• Title/Summary/Keyword: porous hydrophobic ceramic

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Effect of Water Volume and Relaxation Time in the Design of Nano Shock Absorbing Damper Using Silica Particle (실리카 분말을 이용한 나노 충격완화 장치의 설계에서 작동 유체 영향과 복원 시간에 대한 연구)

  • 문병영;김병수
    • Journal of the Korean Ceramic Society
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    • v.40 no.3
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    • pp.286-292
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    • 2003
  • In this study, new shock absorbing system was proposed using silica gel particles according to the nano-technology. For the design and real application of the proposed damper, an experimental investigations are carried out using colloidal damper, which is statically loaded. The porous matrix is composed from silica gel(labyrinth architecture), coated by organo-silicones substances, in order to achieve a hydrophobic surface. Water is considered as associated lyophobic liquid. Reversible colloidal damper static test rig and the measuring technique of the static hysteresis were described. Iufluence of the water volume and particle diameters upon the reversible colloidal damper hysteresis was investigated. Also, influence of the relaxation time on the hysteresis of the damper was investigated. As a result, the proposed new shock absorbing damper is proved as an effective one, which can be replaced for the conventional hydraulic damper.

Effect of Hydrophobizing Method on Corrosion Resistance of Magnesium Alloy with Plasma Electrolytic Oxidation (소수성 처리 방법에 따른 플라즈마 전해 산화 처리된 마그네슘 합금의 내식성)

  • Joo, Jaehoon;Kim, Donghyun;Jeong, Chanyoung;Lee, Junghoon
    • Journal of the Korean institute of surface engineering
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    • v.52 no.2
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    • pp.96-102
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    • 2019
  • Magnesium and its alloys are prone to be corroded, thus surface treatments improving corrosion resistance are always required for practical applications. As a surface treatment of magnesium alloys, plasma electrolytic oxidation (PEO), creating porous stable oxide layer by a high voltage discharge in electrolyte, enhances the corrosion resistance. However, due to superhydrophilicity of the porous oxide layer, which easily allow the penetration of corrosive media toward magnesium alloys substrate, post-treatments inhibiting the transfer of corrosive media in porous oxide layer are required. In this work, we employed a hydrophobizing method to enhance the corrosion resistance of PEO treated Mg alloy. Three types of hydrophobizing techniques were used for PEO layer. Thin Teflon coating with solvent evaporation, self-assembled monolayer (SAM) coating of octadecyltrichlorosilane (OTS) based on solution method and SAM coating of perfluorodecyltrichlorosilane (FDTS) based on vacuum method significantly enhances corrosion resistance of PEO treated Mg alloy with reducing the contact of water on the surface. In particular, the vacuum based FDTS coating on PEO layer shows the most effective hydrophobicity with the highest corrosion resistance.

Development of Ceramic Hollow Fiber Membrane Contactor Modules for Carbon Dioxide Separation (이산화탄소 분리용 세라믹 중공사 접촉막 모듈 기술 개발)

  • Lee, Hong Joo;Che, Jin Woong;Park, Jung Hoon
    • Journal of Climate Change Research
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    • v.7 no.3
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    • pp.249-256
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    • 2016
  • Porous $Al_2O_3$ hollow fiber membranes were successfully prepared by dry-wet spinning/sintering method. The SEM image shows that the $Al_2O_3$ hollow fiber membrane consists mostly of sponge pore structure. The contact angle and the breakthrough pressure were $126^{\circ}$ and 1.91 bar, respectively. This results indicate that the $Al_2O_3$ hollow fiber membranes were successfully modified to hydrophobic surface. The hydrophobic modified $Al_2O_3$ hollow fiber membranes were assembled into a membrane contactor system to separate $CO_2$ from a model gas mixture of the flue gas at elevated gas velocity. The $CO_2$ absorption flux was enhanced when the gas velocity increased from $1{\times}10^{-3}$ to $6{\times}10^{-3}$ m/s. Whereas the $CO_2$ absorption flux was decreased with the number of hollow fiber membrane of a module because of the concentration polarization. Furthermore, we developed an lab-scale $Al_2O_3$ hollow fiber membrane contactor modules and their system (i.e., $CO_2$ absorption using the $Al_2O_3$ membrane and monoethanolamine (MEA)) that could dispose of over $0.02Nm^3/h$ mixture gas (15% $CO_2$) with the removal efficiency higher than 95%. The results can be useful in a field of the membrane contactor for $CO_2$ separation, helping to design and extend a equipment.

Enhancement of Condensation Heat Transfer of Anodized Aluminum by Teflon Coating and Oil-Impregnation (테플론 코팅과 오일 담지를 이용한 알루미늄 양극산화피막의 응축 열전달 향상)

  • Kang, Minjoo;Lee, Jonghoon;Cha, Soojin;Shin, Yeaji;Kim, Donghyun;Kim, Kyung-Ja;Lee, Junghoon
    • Journal of the Korean institute of surface engineering
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    • v.54 no.2
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    • pp.90-95
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    • 2021
  • Surface modification technique enabling the control of condensation provides various benefit in various engineering systems, such as heat transfer, desalination, power plants, and so on. In this study, lubricant oil-impregnation into Teflon-coated nanoporous anodic oxide layer of aluminum to enhance a de-wetting and mobility of water droplet on surface. Due to the surface treatment improving water-repellency, the condensation mode is changed to dropwise, thus the frequency of sliding condensed water droplet on surface is increased. For these reasons, the surface of oil-impregnated Teflon-coated nanoporous anodic aluminum oxide shows significantly enhanced condensation heat transfer compared to bare aluminum surface. In addition, the porosity of anodic aluminum oxide affected the mobility of water droplet even with oil-impregnation and Teflon-coating, indicating that the optimization of porous structure of anodic oxide is required for maximizing the condensation heat transfer.

Decolorization of Azo Dyeing Wastewater Using Underwater Dielectric Barrier Discharge Plasma (수중 유전체장벽방전 플라즈마를 이용한 아조 염색폐수 색도제거)

  • Jo, Jin Oh;Lee, Sang Baek;Mok, Young Sun
    • Applied Chemistry for Engineering
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    • v.24 no.5
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    • pp.544-550
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    • 2013
  • This work investigated the environmental application of an underwater dielectric barrier discharge plasma reactor consisting of a porous hydrophobic ceramic tube to the decolorization of an azo dyeing wastewater. The reactive species generated by the plasma are mostly short-lived, which also need to be transferred to the wastewater right after the formation. Moreover, the gas-liquid interfacial area should be as large as possible to increase the decolorization rate. The arrangement of the present wastewater treatment system capable of immediately dispersing the plasmatic gas as tiny bubbles makes it possible to effectively decolorize the dyeing wastewater alongside consuming less amount of electrical energy. The effect of discharge power, gas flow rate, dissolved anion and initial dye concentration on the decolorization was examined with dry air for the creation of plasma and amaranth as an azo dye. At a gas flow rate of $1.5Lmin^{-1}$, the good contact between the plasmatic gas and the wastewater was achieved, resulting in rapid decolorization. For an initial dye concentration of $40.2{\mu}molL^{-1}$ (volume : 0.8 L; discharge power : 3.37 W), it took about 25 min to attain a decolorization efficiency of above 99%. Besides, the decolorization rate increased with decreasing the initial dye concentration or increasing the discharge power. The presence of chlorine anion appeared to slightly enhance the decolorization rate, whereas the effect of dissolved nitrate anion was negligible.