• 제목/요약/키워드: pore size distributions

검색결과 48건 처리시간 0.021초

시공조건이 시멘트계 고화토의 투수계수에 미치는 영향 (Effects of Some Construction Variables on the Hydraulic Conductivity of Soil-Cement in Low Permeable Applications)

  • 정문경;김강석;우제윤
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2000년도 가을 학술발표회 논문집
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    • pp.427-434
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    • 2000
  • Hydraulic conductivity of soil-cement was measured as a function of some selected construction variables that are often encountered in practice. They are initial (or compaction) water content, delayed compaction after mixing, and repeated freezing and thawing. Sandy and clayey soils were used. The hardening agent used was a cement based soil stabilizer consisting of 80% of ordinary Portland cement and 20% of a combination of supplementary materials. Hydraulic conductivity of soil-cement with varying initial water content was, in trend, similar to that of compacted clay. Hydraulic conductivity of soil-cement decreased with increasing initial water content and reached its minimum when compacted wet of optimum water content. Pore size distributions of soil cement at different initial water contents were analyzed using mercury intrusion porosimetry. The analysis showed that dryer condition led to the formation of larger pores with lesser total pore volume; smaller pores with larger total pore volume at wetter condition. Hydraulic conductivity of soil-cement increased by orders in magnitude when specimen underwent delayed compaction of longer than 4 hours after mixing and repeated freezing and thawing.

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A study on Production of Al Foam by Using of Al Return Scrap for Sound and Vibration Absorption Materials

  • Hur, Bo-Young;Kim, Sang-Youl;Park, Dae-Chol;Jeon, Sung-Hwan;Park, Chan-Ho;Yoon, Ik-Sub
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.198-201
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    • 2001
  • Porous structures of aluminum foam have been studied by using return aluminum scrap. The apparent foam shape, foam height, density, pore size and their distributions in various section areas of the experimental samples have been investigated. The sample have been cast into metallic mold, using aluminum foam prepared from a precursor based on pure Al ingot and return aluminum scrap mixed with various amounts of 1-2wt% increasing viscosity and foam agent materials. The process provides for flexibility in design of foam structures via relatively easy control over the amount of hydrogen evolution and the drainage processes which occur during foam formation. This is facilitated by manipulating parameters such as the foaming agent, thermal histories during solidification and mix melt viscosities. A metal for producing the foamed are decomposing a foaming agent in a molten metal such that there is an initial and a subsequent expansion due to foaming agent. It has been found that the Al porous foaming with variation amount of 1∼2wt% foam agent and at 2min holding time, which melting temperature has appeared homogeneous pore size at 650∼700$^{\circ}C$. The compression strength were 10-13 kg/min at 125ppi, and increased by higher pore density. The acoustical performance of the panel made with the foamed aluminum is considerably improved; its absorption coefficient shows NRC 0.6-0.8. It has been found that the Al foam is very preferable for the compactness of the thermal system.

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Rejection Properties of Silica Nanoparticles from Ultrafiltration Membranes

  • Hiromitsu Takaba;Yoshiaki Ito;Nakao, Shin-ichi
    • Korean Membrane Journal
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    • 제5권1호
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    • pp.54-60
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    • 2003
  • The rejection properties and flux rates of silica nanoparticles in ultrafiltration membranes has been investigated. Cross-flow permeation experiments were conducted using polycarbonate track-etch flat membranes with pore sizes of 30 and 50 nm, and a silica nanoparticle solute with particle sizes of 5 and 18 nm with narrow size distributions. The fluxes and rejection factors were investigated at various particle concentrations, cross-flow velocities, pH, and ionic strengths of solution. Even though the size of the silica nanoparticles was much smaller than that of the membrane pores, the observed rejection rates were very high compared with those for a similar-sized polymer (dextran). The observed rejection rate decreased with increasing ionic strength, which implies that the transport mechanism of the silica nanoparticles is significantly influenced by electrostatic repulsion between particles and membranes.

국부분자배향의 탄소 미세기공 구조에 대한 질소의 흡착 특성 (Adsorption Characteristics of Nitrogen in Carbonaceous Micropore Structures with Local Molecular Orientation)

  • 서양곤
    • 청정기술
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    • 제28권3호
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    • pp.249-257
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    • 2022
  • Grand canonical Monte Carlo 전산모사 방법에 의하여 77.16 K에서 국부분자배향 모델을 가지는 나노 기공 탄소 흡착제에 대한 질소의 평형 흡착량을 계산하였다. 국부분자배향 모델은 일정한 공간을 가지는 규칙적인 격자에 동일한 크기를 배열하였다. 국부분자배향 영역의 연속적인 평면의 직교(out-of-plane)의 제거에 의해 미세기공을 도입하였고, 기본구조단위의 기울임을 통해 기울어진 기공을 도입하였다. 이런 기공 구조는 틈새형 기공 구조보다 나노기공을 가지는 탄소계 흡착제의 흡착 연구에 보다 현실적인 모델이 된다. 또한 이들 기공 구조에 대해 기공도, 표면적 그리고 제한된 비선형 최적화 기법을 활용하여 기공크기분포에 구하였다. 또한 참고 자료로써 틈새형 기공에서의 등온 평형흡착량도 계산하였다. 틈새형 기공에서는 질소분자의 5배 이상의 기공에서 hysteresis 루프가 관찰되었고, 모세관 응축과 응축의 역과정인 증발이 한 압력에서 한 번에 일어났다. 국부분자배향 기공모델에서는 질소분자의 크기의 6배 큰 기공에서 기저 슬립면, armchair 슬립면 그리고 상호연결된 채널에서 각각 세 가지 연속적인 응축이 관찰되었다. 탈착 과정의 hysteresis 루프에서는 단일 또는 두 압력에서 응축의 반대인 증발이 관찰되었다.

함침계 표면보호제에 의한 콘크리트 표면의 세공구조 변화 및 내구성 향상 (Improvement of Durability and Change of Pore Structure for Concrete Surface by the Penetrative Surface Protection Agent)

  • 강석표;김정환
    • 콘크리트학회논문집
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    • 제18권1호
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    • pp.125-132
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    • 2006
  • 최근 들어 툭별한 물리적 방법을 사용하지 않고 내구성능이 저하된 콘크리트의 성능을 회복시키는 방법의 일환으로서 콘크리트 표면보호재에 대한 관심이 높아지고 있다. 표면보호는 직접적인 의미로서는 콘크리트 구조물의 표면을 보호하는 것뿐만아니라 다양한 열화요인의 침투를 억제함으로서 내부의 콘크리트 및 철근의 열화를 억제하여 콘크리트 구조물을 보호하게 된다. 이와 같은 표면보호재 중 함침계 표면보호재는 콘크리트 표면층의 공극에 충전 혹은 생성물을 석출시켜 치밀한 층으로 하느 충전계와 콘크리트 표면층의 외부 및 내부표면의 성질을 개선하는 표면계로 분류하는 것이 가능하다. 따라서 본 연구는 규플르오르화염을 주성분으로 하는 표면형 함침계 표면보호제 도포에 의한 콘크리트 표면의 세공구조의 변화 및 중성화, 염해, 화학적 침식 등의 내구성 향상을 실험실증적으로 검토함으로서 콘크리트 구조물의 내구성향상 방안을 제시하고자 한다. 그 결과, 표면보호제를 도포함으로서 모든 물시멘트비에서 도포전과 비교하여 전세공용적이 감소하고 있으며, 특히 50nm이상의 비교적 큰 세공경인 모세관공극의 용적이 감소함으로서 물흡수성, 중성화 저항성, 내황산성, 염소이온침투 저항성 등의 내구성 향상에 기여하는 것으로 나타났으며, 그 효과는 물시멘트비가 클수록 높게 나타났다.

전기선 폭발법에 의하여 제조된 Al-Ni 합금 나노분말의 선택적 침출 (The Selective Leaching of Al-Ni Alloy Nano Powders Prepared by Electrical Wire Explosion)

  • 박제신;김원백;서창열;장한권;안종관;김병규
    • 한국분말재료학회지
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    • 제15권4호
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    • pp.308-313
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    • 2008
  • Al-Ni alloy nano powders have been produced by the electrical explosion of Ni-plated Al wire. The porous nano particles were prepared by leaching for Al-Ni alloy nano powders in 20wt% NaOH aqueous solution. The structural properties of leached porous nano powder were investigated by nitrogen physisorption, X-ray diffraction (XRD) and transmission Microscope (TEM). The surface areas of the leached powders were increased with amounts of AI in alloys. The pore size distributions of these powders were exhibited maxima at range of pore diameters 3.0 to 3.5 nm from the desorption isotherm. The maximum values of those were decreased with amounts of Al in alloys.

Experimental study on treatment of waste slurry by vacuum preloading with different conditioning agents

  • Wu, Yajun;Jiang, Haibo;Lu, Yitian;Sun, Dean
    • Geomechanics and Engineering
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    • 제17권6호
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    • pp.543-551
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    • 2019
  • In China, serious environmental problems are induced by the extremely soft construction waste slurries in many urban areas, and there is no appropriate method to treat it presently. In this paper, four model tests were conducted to investigate the efficiency of waste slurry treatment by combining three conditioning agents which can change characteristics of the slurries with a traditional vacuum preloading method. The tests of size analysis of particle aggregate were conducted to investigate the influence of different conditioning agents on the size distributions of particle aggregate. During the model test, the discharged water volumes were monitored. The pore-size distribution and void ratio of the waste slurries after the vacuum preloading were measured by mercury intrusion porosimetry (MIP). It is found that 1) During the natural precipitation, volume of water out of the organic agent is higher than that of the mixed agent, but it is smaller than that of the mixed agent in the vacuum preloading stage; 2) the mixed agent has a higher total volume of water out than the organic agent and the inorganic agent after test, while the organic agent and the inorganic agent have little difference with respect to the drainage effect. The results demonstrate that the combination of mixed conditioning agent and vacuum preloading for the solid-liquid separation in waste slurry has a satisfactory effect and can be applied in engineering practice.

화상분석기를 이용한 경화콘크리트의 기포분포분석에 관한 기초적 연구 (Image Analysis of an Air-Void System in hardened concrete)

  • 김기철;정재동
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1997년도 가을 학술발표회 논문집
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    • pp.313-318
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    • 1997
  • Air voids existed in hardened concrete have an important influence on concrete deterioration such as carbonation, freezing and thawing, and corrosion of embedded steel in concrete. Therefore it is very significant to investigate the pore structure of system (size, number and continuity of air voids) to solve the reason caused concrete deterioration. The purpose of this study is to develop th standard method of measuring air voids which affect properties in hardened concrete using image analyzing system. This paper presents the settlement of rapid and exact experimental method which extracts fine bubbles, calculates the number of air voids, and determines air-voids distributions using image analyzing system with computer.

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Nonlocal strain gradient thermal vibration analysis of double-coupled metal foam plate system with uniform and non-uniform porosities

  • Fenjan, Raad M.;Ahmed, Ridha A.;Alasadi, Abbas A.;Faleh, Nadhim M.
    • Coupled systems mechanics
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    • 제8권3호
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    • pp.247-257
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    • 2019
  • Fee vibrational characteristics of porous steel double-coupled nanoplate system in thermo-elastic medium is studied via a refined plate model. Different pore dispersions called uniform, symmetric and asymmetric have been defined. Nonlocal strain gradient theory (NSGT) containing two scale parameters has been adopted to stablish size-dependent modeling of the system. Hamilton's principle has been adopted to stablish the governing equations. Obtained results from Galerkin's method are verified with those provided in the literature. The effects of nonlocal parameter, strain gradient, foundation parameters, porosity distributions and porosity coefficient on vibration frequencies of metal foam nanoscale plates have been examined.

Experimental study on vacuum preloading with flocculation for solid-liquid separation in waste slurry

  • Wu, Yajun;Kong, Gangqiang;Lu, Yitian;Sun, De'an
    • Geomechanics and Engineering
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    • 제13권2호
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    • pp.319-331
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    • 2017
  • This vacuum preloading combined with polyacrylamide (PAM) flocculation was proposed to separating solid-liquid in waste slurry and to improving bearing capacity of soft soil ground. By using waste slurry taken from drilled shaft construction site in Shanghai, China, a series of settling column tests with four typical flocculants and one normal for waste slurry were carried out for comparative analysis. The optimal amounts for each flocculant were obtained from the column tests. Then, model tests on vacuum preloading with anionic polyacrylamide (APAM) flocculation and without flocculants were carried out. The out of water and the settlement of slurry surface ground were monitored during the model tests, and the changes in water content, particle-size and pore-size distributions in different positions after the model tests were measured and discussed. It is found that water content of the waste slurry without APAM flocculation changed from 204 to 195% by 24 hours standing and 15 hours vacuum preloading, while the water content of the waste slurry with APAM flocculation was declined from 163 to 96% by 24 hours standing, and was further reduced into 37% by 136 hours vacuum preloading, which shows that the combined method is feasible and effective.