• 제목/요약/키워드: pore size distributions

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Mapping Particle Size Distributions into Predictions of Properties for Powder Metal Compacts

  • German, Randall M.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.704-705
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    • 2006
  • Discrete element analysis is used to map various log-normal particle size distributions into measures of the in-sphere pore size distribution. Combinations evaluated range from monosized spheres to include bimodal mixtures and various log-normal distributions. The latter proves most useful in providing a mapping of one distribution into the other (knowing the particle size distribution we want to predict the pore size distribution). Such metrics show predictions where the presence of large pores is anticipated that need to be avoided to ensure high sintered properties.

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폴리에테르술폰 정밀여과막의 제조 및 특성 연구 (Preparation and Characteristics of Polyethersulfone Microfiltration Membranes)

  • 김노원
    • 멤브레인
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    • 제17권4호
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    • pp.329-337
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    • 2007
  • 본 연구에서는 p-toluenesulfonic acid (TSA)와 polyvinylpyrrolidone (PVP)를 함유한 polyethersulfone (PES) 고분자 용액을 이용하여 PES 멤브레인 내에 최소 공경을 갖는 내부 분리층을 만드는 방법에 관한 새로운 방법을 제시하고자 한다. 팽윤제로 사용된 PVP와 응고제로 사용된 TSA를 함유한 평막형 PES 멤브레인의 제조 및 구조적인 특성 조사가 수행되었으며, 상업용 막에 대등할 만한 투과 성능과 좁은 pore size distribution을 가지는 멤브레인을 제조할 수 있음을 확인하였다. 또한 PVP의 첨가는 멤브레인의 단면구조와 투과 성능에, TSA는 투과 성능보다는 pore size distribution에 영향을 준다는 것을 확인하였으며 이는 FE-SEM 결과와 TSA를 첨가한 멤브레인의 단면 사진에서 내부 최소 기공층의 두께가 두꺼워짐을 확인할 수 있었다.

A model to characterize the effect of particle size of fly ash on the mechanical properties of concrete by the grey multiple linear regression

  • Cui, Yunpeng;Liu, Jun;Wang, Licheng;Liu, Runqing;Pang, Bo
    • Computers and Concrete
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    • 제26권2호
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    • pp.175-183
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    • 2020
  • Fly ash has become an important component of concrete as supplementary cementitious material with the development of concrete technology. To make use of fly ash efficiently, four types of fly ash with particle size distributions that are in conformity with four functions, namely, S.Tsivilis, Andersen, Normal and F distribution, respectively, were prepared. The four particle size distributions as functions of the strength and pore structure of concrete were thereafter constructed and investigated. The results showed that the compressive and flexural strength of concrete with the fly ash that conforming to S.Tsivilis, Normal, F distribution increased by 5-10 MPa and 1-2 MPa, respectively, compared to the reference sample at 28 d. The pore structure of the concrete was improved, in which the total porosity of concrete decreased by 2-5% at 28 d. With regarding to the fly ash with Andersen distribution, it was however not conducive to the strength development of concrete. Regression model based on the grey multiple linear regression theory was proved to be efficient to predict the strength of concrete, according to the characteristic parameters of particle size and pore structure of the fly ash.

Effect of Processing and Reactive Dyeing on Swelling and Pore Structure of Lyocell Fibers

  • Sasaki, Hiroaki;Donkai, Nobuo;Kasahara, Katusji
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.33-34
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    • 2003
  • Lyocell yarns were treated with NaOH, liquid ammonia, high pressure steam and polycarboxylic acids, and dyed with five reactive dyes. The water content of the samples was also measured by the centrifugal and chromatographic techniques. The total pore volume w as substantially increased by NaOH treatment, while decreased by high pressure steaming. The pore size distributions for the dyed samples were affected by the dyes used.

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Identification and Three-Dimensional Characterization of Micropore Networks Developed in Granite using Micro-Focus X-ray CT

  • Choo, Chang-Oh;Takahashi, Manabu;Jeong, Gyo-Cheol
    • 지질공학
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    • 제24권2호
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    • pp.179-189
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    • 2014
  • We analyzed the three-dimensional distribution of micropores and internal structures in both fresh and weathered granite using micro-focus X-ray computed tomography (micro-CT). Results show that the pore radius in fresh granite is mostly in the range of $17-50{\mu}m$, the throat radius is in the range of $5-25{\mu}m$, and the coordination number (CN) of pores is less than 10. In contrast, the pore radius in weathered granite is mostly in the range of $20-80{\mu}m$, the throat radius is in the range of $8-30{\mu}m$, and the CN is less than 12. In general, a positive linear relationship exists between pore radius and CN. In addition, both the size and the density of pores increase with an increasing degree of rock weathering. The size of the throats that connect the pores also increases with an increasing degree of weathering, which induces fracture propagation in rocks. Micro-CT is a powerful and versatile approach for investigating the three-dimensional distributions of pores and fracture structures in rocks, and for quantitatively assessing the degree of pore connectivity.

EDLC 전극용 카본에어로젤의 합성조건에 따른 기공구조 및 전기화학적 특성 (Pore Structure and Electrochemical Properties of Carbon Aerogels as an EDLC-Electrode with Different Preparation Conditions)

  • 서혜인;정지철;김명수
    • 한국재료학회지
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    • 제28권1호
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    • pp.50-61
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    • 2018
  • Various carbon aerogels (CAs) were prepared from polymerization of resorcinol and formaldehyde and applied as the electrode materials of an electric double layer capacitor (EDLC) with the aim of controlling the textural and electrochemical properties of CAs by the type of base catalyst and the ratio of resorcinol to catalyst (R/C). The CAs from $NaHCO_3$ and $KHCO_3$ with $H^+$ ions had higher specific surface areas but exhibited lower electrochemical properties than those from $K_2CO_3$ and $Na_2CO_3$, which had more uniform pore size distributions. The electrochemical properties of $Na_2CO_3$ were superior to those of $K_2CO_3$ probably because the polarizing power of $Na^+$ ions was higher than $K^+$ ions. With an increasing R/C ratio, the pore sizes of CA showed a tendency to increase but the uniformity of the pore size distribution got worse. For the four base catalysts, the highest electrochemical property was obtained at the R/C ratio of 500.

포졸란재 함유 콘크리트의 세공구조와 염화물이온 침투 저항성 (Resistance In Chloride ion Penetration and Pore Structure of Concrete Containing Pozzolanic Admixtures)

  • 소양섭;소형석
    • 콘크리트학회논문집
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    • 제14권1호
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    • pp.100-109
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    • 2002
  • 본 연구에서는 콘크리트의 염화물이온 침투 저항성에 미치는 포졸란재의 사용 효과를 평가하고자 물-결합재비와 혼화재의 종류 및 치환율, 양생기간을 변수로 제작된 각 콘크리트에 대해 세공용적, 염화물이온 투과성, 10% 염화나트륨용액 침지실험을 실시하여 보통콘크리트와 비교ㆍ분석하였으며 염화물이온 투과성과 세공구조 및 염화물이온 침투깊이의 상호관계를 검토하였다. 연구결과, 포졸란재의 사용은 콘크리트 내 세공들의 전체용적의 감소보다 모세관공극(50nm이상) 용적의 큰 감소에 더욱 효과적이었으며 이러한 효과로부터 포졸란 함유 콘크리트의 염화물이온 침투 저항성은 동일 배합의 보통콘크리트보다 매우 우수하게 나타났다. 콘크리트의 염화물이온 투과성은 콘크리트의 전세공용적에 관련하고 있지만 상관계수가 낮았으며 오히려 침투 및 확산이 용이한 모세관공극의 용적비(세공경 분포)에 더욱 관련하고 있었으며 침지실험에 의한 염화물이온 침투 깊이와 높은 상관관계를 나타내어 콘크리트의 염화물이온 침투 저항성 평가에 기초자료로서 활용될 수 있을 것으로 판단된다.

액체유출법에 의한 폴리에스테르 직물의 기공 크기 및 분포 측정 (Pore Size and Distribution of Polyester Fabrics Determined by Liquid Extraction Method)

  • 이동화;여숙영;김은애
    • 한국의류학회지
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    • 제21권1호
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    • pp.206-216
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    • 1997
  • The purpose of this study was to determine the pore size distributions (PSDs) of polyester woven fabrics by using liquid extraction method. Three types of PSDs-percent PSD, PSD per unit area of sample and PSD per unit weight of sample-were evaluated. Plain, twill and satin polyester fabrics with various fabric counts were used as specimens. Results showed that the interyarn PSDs reflected the fabric characteristics such as the fabric count and the weave type and the intrayarn PSDs reflected the thread characteristics such as the number of fibers, the fiber diameter, the thread diameter and the thread twist. Of three types of PSDs, the PSD per unit area of sample best reflect fabric and thread characteritics. As the fabric count decreased, rc increased and interyarn pore volume increased. The PSDs were skewed to the small pore sizes and the pore volumes decreased in the order of plain> twill> satin. As the number of fibers, the fiber diameter and the thread twist decreased, the intrayarn pore volumes were increased.

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상분리법에 의한 다공질유리의 제조 및 탈염특성 (Preparation of Microporous Glasses by the Phase-Separation Technique and Their Salt-Rejection Characteristics)

  • 현상훈;김계태
    • 한국세라믹학회지
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    • 제23권5호
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    • pp.93-101
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    • 1986
  • Microporous glasses were prepared from the 50 $SiO_2-44$ $B_2O_3-6$ $Na_2O$(wt%) parent glass by the phase eparation technique and were characterized by SEM, BET, and Gas Adsorption methods to investigate the possiblity of their use as salt-rejection membranes for reverse osmosis. The conditions of the phase separation for the possible glass membranes were optimized for the given parent glass. The temperature and duration of heat-treatment were desired to be lower(853K) and shorter (1/2~1 hr) respectively. The specific surface areas of porous glasses prepared in this study were about 80~120$m^2$/g and their pore size distribution had a unimodal shape(peak pore radius less than 15$\AA$) It was suggested that the porous glass obtained in this work could be effective for salt-rejection in point of pore size distributions but the way to increase its surface area for the high flux must be studied.

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