• Title/Summary/Keyword: porous foam

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Effect of Process Conditions on the Microstructure of Particle-Stabilized Al2O3 Foam

  • Ahmad, Rizwan;Ha, Jang-Hoon;Hahn, Yoo-Dong;Song, In-Hyuck
    • Journal of Powder Materials
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    • v.19 no.4
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    • pp.278-284
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    • 2012
  • $Al_2O_3$ foam is an important engineering material because of its exceptional high-temperature stability, low thermal conductivity, good wear resistance, and stability in hostile chemical environment. In this work, $Al_2O_3$ foams were designed to control the microstructure, porosity, and cell size by varying different parameters such as the amount of amphiphile, solid loading, and stirring speed. Particle stabilized direct foaming technique was used and the $Al_2O_3$ particles were partially hydrophobized upon the adsorption of valeric acid on particles surface. The foam stability was drastically improved when these particles were irreversibly adsorbed at the air/water interface. However, there is still considerable ambiguity with regard to the effect of process parameters on the microstructure of particle-stabilized foam. In this study, the $Al_2O_3$ foam with open and closed-cell structure, cell size ranging from $20{\mu}m$ to $300{\mu}m$ having single strut wall and porosity from 75% to 93% were successfully fabricated by sintering at $1600^{\circ}C$ for 2 h in air.

Hydrogen Production with High Temperature Solar Heat Thermochemical Cycle using CeO2/ZrO2 Foam Device (CeO2/ZrO2 Foam Device를 이용한 고온 태양열 열화학 싸이클의 수소 생산)

  • Lee, Jin-Gyu;Seo, Tae-Beom
    • Journal of the Korean Solar Energy Society
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    • v.34 no.6
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    • pp.11-18
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    • 2014
  • Two-step water splitting thermochemical cycle with $CeO_2$ foam device was investigated by using a solar simulator composed of 2.5 kW Xe-Arc lamp and mirror reflector. The hydrogen production of $CeO_2$ foam device depending on reaction temperature of Thermal-Reduction step and Water-Decomposition step was analyzed, and the hydrogen production of $CeO_2$ and $NiFe_2O_4/ZrO_2$ foam devices was compared. As a result, the amount of reduced $CeO_2$ considerably varies according to the reaction temperature of Thermal-Reduction step. and hydrogen production was not much when the amount of reduced $CeO_2$ decreased even if the reaction temperature of Water-Decomposition step was high. Therefore, it is very important to keep the reaction temperature of Thermal-Reduction step high in two-step thermochemical cycle with $CeO_2$.

Supercapacitive Properties of Co-Ni Mixed Oxide Electrode Adopting the Nickel Foam as a Current Collector

  • Cho, Hyeon Woo;Nam, Ji Hyun;Park, Jeong Ho;Kim, Kwang Man;Ko, Jang Myoun
    • Bulletin of the Korean Chemical Society
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    • v.33 no.12
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    • pp.3993-3997
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    • 2012
  • Three-dimensional porous nickel foam was used as a current collector to prepare a Co-Ni oxide/Ni foam electrode for a supercapacitor. The synthesized Co-Ni oxide was proven to consist of mixed oxide phases of $Co_3O_4$ and NiO. The Co-Ni oxide/Ni foam electrode prepared was characterized by morphological observation, crystalline property analysis, cyclic voltammetry, and impedance spectroscopy. Cyclic voltammetry for the electrode showed high specific capacitances, such as 936 F $g^{-1}$ at 5 mV $s^{-1}$ and 566 F $g^{-1}$ at 200 mV $s^{-1}$, and a comparatively good cycle performance. These improved results were mainly due to the dimensional stability of the nickel foam and its high electrical contact between the electrode material and the current collector substrate.

Numerical Study on Flow Distribution in PEMFC with Metal foam Bipolar Plate (다공성 분리판을 적용한 고분자 전해질 연료전지의 유동 분포에 관한 전산해석 연구)

  • SONG, MYEONGHO;KIM, KYOUNGYOUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.1
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    • pp.29-35
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    • 2016
  • It is important to uniformly supply the fuel gas into the reaction activity area in polymer electrolyte membrane fuel cell (PEMFC). Recent studies have shown that the cell performance can be significantly improved by employing metal foam gas distributor as compared with the conventional bipolar plate types. The metal foam gas distributor has been reported to be more efficient to fuel transport. In this study, three-dimensional computational fluid dynamics (CFD) simulations have been performed to examine the effects of metal foam flow field design on the fuel supply to the reaction site. Darcy's law is used for the flow in the porous media. By solving additional advection equation for fluid particle trajectory, the gas transport has been visualized and examined for various geometrical configuration of metal foam gas distributor.

Combustion of Al-Ni Precursor Al3Ni Foam Manufacture of Composite Structure with Hollow Pipe and Filling of Foam and Investigation of Pore Condition (Al-Ni 전구체의 연소합성 발포에 의한 Al3Ni 폼과 할로우 파이프의 복합구조체 제작 및 폼의 충진성과 기공상태 조사)

  • Han, Chang-Suk;Jin, Sung-Yooun;Kwon, Hyuk-Ku
    • Korean Journal of Materials Research
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    • v.29 no.10
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    • pp.617-622
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    • 2019
  • In order to develop a process for manufacturing a composite structure of an intermetallic compound foam and a hollow material, the firing and pore form of the Al-Ni precursor in a steel pipe are investigated. When the Al-Ni precursor is foamed in a hollow pipe, if the temperature distribution inside the precursor is uneven, the pore shape distribution becomes uneven. In free foaming, no anisotropy is observed in the foaming direction and the pore shape is isotropic. However, in the hollow pipe, the pipe expands in the pipe axis direction and fills the pipe. The interfacial adhesion between $Al_3Ni$ foam and steel pipe is excellent, and interfacial pore and reaction layer are not observed by SEM. In free foaming, the porosity is 90 %, but it decreases to about 80 % in the foam in the pipe. In the pipe foaming, most of the pore shape appears elongated in the pipe direction in the vicinity of the pipe, and this tendency is more remarkable when the inside pipe diameter is small. It can be seen that the pore size of the foam sample in the pipe is larger than that of free foam, because coarse pores remain after solidification of the foam because the shape of the foam is supported by the pipe. The vertical/horizontal length ratio expands along the pipe axis direction by foaming in the pipe, and therefore circularity is reduced.

Porous Materials from Waste Bottle Glasses by Hydrothermal Treatment (수열처리에 의한 폐병유리의 다공질 재료화)

  • Lim, Dong-Kyu;Kang, Eun-Tae
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.275-281
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    • 2009
  • Porous materials were manufactured by hydrothermal treatment of waste bottle glass without foam agent. Factorial design was applied to analyze data by statistical methods and deal with the important factors for a process. The largest effect for porosity was for temperature of hydrothermal treatment. Amount of water and temperature-water interaction appeared to have little effect. The particle size of raw material was also identified as a major factor by one-way ANOVA and the porosity decreased as the size increased. The sintering temperature was not statistically significant for the porosity but was significant for the pore size. The porous material had compressive strength and thermal conductivity comparing with those of ALC (autoclaved lightweight concrete), although it has higher porosity than for ALC.

Experimental Study on the Partial Oxidation Reforming of CH4/O2 Mixture in Two-Section Porous Media (CH4/O2 혼합기의 2단 다공체 내 부분산화 개질에 관한 실험적 연구)

  • Guahk, Young Tae;Lee, Dae Keun;Ko, Chang-Bog
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.249-251
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    • 2014
  • Synthesis gas such as hydrogen and carbon monoxide was produced from $CH_4//oxygen$ mixture using two-section porous media combustor. Heat recirculation through the inner foam structure could extend the flow velocity of stable region over the laminar burning velocity. $H_2/CO$ ratio and module M from concentration of flue gas measured by Gas Chromatography was similar to those calculated by equilibrium. But it was made sure that the heat loss effect becomes more influential than heat recirculation effect as the mixture gets richer. To generate synthesis gas appropriate for methanol production, insulated pressurized porous media combustor will be designed and built in the future.

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Evaluation of Mechanical Properties of Highly Porous Titanium Considering its Application as a Biomaterial

  • Schiefer, Herwig;Bram, Martin;Buchkremer, Hans Peter;Stover, Detlev
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.309-310
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    • 2006
  • Porous titanium implants can be produced by powder metallurgy in combination with suitable space holder materials. Various mechanical experiments were done to characterize this material regarding the influence of the processing parameters on microstructure and mechanical properties taking into account the properties of the human bone. In this paper, the anistropic behaviour of uniaxially compacted samples was analysed in compression tests and compared to the behaviour of isostatically pressed samples. The failure of the struts of the porous titanium and the crack- initiation and -growth was examined by in-situ SEM analysis.

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Effect of Nickel Foam Current Collector on the Supercapacitive Properties of Cobalt Oxide Electrode (코발트 산화물 전극의 수퍼커페시터 성질에 미치는 니켈 폼 집전체 효과)

  • Yoon, Yu-Il;Kim, Kwang-Man;Ko, Jang-Myoun
    • Journal of the Korean Ceramic Society
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    • v.45 no.6
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    • pp.368-373
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    • 2008
  • An electrode for supercapacitor using 3-dimensional porous nickel foam as a current collector and cobalt oxide as an active material was prepared and characterized in terms of morphology observation, crystalline property analysis, and the investigation of electrochemical property. The electrode surface showed that the cobalt oxide was homogeneously coated as the crystalline phase of $Co_3O_4$. Cyclic voltammetry for the $Co_3O_4$/nickel foam electrode exhibited higher specific capacitance values (445 F/g at 10 mV/s and 350 F/g at 200 mV/s) and excellent capacitance retention ratio (99% after $10^4$ cycles). It was proved that the nickel foam substrate played the roles in reducing the interfacial resistance with cobalt oxide and in improving the electrode density by embedding greater amount of cobalt oxide within it.

Characteristics of Micro-pore Structure of Foam Composite using Palm-based Activated Carbon (야자계 활성탄을 활용한 폼 복합체의 미세기공 구조특성)

  • Choi, Young-Cheol;Yoo, Sung-Won
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.5
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    • pp.157-164
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    • 2021
  • Recently, a number of studies have been conducted on photocatalysts and adsorbents that can remove harmful substances to improve environmental problems related to fine particles. In this study, a porous foam composites were fabricated using palm-based activated carbon having a large amount of micro-pores and foam concrete with a significantly larger total pore volume compared to general construction materials. To evaluate the adsorption potential of fine particles, the pore structure of the foam composites were analyzed. For the analysis of the pore structure of the foam composite, BET and Harkins-jura theory were applied from the measured nitrogen adsorption isotherm. From the results of the analysis, the specific surface area and micro-pore volume of the foam composite containing activated carbon increased significantly compared to Plain. As thereplacement of activated carbon increased, the specific surface area and micro-pore volume of the foam composite tended to increase. It seems that the foam composite has high adsorption performance for gaseous fine particle precursor such as nitrogen oxides.