 2021. After then, the rate is decreasing gradually. When the RDF facility is installed, the rate is decreasing after peaking at 1,956.9 CH4 ton/year in 2013. The generation rate of LFG emitted from waste landfill of B city was analyzed to 9.92 $m^3$/min, similar to 10.11 $m^3$/min for other city.

• Polymer(Korea)
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• v.31 no.3
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• pp.215-220
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• 2007

The control of the surface energy by electrohydrodynamic force provides electrospraying with various potential advantages such as simple particle size control, mono-dispersity, high recovery, and mild processing conditions. The advantages are quite helpful to improve the stability of protein drug and control its release. Herein, the nano-encapsulation of protein drugs using electrospraying was investigated. Albumin as a model protein was processed using uniaxial and co-axial electrospraying, and chitosan, polycaporlactone (PCL), and poly (ethylene glycol) (PEG) were used as encapsulation materials. The major processing parameters such as the conductivity of spraying liquids, flow rate, the distance of electrical potential gradient, etc were measured to obtain the maximum efficiency. In the chitosan systems, mean particles size decreases as flow rate and the distance between nozzle and the collecting part decreases. In the uniaxial technique of the PCL systems, mean particles size decreases as flow rate decreases. In the coaxial technique of the PCL systems, it was found that the particles size gets larger under the application of the higher ratio of inner-to-outer liquid flow rates. The primary particles formed out of an electrospraying nozzle showed narrow particle size distribution, but once they arrived to the collecting part, aggregation behavior was observed obviously. Efficient nano-encapsulation of albumin with PCL, PEG, and chitosan was conveniently achieved using electrospraying at above 12 kV.

• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.7
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• pp.1074-1081
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• 2021

Nitrous oxide (N₂O) is one of the six major greenhouse gases and is known to produce a greenhouse ef ect by absorbing infrared radiation in the atmosphere. In particular, its global warming potential (GWP) is 310 times higher than that of CO₂, making N₂O a global concern. Accordingly, strong environmental regulations are being proposed. N₂O reduction technology can be classified into concentration recovery, catalytic decomposition, and pyrolysis according to physical methods. This study intends to provide information on temperature conditions and reaction time required to reduce nitrogen oxides with cost. The high-temperature ranges selected for pyrolysis conditions were calculated at intervals of 100 K from 1073 K to 1373 K. Under temperatures of 1073 K and 1173 K, the N₂O reduction rate and nitrogen monoxide concentration were observed to be proportional to the residence time, and for 1273 K, the N₂O reduction rate decreased due to generation of the reverse reaction as the residence time increased. Particularly for 1373 K, the positive and reverse reactions for all residence times reached chemical equilibrium, resulting in a rather reduced reaction progression to N₂O reduction.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.10
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• pp.2786-2793
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• 2009

Recently, the development and spread of the new recyclable energy becomes urgent because of the depletion of fossil fuel and strengthening the environmental regulation. To recovery from the waste out of the many new recyclable energies has been proved as the most favorable when the potential value of energy source is compared. The RDF from the waste has been approved as the most economical method out of the other methods. However, the toxic gases (HCl, Dioxin etc) and heavy metals generated during the burning of the industrial wastes have been pointed out as problems. The PVC, alkali metal chloride, and alkaline earth metal chloride are major materials for emitting the chlorine and chlorine compounds have the problem such as the erosion on the heat collection device. This research has analyzed the heavy metal components containing in the industrial waste, and the concentration of Cl and S in the industrial waste generated in B industrial complex are slightly high than that of the A industrial complex. The results can be used to discuss the origin of inorganic components in industrial waste and utilized as a base data to improve the performance of the RDF as fuel.

• Journal of the Korean Institute of Gas
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• v.17 no.2
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• pp.59-69
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• 2013

This study presents development of the ANN simulator for well placement of infill drilling in gas fields. The input data of the ANN simulator includes the production time, well location, all inter well distances, boundary inter well distance, infill well position, productivity potential, functional links, reservoir pressure. The output data includes the bottomhole pressure in addition to the production rate. Thus, it is possible to calculate the productivity and bottomhole pressure during production period simultaneously, and it is expected that this model could replace conventional simulators. Training for the 20 well placement scenarios was conducted. As a result, it was found that accuracy of ANN simulator was high as the coefficient of correlation for production rate was 0.99 and the bottomhole pressure 0.98 respectively. From the resultes, the validity of the ANN simulator has been verified. The term, which could produce Maximum Daily Quantity (MDQ) at the gas field and the productivity according to the well location was analyzed. As a result, the MDQ could be maintained for a short time in scenario C-1, which has the three infill wells nearby aquifer boundary, and a long time in scenario A-1. In conclusion, it was found that scenario A maintained the MDQ up to 21% more than those of scenarios B and C which include parameters that might affect the productivity. Thus, the production rate can be maximized by selecting the location of production wells in comprehensive consideration of parameters that may affect the productivity. Also, because the developed ANN simulator could calculate both production rate and bottomhole pressure, respectively, it could be used as the forward simulator in a various inverse model.