• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.163.2-163.2
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• 2010

In this work, nano-flake shaped nickel oxide (NiO) films were synthesized by chemical bath deposition technique for electrochemical capacitors. The deposition was carried out for 1 and 2 h at room temperature using nickel foam as the substrate and the current collector. The structure and morphology of prepared NiO film were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). And, electrochemical properties were characterized by cyclic voltammetry, galvanostatic charge-discharge, and AC impedence measurement. It was found that the NiO film was constructed by many interconnected NiO nano-flakes which arranged vertically to the substrate, forming a net-like structure with large pores. The open macropores may facilitate the electrolyte penetration and ion migration, resulted in the utilization of nickel oxide due to the increased surface area for electrochemical reactions. Furthermore, it was found that the deposition onto nickel foam as substrate and curent collector led to decrease of the ion transfer resistance so that its specific capacitance of a NiO film had high value than NiO nano flake powder.

• Corrosion Science and Technology
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• v.18 no.6
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• pp.228-231
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• 2019

Aluminum and its alloys have been widely used in various fields because of low weight, high strength, good conductivity, and low price. It is well known that aluminum alloys that cause natural oxide film can inhibit corrosion in wet, salty environments. However, these oxides are so thin that corrosion occurs in a variety of environments. To prevent this problem, an electrochemical anodizing technique was applied to the aluminum alloy surface to form a thick layer of oxide and a unique oxide shape, such as a hierarchical pore structure simultaneously combining large and small pores. The shape of the structures was implemented using stepwise anodization voltages such as 40 V for mild anodizing and 80 V for hard anodizing, respectively. To maximize water repellency, it is crucial to the role of surface structures shape. And a hydrophobic thin film was coated by 1H, 1H, 2H, 2H-Perfluorodecyltrichlorosilane (FDTS) to minimize surface energy of the structure surface. Thus, such nanoengineered superhydrophobic surface exhibited a high water contact angle and excellent corrosion resistance such as low corrosion current density and inhibition efficiency.

• Journal of the Korean Ceramic Society
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• v.56 no.6
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• pp.534-540
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• 2019

Carbon dioxide emissions involved in global warming are one of the most important issues in the world, and carbon dioxide emissions from the cement industry are about 7% of total carbon dioxide emissions. Thus, reduction in the amount of utilized cement can contribute to a reduction of carbon dioxide emissions. The average life of concrete is 20 ~ 30 years, and if concrete life can be improved by ten years, cement use will be much lower. In this study, we examined the use and effect of fructan from microbes as a method for the densification of the pore structure of cement. The effect of fructan on the hydration reaction and pore distribution, as well as the water absorption of hardened cement mortar were studied. Pores distribution increased in mesopore OPC, and absorption rate was found to decrease with the use of fructan, which has a glue-like and swelling character.

• Journal of the Korean Ceramic Society
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• v.50 no.2
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• pp.127-133
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• 2013

Porcelain with high thermal shock resistance was successfully fabricated by a lithium solution infiltration method with a lithium hydroxide solution. Lithium hydroxide solutions having various lithium concentrations were infiltrated into pre-sintered porcelain bodies. The porcelain sample infiltrated by the 9 wt% lithium solution and heat treated at $1250^{\circ}C$ for 1 h showed a low thermal expansion coefficient of $1.0{\times}10^{-6}/^{\circ}C$ with excellent thermal shock resistance. The highly thermally resistant porcelain had a well-developed ${\beta}$-spodumene phase with the general phases observed in porcelain. Furthermore, the porcelain showed a denser structure of $2.41g/cm^3$ sintering density and excellent whiteness in comparison with commercial thermally resistible porcelains. The lithium hydroxide in the samples readily reacted with moisture, and liquid phase reactants were formed during the fabrication process. In the case of an excess amount of lithium in the sample body, the lithium reactants were forced to the surface and re-crystallized at the surface, leaving large pores beneath the surface. These phenomena resulted in an irregular structure in the surface area and led to cracking in samples subjected to a thermal shock test.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2002.05a
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• pp.91-96
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• 2002

This study is to investigate the insulation performance of lightweight concrete using recycled lightweight aggregate, to develop lightweight concrete products which have an excellence on the insulation performance are satisfied with properties of building materials. As a result of this study, recycled EPS aggregate is considered to have an independent pores which is closed by dense partitions. So, it is showed that the insulation performance of lightweight concrete using recycled EPS aggregate are excellent. Especially, in the case of lightweight concrete under conditions of replacement ratio over 100%, it is considered that insulation performance is very excellent as thermal conductivity is showed about 0.2kcal/mh$^{\circ}C$. According to considering the relation between ultrasonic pulse velocity, unit weight and thermal conductivity through the graph, the result of relation between ultrasonic pulse velocity, unit weight and thermal conductivity on the graph expressed their high interaction shown as direct proportion on the graph. So that it is possible to extract the insulation performance of lightweight concrete using recycled EPS aggregate by ultrasonic pulse velocity and unit weight.

• Journal of the Korea Concrete Institute
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• v.17 no.5 s.89
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• pp.857-868
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• 2005

This paper deals with the accumulated damage in concrete structures due to the cyclic freeze-thaw as an environmental load. The cyclic ice body nucleation and growth processes in porous systems are affected by the thermo-physical and mass transport properties, and gradients of temperature and chemical potentials. Furthermore, the diffusivity of deicing chemicals shows significantly higher value under cyclic freeze-thaw conditions. Consequently, the disintegration of concrete structures is aggravated at marine environments, higher altitudes, and northern areas. However, the properties of cyclic freeze-thaw with crack growth and diffusion of chloride ion effects are hard to be identified in tests, and there has been no analytic model for the combined degradations. The main objective is to determine the driving force and evaluate the reduced strength and stiffness by freeze-thaw. For the development of computational model of those coupled deterioration, micro-pore structure characterization, pore pressure based on the thermodynamic equilibrium, time and temperature dependent super-cooling with or without deicing salts, nonlinear-fracture constitutive relation for the evaluation of internal damage, and the effect of entrained air pores (EA) has been modeled numerically. As a result, the amount of ice volume with temperature dependent surface tensions, freezing pressure and resulting deformations, and cycle and temperature dependent pore volume has been calculated and compared with available test results. The developed computational program can be combined with DuCOM, which can calculate the early aged strength, heat of hydration, micro-pore volume, shrinkage, transportation of free water in concrete. Therefore, the developed model can be applied to evaluate those various practical degradation cases as well.

• Carbon letters
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• v.13 no.3
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• pp.161-166
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• 2012

Carbon materials were synthesized by pyrolysis from fibers of Corn-straw (Zea mays), Rice-straw (Oryza sativa), Jute-straw (Corchorus capsularis) Bamboo (Bombax bambusa), Bagass (Saccharum officinarum), Cotton (Bombax malabaricum), and Coconut (Cocos nucifera); these materials were characterized by scanning electron microscope, X-ray diffraction (XRD), and Raman spectra. All carbon materials are micro sized with large pores or channel like morphology. The unique complex spongy, porous and channel like structure of Carbon shows a lot of similarity with the original anatomy of the plant fibers used as precursor. Waxy contents like tyloses and pits present on fiber tracheids that were seen in the inherent anatomy disappear after pyrolysis and only the carbon skeleton remained; XRD analysis shows that carbon shows the development of a (002) plane, with the exception of carbon obtained from bamboo, which shows a very crystalline character. Raman studies of all carbon materials showed the presence of G- and D-bands of almost equal intensities, suggesting the presence of graphitic carbon as well as a disordered graphitic structure. Carbon materials possessing lesser density, larger surface area, more graphitic with less of an $sp^3$ carbon contribution, and having pore sizes around $10{\mu}m$ favor hydrogen adsorption. Carbon materials synthesized from bagass meet these requirements most effectively, followed by cotton fiber, which was more effective than the carbon synthesized from the other plant fibers.

• Journal of the Korea Concrete Institute
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• v.16 no.2 s.80
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• pp.277-282
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• 2004

In a hardened concrete, diffusion of oxygen, carbon dioxide, aggressive ions, and moisture from the environment to the concrete takes place through the pore network. It is well known that making dense cement matrix enhances the durability of concrete as well as all the characteristics including strength of concrete. In this paper,9 mix concretes with water to cementitious material ratio (40,45, and $50\%$) and replacement ratio of GGBFS (40 and $60\%$ of cement by weight) were studied on the micro-pore structure by mercury intrusion porosimetry and the accelerated chloride diffusion test by potential difference. From the results the average pore diameter and accelerated chloride diffusivity of concrete were ordered NPC > G4C > G6C. It is concluded that there is a good correlation between the average pore diameter and the chloride diffusivity, and the mineral admixtures has a filling effect, which increases the tortuosity of pore and makes large pores finer, on the pore structure of cement matrix due to the latent hydraulic reaction with hydrates of cement.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.14 no.5
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• pp.1081-1089
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• 1994

Polypropylene Fibers have been used to increase the toughness of concrete and to increase the resistance to crack formation. However, there are many contradictory argument about the effectiveness of the fiber due to the lack of knowledge about the mechanism of fiber in concrete. One of the mechanism which changes the concrete properties on the addition of fiber is the change of the micropore structures. In this study, the change of pore structure due to the addition of fiber has been analysized by a permeability and a pore size distributuion test. The added fiber is found to provide a path for moisture movement, which increases drying shrinkage and pore size. It is found that the size of pores formed around the fiber ranges from $0.05{\mu}m$ to $5.0{\mu}m$.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1997.10a
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• pp.163-166
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• 1997

Aluminium foam material is a highly porous material having complicated cellular structure defined by randomly distributed air pores in metallic matrix. this structure gives the aluminium a set of properties which cannot be achieved by any of conventional treatments. The properties of aluminium foam material significantly depend on its porosity, so that a desired profile of properties can be tailored by changing the foam density. Melting method is the one of foaming processes, which the production has long been considered difficult to realize becaues of such problems as the low foamability of molten metal, the varying size of. cellular structures, solidification shrinkage and so on. These problems, however, have gradually been solved by researchers and some manufacturers are now producing foamed aluminum by their own methods. Most of all, the parameters of solving problem in electric furnace were stirring temperature, stirring velocity, foaming temper:iture, and so on. But it has not considered about those in induction heating, foaming velocity and foaming temperature in semi-solid state yet. Therefore, this paper presents the effects on these parameter to control cell size, quantity and distribution.