• 제목/요약/키워드: pore-filled

검색결과 134건 처리시간 0.025초

The Effect of Si3N4 Addition on Nitriding and Post-Sintering Behavior of Silicon Powder Mixtures

  • Park, Young-Jo;Ko, Jae-Woong;Lee, Jae-Wook;Kim, Hai-Doo
    • 한국세라믹학회지
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    • 제49권4호
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    • pp.363-368
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    • 2012
  • Nitriding and post-sintering behavior of powder mixture compacts were investigated. As mixture compacts are different from simple Si compacts, the fabrication of a sintered body with a mixture composition has engineering implications. In this research, in specimens without a pore former, the extent of nitridation increased with $Si_3N_4$ content, while the highest extent of nitridation was measured in $Si_3N_4$-free composition when a pore former was added. Large pores made from the thermal decomposition of the pore former collapsed, and they were filled with a reaction product, reaction-bonded silicon nitride (RBSN) in the $Si_3N_4$-free specimen. On the other hand, pores from the decomposed pore former were retained in the $Si_3N_4$-added specimen. Introduction of small $Si_3N_4$ particles ($d_{50}=0.3{\mu}m$) into a powder compact consisting of large silicon particles ($d_{50}=7{\mu}m$) promoted close packing in the green body compact, and resulted in a stable strut structure after decomposition of the pore former. The local packing density of the strut structure depends on silicon to $Si_3N_4$ size ratio and affected both nitriding reaction kinetics and microstructure in the post-sintered body.

Microstructure of Non-Sintered Inorganic Binder using Phosphogypsum and Waste Lime as Activator

  • Kim, Ji-Hoon;An, Yang-Jin;Mun, Kyung-Ju;Hyung, Won-Gil
    • 한국건축시공학회지
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    • 제18권3호
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    • pp.305-312
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    • 2018
  • This study is about the development of a non-sintered binder (NSB) which does not require a sintering process by using the industrial by-products Phosphogypsum (PG), Waste Lime (WL) and Granulated Blast Furnace Slag (GBFS). In this report, through SEM analysis of the NSB paste hardening body, micropore analysis of paste using the mercury press-in method and microstructure observation were executed to consider the influence of the formation of the pore structure and the distribution of pore volume on strength, and the following conclusions were reached. 1) Pore structure of NSB paste of early age is influenced by hydrate generation amount by GBFS and activator. 2) Through observing the internal microstructure of NSB binder paste, it was found that the strength expression at early age due to hydration reaction was achieved with a large amount of ettringite serving as the frame with C-S-H gel generated at the same time. It was confirmed that C-S-H gel wrapped around ettringite, and as time passed, the amount generated continually increased, and C-S-H gel tightly filled the pores of hardened paste, forming a dense network-type web structure. 3) For NSB-type cement, the degree of formation of gel pores below $10{\mu}m$ had a greater influence on strength improvement than simple pore reduction by charging capillary pores, and the pore size that had the greatest effect on strength was micropores with diameter below $10{\mu}m$.

Stability assessment of soil slopes in three dimensions: The effect of the width of failure and of tension crack

  • Pantelidis, Lysandros;Gravanis, Elias;Gkotsis, Konstantinos-Paraskevas
    • Geomechanics and Engineering
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    • 제22권4호
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    • pp.319-328
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    • 2020
  • This paper investigates the effect of the width of failure and tension crack (TC) on the stability of cohesive-frictional soil slopes in three dimensions. Working analytically, the slip surface and the tension crack are considered to have spheroid and cylindrical shape respectively, although the case of tension crack having planar, vertical surface is also discussed; the latter was found to return higher safety factor values. Because at the initiation of a purely rotational slide along a spheroid surface no shear forces develop inside the failure mass, the rigid body concept is conveniently used; in this respect, the validity of the rigid body concept is discussed, whilst it is supported by comparison examples. Stability tables are given for fully drained and fully saturated slopes without TC, with non-filled TC as well as with fully-filled TC. Among the main findings is that, the width of failure corresponding to the minimum safety factor value is not always infinite, but it is affected by the triggering factor for failure (e.g., water acting as pore pressures and/or as hydrostatic force in the TC). More specifically, it was found that, when a slope is near its limit equilibrium and under the influence of a triggering factor, the minimum safety factor value corresponds to a near spherical failure mechanism, even if the triggering factor (e.g., pore-water pressures) acts uniformly along the third dimension. Moreover, it was found that, the effect of tension crack is much greater when the stability of slopes is studied in three dimensions; indeed, safety factor values comparable to the 2D case are obtained.

이미다졸륨 고분자 코팅을 통한 음이온교환막의 물분해 특성 제어 (Controlling Water Splitting Characteristics of Anion-Exchange Membranes by Coating Imidazolium Polymer)

  • 김도형;박진수;강문성
    • 멤브레인
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    • 제25권2호
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    • pp.152-161
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    • 2015
  • 본 연구에서는 이온교환막을 이용한 전기화학적 수처리 공정의 효율을 향상시키기 위해 낮은 전기적 저항, 높은 이온선택 투과성, 및 농도분극 조건에서 낮은 물분해 플럭스 특성을 갖는 새로운 세공충진 음이온 교환막을 개발하였다. 다공성 폴리올레핀 기재에 이온교환능이 우수한 4급 암모늄기를 포함한 공중합 고분자를 충진하여 상용막 이상의 성능을 갖는 기저 멤브레인을 제조하였다. 또한 기저 막 표면에 이미다졸륨 고분자를 코팅하여 전기화학적 성능을 유지하며 동시에 물분해 플럭스를 효과적으로 제어할 수 있음을 확인하였다. 제조된 세공충진 음이온 교환막은 상용막 대비 약 1/6~1/8 수준의 매우 낮은 전기적 저항을 나타내었으며 동시에 농도분극 조건에서 양이온 교환막 수준의 낮은 물분해 플럭스를 나타내었다.

사질토양(砂質土壤)에서의 Zeolite 유실(流失) 가능성(可能性)의 추정(推定) (The Estimation of the Loss Possibility of Zeolite in Sandy Soil)

  • 강신정;최정
    • Applied Biological Chemistry
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    • 제29권3호
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    • pp.311-317
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    • 1986
  • 공극(孔隙)의 크기가 다른 sand column에서 Zeolite의 유실실험(流失實驗)을 하여 Zeolite의 이동로(移動路)가 되는 최소(最少) 공극(孔隙)크기를 추적한 다음 실제(實際) 포장(圃場)에서의 Zeolite 유실가능성(流失可能性) 및 유실(流失) 가능(可能) 입자(粒子)의 크기를 추정실험(推定實驗)한 결과(結果)는 다음과 같다. 1. Sand column별 Zeolite의 유실량(流失量)은 $2{\sim}1>1{\sim}0.5>0.5{\sim}0.25mm$ sand column 순으로 증가하였다. 2. $1{\sim}0.5,\;0.5{\sim}0.25mm$ sand column에서 유실(流失)된 Zeolite는 모두 $2{\mu}m$ 이하(以下)의 입자(粒子)였다. 3. Zeolite가 유실(流失)될 수 있는 공극(孔隙)의 크기는 $150{\mu}m$ 이상(以上) 이었고 장천토양(長川土壤)의 심토(心土)는 $2{\mu}m$ 이하(以下)의 Zeolite가 유실(流失)될 가능성(可能性)이 있는 것으로 추정(推定)되었다. 4. 사질토양(砂質土壤)에 시용(施用)될 Zeolite의 최적입도(最適粒度)는 $2{\mu}m$ 이상(以上)의 획분(劃分)으로 추정(推定)되었다.

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파랑으로 인한 불포화된 다층 해저지반의 거동;준해석적 방법 (Wave-Induced Response of Unsaturated and Multi-layered Seabed; A Semi-analytical Method)

  • 박종관
    • 한국지반공학회논문집
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    • 제15권6호
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    • pp.45-55
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    • 1999
  • 파랑에 의한 불포화된 해저지반의 거동, 액상화와 전단파괴에 대한 연구이다. 불포화된 지반은 유체가 채워진 다공성 탄성체로 모델화 하였다. 유체의 흐름과 토립자의 변형은 Biot의 이론에 따른 지배방정식으로 나타내었다. 이 방정식은 준해석적 방법으로 풀어 불포화된 다층의 지반에 대하여 응력과 간극수압을 평가하였다 준해석적 방법은 기존의 해석방법과 달리 다층의 이방성 지반을 연속적으로 해석할 수 있다. 해석결과에 의하면, 지반의 포화도는 불포화된 다층의 지반에서 응력과 간극수압의 크기에 가장 큰 영향을 미치고 있는 것으로 나타났다. 또한, 해석결과를 토대로 지반의 액상화 발생과 전단파괴에 대한 검토를 실시하였으며, 그 결과 최대 전단파괴가 발생된 깊이가 최대 액상화 발생지역 보다 깊은 것으로 나타났다.

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Pressure Loss and Enhancement of Heat Transfer in an Annulus Filled with Aluminum Foam

  • Noh, Joo-Suk;Han, Young-Hee;Lee, Kye-Bock;Lee, Chung-Gu
    • International Journal of Air-Conditioning and Refrigeration
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    • 제15권1호
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    • pp.17-24
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    • 2007
  • An experimental investigation was carried out for 4 different types of the aluminum foam heat sinks which were inserted into the annulus. The purpose of this study is to examine the feasibility of a heat sink with high performance forced convective water cooling in the annulus. The local wall temperature distribution, inlet and outlet pressures and temperatures, and heat transfer coefficients were measured for heat flux of 13.6, 18.9, 25.1, 31.4 $kW/m^2$ and Reynolds number ranged from 120 to 9,000. Experimental results show that the departure from the Darcy's law is evident from the pressure loss and the friction factor is much higher while the significant enhancement in Nusselt number is obtained, and average Nusselt number of aluminum foam with high pore density is much higher than that of aluminum foam with low pore density. Correlations for the friction factor is proposed and used for design of thermal applications.

비이온계 계면활성제 수용액에서 모직물의 표면적심과 액체보유력 향상 (Improvement of Liquid Wetting and Retention Properties of Wool Fabric in Nonionic Surfactant Solutions)

  • 김천희
    • 한국염색가공학회지
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    • 제21권2호
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    • pp.7-13
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    • 2009
  • The effects of 0.1g/dl nonionic surfactant solutions on liquid wetting and retention properties of wool fabric are reported. The 10 different nonionic surfactants (Span 20, Tween 20, 40, 60, 80, 21, 61, 81, 65, 85), wool cloth (EMPA 217), and wool soiled cloth (EMPA 107) are used in the study. Both EMPA 217 and 107 have water contact angle($\Theta$)>$90^{\circ}$, which indicates that water spreading over a fabric surface and penetration into the fabric rarely occur. However, EMPA 217 and 107 are easily wetted with perchloroethylene(PCE) having very low values of $\Theta$'s and high values of liquid retention. Water wetting properties are greatly improved by adding nonionic surfactants into the system. Generally, hydrophilic surfactants which have low number of carbon atoms or unsaturated hydrophobic structures are effective in improving water wetting of wool fabrics. The water retention of EMPA 217 and 107 in surfactant solutions have positive relations with $cos{\Theta}$, adhesion tension, and work of adhesion. 40.3% pore volume of EMPA 217 and 26.1% pore volume of EMPA 217 can be filled with water even when we assume $cos{\Theta}=1$ (${\Theta}=0^{\circ}$).

수종(數種) 치과(齒科) 수복용(修復用) 복합(複合)레진의 세포독성(細胞毒性)에 관(關)한 실험적(實驗的) 연구(硏究) (AN EXPERIMENTAL STUDY ON THE CYTOTOXICITY OF SEVERAL COMPOSITE RESINS)

  • 명제근;이명종
    • Restorative Dentistry and Endodontics
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    • 제14권1호
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    • pp.25-40
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    • 1989
  • This study was conducted to evaluate the influence of 5 microfilled composite resin to fibroblast cultivated from human pulp (age 13). Each composite resin was manually mixed and filled in cylinder. Resin filled cylinders were placed in dishes (35mm in diameter) containing 3 ml of ${\alpha}$-MEM. Filters (pore size 0.22 ${\mu}m$) to simulate dentin were also placed between the bottom of cylinder and the dish floor. Then stored in 5% $CO_2$ containing incubator for 1 and 2 weeks at the temperature 36.6 C. The results analysed after 1 and 2 weeks were as follows: 1. Experimental group except group 2, 2 weeks incubation cases showed the cytotoxicity compared to the control group in cell count. 2. After 2 week-incubation of group 1 and group 4, cell count was more decreased than 1 week cases and cytotoxicity seemed to be constantly influenced to the cell multiplication. 3. The cell growth rate of 1 week incubation in group 3 and group 5 was similar to the control group and recognized the cytotoxicities of these groups were mild. 4. The cell multiplication rate of 2 week incubation cases in group 2 was greater than control group.

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계측관리를 통한 방조제 바닥보호공의 침투거동분석 (Analysis of Seepage Behavior of Bottom Protection Layer by Filed Monitoring)

  • 강병윤;오영인;김기년;김현태
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2008년도 추계 학술발표회
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    • pp.806-813
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    • 2008
  • In this research, mainly research about the structural and functional stability of sea dyke with variation of seepage condition after final closure. The piezometric head (water head in embankment) monitoring system was installed at two representative final closure section. The dredged fine sand filling condition was evaluated by in-situ test results. Also, the numerical analysis was performed to determine the permeability of bottom protection layer filled with dredged fine sand by monitoring results. According to numerical back analysis results, the coefficient of permeability of bottom protection section of is $7.6{\times}10^{-6}$ m/sec. These results are noted that the bottom protection layer of sea dyke was strong and intensively filled with dredged sand. Also, based on the seepage analysis, the seepage flux of this sea dyke was calculated about $2.42m^3$/day/m which is 29% decreased value compare with adjacent sea dyke.

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