• Title/Summary/Keyword: pore water salinity

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Changes in Methane Production in Coastal Mud Flat under Different Temperature and Salinity (온도 증가와 염도 감소에 따른 갯벌토양에서 메탄발생량의 변화)

  • Kim, Young Joo;Jung, Soo Hyun;Kang, Ho jeong
    • Journal of Wetlands Research
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    • v.8 no.4
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    • pp.41-47
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    • 2006
  • Global climatic changes are expected to influence various biogeochemical processes in wetland ecosystems. In particular, coastal mud flat is anticipated to be affected directly by temperature increase as well as indirectly by a sea level rise and changes in precipitation. This study aimed to determine changes in methane production under different temperature and salinity by employing a laboratory-scale manipulation experiment. Soil samples were collected from a mud flat in Dong-Gum Kang-Hwa island in winter and two types of experiments were conducted. In the first experiment soil samples at 0-5 cm, 5-10 cm depth were incubated under same salinity with pore water and diluted salinity to 50 % of natural condition for 20 days and methane production was measured every other days. In the second experiment, soil samples at 5-10 cm depth were incubated in different temperature, $5^{\circ}C$ and $15^{\circ}C$, under same salinity conditions with first experiment for 31 days and methane production was measured. Results of the first experiment revealed that higher amount of methane was produced at 5-10 cm depth, and salinity effect was predominant at the end of the experiment. The second experiment showed that methane production was higher in $15^{\circ}C$ than $5^{\circ}C$. In addition, methane production was higher when sea water diluted to 50 % compared to control. Global climatic changes are expected to influence various biogeochemical processes in wetland ecosystems. In particular, coastal mud flat is anticipated to be affected directly by temperature increase as well as indirectly by a sea level rise and changes in precipitation. This study aimed to determine changes in methane production under different temperature and salinity by employing a laboratory-scale manipulation experiment. Soil samples were collected from a mud flat in Dong-Gum Kang-Hwa island in winter and two types of experiments were conducted. In the first experiment soil samples at 0-5 cm, 5-10 cm depth were incubated under same salinity with pore water and diluted salinity to 50 % of natural condition for 20 days and methane production was measured every other days. In the second experiment, soil samples at 5-10 cm depth were incubated in different temperature, $5^{\circ}C$ and $15^{\circ}C$, under same salinity conditions with first experiment for 31 days and methane production was measured. Results of the first experiment revealed that higher amount of methane was produced at 5-10 cm depth, and salinity effect was predominant at the end of the experiment. The second experiment showed that methane production was higher in $15^{\circ}C$ than $5^{\circ}C$. In addition, methane production was higher when sea water diluted to 50 % compared to control. These results suggest that methane production is highly influenced by changes in temperature and salinity in coastal mud flat. And that global climatic change may induce biological feedback by affecting production of another greenhouse gas, namely methane from coastal mud flat.

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Influencing factors on electrical conductivity of compacted kaolin clay

  • Lee, J.K.;Shang, J.Q.
    • Geomechanics and Engineering
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    • v.3 no.2
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    • pp.131-151
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    • 2011
  • The electrical conductivity of a soil-water system is related to its engineering properties. By measuring the soil electrical conductivity, one may obtain quantitative, semi-quantitative, or qualitative information to estimate the in-situ soil behavior for site characterization. This paper presents the results of electrical conductivity measured on compacted kaolin clay samples using a circular two-electrode cell in conjunction with a specially designed compaction apparatus, which has the advantage of reducing errors due to sample handling and increasing measurement accuracy. The experimental results are analyzed to observe the effects of various parameters on soil electrical conductivity, i.e. porosity, unit weight, water content and pore water salinity. The performance of existing analytical models for predicting the electrical conductivity of saturated and unsaturated soils is evaluated by calculating empirical constants in these models. It is found that the Rhoades model gives the best fit for the kaolin clay investigated. Two general relationships between the formation factor and soil porosity are established based on the experimental data reported in the literature and measured from this study for saturated soils, which may provide insight for understanding electrical conduction characteristics of soils over a wide range of porosity.

Salt Removal in a Reclaimed Tidal Land Soil with Gypsum, Compost, and Phosphate Amendment

  • Lee, Jeong-Eun;Seo, Dong-Hyuk;Yun, Seok-In
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.5
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    • pp.326-331
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    • 2015
  • High salinity and sodicity of soils play a negative role in producing crops in reclaimed tidal lands. To evaluate the effects of soil ameliorants on salt removal in a highly saline and sodic soil of reclaimed tidal land, we conducted a column experiment with treating gypsum, compost, and phosphate at 0-2 cm depth and measured the salt concentration of leachate and soil. Electrical conductivity of leachate was $45-48dSm^{-1}$ at 1 pore volume (PV) of water and decreased to less than $3dSm^{-1}$ at 3 PV of water. Gypsum significantly decreased SAR (sodium adsorption ratio) of leachate below 3 at 3 PV of water and soil ESP (exchangeable sodium percentage) below 3% for the whole profile of soil column. Compost significantly decreased ESP of soil at 0-5 cm depth to 5% compared with the control (20%). However, compost affected little the composition of cations below a depth of 5 cm and in leachate compared with control treatment. It was concluded that gypsum was effective in ameliorating reclaimed tidal lands at and below a soil layer receiving gypsum while compost worked only at a soil layer where compost was treated.

Development and Application of Micromodel for Visualization of Supercritical CO2 Migration in Pore-scale (공극 규모에서의 초임계상 이산화탄소 거동 가시화를 위한 마이크로모델의 개발과 적용)

  • Park, Bogyeong;Lee, Minhee;Wang, Sookyun
    • Journal of Soil and Groundwater Environment
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    • v.20 no.4
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    • pp.73-82
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    • 2015
  • Despite significant effects on macroscopic migration and distribution of CO2 injected during geological sequestration, only limited information is available on wettability in microscopic scCO2-brine-mineral systems due to difficulties in pore-scale observation. In this study, a micromodel had been developed to improve our understanding of how scCO2 flooding and residual characteristics of porewater are affected by the wettability in scCO2-water-glass bead systems. The micromodel (a transparent pore structure made of glass beads and glass plates) in a pressurized chamber provided the opportunity to visualize scCO2 spreading and porewater displacement. CO2 flooding followed by fingering migration and dewatering followed by formation of residual water were observed through an imaging system. Measurement of contact angles of residual porewater in micromodels were conducted to estimate wettability in a scCO2-water-glass bead system. The measurement revealed that the brine-3M NaCl solution-is a wetting fluid and the surface of glass beads is water-wet. It is also found that the contact angle at equilibrium decreases as the pressure decreases, whereas it increases as the salinity increases. Such changes in wettability may significantly affect the patterns of scCO2 migration and porewater residence during the process of CO2 injection into a saline aquifer at high pressures.

Utilization of induced polarization for predicting ground condition ahead of tunnel face in subsea tunnelling: laboratory test (유도분극을 활용한 해저터널 굴착면 전방 지반상태 예측: 실내실험)

  • Park, Jinho;Lee, Kang-Hyun;Lee, Seong-Won;Ryu, Young-Moo;Lee, In-Mo
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.17 no.3
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    • pp.383-392
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    • 2015
  • In subsea tunnelling, prediction of the fractured zone (or water bearing zone) ahead of tunnel face saturated by seawater with high water pressure has been a key factor for safe construction. This study verified the feasibility of utilizing induced polarization (IP) survey at tunnel face for predicting the ground condition ahead of the subsea tunnel face. A pore model was proposed to compute chargeability in granular material, and the relationship correlating chargeability with the variables affecting the chargeability was derived from the model. Parametric study has been performed on the variables to figure out the most influential factors affecting the chargeability. The results of the parametric study show that the size of narrow pores ($r_1$) and the salinity of pore water are the most influential factors on chargeability. Laboratory tests were conducted on various types of ground condition by changing the salinity of pore water, the thickness of the fracture zone and the existence of gouge (weathered granite) within the joints of the fractured zone to figure out the effect of the ground characteristics on the IP phenomenon. Test results show that the chargeability of the fractured zone saturated by seawater increases if the joints in the fractured zone are filled with gouge since the infilled gouge will decrease the size of narrow pores ($r_1$).

Utilization of Induced Polarization and Electrical Resistivity for Identifying Rock Condition (유도분극 전하 충전성과 전기비저항을 활용한 암반 상태 파악 가능성 연구)

  • Park, Jinho;Ryu, Jinwoo;Jung, Jeehee;Lee, In-Mo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.36 no.3
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    • pp.493-502
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    • 2016
  • This study examines how rock condition affects the variation of the chargeability and electrical resistivity of the rock. In the theoretical study, the relationship correlating chargeability with the variables affecting it is derived. A parametric study utilizing the derived relationship reveals that the size of narrow pores ($r_1$) is the most influential factor on chargeability, and the salinity of pore water ($C_0$) is the second. In the laboratory experiments, small scale rock fracturing zone is modelled using sand stone. Chargeability and resistivity are measured by changing the size of the joint aperture, the location of fractured zone and the existence of clay gouge and/or clay layer which shows lower chargeability than the sand stone layer in the multi-layered ground. Test results show that chargeability is controlled not by the rock fracturing condition but by the size of narrow pore ($r_1$) where each line of current flow passes through. Also, the chargeability decreases with increase of the pore water salinity ($C_0$). In conclusion, the ground condition can be identified more efficiently by measuring the induced polarization along with the electrical resistivity; identifying the existence of sea water, the layered ground and/or the fractured rock becomes more reliable.

Application of the Electrical Impedance of Rocks in Characterizing Pore Geometry (암석 내 공극구조의 평가를 위한 전기임피던스의 적용)

  • Choo, Min-Kyoung;Song, In-Sun;Lee, Hi-Kweon;Kim, Tae-Hee;Chang, Chan-Dong
    • The Journal of Engineering Geology
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    • v.21 no.4
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    • pp.323-336
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    • 2011
  • The hydro-mechanical behavior of the Earth's crust is strongly dependent on the fractional volume and geometrical structure of effective pore spaces. This study aims to understand the characteristics of pores using electrical impedance. We measured the electric impedance of core samples (diameter, 38-50 mm; length, 70-100 mm) of three types of granite (Hwangdeung, Pocheon, and Yangsan) and two types of sandstone (Boryung and Berea) with different porosities and pore structures, after saturation with saline water of varying salinities. The results show that resistance decreases but capacitance increases with increasing salinity of the pore fluid. For a given salinity, the resistivity and formation factor are reduced with increasing porosity of the rocks, and the capacitance increases. Berea sandstone shows anisotropy in resistance, tortuosity, and cementation factor, with these factors being highest normal to bedding planes. This result indicates that the connectivity of pores is weakest normal to bedding. In conclusion, the electrical characteristics of the tested samples are related not only to their porosity but also to the pore geometry.

Effects of Heavy Metal and Salinity on Electrical Conductivity in Fully Saturated Sand (포화된 사질토의 전기전도도에 중금속과 염분 농도가 미치는 영향)

  • Lee, Dongsoo;Hong, Young-Ho;Hong, Won-Teak;Chae, Kwang-Seok;Lee, Jong-Sub
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.10
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    • pp.23-34
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    • 2017
  • As the electrical property of fully saturated soils is dependent on the pore water, it has been commonly used for the detection of the contamination into the ground. The objective of this study is to investigate the electrical characteristics according to the salinity and the lead concentration in fully saturated soils. Fresh water and saline water with the salinity of 1%, 2% and 3%, which are mixed with 6 different lead solutions with the range of 0~10 mg/L, are prepared in the cylindrical cell incorporated with sensors for measuring electrical resistance and time domain reflectometry signal. Then, the dried sands are water-pluviated into the cell. The electrical resistance and the time domain reflectometry signal are used to estimate the electrical conductivity. Test results show that electrical conductivity determined from electrical resistance at the frequency of 1 kHz continuously increases with an increase in the lead concentration, thus it may be used for the estimation of the contaminant level. In addition, the electrical conductivity estimated by the time domain reflectometry changes even at very low concentration of lead, the variation rate decreases as the lead concentration increases. Thus, the time domain reflectometry can be used for the investigation of the heavy metal leakage. This study demonstrates that complementary characteristics of electrical resistance and time domain reflectometry may be used for the detection of the leakage and contamination of heavy metal in coastal and marine environments.

Salinity Effects on the Hydraulic Conductivity of Uplands (밭토양(土壌)의 수리전도도(水理伝導度)에 대(対)한 염류효과(塩類効果))

  • Park, Chang-Seo;O'Connor, George A.
    • Korean Journal of Soil Science and Fertilizer
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    • v.16 no.1
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    • pp.7-13
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    • 1983
  • Laboratory determinations of saturated hydraulic conductivity were conducted with four soils varying in texture from sand to clay and with five waters with different salinity level. The waters varied in total dissolved solids from 1,250 to $15,000mg/{\ell}$ and in SAR from 16 to 57 and were representative of saline waters in New Mexico. Saturated hydraulic conductivities of the soils were not significantly affected by water salinity if these waters were the sole source of irrigation water. However, small additions of distilled water, assuming simulated to rain, to soils previously equilibrated with the saline waters significantly decreased soil permeability. Dispersion and short or long-distance transport of clay apparently clogged conducting pores when distilled water was introduced. Swelling was an important mechanism in reducing soil permeability only in the clay soil. The data suggest that, when saline water is the dominant irrigation source and is supplemented by rain, (1) all saline waters could be used on very sandy soils, (2) no saline waters should be used on very heavy soils, and (3) slightly saline, but not very saline, waters could be used on medium-textured soils.

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Effect of the Fate Mechanisms of Phenol on the Remediation Efficiency of In-Situ Capping Applied to Sediment Contaminated by Phenol Chemical Spills (페놀 화학사고 발생으로 오염된 퇴적물에서 페놀의 거동 기작이 원위치 피복의 정화 효율에 미치는 영향)

  • Lee, Aleum;Choi, Yongju
    • Journal of Soil and Groundwater Environment
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    • v.27 no.1
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    • pp.60-70
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    • 2022
  • We evaluated the performance of in-situ capping to prevent the release of phenol, one of hazardous chemicals of concern for their impact on sediment. Sediment near the estuary of Hyeongsan River, Korea, and commercially-available sand were collected to evaluate their physical properties and phenol sorption characteristics. Biodegradation kinetics of phenol spiked into the sediment was evaluated under freshwater and estuarine salinity conditions. These experimental measurements were parameterized and used as input parameters for executing CapSim, a software predicting the performance of in-situ capping. The CapSim simulation demonstrated that capping with 50-cm sand reduced the phenol release by several orders of magnitude over 0.25- and 1-year duration for almost all simulation scenarios. The variables tested, i.e., cap thickness, pore-water movement, and biodegradation rate, showed high correlation to each other to influence the extent of phenol release from sediment to the water column. The findings and the framework employed to evaluate the performance of in-situ capping in this study can be adopted to determine whether in-situ capping is appropriate remedial approach at sediment sites impacted by hazardous chemicals due to accidental spills.