• Title/Summary/Keyword: pore scale

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Study on Hindered Diffusion of Single Polyelectrolyte Chain in Micro-Pores by Employing Brownian Dynamics Simulations (브라운 동력학 시뮬레이션에 의한 미세기공에서 단일한 다가전해질 사슬의 제한확산 연구)

  • 전명석;곽현욱
    • Membrane Journal
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    • v.12 no.4
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    • pp.207-215
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    • 2002
  • The hindered diffusion in confined spaces is an important phenomenon to understand in a micro-scale the filtration mechanism determined by the particle motion in membrane pores. Compared to the case of spherical colloids, both the theoretical investigations and the experiments on the hindered diffusion of polyelectrolytes is actually more difficult, due to lots of relevant parameters resulting from the complicated conformational properties of the polyelectrolyte chain. We have successfully performed the Brownian dynamics simulations upon a single polyeiectrolyte confined in a slit-like pore, where a coarse-grained bead-spring model incorporated with Debye-Huckel interaction is properly adopted. For the given sizes of both the polyelectrolyte and the pore width, the hindered diffusion coefficient decreases as the solution ionic concentration decreases. It is evident that a charge effect of the pore wall enhances the hindered diffusion of polyelectrolyte. Simulation results allow us to make sense of the diffusive transport through the micro-pore, which is restricted by the influences of the steric hindrance of polyelectrolytes as well as the electrostatic repulsion between the polyelectrolytes and pore wall.

Injection molding using porous nano-scale patterned master with Pettier devices (펠티어 소자를 이용한 다공성 나노패턴의 사출에 대한 연구)

  • Hong, N.P.;Kwon, J.T.;Shin, H.G.;Seo, Y.H.;Kim, B.H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.513-516
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    • 2008
  • We have replicated nanopillar arrays using injection molding process of active heating and cooling method by several peltier devices. The injection melding has a high accuracy ed good reproducibility that are essential for mass production at low cost. Conventional molding processes widely use the water-based mold heating and air cooling methods. However, in case of replication for nano-patterned structures, it caused several defects such as air-flow mark, non-fill, sticking and tearing. In this study, periodic nano-scale patterns are replicated by using injection molding with Peltier devices. Porous nano-scale patterns, which have pore diameter range from 120nm to 150nm, were fabricated by using anodizing process. Periodic nano-pore structures ( $20mm\;{\times}\;20mm$) were used as a mold stamp of injection molding. Finally, PMMA with nanopillar arrays was obtained by injection molding process. By using the Peltier devices, the temperature of locally adiabatic molds can be dramatically controlled and the quality of the molded patterns can be slightly improved.

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Dynamic response of size-dependent porous functionally graded beams under thermal and moving load using a numerical approach

  • Fenjan, Raad M.;Ahmed, Ridha A.;Faleh, Nadhim M.;Hani, Fatima Masood
    • Structural Monitoring and Maintenance
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    • v.7 no.2
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    • pp.69-84
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    • 2020
  • Based on differential quadrature method (DQM) and nonlocal strain gradient theory (NSGT), forced vibrations of a porous functionally graded (FG) scale-dependent beam in thermal environments have been investigated in this study. The nanobeam is assumed to be in contact with a moving point load. NSGT contains nonlocal stress field impacts together with the microstructure-dependent strains gradient impacts. The nano-size beam is constructed by functionally graded materials (FGMs) containing even and un-even pore dispersions within the material texture. The gradual material characteristics based upon pore effects have been characterized using refined power-law functions. Dynamical deflections of the nano-size beam have been calculated using DQM and Laplace transform technique. The prominence of temperature rise, nonlocal factor, strain gradient factor, travelling load speed, pore factor/distribution and elastic substrate on forced vibrational behaviors of nano-size beams have been explored.

Characterization of nano-fiber web structures using a morphological image processing

  • Kim, Jooyong;Lee, Jung-Hae
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.100-100
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    • 2003
  • An image processing algorithm has been developed in order to analyze the nanofiber web images obtained from a high magnification microscope. It has been known that precise pore detection on thick webs is extremely difficult mainly due to lack of light uniformity, difficulty of fine focusing and translucency of nanofiber web. The pore detection algorithm developed has been found to show excellent performance in characterizing the porous structure, thus being a promising tool for on-line quality control system under mass production. Since the images obtained from an optical microscope represent only web surface, a scale factor has been introduced to estimate the web structure as a whole. Resulting web structures have been compared to those by mercury porosimetry, especially in pore size distribution. It has been shown that those two structures have a strong correlation, indicating that scaling of a single layer web structure can be an effective way of estimating the structure of thick fiber webs.

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A Study on Stability of Earthquake in Estuary Barrage through Shaking Table Test (실내 진동대 실험을 통한 하구둑 구조물의 내진 안정성에 관한 연구)

  • Shin, Eun-Chul;Kang, Hyoun-Hoi;Ryu, Byung-Hyun
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.09b
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    • pp.38-44
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    • 2010
  • Shaking table tests were performed to reproduce the dynamic behavior of estuary barrage and its subbase soil which can be potentially damaged during earthquake loading. For understanding the vibration effect to the ground during earthquake, the model was formulated with 1/300 scale of prototype estuary barrage and subbase soil. Scott and Iai(1989) proposed the law of the similarity for similar experimental conditions. The laboratory model shaking table test was conducted under the vibration condition of simulated earthquake of 0.154g. The horizontal displacement on the structure was measured during the shaking table test. The pore water pressure was also monitored for the underground layers of soil. The field horizontal displacement and the pore water pressure can be predicted by using the results of the laboratory shaking table test.

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High Temperature Oxidation Behavior of Ni based Porous Metal (Ni계 다공체 금속의 고온 산화 거동)

  • Choi, Sung-Hwan;Yun, Jung-Yeul;Lee, Hye-Mun;Kong, Young-Min;Kim, Byoung-Kee;Lee, Kee-Ahn
    • Journal of Powder Materials
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    • v.18 no.2
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    • pp.122-128
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    • 2011
  • This study investigated the high temperature oxidation behavior of Ni-22.4%Fe-22%Cr-6%Al (wt.%) porous metal. Two types of open porous metals with different pore sizes of 30 PPI and 40 PPI (pore per inch) were used. A 24-hour TGA test was conducted at three different temperatures of $900^{\circ}C$, $1000^{\circ}C$ and $1100^{\circ}C$. The results of the BET analysis revealed that the specific surface area increased as the pore size decreased from 30 PPI to 40 PPI. The oxidation resistance of porous metal decreased with decreasing pore size. As the temperature increased, the oxidation weight gain of the porous metal also increased. Porous metals mainly created oxides such as $Al_2O_3$, $Cr_2O_3$, $NiAl_2O_4$, and $NiCr_2O_4$. In the 40 PPI porous metal with small pore size and larger specific surface area, the depletion of stabilizing elements such as Al and Cr occurred more quickly during oxidation compared to the 30 PPI porous metal. Ni-Fe-Cr-Al porous metal's high-temperature oxidation micro-mechanism was also discussed.

Behavior of Failure on Agricultural Reservoirs Embankment by Riprap Reinforcement Method (Riprap으로 보강된 농업용 저수지 제체의 붕괴거동)

  • Lee, Dal Won;Noh, Jae Jin
    • Journal of The Korean Society of Agricultural Engineers
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    • v.56 no.6
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    • pp.63-73
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    • 2014
  • In this study, the large scale test was performed to investigate the behavior of failure on the embankment and spillway transitional zone by overtopping. The pore water pressure, earth pressure, settlement and failure behaviors according to several reinforcing method were compared and analyzed. The pore water pressure showed a small change in the spillway transition zone and core, indicating that the riprap and geotextile efficiently reinforced the embankment, but non-reinforcement showed a largely change in pore water pressure. The earth pressure by riprap and geotextile at upstream slope and bottom core increased rapidly with the infiltration of the pore water by overtopping. And the earth pressure at crest showed a smally change due to effect of the inclined core. A settlement by riprap showed a small change and the geotextile decreased a rapidly due to failure of crest. The width of failure by riprap at intermediate stage (50 min) showed a largely due to sliding of crest. But, the width and depth of the seepage erosion after the intermediate overtopping period (100 min) were very small due to the effect of riprap than geotextile and non-reinforcement which delayed failure. It has the effect that protect reservoir embankment from erosion in the central part. The pore water pressure at the spillway transition zone due to overtopping increased a rapidly in the case of non-reinforcement, but the reinforced methods by geotextile and riprap showed a smally change. Therefore, the reinforced method by riprap and geotextile was a very effective method to protect permanently and the emergency an embankment due to overtopping, respectively.

Quantification of 3D Pore Structure in Glass Bead Using Micro X-ray CT (Micro X-ray CT를 이용한 글라스 비드의 3차원 간극 구조 정량화)

  • Jung, Yeon-Jong;Yun, Tae-Sup
    • Journal of the Korean Geotechnical Society
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    • v.27 no.11
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    • pp.83-92
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    • 2011
  • The random and heterogeneous pore structure is a significant factor that dominates physical and mechanical behaviors of soils such as fluid flow and geomechanical responses driven by loading. The characterization method using non-destructive testing such as micro X-ray CT technique which has a high resolution with micrometer unit allows to observe internal structure of soils. However, the application has been limited to qualitatively observe 2D and 3D CT images and to obtain the void ratio at macro-scale although the CT images contain enormous information of materials of interests. In this study, we constructed the 3D particle and pore structures based on sequentially taken 2D images of glass beads and quantitatively defined complex pore structure with void cell and void channel. This approach was enabled by implementing image processing techniques that include coordinate transformation, binarization, Delaunay Triangulation, and Euclidean Distance Transform. It was confirmed that the suggested algorithm allows to quantitatively evaluate the distribution of void cells and their connectivity of heterogeneous pore structures for glass beads.

Use of an Imaging Technology for Characterizing Core-scale Multiphase Flow: Application to CO2 Geological Storage (이미징기술을 활용한 코어규모의 다상유체 유동 특성화: 이산화탄소 지중저장 연구에의 적용)

  • Kim, Kue-Young
    • The Journal of Engineering Geology
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    • v.28 no.1
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    • pp.35-45
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    • 2018
  • Imaging technologies are applied at various geological scales including pore scale, core scale and intermediate scale in order to characterize pore space of rocks as well as to map the fluid distribution in porous media. This technical report presents experimental results using core-flooding apparatus suited with imaging technology. Three different core samples, that are homogeneous, fractured and heterogeneous cores, were used to assess the two-phase fluid migration behavior as $CO_2$ displaces resident brine. We show that imaging technology can be effective in characterizing salt-precipitation, capillary pressure and spatio-temporal variation of trapping mechanisms.

Long-Term Leaching Characteristics of Arsenic Contaminated Soils Treated by the Stabilization Method (안정화 처리된 비소오염토양의 장기 용출특성)

  • Yu, Chan;Yun, Sung-Wook;Baek, Seung-Hwan;Park, Jin-Chul;Lee, Jung-Hoon
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.10a
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    • pp.1463-1474
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    • 2008
  • In order to investigate stabilization effect and sustainability on As-contaminated farmland soils which were affected the abandoned mine site and stabilized by zerovalent iron(ZVI) and industrial by-products, batch-scale and pilot-scale tests were carried out. In batch tests, ZVI and industrial by-products(blast furnace slag, steel refining slag and oyster shell powder) were used in treatment materials to reduce the As leaching. Industrial by-products were mixed with As-contaminated soils, in the ratio of 1%, 3%, 5% and 7% on the weight base of dried soil. The results of batch-scale tests was shown that the reduction of As concentration was observed in all samples and it was expected that ZVI and steel refining slag were more effective than other treatment materials to stabilize As compounds. In pilot-scale tests, columns were filled with untreated soils and treated soils mixed with ZVI and steel refining slag in the same mixing ratio of 3%. Distilled water was discharged into the columns with the velocity of 0.3 pore volume/day. During the test, pH, EC, Eh and As concentration were measured in the regular term(1pore volume). after six months, pilot-scale tests were retested to investigate sustainability of treatment materials. As a result, It was shown that the leachate from control column was continuously released during the test period and its concentration was greater than $100ug{\cdot}L^{-1}$ which was exceeded the national regulation of water discharged to river or stream ($50ug{\cdot}L^{-1}$). On the other hand, soil treated with ZVI and steel refining slag showed that the concentrations of leachate were lower than national regulation of water discharged to river or stream. Therefore it was expected that ZVI and steel refining slag could be applied to the farmland site as the alternative treatment materials.

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