• Title/Summary/Keyword: pore-size

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Analysis of the Behavior of Undrained Pore Water Pressure in Saturated Sand by Isotropic Loading Test (포화된 사질토에서 등방재하시험에 의한 비배수 공극수압의 거동분석)

  • Eam, Sung-Hoon
    • Journal of The Korean Society of Agricultural Engineers
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    • v.47 no.4
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    • pp.43-52
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    • 2005
  • It is known in some literatures that the B value is not equal to unity in saturated soil when effective stress is given, in which the B Value is the ratio of measured excess pore water pressure and isometric loading pressure. In this study the B value was measured on various effective stresses and on various incremental loading stresses in various grain size of specimens with saturated sand. The test results showed that the B value was affected largely by grain size of sand in specimen and the amount of effective stress. There was the semi-logarithmic relationship between B value and effective stress, and also there was the linear relationship between the gradient of the former semi-logarithmic relationship and grain size of specimen.

Thermal Spalling and Resistance to Slag Attack in Porous High Alumina Ceramic (According to Pore Size) (고Alumina질 다공성 세라믹스의 내열충격성 및 내Slag성 (기공크기에 따른))

  • 김병훈;나용한
    • Journal of the Korean Ceramic Society
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    • v.30 no.9
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    • pp.747-753
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    • 1993
  • The investigation was carried out to study the behaviors of the pore size and porosity, the mechanical strength, the resistance to thermal spallings and slag attacks according to particle sizes of starting raw materials in porous high Alumina ceramics. This porous ceramics have been used in processing of the clean steel by the blowing of the inert gas. The required properties in the practice are the suitable pores size, the sharp pores distribution for a uniform blowing of the gas, the strong corrosion resistance to slags and molten metals and the resistance to thermal spalling. The optimized properties in porous high alumina ceramics of the specimen No. 3 was found to be the very low slag intrusion and the superior resistance to thermal spalling because of the suitable pore size of 2.5${\mu}{\textrm}{m}$, the porosity of 30% and the high sinterability.

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Microstructure and Pore Size Control of Silica Membrane for Gas Separation at Elevated Temperatures

  • Lee Kew-Ho;Sea Bongkuk;Lee Dong-Wook
    • Korean Membrane Journal
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    • v.7 no.1
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    • pp.42-50
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    • 2005
  • Among ceramic membranes developed to date, amorphous silica membranes are attractive for gas separation at elevated temperatures. Most of the silica membranes can be formed on a porous support by sol-gel or chemical vapor deposition (CVD) process. To improve gas permselectivity of the membrane, well-controlled pores having desired size and chemical affinity between permeates and membrane become important factors in the preparation of membranes. In this article, we review the literature and introduce our technologies on the microstructure to be solved and pore size control of silica membranes using sol-gel and CVD methods.

Preparation of Porous Inorganic Materials by Foaming Slurry (슬러리 발포에 의한 연속성 무기질 다공체의 제조)

  • 박재구;이정식
    • Journal of the Korean Ceramic Society
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    • v.35 no.12
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    • pp.1280-1285
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    • 1998
  • Foaming method is presented the preparation of porous materials from high-concentrated kaolin silica and flyash slurries. The slurries were foamed dried and sintered respectively. The porosity of sintered ma-terials was about 70-75% Mean pore-size was the range of 70-150$\mu\textrm{m}$ and pore structure was continuous Sodium lauryl sulfate anionic surfactant was used as a foaming agent. The foaming ability and the froth sta-bility were increased with increasing the concentration of the foaming agent. But the size of the constituent bubble of froth after foaming process was not affected by the concentration of the foaming agent. These results showed that the mean pore-size of sintered materials was closely related to the froth stability which is related to the change of bubble-size during the drying process.

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Amperometric Determination of Histamine using Immobilized Enzyme Reactors with Different Carriers (담체 고정화 효소 반응기를 이용한 Histamine의 전기화학적 측정)

  • Ji, Jung-Youn;Jeon, Yeon-Hee;Kim, Mee-Ra
    • Journal of the East Asian Society of Dietary Life
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    • v.22 no.1
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    • pp.88-94
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    • 2012
  • Histamine is a kind of primary biogenic amine arising from the decarboxylation of the amino acid L-histidine. The toxicology of histamine and its occurrence and formation in foods are especially emphasized in fermented foods. In this study, the biosensor for detection of histamine with functionalized multi-walled carbon nanotubes (MWCNT) was developed. We also searched for an appropriate insoluble substrate to immobilize the enzyme. The developed biosensor showed a detection limit of $0.1{\mu}M$ hydrogen peroxide. The enzyme reactor was prepared with diamine oxidase immobilized on insoluble carriers including CNBr-activated sepharose 4B, calcium alginate, and controlled pore size glass beads. The coupling efficiency of CNBr-activated sepharose 4B, calcium alginate, and controlled pore size glass beads were 48.5%, 40.3%, and 51.0%, respectively. In addition, the response currents on histamine with each immobilized enzyme reactor prepared with CNBr-activated sepharose 4B, calcium alginate, and controlled pore size glass beads were 120 nA, 110 nA, and 140 nA at $100{\mu}M$ of histamine concentration, respectively. Therefore, it is suggested that controlled pore size glass beads are the best carriers for immobilizing diamine oxidase to detect histamine in this biosensor.

High Temperature Oxidation Behavior of Ni based Porous Metal (Ni계 다공체 금속의 고온 산화 거동)

  • Choi, Sung-Hwan;Yun, Jung-Yeul;Lee, Hye-Mun;Kong, Young-Min;Kim, Byoung-Kee;Lee, Kee-Ahn
    • Journal of Powder Materials
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    • v.18 no.2
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    • pp.122-128
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    • 2011
  • This study investigated the high temperature oxidation behavior of Ni-22.4%Fe-22%Cr-6%Al (wt.%) porous metal. Two types of open porous metals with different pore sizes of 30 PPI and 40 PPI (pore per inch) were used. A 24-hour TGA test was conducted at three different temperatures of $900^{\circ}C$, $1000^{\circ}C$ and $1100^{\circ}C$. The results of the BET analysis revealed that the specific surface area increased as the pore size decreased from 30 PPI to 40 PPI. The oxidation resistance of porous metal decreased with decreasing pore size. As the temperature increased, the oxidation weight gain of the porous metal also increased. Porous metals mainly created oxides such as $Al_2O_3$, $Cr_2O_3$, $NiAl_2O_4$, and $NiCr_2O_4$. In the 40 PPI porous metal with small pore size and larger specific surface area, the depletion of stabilizing elements such as Al and Cr occurred more quickly during oxidation compared to the 30 PPI porous metal. Ni-Fe-Cr-Al porous metal's high-temperature oxidation micro-mechanism was also discussed.

Sintered Metal Wicks Development for the High Performance Loop Heat Pipe(LHP) Systems

  • Choi, Jee-Hoon;Sung, Byung-Ho;Yoo, Jung-Hyun;Seo, Min-Whan;Kim, Chul-Ju
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2136-2141
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    • 2007
  • The Loop Heat Pipe(LHP) system uses capillary forces so as to pump the working fluid from heat acquisition to heat rejecting systems. The performance of the LHP systems depends mainly upon the operating performance of the wick structure. The capillary pressure increases with decreasing the pore size of the wick structure. By the way, the wick structure's permeability decreases with decreasing the pore size and the porosity. To obtain an ideal wick, the wick structure should possess several characteristics such as the small pore size, high porosity and chemical compatibility with working fluid. Sintered metal wicks have been mainly used as the capillary wick structure mounted in LHP because of the fact that the sintered metal wick has some advantages like convenient selection of wick material, smaller pore size and so on as well as high reliability. In this study, sintered metal wicks were developed to meet required several parameters to design the high performance LHP systems for obtaining even more effective cooling technologies.

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Decolorization of Dye Using Immobilized Photocatalyst onto Sponge (스펀지에 고정한 광촉매를 이용한 안료의 탈색)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Health Sciences
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    • v.31 no.5 s.86
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    • pp.415-422
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    • 2005
  • The photocatalytic decolorization of Reactive Red 2B(RR2B) was studied using immobilized photocatalyst/UV System. Two pairs of 20 W UV-B and UV-C lamps were employed as the light source. Immobilization of $TiO_2$ was carried out using sponge (as the photocatalyst body) and silicone sealant(as the binder). The effects of parameters such as the thickness, pore size of sponge photocatalyst and attached material on the reactor bottom were investigated. The results showed that the optimum thickness of sponge photocatalyst was 1 cm. Decolorization of reactor which had the bottom coated $TiO_2$ was higher than that of reactor attached aluminum plate. Decolorization of photocatalyst with large pore size(mean pore size, 3.8 mm) was higher than that of the small(mean pore size, 1.75 mm). Initial decolorization of RR2B could be descrived using the Langmuir-Hinshelwood(L-H) model and gave constant values of $0.55mg/l{\cdot}min(k)\;and\;2.65{\times}10^{-2}l/mg(K)$, respectively.

Properties of Porous SiC Ceramics Prepared by Wood Template Method

  • Ha, Jung-Soo;Lim, Byong-Gu;Doh, Geum-Hyun;Kang, In-Aeh;Kim, Chang-Sam
    • Journal of the Korean Ceramic Society
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    • v.47 no.4
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    • pp.308-311
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    • 2010
  • Porous SiC samples were prepared with three types of wood (poplar, pine, big cone pine) by simply embedding the wood charcoal in a powder mixture of Si and $SiO_2$ at 1600 and $1700^{\circ}C$. The basic engineering properties such as density, porosity, pore size and distribution, and strength were characterized. The samples showed full conversion to mostly $\beta$-SiC with good retention of the cellular structure of the original wood. More rigid SiC struts were developed for $1700^{\circ}C$. They showed similar bulk density ($0.5{\sim}0.6\;g/cm^3$) and porosity (81~84%) irrespective of the type of wood. The poplar sample showed three pore sizes (1, 8, $60\;{\mu}m$) with a main size of $60\;{\mu}m$. The pine sample showed a single pore size ($20\;{\mu}m$). The big cone pine sample showed two pore sizes (10, $80\;{\mu}m$) with a main size of $10\;{\mu}m$. The bend strength was 2.5 MPa for poplar, 5.7 MPa for pine, 2.8 MPa for big cone pine, indicating higher strength with pine.

Determination of Microfiltration Membrane Fouling Characteristics by Liquid Displacement Method (액체전이법을 이용한 정밀여과막 오염의 특성 평가)

  • 장규만
    • Membrane Journal
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    • v.9 no.4
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    • pp.221-229
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    • 1999
  • The nominal pore size 0.2 ${\mu}m polytetrafluroethylene(PTFE, Satorius Co,) membrane was used for the filtration of 0.1 wt% kaolin, bentonite, yeast, and starch solution, respectively. After filtration, the membrane was cleaned and the pore size was measured by liquid displacement method(LDMl using water/iso-butanol system. The pore size for new PTFE membrane evaluated by LDM was comparable with those of which were measured by mercury porosimetry and scanning electron microscope. The membrane pores were severely fouled, and constricted to below 0.3 ${\mu}m in the cases of bentonite and starch solution which contained smaller particles than pores. However, in the case of kaolin - solution, only some parts of membrane pores above 0.35 ${\mu}m were slightly fouled. Hence, the phenomena of membrane fouling could be identified quantitatively by the evaluation of pore size using LDM.

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