• Korean Chemical Engineering Research
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• v.59 no.4
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• pp.574-583
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• 2021

Waste air containing ethanol (100 ppmv) and hydrogen sulfide (10 ppmv) was continuously treated by waste air-treating system composed of two annular photocatalytic reactors (effective volume: 1.5 L) packed with porous SiO₂ media carrying TiO₂-anatase photocatalyst, one of which was alternately operated for 32 d/run while the other was regenerated by 100 ℃ hot air with 15 W UV(-A)-light on. As its elimination-behavior of ethanol, the removal efficiencies of ethanol at 1^st, 2^nd and 3^rd operation of the photocatalytic reactor system(A), turned out to be ca. 60, 55 and 54%, respectively, at their steady state condition. Unlike the elimination-behavior of ethanol, its hydrogen sulfide-elimination behavior showed repeated decrease of hydrogen sulfide removal efficiency by its resultant arrival at a lower level of steady state condition. Nevertheless, the removal efficiencies of hydrogen sulfide at 1^st, 2^nd and 3^rd operation of the photocatalytic reactor system, turned out to be ca. 80, 75 and 73%, respectively, at their final steady state condition, higher by ca. 20, 20 and 19% than those of ethanol, respectively. Therefore, assuming that adsorption on porous SiO₂-photocatalyst carrier was regarded to belong to a reversible deactivation and that decreased % of removal efficiency due to the reversible deactivation of photocatalyst including the adsorption was independent of the number of its use upon regeneration, the increments of the decreased % of removal efficiency of ethanol and hydrogen sulfide, due to an irreversible deactivation of photocatalyst, for the 3^rd use of regenerated photocatalyst, compared with the 2^nd use of regenerated photocatalyst, were ca. 1 and 2%, respectively, which was insignificant or the less than those of ca. 5 and 5%, respectively, for the 2^nd use of regenerated photocatalyst compared with the 1^st use of virgin photocatalyst. This trend of the photocatalytic reactor system was observed to be similar to that of the other alternately-operating photocatalytic reactor system.

• Polymer(Korea)
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• v.32 no.4
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• pp.322-327
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• 2008

In this study, a multi-layered pellet was composed of a seed layer including a water-swellable agent and a drug layer containing doxazosin as a model drug, a porous membrane and a castor oil layer to control drug release. The pellet is prepared by a fluidized bed coating method. To confirm drug release from polymer blending in multi-layered pellet system, it is prepared by containing different ratio such as hydroxypropylmethylcellulose (HPMC) : ethyl cellulose (EC) in drug layer and cellulose acetate(CA) : Eudragit RS in membrane. Also, to confirm the effect of oil in drug release, castor oil is coated. As a result, we observed regularly spherical pellet with diameter of $1500{\mu}m$. Release pattern of drug is confirmed by dissolution tester in aqueous media. The more the ratio of EC in drug layer, CA in membrane, and castor oil layer in pellet, the less the drug release is observed. Formation and the amount of pores in membrane is observed by SEM.

• Polymer(Korea)
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• v.32 no.2
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• pp.103-108
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• 2008

Osmotic pellet, which consisted of water-swellable seed layer, drug layer, and porous membrane layer, has been widely utilized in oral drug delivery system. In this work, we describe the preparation of osmotic pellet with nifedipine as model drug and a mixture of cellulose acetate (CA) and Eudragit RS as membrane layer, and then examined the drug release behavior on the variation of the thickness change of membrane layer (CA and Eudragit RS) and release media. Furthermore, we examined the nifedipine release behavior using sodium alginate as a potential membrane candidate. Osmotic pellet was obtained in the quantitative yield by fluidized bed coater. Osmotic pellet exhibited the round morphology and the size ranging $1500{\sim}1700{\mu}m$ in SEM. The nifedipine release decreased as the thickness of membrane layer (CA and Eudragit RS) increased. In addition, it observed that there is difference of release amount in between intestinal juice (pH 6.8) and gastric juice (pH 1.2). In the case of osmotic pellet coated with sodium alginate, nifedipine release behavior depended on the crosslinking of sodium alginate layer. In conclusion, we found that various membrane layers could control the release amount of nifedipine.

• Korean Journal of Ecology and Environment
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• v.36 no.4 s.105
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• pp.434-446
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• 2003

The fate and transport of many trace metals, metalloids, and radionuclides in porous media is closely linked to the biogeochemical reactions that occur as a result of organic carbon being sequentially degraded by different microorganisms using a series of terminal electron acceptors. The spatial distribution of these biogeochemical reactions is affected by processes that are often unique and/or characteristic to a specific environment. Generic model formulations have been developed and applied to simulate the fate and transport of arsenic in two hydrologic settings, permanently flooded freshwater sediments, namely non-vegetated wetland sediments and vegetated wetland sediments. The key physical processes that have been considered are sedimentation, effects of roots on biogeochemistry, advective transport, and differences in mixing processes. Steady-state formulations were applied to the sedimentary environments. Results of numerical simulations show that these physical processes significantly affect the chemical profiles of different electron acceptors, their reduced species, and arsenate as well as arsenite that will result from the degradation of an organic carbon source in the sediments. Even though specific biological transformations are allowed to proceed only in zones where they are thermodynamically favorable, the results show that mixing as well as abiotic reactions can make the profiles of individual electron acceptors overlap and/or appear to reverse their expected order.

• Journal of Wetlands Research
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• v.14 no.1
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• pp.75-87
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• 2012

Hyporheic zone is a region beneath and alongside a stream, river, or lake bed, where there is mixing of shallow groundwater and surfacewater. Hyporheic exchange controls a variety of physical, biogeochemical and thermal processes, and provides unique ecotones in a aquatic ecosystem. Field and experimental observations, and modeling studies indicate that hyporheic exchange is mainly in response to pressure gradients driven by the geomorphological features of stream beds. In the reach scale of a stream, pool-riffle structures dominate the exchange patterns. Flow over a pool-riffle sequence develops recirculation zones and stagnation points, and this flow structures make irregular pressure gradient which is driving force of the hyporheic exchange. In this study, 3 D hydro-dynamic model solves the Reynolds-averaged Navier-Stokes equations for the surface water and Darcy's Law and the continuity equation for ground water. The two sets of equations are coupled via the pressure distribution along the interface. Simulation results show that recirculation zones and stagnation points in the pool-riffle structures dominantly control the upwelling and downwelling patterns. With decrease of recirculation zones, length of donwelling zone formed in front of riffles is reduced and position of maximum downwelling point moves downward. The numerical simulation could successfully predict the behavior of hyporheic exchange and contribute the field study, river management and restoration.

• Journal of the Korean Geotechnical Society
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• v.36 no.11
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• pp.149-156
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• 2020

Permeation grouting effectively enhances soil strength and decreases permeability of soil; however, the flow of grout is heavily affected by anisotropy of hydraulic conductivity in layers. Therefore, this study investigates the effect of permeability anisotropy on the effective radius of horizontal permeation grout using computational fluid dynamics (CFD). We modeled the horizontal permeation grout flow as a two-phase viscous fluid flow in porous media, and the model incorporated the chemical diffusion and the viscosity variation due to hardening. The numerical simulation reveals that the permeability anisotropy shapes the grout bulb to be elliptic and the dissolution-driven diffusion causes a gradual change in grout pore saturation at the edge of the grout bulb. For the grout pore saturations of 10%, 50% and 90%, the horizontal and vertical radii of grout bulb are estimated when the horizontal-to-vertical permeability ratio varies from 0.01 to 100, and the predictive model equations are suggested. This result contributes to more efficient design of injection strategy in formation layers with permeability anisotropy.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.29 no.6
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• pp.286-304
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• 2017

In this study, we proposed a new-type of circular perforated caisson breakwater consisting of a bundle of latticed blocks that can be applied to a small port such as a fishing port, and numerically investigated the hydraulic characteristics of the breakwater. The numerical method used in this study is OLAFOAM which newly added wave generation module, porous media analysis module and reflected wave control module based on OpenFOAM that is open source CFD software published under the GPL license. To investigate the applicability of OLAFOAM, the variations of wave pressure acting on the three-dimensional slit caisson were compared to the previous experimental results under the regular wave conditions, and then the performance for irregular waves was examined from the reproducibility of the target irregular waves and frequency spectrum analysis. As a result, a series of numerical simulations for the new-type of circular perforated caisson breakwaters, which is similar to slit caisson breakwater, was carried out under the irregular wave actions. The hydraulic characteristics of the breakwater such as wave overtopping, reflection, and wave pressure distribution were carefully investigated respect to the significant wave height and period, the wave chamber width, and the interconnectivity between them. The numerical results revealed that the wave pressure acting on the new-type of circular perforated caisson breakwaters was considerably smaller than the result of the impermeable vertical wall computed by the Goda equation. Also, the reflection of the new-type caisson breakwater was similar to the variation range of the reflection coefficient of the existing slit caisson breakwater.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.18 no.2_spc
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• pp.305-315
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• 2020

For geological disposal of radioactive wastes, a method was proposed to evaluate the radionuclide transport in the biosphere by calculating the elapsed time of nuclide migration. The radionuclides were supposed to be introduced from a natural barrier and reached a large surface water body following a groundwater flow in a shallow subsurface. The biosphere was defined as a shallow subsurface environment that included aquifers on a host rock. Using the proposed method, a calculation algorithm was established, and a computer code that implemented the algorithm was developed. The developed code was verified by comparing the simulation results of the simple cases with the results of the analytical solution and a public program, which has been widely used to evaluate the radiation dose using the radionuclide transport near the surface. A case study was constructed using the previous research for radionuclide transport from the hypothetical geological disposal repository. In the case study, the code calculated the mass discharge rate of radionuclide to a stream in the biosphere. Because the previous research only demonstrated the transport of radionuclides from the hypothetical repository to the host rock, the developed code in the present study could help identify the total transport of radionuclide along the complete pathway.

• The Journal of Engineering Geology
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• v.13 no.1
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• pp.51-65
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• 2003

A series of numerical simulations were carried out using STOMP( Subsurface Transport over Multiple Phase) simulator. The flow and distribution of LNAPL were analyzed in homogeneous fine and coarse sand. Vertical movement of LNAPL is faster in the coarser sand. But the total volume of LNAPL retained in the unsaturated zone is larger in the finer sand. A fine layer in the coarse sand domain is also simulated. The results showed that the retained LNAPL volume and shape are highly influenced by the Position of the fine layer. Flow and distributions of LNAPL were simulated when there were heterogeneous lenses in the sand domain. Water table fluctuation was also considered. In these cases, it was found that the heterogeneous lens was a barrier to LNAPL flow, and water table fluctuation stimulated the downward movement of retained LNAPL. The LNAPL flow and distribution observed in these numerical experiments show that in the subsurface environment, the behaviors of LNAPL highly depend on heterogeneities of unsaturated zone and the dynamic hydrogeologic condition such as water table fluctuation. These results can explain some of the complexity of LNAPL flow and distribution Patterns in LNAPL contaminated field sites.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.10
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• pp.979-988
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• 2012

The 3D structure of GDL for fuel cells was measured using high-resolution X-ray tomography in order to study material transport in the GDL. A computational algorithm has been developed to remove noise in the 3D image and construct 3D elements representing carbon fibers of GDL, which were used for both structural and fluid analyses. Changes in the pore structure of GDL under various compression levels were calculated, and the corresponding volume meshes were generated to evaluate the anisotropic permeability of gas within GDL as a function of compression. Furthermore, the transfer of liquid water and reactant gases was simulated by using the volume of fluid (VOF) and pore-network model (PNM) techniques. In addition, the simulation results of liquid water transport in GDL were validated by analogous experiments to visualize the diffusion of fluid in porous media. Through this research, a procedure for simulating the material transport in deformed GDL has been developed; this will help in optimizing the clamping force of fuel cell stacks as well as in determining the design parameters of GDL, such as thickness and porosity.