• Title/Summary/Keyword: porous cell structure

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Investigation of Anti-Reflection Coatings for Crystalline Si Solar Cells (결정질 실리콘 태양전지에 적용되는 반사방지막에 관한 연구)

  • Lee, Jae-Doo;Kim, Min-Jeong;Lee, Soo-Hong
    • 한국태양에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.367-370
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    • 2009
  • It is important to reduce a reflection of light as a solar cell is device that directly converts the energy of solar radiation to electrical energy in oder to improve efficiency of solar cells. The antireflection coating has proven effective in providing substantial increase in solar cell efficiency. This paper investigates the formation of thin film PSi(porous silicon) layer on the surface of crystalline silicon substrates without other ARC(antirefiection coating) layers. On the other hand the formation of $SO_{2}/SiN_x$ ARC layers on the surface of crystalline silicon substrates. After that, the structure of PSi and $SO_2/SiN_x$ ARC was investigated by SEM and reflectance. The formation of PSi layer and $SO_{2}/SiN_x$ ARC layers on the textured silicon wafer result about 5% in the wavelength region from 0.4 to $1.0{\mu}m$. It is achieved on the textured crystalline silicon solar cell that each efficiency is 14.43%, 16.01%.

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Effect of the Holding Temperature and Vacuum Pressure for the Open Cell Mg Alloy Foams

  • Yue, Xue-Zheng;Hur, Bo-Young
    • Korean Journal of Materials Research
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    • v.22 no.6
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    • pp.309-315
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    • 2012
  • Metal foam has many excellent properties, such as light weight, incombustibility, good thermal insulation, sound absorption, energy absorption, and environmental friendliness. It has two types of macrostructure, a closed-cell foam with sealed pores and an open-cell foam with open pores. The open-cell foam has a complex macrostructure consisting of an interconnected network. It can be exploited as a degradable biomaterial and a heat exchanger material. In this paper, open cell Mg alloy foams have been produced by infiltrating molten Mg alloy into porous pre-forms, where granules facilitate porous material. The granules have suitable strength and excellent thermal stability. They are also inexpensive and easily move out from open-cell foamed Mg-Al alloy materials. When the melt casting process used an inert gas, the molten magnesium igniting is resolved easily. The effects of the preheating temperature of the filler particle mould, negative pressure, and granule size on the fluidity of the open cell Mg alloy foam were investigated. With the increased infiltration pressure, preheat temperature and granule sizes during casting process, the molten AZ31 alloy was high fluidity. The optimum casting temperature, preheating temperature of the filler particle mould, and negative pressure were $750^{\circ}C$, $400-500^{\circ}C$, and 5000-6000 Pa, respectively, At these conditions the AZ31 alloy had good fluidity and castability with the longest infiltration length, fewer defects, and a uniform pore structure.

Fabrication of Nanowellstructured and Nanonetstructured Metal Films using Anodic Porous Alumina Film (다공성 알루미나 박막을 이용한 금속 나노우물과 나노그물 구조의 박막 제작)

  • Noh, Ji-Seok;Chin, Won-Bai
    • Journal of the Korean Vacuum Society
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    • v.15 no.5
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    • pp.518-526
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    • 2006
  • Nanoporous alumina film was fabricated by anodization of an aluminum sheet. Highly ordered nanowellstructured and nanonets-tructured metal films were fabricated by vacuum evaporation of several metals(Al, Sn, and Co) using the anodic nanoporous alumina film as a template. In this experiment, an anodic porous alumina film with the cell size of 100 nm and the pore diameter of 60 nm was used. The resistance heating method was adopted for evaporating a desired metal, and vapor deposition was carried out under the base pressure of torr. It was founded that whether the structure fabricated by vacuum evaporation is nanowell or nanonet is dependent on the amount of deposited material. When an anodic porous alumina film with the cell size of 100 nm and the pore diameter of 60 nm was used, a nanowell-structured film was fabricated when a sufficient amount of metal was suppled to cover the surface pores. On the other hand, nanonet-structured film was fabricated bellow a half the amount of metal required for nanowell-structured film.

Cross-linkable and water-soluble phospholipid polymer as artificial extracellular matrix

  • Maeta, Eri;Ishihara, Kazuhiko
    • Biomaterials and Biomechanics in Bioengineering
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    • v.1 no.3
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    • pp.163-174
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    • 2014
  • The objective of this study is to prepare an artificial extracellular matrix (ECM) for cell culture by using polymer hydrogels. The polymer used is a cytocompatible water-soluble phospholipid polymer: poly[2-methacryloyloxyethyl phosphorylcholine (MPC)-n-butyl methacrylate-p-nitrophenyloxycarbonyl poly(ethylene oxide) methacrylate (MEONP)] (PMBN). The hydrogels are prepared using a cross-linking reaction between PMBN and diamine compounds, which can easily react to the MEONP moiety under mild conditions. The most favorable diamine is the bis(3-aminopropyl) poly(ethylene oxide) (APEO). The effects of cross-linking density and the chemical structure of cross-linking molecules on the mechanical properties of the hydrogel are evaluated. The storage modulus of the hydrogel is tailored by tuning the PMBN concentration and the MEONP/amino group ratio. The porous structure of the hydrogel networks depends not only on these parameters but also on the reaction temperature. We prepare a hydrogel with $40-50{\mu}m$ diameter pores and more than 90 wt% swelling. The permeation of proteins through the hydrogel increases dramatically with an increase in pore size. To induce cell adhesion, the cell-attaching oligopeptide, RGDS, is immobilized onto the hydrogel using MEONP residue. Bovine pulmonary artery endothelial cells (BPAECs) are cultured on the hydrogel matrix and are able to migrate into the artificial matrix. Hence, the RGDS-modified PMBN hydrogel matrix with cross-linked APEO functions as an artificial ECM for growing cells for applications in tissue engineering.

The study of electrochemi-luminescence device fabrication (전기화학형 발광소자의 제작에 관한 연구)

  • Kwon, Hyuk-Moon;Kwak, Dong-Joo;Sung, Youl-Moon;Song, Jae-Eun
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1326_1327
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    • 2009
  • In this study, used simplest sandwich cells containing $Ru2^+$ liquid electrolytes in order to clarify the role of nanoporous $TiO_2$ electrodes. And, the cell structure is as follow: F:$SnO_2$ glass/nanoporous $TiO_2$/ tris(2,2'-bipyridy)ruthenium(II) colplex [$Ru(bpy)_3(PF_6)_2$] in acetonitrile/ F:$SnO_2$ glass. The result, we found that ECL intensities increased rapidly by use of cathodes with nanoporous $TiO_2$ layers. And, porous $TiO_2$ electrodes were confirmed to be efficient for ECL devices as well as solar cell devices. It is thought that the increases in the ECL intensities may be associated with both formation of $Ru^+$ in porous $TiO_2$ electrodes and the process taking place after reduction of $Ru^+$ which occurs in the nanoporous electrodes.

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Prediction of Permeability for Braided Preform (브레이드 프리폼의 투과율 계수 예측)

  • Youngseok Song;Youn, Jae-Roun
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.04a
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    • pp.184-187
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    • 2003
  • Complete prediction of second order permeability tensor for three dimensional circular braided preform is critical to understand the resin transfer molding process of composites. The permeability can be predicted by considering resin flow through the multi-axial fiber structure. In this study, permeability tensor for a 3-D circular braided preform is calculated by solving a boundary problem of a periodic unit cell. Flow field through the unit cell is obtained by using a 3-D finite volume method (FVM) and Darcy's law is utilized to obtain permeability tensor. Flow analysis for two cases that a fiber tow is regarded as impermeable solid and permeable porous medium is carried out respectively. It is found that the flow within the intra-tow region of the braided preform is negligible if inter-tow porosity is relatively high but the flow through the tow must be considered when the porosity is low. To avoid checkerboard pressure field and improve the efficiency of numerical computation, a new interpolation function for velocity variation is proposed on the basis of analytic solutions. Permeability of the braided preform is measured through a radial flow experiment and compared with the permeability predicted numerically.

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Fabrication of Biodegradable Disc-shaped Microparticles with Micropattern using a Hot Embossing Process with Porous Microparticles

  • Hwang, Ji-Yea;Choy, Young-Bin;Seo, Soon-Min;Park, Jung-Hwan
    • Journal of Pharmaceutical Investigation
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    • v.41 no.3
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    • pp.147-151
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    • 2011
  • This paper demonstrates the development of a method for preparing micropatterned microdiscs in order to increase contact area with cells and to change the release pattern of drugs. The microdiscs were manufactured with hot embossing, where a polyurethane master structure was pressed onto both solid and porous microparticles made of polylactic-co-glycolic acid at various temperatures to form a micropattern on the microdiscs. Flat microdiscs were formed by hot embossing of porous microparticles; the porosity allowed space for flattening of the microdiscs. Three types of micro-grooves were patterned onto the flat microdiscs using prepared micropatterned molds: (1) 10 ${\mu}M$ deep, 5 ${\mu}M$ wide, and spaced 2 ${\mu}M$ apart; (2) 10 ${\mu}M$ deep, 9 ${\mu}M$ wide, and spaced 5 ${\mu}M$ apart; and (3) 10 ${\mu}M$ deep, 50 ${\mu}M$ wide, and spaced 50 ${\mu}M$ apart. This novel microdisc preparation method using hot embossing to create micropatterns on flattened porous microparticles provides the opportunity for low-cost, rapid manufacture of microdiscs that can be used to control cell adhesion and drug delivery rates.

Effects by the binder in manufacturing titanium dioxide film for dye sensitized solar cell (염료감응형 태양전지의 이산화티타늄막 제조시 바인더에 따른 영향)

  • Lee, Hyeon-Seok;Gwon, Jeong-Yeol;Kim, Seong-Jun;Park, Jung-Cheul;Lee, Heon-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.230-231
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    • 2006
  • In this paper, we examined effects by the binder in manufacturing titanium dioxide film for dye sensitized solar cell. Binder(PEG and PEO) was added the amount of 10-40wt% to commercial $TiO_2$ (P25), Respectively. All of $TiO_2$ film was showed porous structure owing to the addition of binders. But the difference of film's porosity could not be confirmed. The transmittance of $TiO_2$ film was decreased with the increase of binder's amount, generally. In case of 20wt%, however. The transmittance of $TiO_2$ films was showed the highest value.

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Effects of Process Parameters on Cell Control of Aluminum Foal Material (알루미늄 발포소재의 성형 공정 인자가 기공제어에 미치는 영향)

  • 전용필;강충길
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.163-166
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    • 1997
  • Aluminium foam material is a highly porous material having complicated cellular structure defined by randomly distributed air pores in metallic matrix. this structure gives the aluminium a set of properties which cannot be achieved by any of conventional treatments. The properties of aluminium foam material significantly depend on its porosity, so that a desired profile of properties can be tailored by changing the foam density. Melting method is the one of foaming processes, which the production has long been considered difficult to realize becaues of such problems as the low foamability of molten metal, the varying size of. cellular structures, solidification shrinkage and so on. These problems, however, have gradually been solved by researchers and some manufacturers are now producing foamed aluminum by their own methods. Most of all, the parameters of solving problem in electric furnace were stirring temperature, stirring velocity, foaming temper:iture, and so on. But it has not considered about those in induction heating, foaming velocity and foaming temperature in semi-solid state yet. Therefore, this paper presents the effects on these parameter to control cell size, quantity and distribution.

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Effect of Rubber on Microcellular Structures from High Internal Phase Emulsion Polymerization

  • Park, Ji-Sun;Chun, Byoung-Chul;Lee, Seong-Jae
    • Macromolecular Research
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    • v.11 no.2
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    • pp.104-109
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    • 2003
  • A microcellular, which combines a rubber with the conventional formulation of styrene/divinylbenzene/sorbitan monooleate/water system, was prepared using high internal phase emulsion (HIPE) polymerization. Although the open microcellular foam with low density from the conventional HIPE polymerization shows highly porous characteristics with fine, regular and isotropic structure, the one having much smaller cell size is desirable for various applications. In this study, a polybutadiene was introduced to reduce the cell size with comparable properties. Major interests were focused on the effects of rubber concentration and agitation speed on the cell sizes and compression properties. Scanning electron microscopy was used to observe the microcellular morphology and compression tests were conducted to evaluate the stress-strain behaviors. It was found that the cell size decreased as rubber concentration increased, reflecting a competition between the higher viscosity of continuous phase and the lower viscosity ratio of dispersed to continuous phases due to the addition of high molecular weight rubber into the oil phase of emulsion. A correlation for the average cell size depending on agitation speed was attempted and the result was quite satisfactory.