• Title/Summary/Keyword: pore scale

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Morphological Variation and Recovery Mechanism of Residual Crude Oil by Biosurfactant from Indigenous Bacteria: Macro- and Pore-Scale Experimental Investigations

  • Song, Zhi-Yong;Han, Hong-Yan;Zhu, Wei-Yao
    • Journal of Microbiology and Biotechnology
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    • v.25 no.6
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    • pp.918-929
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    • 2015
  • Microbial enhanced oil recovery (MEOR) is being used more widely, and the biological contributions involved in MEOR need to be identified and quantified for the improvement of field applications. Owing to the excellent interfacial activity and the wide distribution of producing strains in oil reservoirs, lipopeptides have proved to be an essential part of the complex mechanisms in MEOR. In this study, crude lipopeptides were produced by a strain isolated from an indigenous community in an oil reservoir. It was found that crude lipopeptides can effectively reduce the IFT (interfacial tension) to 10-1~10-2 mN/m under high salinity without forming stable emulsions, and the wettability of natural sandstone can be enhanced (Amott index, from 0.36 to 0.48). The results of core flooding experiments indicate that an additional 5.2% of original oil in place can be recovered with a 9.5% reduction of injection pressure. After the shut-in period, the wettability of the core, the reduction of injection pressure, and the oil recovery can be improved to 0.63, 16.2% and 9.6%, respectively. In the microscopic flooding experiments, the crude oil in membrane, cluster, and throat states contribute nearly 90% in total of the additional oil recovery, and the recovery of membranestate oil was significantly enhanced by 93.3% after shut in. Based on the results in macro and pore scale, the IFT reduction and the wettability alteration are considered primary contributors to oil recovery, while the latter was more dominant after one shut-in period.

Loading Effects on Thermal Conductivity of Soils: Particle-Scale Study (하중 조건이 지반의 열전도도에 미치는 영향: 입자 스케일에서의 연구)

  • Lee, Jung-Hwoon;Choo, Jin-Hyun;Yun, Tae-Sup;Lee, Jang-Guen;Kim, Young-Seok
    • Journal of the Korean Geotechnical Society
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    • v.27 no.9
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    • pp.77-86
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    • 2011
  • The stress condition mainly dominates the thermal conductivity of soils whereas governing factors such as unit weight and porosity suggested by empirical correlations are still valid. The 3D thermal network model enables evaluation of the stress-dependent thermal conductivity of particulate materials generated by discrete element method (DEM). The relationship among dominant factors is analyzed based on the coordination number and porosity determined by stress condition and thermal conductivity of pore fluid. Results show that the variation of thermal conductivity is strongly attributed to the enlargement of inter-particle contact area by loading history and pore fluid conductivity. This study highlights that the anisotropic evolution of thermal conductivity depends on the directional load and that the particle-scale mechanism mainly dictates the heat transfer in soils.

Evaluation of Aseismic Performance for Reservoir Dams in Korea (국내 저수지 댐의 내진 성능 평가)

  • Park, Innjoon;Kim, Seungwook;Jang, Woonghee;Kim, Hyuntae;Yoo, Chanho
    • Journal of the Korean GEO-environmental Society
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    • v.7 no.6
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    • pp.89-100
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    • 2006
  • Recently, lots of lives and properties have been lost because comparatively large magnitude earthquakes were occurred in relatively safe regions and nations. It has been reported that number of earthquakes was increased rapidly in Korea. Hence, recently civil constructions were ensured against risks about earthquake not only large-scale structures but also comparative small-scale structures such as reservoir dams and life line by systematic aseismic design. Therefore, in this study, the seismic stability was ensured to evaluate aseismic performance for major planned reservoir dams in Korea. The seismic response analyses were conducted using SHAKE program on new reservoir dams under short-period, long-period and artificial seismic wave. The liquefaction potential for reservoir dams was assessed by using results from seismic response analysis (simplified assessment method for liquefaction potential). Also, fully coupled analysis--interaction of pore-pressure and soil--was performed to investigate both the development of excess pore water pressure and the characteristic of dynamic shear strain.

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Analysis of Ship Groundings on Soft Sea Beds

  • Simonsen, B. Cerup;Redersen, P. Terndrup
    • Journal of Ship and Ocean Technology
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    • v.1 no.1
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    • pp.35-47
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    • 1997
  • The consequences associated with ships running aground depend very much on the soil characteristics of the sea bed and the geometrical shape of the ship bow. The penetration into the sea bed depends on these factors and the penetration is an important factor for the ship motion because it influences the ship heave and pitch motions as well as the friction between the ship and the soil. In this paper a rational calculation model is presented for the sea bed soil reaction forces on the ship bottom. The model is based on the assumption that the penetration of the ship bow generates a flow of pore water through the grain skeleton of the soil. The flow is governed by Darcy\`s law and it is driven by the pressure of the pore water at the bow. In addition to this pore water pressure, the bow is subjected to the effective stresses in the grain skeleton at the bow surface. These stresses are determined by the theory of frictional soils in rupture. Frictional stresses on the bow surface are assumed to be related to the normal pressure by a simple Coulomb relation. The total soil reaction as a function of velocity and penetration is found by integration of normal pressure and frictional stresses over the surface of the bow. The analysis procedure is implemented in a computer program for time domain rigid body analysis of ships running aground and it is verified in the paper through a comparison of calculated stopping lengths, effective coefficients of friction, and sea bed penetrations with corresponding experimental results obtained by model tests as well as large, scale tests.

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A study on membrane technology for surface water treatment: Synthesis, characterization and performance test

  • Haan, Teow Yeit;Shah, Mubassir;Chun, Ho Kah;Mohammad, Abdul Wahab
    • Membrane and Water Treatment
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    • v.9 no.2
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    • pp.69-77
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    • 2018
  • The use of membrane as an innovative technology for water treatment process has now widely been accepted and adopted to replace the conventional water treatment process in increasing fresh water production for various domestic and industrial purposes. In this study, ultrafiltration (UF) membranes with different formulation were fabricated via phase inversion method. The membranes were fabricated by varying the polymer concentration (16 wt%, 18 wt%, 20 wt%, and 21 wt%). A series of tests, such as field emission scanning electron microscope (FESEM), pore size and porosity, contact angle, and zeta potential were performed to characterize the membranes. The membrane performance in terms of permeation flux and rejection were evaluated using a laboratory bench-scale test unit with mine water, lake water and tube well as model feed solution. Long hour filtration study of the membranes provides the information on its fouling property. Few pore blocking mechanism models were proposed to examine the behaviour of flux reduction and to estimate the fouling parameters based on different degree of fouling. 21 wt% PVDF membrane with smaller membrane pore size showed an excellent performance for surface water treatment in which the treated water complied with NWQS class II standard.

Erosion behavior according to location of conduit cracks in agricultural reservoir

  • Ryu, Jung-Hyun;Heo, Joon;Shim, Jae-Woong;Kim, Cheol-Han;Yun, Bora;Lee, Yong-Hak;Lee, Dal-Won
    • Korean Journal of Agricultural Science
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    • v.47 no.4
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    • pp.1159-1168
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    • 2020
  • The conduits of agricultural reservoirs undergo deterioration over a considerable period of time and this is highly likely to cause structural problems such as cracks. It is therefore important to consider the effects of structural defects on the body from the viewpoint of stability and maintenance of the embankment. In this study, basic data on the effects of the crack location on the stability of the embankment is obtained by identifying, comparing, and analyzing the erosion characteristics and pore water pressure behavior through a large-scale model experiment that involves classifying the location of the conduit cracks. From the results of the experiment, it was confirmed that when a crack occurred, the amount of leakage increased as the location of the crack portion was closer to the water level, and the internal erosion phenomenon accelerated, thereby increasing the possibility of piping. It was also found that an upstream conduit crack affects the erosion and water pressure change of the central and downstream conduit of the embankment, and the conduit crack has a very large effect on the pore water pressure despite the low upstream water level. Therefore, the seepage behavior of the embankment for each conduit crack identified in this study is considered to be useful basic data for preparing a repair and reinforcement plan according to the crack location in the future.

Study of Chloride Corrosion Organic Inhibitors in Alkaline Pore Solution

  • Cabrini, M.;Lorenzi, S.;Pastore, T.;Pellegrini, S.
    • Corrosion Science and Technology
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    • v.17 no.5
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    • pp.203-210
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    • 2018
  • This paper compares the inhibition properties of aspartic and lactic acid salts with nitrite ions and their effect on critical chloride concentration. The tests were carried employing carbon steel specimens in saturated lime solution with varying pH in the range between13 to 13.6. The critical chloride concentration was estimated through multiple specimen potentiostatic tests at potentials in the usual range for passive rebar in the alkaline concrete of atmospheric structures. During tests, chloride salt was added every 48 h until all the specimens showed localized attacks. The cumulative distribution curves, i.e. the number of corroded specimens as a function of the chlorides concentration was obtained. Furthermore, IR spectra were recorded for the evaluation of the presence of the organic inhibitors on the passivity film. The results confirmed the inhibitory effect of 0.1M aspartate comparable with nitrite ions, at a similar concentration. Addition of calcium lactate did not result in an increase in the critical chloride concentration. However, the formation of a massive scale containing the substance that could reduce the corrosion propagation was observed.

On-line Measurement and Characterization of Nano-web Qualities Using a Stochastic Sensor Fusion System Design and Implementation of NAFIS(NAno-Fiber Information System)

  • Kim, Joovong;Lim, Dae-Young;Byun, Sung-Weon
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.45-46
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    • 2003
  • A process control system has been developed for measurement and characterization of the nanofiber web qualities. The nano-fiber information system (NAFIS) developed consists of a measurement device and an analysis algorithm, which are a microscope-laser sensor fusion system and a process information system, respectively. It has been found that NAFIS is so successful in detecting irregularities of pore and diameter that the resulting product has been quitely under control even at the high production rate. Pore distribution, fiber diameter and mass uniformity have been readily measured and analyzed by integrating the non-contact measurement technology and the random function-based time domain signal/image processing algorithm. Qualifies of the nano-fiber webs have been revealed in a way that the statistical parameters for the characteristics above are calculated and stored in a certain interval along with the time-specific information. Quality matrix, scale of homogeneity is easily obtained through the easy-to-use GUI information. Finally, ANFIS has been evaluated both for the real-time measurement and analysis, and for the process monitoring.

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Effect of powder activated carbon replacement on HCPAC-MBR system operation (고농도 분말활성탄 결합 MBR 운전에 대한 활성탄 교체주기의 영향)

  • Lee, Chae-Ha;Kim, Jin-Tae;Lee, Jung-Hyun;Seo, Gyu-Tae;Kim, In S.
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.1
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    • pp.141-148
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    • 2008
  • This study was conducted to evaluate the effect of PAC(Powder Activated Carbon) retention time on stable operation of high concentration powered activated carbon(HCPAC-MBR) in the treatment of secondary domestic wastewater. The pilot scale HCPAC-MBR system was operated at two different SRTs, 25 days and 100 days. The main drawback of HCPAC-MBR system was the rapid increase of trans-membrane pressure. The increase rate of trans-membrane pressure was proportional to SRT value at constant flux. This result seemed to be caused by reduced amount of EPS adsorbed on the PAC in the reactor by decreasing the SRT of the PAC. The particle size of the PAC was also influenced by SRT. The PAC size was decreased as SRT was increased. The change of particle size could be one reason for the change of trans-membrane pressure. The pore volume in the cake-layer formed on the membrane surface became to be increased by reducing SRT, because the cake-layer was highly composed of the PAC. Therefore, increased pore volume might play a role to reduce the trans-membrane pressure. The removal rate of E260 and TOC was also inversely proportional to SRT value.

Gasification reactivity of Chinese Shinwha Coal Chars with Steam (스팀을 이용한 중국산 신화 석탄 촤 가스화 반응에 관한 연구)

  • Kang, Min-Woong;Seo, Dong-Kyun;Kim, Yong-Tak;Hwang, Jung-Ho
    • Journal of the Korean Society of Combustion
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    • v.15 no.1
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    • pp.22-29
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    • 2010
  • In this study, carbon conversion was measured using an electronic mass balance. In a lab scale furnace, each coal sample was pyrolyzed in a nitrogen environment and became coal char, which was then gasified with steam under isothermal conditions. The reactivity of coal char was investigated at various temperatures and steam concentrations. The VRM(volume reaction model), SCM(shrinking core model), and RPM(random pore model) were used to interpret experimental data. For each model the activation energy(Ea), pre-exponential factor (A), and reaction order(n) of the coal char-steam reaction were determined by applying the Arrhenius equation into the data obtained with thermo-gravimetric analysis(TGA). According to this study, it was found that experimental data agreed better with the VRM and SCM for 1,000 and $1,100^{\circ}C$, and the RPM for 1,200 and $1,300^{\circ}C$. The reactivity of chars increased with the increase of gasification temperature. The structure parameter(${\psi}$) of the surface area for the RPM was obtained.