• Computers and Concrete
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• v.17 no.1
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• pp.107-127
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• 2016

Concrete is a heterogeneous material containing many weaknesses such as micro-cracks, pores and grain boundaries. The crack growth mechanism and failure behavior of concrete structures depend on the plastic deformation created by these weaknesses. In this article the non-linear finite element method is used to analyze the effect of presence of micro pore near a crack tip on both of the characteristics of crack tip plastic zone (its shape and size) and crack growth properties (such as crack growth length and crack initiation angle) under pure shear loading. The FE Code Franc2D/L is used to carry out these objectives. The effects of the crack-pore configurations and the spacing between micro pore and pre-excising crack tip on the characteristics of crack tip plastic zone and crack growth properties is highlighted. Based on the obtained results, the relative distance between the crack tip and the micro pore affects in very significant way the shape and the size of the crack tip plastic zone. Furthermore, crack growth length and crack initiation angle are mostly influenced by size and shape of plastic zone ahead of crack tip. Also the effects of pore decrease on the crack tip by variation of pore situation from linear to perpendicular configuration. The critical position for a micro pore is in front of the crack tip.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.33 no.1
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• pp.53-61
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• 2001

This study was carried out to evaluate the effect of coating pigments on the printability by investigating the pore structure of casting layer such as the number, size and distribution of pores and the pore rate. The coating structure was mainly determined by the interaction between pigment and binder. It means that the structure of pores was chiefly affected by the shape and size distribution of pigments and their packing rate. The physical properties of pore have close relationships with ink set-off, the speed of ink penetration and printing gloss. The results suggested that the rate and number of pores were greatly affected by the particle size distribution and shape of pigments. The rate of pore increased with the reduction of particle size distribution of pigments. Calcite was effective to improve greatly the printability of coated paper.

• Computers and Concrete
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• v.22 no.5
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• pp.469-479
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• 2018

The Brazilian tensile strength of concrete samples is a key parameter in fracture mechanics since it may significantly change the quality of concrete materials and their mechanical behaviors. It is well known that porosity is one of the most often used physical indices to predict concrete mechanical properties. In the present work the influence of porosity shape on concrete tensile strength characteristics is studied, using a bonded particle model. Firstly numerical model was calibrated by Brazilian experimental results and uniaxial test out puts. Secondly, Brazilian models consisting various pore shapes were simulated and numerically tested at a constant speed of 0.016 mm/s. The results show that pore shape has important effects on the failure pattern. It is shown that the pore shape may play an important role in the cracks initiation and propagation during the loading process which in turn influence on the tensile strength of the concrete samples. It has also been shown that the pore size mainly affects the ratio of uniaxial compressive strength to that of the tensile one in the simulated material samples.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.557-558
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• 2006

In all conventional sintered PM products, the pores present are of two types, primary and secondary. Primary pores forming during compaction and latter during sintering, due to penetration of formed liquid through the matrix grain boundary. Effect of carbon addition on diffusion of Cu in SH737-2Cu system was investigated. After compaction and transient liquid phase sintering at $1120^{\circ}C$ and $1180^{\circ}C$, samples were characterized for densification, showing rise in sintering density and reduction in swelling on carbon addition. Quantitative microstructural characterization (shape factor and pore size) revealed bimodal distribution for 0% carbon, more rounded pores for 0.9% carbon and higher sintering temperature, and pore coarsening at higher sintering temperature.

• Journal of Powder Materials
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• v.9 no.2
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• pp.96-102
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• 2002

In the present study, equiatomic porous TiNi shape-memory alloys have been successfully prepared by self-propagating high-temperature synthesis (SHS) using elemental titanium and nickel powders. The porous TiNi alloys thus obtained have an open porous structure with about 64 vol.% porosity, and the pore size is about 1.8 mm. The effect of preheating temperature on the microstructure have been investigated. It is found that the pore size increases with increasing preheating temperature. Moreover, the preheating temperature was shown to have a significant effect on the microstructrue of the SHS-synthesized porous TiNi shape memory alloys.

• Journal of Powder Materials
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• v.22 no.5
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• pp.362-366
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• 2015

The effect of sublimable vehicle composition in the camphor-naphthalene system on the pore structure of porous Cu-Ni alloy is investigated. The CuO-NiO mixed slurries with hypoeutectic, eutectic and hypereutectic compositions are frozen into a mold at $-25^{\circ}C$. Pores are generated by sublimation of the vehicles at room temperature. After hydrogen reduction at $300^{\circ}C$ and sintering at $850^{\circ}C$ for 1 h, the green body of CuO-NiO is completely converted to porous Cu-Ni alloy with various pore structures. The sintered samples show large pores which are aligned parallel to the sublimable vehicle growth direction. The pore size and porosity decrease with increase in powder content due to the degree of powder rearrangement in slurry. In the hypoeutectic composition slurry, small pores with dendritic morphology are observed in the sintered Cu-Ni, whereas the specimen of hypereutectic composition shows pore structure of plate shape. The change of pore structure is explained by growth behavior of primary camphor and naphthalene crystals during solidification of camphor-naphthalene alloys.

• Journal of Powder Materials
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• v.21 no.5
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• pp.366-370
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• 2014

The present study demonstrates the effect of solidification condition on the pore structure in freeze drying process using the slurries of CuO/sublimable vehicles. Camphene and Camphor-45 wt% naphthalene based slurries with 14 vol% CuO powder were frozen into a mold at $-25^{\circ}C$, followed by sublimation at room temperature. The green bodies were hydrogen-reduced and sintered at $500^{\circ}C$ for 1 h. The porous Cu specimen, frozen the CuO/camphene slurry into the heated mold of the upper part, showed large pores with unidirectional pore channels and small pores in their internal wall. Also, it was observed that the size of large pores was decreasing near the bottom part of specimen. The change of pore structure depending on the freezing condition was explained by the nucleation behavior of camphene crystals and rearrangement of solid powders during solidification. In case of porous Cu prepared from CuO/Camphor-naphthalene system, the pore structure exhibited plate shape as a replica of the original structure of crystallized vehicles with hypereutectic composition.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.219.2-219.2
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• 2011

The oxyfluorination effects of electrospun carbon nanofibers (OFACFs) were investigated for $CO_2$ storage. Carbon nanofibers were prepared form poly acrylonitrile / N,N-dimethylformamide solution through electrospinning method and heat treatment. Chemical activation of carbon nanofibers were carried out in order to improve the pore structure. And the surface modification of activated carbon nanofibers was conducted by oxyfluorination to improve the $CO_2$ storage on effect of introduced functional groups. The samples were labeled CF (electrospun carbon nanofiber), ACF (activated carbon nanofibers), OFACF-1 ($F_2:O_2$ = 3:7), OFACF-2 ($F_2:O_2$ = 5:5) and OFACF-3 ($F_2:O_2$ = 7:3). The functional group of OFACFs was investigated by x-ray photoelectron spectroscopy analysis. The specific surface area, pore volume and pore size of OFACFs were calculated and pore shape was estimated by the BET equation. Through the adsorption isotherm, the specific surface area and pore volume significantly decreased by oxyfluorination.

• The Korean Journal of Ceramics
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• v.6 no.3
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• pp.209-213
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• 2000

Microstructural changes of AlOOH doped UO$_2$pellet after annealing up to 216h have been observed and they were compared with those of the standard pellet. Grain and pore size of UO$_2$pellet increased with the addition of AlOOH and its effect was still validated during annealing. Densification rate was reduced by the addition of AlOOH and it was attributed to coarsened pores with spherical shape. Grain and pore growth was stopped and density increase was the least after 144h of annealing. The variation of pore size resulting from annealing has a linear relationship with that of grain size.

• Journal of Powder Materials
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• v.22 no.4
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• pp.240-246
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• 2015

Anodic aluminum oxide (AAO) has been widely used for the development and fabrication of nano-powder with various morphologies such as particle, wire, rod, and tube. So far, many researchers have reported about shape control and fabrication of AAO films. However, they have reported on the shape control with different diameter and length of anodic aluminum oxide mainly. We present a combined mild-hard (or hard-mild) anodization to prepare shape-controlled AAO films. Two main parameters which are combination mild-hard (or hard-mild) anodization and run-time of voltage control are applied in this work. The voltages of mild and hard anodization are respectively 40 and 80 V. Anodization was conducted on the aluminum sheet in 0.3 mole oxalic acid at $4^{\circ}C$. AAO films with morphologies of varying interpore distance, branch-shaped pore, diameter-modulated pore and long funnel-shaped pore were fabricated. Those shapes will be able to apply to fabricate novel nano-materials with potential application which is especially a support to prevent volume expansion of inserted active materials, such as metal silicon or tin powder, in lithium ion battery. The silicon powder electrode using an AAO as a support shows outstanding cycle performance as 1003 mAh/g up to 200 cycles.