• Membrane Journal
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• v.17 no.4
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• pp.329-337
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• 2007

This is the research about a new method to make the internal separation layer with smallest pore size in polyethersulfone (PES) membrane by adding p-toluenesulfonic acid (TSA) and polyvinylpyrolidone (PVP) to polymeric PES solution. The preparation and morphological characterization of PES sheet membranes containing PVP as a hydrophilic swelling material and TSA as a demixing material were performed. As a result by microflow porometery, the PVP and TSA added PES membranes showed good permeabilities and narrow pore size distributions, comparable to those of the commercial membranes. The concentration of PVP affected the PES characteristics on air permeability and surface structure. The concentration of TSA influenced on pore size distribution but do not affect air permeability. The surface images of FE-SEM shows similar pore size when TSA added or not. However, the cross-section images of FE-SEM show that the TSA added PES membranes have a increase of internal layer thickness with smallest pore size.

• Smart Structures and Systems
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• v.34 no.1
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• pp.51-62
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• 2024

Application of biopolymers to improve the mechanical properties of soils has been extensively reported. However, a comprehensive understanding of various engineering applications is necessary to enhance their effectiveness. While numerous experimental studies have investigated the use of biopolymers as injection materials, a detailed understanding of their injection behavior in soil through numerical analyses is lacking. This study aimed to address this gap by employing pore network modeling techniques to analyze the injection characteristics of biopolymer solutions in soil. A pore network was constructed from computed tomography images of Ottawa 20-30 sand. Fluid flow simulations incorporated power-law parameters and governing equations to account for the viscosity characteristics of biopolymers. Agar gum was selected as the biopolymer for analysis, and its injection characteristics were evaluated in terms of concentration and pore-size distribution. Results indicate that the viscosity properties of biopolymer solutions significantly influence the injection characteristics, particularly concerning concentration and injection pressure. Furthermore, notable trends in injection characteristics were observed based on pore size and distribution. Importantly, in contrast to previous studies, meaningful correlations were established between the viscosity of the injected fluid, injection pressure, and injection distance. Thus, this study introduces a novel methodology for integrating pore network construction and fluid flow characteristics into biopolymer injections, with potential applications in optimizing field injections such as permeation grouting.

• Journal of the Korean Ceramic Society
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• v.40 no.6
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• pp.572-576
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• 2003

Open/closed porosity, pore size and its distribution and pore type as a funtion of sintered density of UO$_2$-20 wt％CeO$_2$ pellets were investigated. Pore appeared almost closed-type with the density above 96％ of the theoretical density. Bimodal pore size distribution was observed regardless of the sintered density, but the number of pore decreased with increasing the sintered density. The shape of pore was changed from irregular shape to round type with increasing the sintered density.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 1996.06a
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• pp.494-496
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• 1996

The purpose of this study is to investigate the effect of process conditions on pore distribution in porous silicon layer prepared by electrochemical reaction. Porous silicon layers formed on p-type silicon wafer show the network structure of fine porse whose diameters are less than 100${\AA}$. In n-type porous silicon, selective growth was found on the pore surface by wet etching process after PR patterning. And numerical method showed high current density on the pore tip. With this result we confirmed that pore formation has two steps. First step is the initial attack on the surface and second step is the directional growth on the pore tip.

• Bulletin of the Korean Chemical Society
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• v.9 no.2
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• pp.94-98
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• 1988

An improvement over the method of pore size distribution analysis has been made in this work. The improved method is based upon the idea of the micro pore analysis of Mikhail, Brunauer, and Bodor, and utilizes the V-t curve of nitrogen adsorption. Two pore models are assumed, and the deviation of the initial slope of the V-t plot is ascribed to the pore filling and to the adsorption on the wall of unfilled pores. The improved method of this work is very convenient in that the analysis starts from the small pore regions. The method of this work is however quite distinct from the similar V-t plot method proposed by Sellevold and Radjy. The proposed method is applied to a few adsorbents, and very satisfactory results are obtained. The cumulative surface area calculated by this method also agrees very well with those obtained by the BET plot or by the t-method.

• YAKHAK HOEJI
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• v.29 no.4
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• pp.176-182
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• 1985

As a part of the studies on adsorptive properties of Korean halloysite clays, Hadong white clays of premium grade were examined for geometric pore structured by mercury porosimetry and for specific surface areas by nitrogen adsorption according to the BET procedure. Three size fractions of the native clay sample were derived from passage BS #100, #200 and #325 meshes, respectively. Several parameters lhus observed in relation to the pore structures are shown below: 1. The size fraction of BS #100, #200 and #325 show internal pore volumes of 25.3, 30.2 and $35.0m^2g^{-1}$, respectively. 2. In the distribution curves of the cumulative pore volume against pore diameter, it has been shown that the larticle sizes, the steeper the distribution over the larger ranges of pore diameters. The converse is true the smaller particles. 3. Internal pore areas increase with decrease in pore sizes. It follows that the pores having diameters of $\leq$0.1$\mu\textrm{m}$ are responsible for more than 90% of the total pore area. 4. The behaviour of nitrogen adsorption can be best described by BET type IV isotherm. Further, the hysteresis loops of the adsorptiondesorption curves become narrower with decresing particle sizes. 5. The specific surface areas observed for the fractions of BS #100, BS #200 and BS #325 are 34.6, 35.4 and 43.2m $^2g^{-1}$, respectively. and the calcined clay of BS #325 has a specific surface area near $30.4m^2g^{-1}$.

• Journal of the Korean Ceramic Society
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• v.40 no.7
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• pp.677-682
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• 2003

The physical properties of sintered body made from 3 kinds of slip, F (Flocculated), M (Moderate), and D (Dispersed) for coal fly ash 70-clay 30 (wt%) were studied in terms of slip states and pore size distribution of sintered bodies. The floc particle size distribution for slip F was wider than slip D and the slip F contained flocs larger than 11 $\mu\textrm{m}$. The pore size distribution of the green body of all slips ranged over 1∼4 $\mu\textrm{m}$. The pores smaller than 1 $\mu\textrm{m}$ almost disappeared during the sintering process, while the larger pore of 2.5∼3 $\mu\textrm{m}$ growed by 1 $\mu\textrm{m}$. The pore distribution for the green body of slip F became a narrow in width and high in height after sintering and the large pore limit in a slip F sintered body was 5.1 $\mu\textrm{m}$ which is smaller than that of other slip. The slip F rather flocculated was favorable over slip D well dispersed, in offering a higher compressive strength. From these results, the mechanical strength of sintered body is dependent on the pore distribution which could be controlled by dispersion state of the slips.

• Journal of the Korea institute for structural maintenance and inspection
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• v.3 no.4
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• pp.179-189
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• 1999

This study attempts to propose an evaluation considering the property of concrete pore which affects the deterioration of neutralization and the rebar resistance of concrete. Understanding pore property of concrete in using extent, for practical using of concrete manufacturing condition. basic quality property and durability estimation etc, the results of the experiment are as follows. 1) The result of analysis pore property of every specimen with the method of area ratio, in limitation of $10^{-6}{\sim}10^{-5}m$, the pore distribution ratio was maximum. It was high value as W/C was increased and the unit cement content was decreased. 2) In case of using admixture. the volume of pores was some increased as variation of mixing content. In high W/C range, it was very increased compared with plain concrete. 3) Concerned with compressive strength and volume of pores in hardened concrete, it is possible compressive strength estimation using the property of concrete pores. 4) Direct measurement of concrete pore property is difficult. the valuation of the dynamic modulus of elasticity using ultrasonic wave velocity was available. 5) Quantitatively evaluation of concrete structure durability by past result of pore distribution estimation, and it can be estimative scale of property study on the concrete materials.

• Geomechanics and Engineering
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• v.35 no.6
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• pp.627-636
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• 2023

The essence of subgrade mud pumping under train load is the migration of fine particles in subgrade soil. The migration of fine particles will change the pore structure of overlying ballast, thus affecting the mechanical properties and hydraulic properties of ballast layer. It is of great theoretical significance and engineering value to study the effect of fine particle migration on the pore structure of ballast layer under cyclic loading. In this paper, a tailor-made subgrade mud pumping test model and an X-ray computed tomography (CT) scanning equipment were used to study the influence of migration of fine particles in subgrade soil on the pore parameters (plane porosity, volume porosity, pore distribution and pore connectivity) of overlying ballast under cyclic loading. The results show that the compression of ballast pores and the blockage of migrated fine particles make the porosity of ballast layer decreases gradually. And the percentage of small pores in ballast layer increases, while the percentage of large pores decreases; the connectivity of pores also gradually decreases. Based on the test results, an empirical model of ballast porosity evolution under cyclic loading is established and verified.

• Proceedings of the Membrane Society of Korea Conference
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• 1991.10a
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• pp.4-8
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• 1991

The characterization of pore properties (mean pore size and pore size distribution) of the active layer in a UF membrane is important not only in order to obtain information about the factors affecting pore formation during membrane manufacturing but also to understand deeply the mechanism of solute and solvent transport through pores. Many methods of characterizing quantitatively the pore properties of UF membranes have been suggested in the literature: solvent and gas flow measurement, bubble point determination, electron microscopy, gas adsorption/desorption measurement, rejection measurement etc. But most of these methods involve time-consuming procedures and involve some wellknown problems and uncertainties.