• Title/Summary/Keyword: porosity reduction

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Size Effects of the Catalyst on Characteristics of Zn/Air Batteries (MnO2입자 크기에 따른 아연공기전지의 특성연구)

  • 김지훈;엄승욱;문성인;윤문수;김주용;박정식;박정후
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.12
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    • pp.1150-1154
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    • 2003
  • The voltage profile during discharge of the zinc air battery has very flat pattern until reach to end of discharge voltage. But, when zinc air battery is discharged by high current, the discharge voltage and energy becomes low. Therefore, we focused on effects of catalyst size to solve this problems by increasing active sites of oxygen reduction reaction. The size of catalyst was reduced from 27 to l${\mu}{\textrm}{m}$ and we examined average discharge voltage, capacity, energy, resistance and characteristics during GSM pulse discharge of zinc air battery with change of current density. And we also measured porosity of the cathode according to the ASTM. So we have got improvement of average discharge voltage and energy when catalyst was minimized and we have got optimum size of catalyst at 5${\mu}{\textrm}{m}$.

Porosity Reduction in Laser Welding of Nitrided Carbon Steel (질화처리된 저탄소강 레이저 용접부의 기공 감소)

  • Ahn, Young-Nam;Kim, Cheolhee;Lee, Wonbeom;Kim, Jeonhan
    • Journal of Welding and Joining
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    • v.31 no.6
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    • pp.71-76
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    • 2013
  • Gas nitriding is a surface hardening process where nitrogen is introduced into the surface of a ferrous alloy. During fusion welding of nitrided carbon steel, the nitride inside weld metal is dissolved and generates nitrogen gas, which causes porosities - blow holes and pits. In this study, several laser welding processes such as weaving welding, two-pass welding, dual beam welding and laser-arc hybrid welding were investigated to elongate the weld pool to enhance nitrogen gas evacuation. The surface pits were successfully eliminated with elongated weld pool. However blowholes inside the weld metal were effective reduced but not fully disappeared.

Geopolymer composite binders of soda-lime glass (GP) & Ground Granulated Blast Furnance Slag (GGBS): The strength & microstructure

  • Sasui, Sasui;Kim, Gyu Yong;Lee, Sang Kyu;Son, minjae;Hwang, Eui Chul;Nam, Jeong Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.19-20
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    • 2019
  • This study investigated the possibility of strength development by incorporating the slighly coarser soda-lime glass powder (GP) with 0-100 wt.% of Ground Granulated Blast Furnace Slag (GGBS) to synthesis GGBS based geopolymer. Compressive strength, water absorption & apparent porosity, were experimentally determined. To determine the homogeneity of mix, the microstructure & elemental composition of samples were studied using SEM-EDS. Study reveals the improvement in strength and reduction in porosity for the samples containing up to 30% GP. Furthermore, the microstructure analyses confirmed the development of denser and compact structure with the incorporation of glass powder up to 30%.

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Microstructure modeling of carbonation of metakaolin blended concrete

  • Wang, Xiao-Yong;Lee, Han-Seung
    • Advances in concrete construction
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    • v.7 no.3
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    • pp.167-174
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    • 2019
  • Metakaolin (MK), which is increasingly being used to produce high performance concrete, is produced by calcining purified kaolinite between 650 and $700^{\circ}C$ in a rotary kiln. The carbonation resistance of metakaolin blended concrete is lower than that of control concrete. Hence, it is critical to consider carbonation durability for rationally using metakaolin in the concrete industry. This study presents microstructure modeling during the carbonation of metakaolin blended concrete. First, based on a blended hydration mo del, the amount of carbonatable substances and porosity are determined. Second, based on the chemical reactions between carbon dioxide and carbonatable substances, the reduction of concrete porosity due to carbonation is calculated. Furthermore, $CO_2$ diffusivity is evaluated considering the concrete composition and exposed environment. The carbonation depth of concrete is analyzed using a diffusion-based model. The proposed microstructure model takes into account the influences of concrete composition, concrete curing, and exposure condition on carbonation. The proposed model is useful as a predetermination tool for the evaluation of the carbonation service life of metakaolin blended concrete.

A Passive Control of Interaction of Condensation Shock Wave anc Boundary Layer(I) (응축충격파와 경계층 간섭의 피동제어(I))

  • Choe, Yeong-Sang;Jeong, Yeong-Jun;Gwon, Sun-Beom
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.2
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    • pp.316-328
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    • 1997
  • There were appreciable progresses on the study of shock wave / boundary layer interaction control in the transonic flow without nonequilibrium condensation. But in general, the actual flows associated with those of the airfoil of high speed flight body, the cascade of steam turbine and so on accompany the nonequilibrium condensation, and under a certain circumstance condensation shock wave occurs. Condensation shock wave / boundary layer interaction control is quite different from that of case without condensation, because the droplets generated by the result of nonequilibrium condensation may clog the holes of the porous wall for passive control and the flow interaction mechanism between the droplets and the porous system is concerned in the flow with nonequilibrium condensation. In these connections, it is necessary to study the condensation shock wave / boundary layer interaction control by passive cavity in the flow accompanying nonequilibrium condensation with condensation shock wave. In the present study, experiments were made on a roof mounted half circular arc in an indraft type supersonic wind tunnel to evaluate the effects of the porosity, the porous wall area and the depth of cavity on the pressure distribution around condensation shock wave. It was found that the porosity of 12% which was larger than the case of without nonequilibrium condensation produced the largest reduction of pressure fluctuations in the vicinity of condensation shock wave. The results also showed that wider porous area, deeper cavity for the same porosity of 12% are more favourable "passive" effect than the cases of its opposite. opposite.

Model Test for Heave Motion Reduction of a Circular Cylinder by a Damping Plate (감쇠판에 의한 원기둥의 상하운동 저감 모형시험)

  • Koh, Hyeok-Jun;Kim, Jeong-Rok;Cho, Il-Hyoung
    • Journal of Ocean Engineering and Technology
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    • v.27 no.4
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    • pp.76-82
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    • 2013
  • Motion reduction of an offshore structure at resonant frequency is essential for avoiding critical damage to the topside and mooring system. A damping plate has a distinct advantage in reducing the motion of a floating structure by increasing the added mass and the damping coefficient. In this study, the heave motion responses of a circular cylinder with an impermeable and a permeable damping plate attached at the bottom of the cylinder were investigated thru a model test. The viscous damping coefficients for various combinations of porosity were obtained from a free-decay test by determining the ratio between any pair of successive amplitudes. Maximum energy dissipation occurred at a porous plate with a porosity P = 0.1008. Experimental results for regular and irregular waves were compared with an analytical solution by Cho (2011). The measured heave RAO and spectrum reasonably followed the trends of the predicted values. A significant motion reduction at resonant frequency was pronounced and the heaving-motion energy calculated by the integration of the area under the heave motion spectrum was reduced by more than 75% by the damping plate. However, additional energy dissipation by eddies of strong vorticity and flow separation inside a porous damping plate was not found in the present experiments.

박테리아에 의한 클로깅 현상에 따른 임계 상태 균열 암반의 유체투과율 감소에 관한 전산 연구

  • 한충용;강주명;최종근
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.73-76
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    • 2001
  • We have simulated the effect of fracture characteristics on reduction of effective permeability of the fractured rocks due to in-situ bacteria growth. A nutrient is injected continuously for growth of in-situ bacteria. We used a power law for fracture length distribution and a fBm for fracture aperture spatial distribution. The results show that in-situ bacteria growth reduces the Permeability hyperbolically, but the porosity of backbone fracture does not change significantly. It shows that reduction of the permeability proceeds at faster speed for smaller value of length exponent(a) and for larger value of Hurst exponent(H). The fracture length distribution has stronger effect on speed of reduction than the aperture spatial distribution. The time needed to reduce permeability is inversely proportional to the hydraulic gradient.

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Effect of Cathode Porosity on the Cathodic Polarization Behavior of Mixed Conducting LSCF(La0.6Sr0.4Co0.2Fe0.8O3) (혼합전도체 LSCF(La0.6Sr0.4Co0.2Fe0.8O3) 양극의 기공률에 따른 양극분극 특성)

  • Yun, Joong-Cheul;Lee, Jong-Ho;Kim, Joosun;Lee, Hae-Weon;Kim, Byong-Ho
    • Journal of the Korean Ceramic Society
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    • v.42 no.4
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    • pp.251-259
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    • 2005
  • In order to characterize the influence of the reaction-site density on the cathodic polarization property of LSCF, we chose the porosity of LSCF as a main controlling variable, which is supposed to be closely related with active sites for the cathode reaction. To control the porosity of cathodes, we changed the mixing ratio of fine and coarse LSCF powders. The porosity and pore perimeter of cathodes were quantitatively analyzed by image analysis. The electrochemical half cell test for the cathodic polarization was performed via 3-probe AC-impedance spectroscopy. According to the investigation, the reduction of oxygen at LSCF cathode was mainly controlled by following two rate determining steps; i) surface diffusion and/or ionic conduction of ionized oxygen through bulk LSCF phase, ii) charge transfer of oxygen ion at cathode/electrolyte interface. Moreover, the overall cathode polarization was diminished as the cathode porosity increased due to the increase of the active reaction sites in cathode layer.

Fabrication and Characterization of Porous Nickel Membrane for High Precision Gas Filter by In-situ Reduction/Sintering Process (In-situ 환원/소결법을 이용한 다공성 니켈 멤브레인 가스필터의 제조 및 평가)

  • Kim, Nam-Hoon;Song, Han-Bok;Choi, Sung-Churl;Choa, Yong-Ho
    • Journal of Powder Materials
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    • v.16 no.4
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    • pp.262-267
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    • 2009
  • Disk type porous nickel membrane was fabricated by in-situ reduction/sintering process using compacted NiO/PMMA (PMMA; Polymethyl methacrylate) mixture at $800^{\circ}C$ in hydrogen atmosphere. The porosity (49$\sim$58%) of these membrane was investigated as an amount of PMMA additive. The thermal decomposition and reduction behavior of NiO/PMMA were analyzed by TG/DTA in hydrogen atmosphere and the activation energy for the hydrogen reduction of NiO and thermal degradation of PMMA was calculated as 61.1 kJ/mol, evaluated by Kissinger method. Finally, the filtering performance and pressure drop were measured by particle counting system.

Phase Transition and Metalization of DRI According to the Quality of Iron Oxide

  • Yun, Young Min;Jung, Jae Hyun;Seo, Sung Kwan;Chu, Yong Sik
    • Journal of the Korean Ceramic Society
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    • v.52 no.5
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    • pp.389-394
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    • 2015
  • Direct reduced iron was made using an electric furnace. The reduction ratio of direct reduced iron varied depending on the grade of iron ore. Coal played an important role as a reducing agent in making the direct reduced iron. The coal must contain a suitable amount of volatile components having high calorie values and low impurity content. In this study, oxidized pellets were directly reduced using anthracite as a reductant in an electric furnace. Direct reduction behaviors of hematite and magnetite pellets were confirmed in a coal-based experiment. Reduction behaviors were demonstrated by analyzing the chemical compositions, measuring the reducibility, and observing the phase changes and microstructure. The superior reducibility of hematite pellets can be ascribed to their high effective diffusivity, which is due to their high porosity. The quickly after reducing for 40min and achieves a high value at the end of the reduction.