• Bulletin of the Korean Chemical Society
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• v.32 no.10
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• pp.3696-3701
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• 2011

The single-crystal structure of partially dehydrated partially $Mg^{2+}$-exchanged zeolite Y, ${\mid}Mg{30.5}Na_{14}(H_2O)_{2.5}{\mid}$ [$Si_{117}Al_{75}O_{384}$]-FAU per unit cell, ${\alpha}$ = 25.5060(1) ${\AA}$, dehydrated at 723 K and $1{\times}10^{-4}$ Pa, has been determined by single-crystal X-ray diffraction techniques in the cubic space group Fd$\bar{3}$ m at 100(1) K. The structure was refined using all intensities to the final error indices (using only the 561 reflections with $F_{\circ}$ > $4{\sigma}(F_{\circ})$) $R_1$ = 0.0377 (Based on F) and $R_2$ = 0.1032 (Based on $F^2$). About 30.5 $Mg^{2+}$ ions per unit cell are found at four different crystallographic sites. The 14 $Mg^{2+}$ ions occupy at site I at the center of double 6-ring (Mg-O = 2.231(3) ${\AA}$, O-Mg-O = $89.15(11)^{\circ}$ and $90.85(11)^{\circ}$). Four $Mg^{2+}$ ions are found at site I' in the sodalite cavity; the $Mg^{2+}$ ions are recessed 1.22 ${\AA}$ into the sodalite cavity from their 3-oxygen plane (Mg-O = 2.20(3) ${\AA}$ and O-Mg-O = $92.3(14)^{\circ}$). Site II' positions (opposite single 6-rings in the sodalite cage) are occupied by 2.5 $Mg^{2+}$ ions, each coordinated to an $H_2O$ molecule (Mg-O = 2.187(20) ${\AA}$ and O-Mg-O = $114.2(16)^{\circ}$). The 10 $Mg^{2+}$ ions are nearly three-quarters filled at site II in the supercage, being recessed 0.12 ${\AA}$ into the supercage (Mg-O = 2.123(4) A and O-Mg-O = $119.70(19)^{\circ}$). About 14 $Na^+$ ions per unit cell are found at one crystallographic site; the $Na^+$ ions are located at site II in the supercage (Na-O = 2.234(7) ${\AA}$ and O-Mg-O = $110.5(4)^{\circ}$).

• Bulletin of the Korean Chemical Society
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• v.28 no.1
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• pp.41-48
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• 2007

Large colorless single crystals of sodium zeolite X, stoichiometry |Na80 |[Si112Al80O384]-FAU, with diameters up to 200 μm and Si/Al = 1.41 have been synthesized from gels with the composition of 2.40SiO2 : 2.00NaAlO2 : 7.52NaOH : 454H2O : 5.00TEA. One of these, a colorless octahedron about 200 μm in cross-section has been treated with aqueous 0.1 M KNO3 for the preparation of K+-exchanged zeolite X. The crystal structure of |K80|[Si112Al80O384]-FAU per unit cell, a = 24.838(4) A, dehydrated at 673 K and 1 × 10-6 Torr, has been determined by single-crystal X-ray diffraction techniques in the cubic space group Fd at 294 K. The structure was refined using all intensities to the final error indices (using only the 707 reflections for which Fo > 4σ (Fo)) R1 = 0.075 (based on F) and R2 = 0.236 (based on F2). About 80 K+ ions per unit cell are found at an unusually large number of crystallographically distinct positions, eight. Eleven K+ ions are at the centers of double 6-rings (D6Rs, site I; K-O = 2.492(6) A and O-K-O (octahedral) = 88.45(22)o and 91.55(22)o). Site-I' position (in the sodalite cavities opposite D6Rs) is occupied by five K+ ions per unit cell; these K+ ions are recessed 1.92 A into the sodalite cavities from their 3-oxygen planes (K-O = 2.820(19) A, and O-K-O = 78.6(6)o). Twety-three K+ ions are found at three nonequivalent site II (in the supercage) with occupancies of 5, 9, and 9 ions; these K+ ions are recessed 0.43 A, 0.75 A, and 1.55 A, respectively, into the supercage from the three oxygens to which it is bound (K-O = 2.36(13) A, 2.45(13) A, and 2.710(13) A, O-K-O = 116.5(20)o, 110.1(17)o, and 90.4(6)o, respectively). The remaining sixteen, thirteen, and twelve K+ ions occupy three sites III' near triple 4-rings in the supercage (K-O = 2.64(3) A, 2.94(3) A, 2.73(5) A, 2.96(6) A, 3.06(4) A, and 3.08(3) A).

• Computational Structural Engineering
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• v.10 no.1
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• pp.135-148
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• 1997

The main objective of this paper is to analyze the rectangular stiffened plates with two opposite ends elastically restrained and the others simply supported subjected to in-plane bending by Finite Element Method. Another objective is to develope Classical Method analyzing the unstiffened rectangular plates with the above boundary conditions. In order to validate finite element and classical methods, the buckling strengths of the rectangular plates with four simply supported ends, and with two simply supported and the others fixed ends by finite element method and classical method are compared with those of references. In finite element method, elastically restrained ends can be obtained as considering torsional and warping rigidities of end stiffeners. The buckling strengths of the rectangular plates with elastically restrained ends by finite element and classical methods are calculated and compared with each other. In case of stiffened plates, to validate finite element method, the buckling strengths of the rectangular stiffened plates with four simply supported ends, and with two simply supported and the others fixed ends are also compared with those of references. The buckling strengths of the rectangular stiffened plates with elastically restrained ends by finite element method are calculated as solving eigenvalue problems which are obtained as assembling rectangular plate elements and beam elements considered torsional and warping rigidities. The buckling strengths of rectangular stiffened plates according to various positions of rectangular intermediate stiffener, J and I/sub w/ of end stiffeners are also obtained, which are compared to determine the efficient position of intermediate stiffener.

• Korean journal of applied entomology
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• v.54 no.3
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• pp.159-167
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• 2015

In order to establish B. tabaci control in paprika greenhouses a fixed-precision-level sampling plan was developed. The sampling plan consisted of spatial distribution analysis, a sampling stop line, and decision making. Sampling was conducted simultaneously in two independent greenhouses (GH 1, GH 2). GH 1 and 2 were surveyed every week for 22 consecutive weeks, using 19 sampling locations in GH 1 and 9 sampling locations in GH 2. The plant in both greenhouses were divided into top (180-220 cm from the ground), middle (80-120 cm from the ground) and bottom (30-70 cm from the ground) sections and B. tabaci adults and pupae were observed on three paprika leaves at each position and recorded separately. GH 2 data were used to validate the fixed-precision sampling plan, which was developed using GH 1 data. In this study, spatial distribution analysis was performed using Taylor's power law with the pooled data of the top and bottom position (B. tabaci adults), and the middle and bottom positions (B. tabaci pupae), based on a 1-leaf sampling unit. Decision making was undertaken using the maximum of action threshold in accordance with previously published method, and the value was decided by the price of the plants. Using the results obtained in the greenhouse, simulated validation of the developed sampling plan by RVSP (Resampling Validation for Sampling Plan) indicated a reasonable level of precision.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.31 no.3D
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• pp.433-439
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• 2011

The frost depth(frost penetration) is used to install anti-frost heave layers in pavement designs. The freezing index is calculated by an annual accumulated value of multiplying the period of time with temperatures below zero, and the corresponding temperature. Therefore, the DAAT(daily average air temperature) calculation method may play an effect on the FI(freezing index). The Weather Observatory used to supply 4 average air temperatures per day, but currently supplies 8 per day. With this study, we divided the southern part(below FI=$350^{\circ}C{\cdot}day$) of the Korean peninsula into 6 areas according to site conditions(low embankment, embankment-cutting slope, and the cutting slope) and established a field measurement system for 15 positions to check the effects on the result of FI according to differing DAAT calculation methods. The air temperatures obtained by the field measurement system was used to calculate and compare the FI. As a result, the freezing index calculated based on the $DAAT_4(T_4)$ is normally greater by 3% than the one on $DAAT_8(T_8)$. In addition, the calibration equation for the freezing index using air temperatures was proposed through the research.

• Advanced Composite Materials
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• v.17 no.1
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• pp.25-40
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• 2008

The research and development in soundproof materials for preventing noise have attracted great attention due to their social impact. Noise insulation materials are especially important in the field of soundproofing. Since the insulation ability of most materials follows a mass rule, the heavy weight materials like concrete, lead and steel board are mainly used in the current noise insulation materials. To overcome some weak points in these materials, fiber reinforced composite materials with lightweight and other high performance characteristics are now being used. In this paper, innovative insulation sheet materials with carbon and/or glass fabrics and nano-silica hybrid PU resin are developed. The parameters related to sound performance, such as materials and fabric texture in base fabric, hybrid method of resin, size of silica particle and so on, are investigated. At the same time, the wave analysis code (PZFlex) is used to simulate some of experimental results. As a result, it is found that both bundle density and fabric texture in the base fabrics play an important role on the soundproof performance. Compared with the effect of base fabrics, the transmission loss in sheet materials increased more than 10 dB even though the thickness of the sample was only about 0.7 mm. The results show different values of transmission loss factor when the diameters of silica particles in coating materials changed. It is understood that the effect of the soundproof performance is different due to the change of hybrid method and the size of silica particles. Fillers occupying appropriate positions and with optimum size may achieve a better effect in soundproof performance. The effect of the particle content on the soundproof performance is confirmed, but there is a limit for the addition of the fillers. The optimization of silica content for the improvement of the sound insulation effect is important. It is observed that nano-particles will have better effect on the high soundproof performance. The sound insulation effect has been understood through a comparison between the experimental and analytical results. It is confirmed that the time-domain finite wave analysis (PZFlex) is effective for the prediction and design of soundproof performance materials. Both experimental and analytical results indicate that the developed materials have advantages in lightweight, flexibility, other mechanical properties and excellent soundproof performance.

• Composites Research
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• v.33 no.4
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• pp.228-233
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• 2020

In this paper, a single lap shear test was performed using a glass fiber reinforced composite material (GFRC). Pencil lead drawn paper sensor (PLDPS) was applied for single lap shear test being performed. Bisphenol-A epoxy and amine hardener were used as adhesives combining with composite materials. To make a difference in adhesive properties, the adhesive was cured under different conditions. PLDPS was made of a 4B pencil on A4 paper. Because graphite in a pencil was an electrically conductive substance, electric resistance (ER) could be measured. A change in ER was observed by a position where a PLDPS was attached to single lap shear specimens. It was confirmed that the change in ER was different depending on two attached positions and was observed by lap shear strain as well. In case the lap shear strain was large, the change in ER of PLDPS was high. This was because the larger the extension of the adhesive part, the larger the degree of bending of the specimen and thus the larger the distance change between two electrodes.

• Journal of Advanced Marine Engineering and Technology
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• v.40 no.9
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• pp.836-841
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• 2016

An indoor positioning system using Wi-Fi is essential to produce a radio map that combines the indoor space of two or more dimensions, the information of node positions, and etc. in processing for constructing the radio map, the measurement of the received signal strength indicator(RSSI) and the confirmation of node placement information counsume substantial time. Especially, when the installed wireless environment is changed or a new space is created, easy installation of the node and fast indoor radio mapping are needed to provide indoor location-based services. In this paper, to reduce the time consumption, we propose an algorithm to distinguish the straight and curve lines of a corridor section by RSSI visualization and Sobel filter-based edge detection that enable accurate node deployment and space analysis using cable-type Wi-Fi node installed at a 3 m interval. Because the cable type Wi-Fi is connected by a same power line, it has an advantage that the installation order of nodes at regular intervals could be confirmed accurately. To be able to analyze specific sections in space based on this advantage, the distribution of the signal was confirmed and analyzed by Sobel filter based edge detection and total RSSI distribution(TRD) computation through a visualization process based on the measured RSSI. As a result to compare the raw data with the performance of the proposed algorithm, the signal intensity of proposed algorithm is improved by 13.73 % in the curve section. Besides, the characteristics of the straight and the curve line were enhanced as the signal intensity of the straight line decreased by an average of 34.16 %.

• Progress in Medical Physics
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• v.24 no.4
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• pp.290-294
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• 2013

Stereotactic Radiosurgery require high accuracy and precision of patient positioning and target localization. We evaluate the real time positioning accuracy of isocenter using optic guided patient positioning system, ExacTrac (BrainLab, Germany), during spinal radiosurgery procedure. The system is based on real time detect multiple body markers attached on the selected patient skin landmarks. And a custom designed patient positioning verification tool (PPVT) was used to check the patient alignment and correct the patient repositioning before radiosurgery. In this study, We investigate the selected 8 metastatic spinal tumor cases. All type of tumors commonly closed to thoracic spinal code. To evaluate the isocenter positioning, real time patient alignment and positioning monitoring was carried out for comparing the current 3-dimensional position of markers with those of an initial reference positions. For a selected patient case, we have check the isocenter positioning per every 20 millisecond for 45 seconds during spinal radiosurgery. In this study, real time average isocenter positioning translation were $0.07{\pm}0.17$ mm, $0.11{\pm}0.18$ mm, $0.13{\pm}0.26$ mm, and $0.20{\pm}0.37$ mm in the x (lateral), y (longitudinal), z (vertical) directions and mean spatial error, respectively. And body rotations were $0.14{\pm}0.07^{\circ}$, $0.11{\pm}0.07^{\circ}$, $0.03{\pm}0.04^{\circ}$ in longitudinal, lateral, table directions and mean body rotation $0.20{\pm}0.11^{\circ}$, respectively. In this study, the maximum mean deviation of real time isocenter positioning translation during spinal radiosurgery was acceptable accuracy clinically.

• Investigative Magnetic Resonance Imaging
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• v.17 no.3
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• pp.169-180
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• 2013

Purpose : The purpose of this study was to setup a concuurent transcranial magnetic stimulation (TMS)-functional MRI (fMRI) system for understanding causality of the functional brain network. Materials and Methods: We manufactured a TMS coil holder using nonmagnetic polyether ether ketone (PEEK). We simulated magnetic field distributions in the MR scanner according to TMS coil positions and angles. To minimize image distortions caused by TMS application, we controlled fMRI acquisition and TMS sequences to trigger TMS during inter-volume intervals. Results: Simulation showed that the magnetic field below the center of the coil was dramatically decreased with distance. Through the MR phantom study, we confirmed that TMS application around inter-volume acquisition time = 100 miliseconds reduced imaging distortion. Finally, the applicability of the concurrent TMS-fMRI was tested in preliminary studies with a healthy subject conducting a motor task within TMS-fMRI and passive motor movement induced by TMS in fMRI. Conclusion: In this study, we confirmed that the developed system allows use of TMS inside an fMRI system, which would contribute to the research of brain activation changes and causality in brain connectivity.