• Title/Summary/Keyword: pore connectivity

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Preparation of Macroporous Pellet from Industrial Waste Flyash by Foaming Method

  • Park, Jai-Koo;Kim, Hyun-Jung
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.638-643
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    • 2001
  • Macroporous pellets were prepared from industrial waste flyash by foaming method. The surface and inside of flyash pellets, the shape was almost spherical and the average size was about 3 mm, were composed of the spherical pores interconnected through windows. The controlling of pellet size was conducted with solid loading. The flyash pellets with different relative density were characterized for porosity, average pore size, and specific surface area. As results, most physical properties had a tendency to increase as relative density decreased - extension ratio increased. The correlation between relative density and other properties was inspected through microstructural features evaluated by SEM. As a result, high porosity and high specific surface area were estimated to result from the superior connectivity between pores.

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Evaluation of Mg size dependence on superconductivity of MgB2

  • Sinha, B.B.;Jang, S.H.;Chung, K.C.;Kim, J.H.;Dou, S.X.
    • Progress in Superconductivity and Cryogenics
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    • v.15 no.2
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    • pp.39-43
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    • 2013
  • $MgB_2$ bulk samples are synthesized through solid state reaction route using Mg precursors with different particle size by keeping the boron precursor unchanged. Scanning electron microscopy study of the fractured surface for all the samples depicts quite distinct structure depending on the Mg precursor. Big size of Mg precursor resulted in to largely elongated and deep pores while smaller one gave roughly ellipsoidal and shallow pore structure. Influence of the Mg particle size on the grain to grain connectivity reflected in the critical current density value which was greater for samples with smaller Mg precursor. All the synthesized samples undergo a superconducting transition at around 36.5 K irrespective of different Mg precursor particle size.

Effect of Interface Porosity on the Dielectric and Piezoelectric Properties of 0-3 Type-Polymer Composites (O-3형 PZT-폴리머 복합체 제조시 압전 복합체내의 경계 기공이 유전, 압전 특성에 미치는 영향)

  • 이형규;천재일;김호기
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1988.10a
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    • pp.21-26
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    • 1988
  • Composition with O-3 connectivity were fabricated from PZT and phenolic resin powders. These composites were investigated for dielectric and pizoelectric properties with PZT-polymer interface porosity variation. The interface porosity dependence of dielectric and piezoelectric properties was especially discussed by porosity factors. The interface porosity dependence of piezoelectric constant was larger than that of dielectric constant. It was considered that the interface pore plays the role of a stress buffer. Thus the local stress applied on PZT particles in the composite was remarkably diminish.

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Application of the Electrical Impedance of Rocks in Characterizing Pore Geometry (암석 내 공극구조의 평가를 위한 전기임피던스의 적용)

  • Choo, Min-Kyoung;Song, In-Sun;Lee, Hi-Kweon;Kim, Tae-Hee;Chang, Chan-Dong
    • The Journal of Engineering Geology
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    • v.21 no.4
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    • pp.323-336
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    • 2011
  • The hydro-mechanical behavior of the Earth's crust is strongly dependent on the fractional volume and geometrical structure of effective pore spaces. This study aims to understand the characteristics of pores using electrical impedance. We measured the electric impedance of core samples (diameter, 38-50 mm; length, 70-100 mm) of three types of granite (Hwangdeung, Pocheon, and Yangsan) and two types of sandstone (Boryung and Berea) with different porosities and pore structures, after saturation with saline water of varying salinities. The results show that resistance decreases but capacitance increases with increasing salinity of the pore fluid. For a given salinity, the resistivity and formation factor are reduced with increasing porosity of the rocks, and the capacitance increases. Berea sandstone shows anisotropy in resistance, tortuosity, and cementation factor, with these factors being highest normal to bedding planes. This result indicates that the connectivity of pores is weakest normal to bedding. In conclusion, the electrical characteristics of the tested samples are related not only to their porosity but also to the pore geometry.

Durability Properties and Microstructure of Ground Granulated Blast Furnace Slag Cement Concrete

  • Divsholi, Bahador Sabet;Lim, Tze Yang Darren;Teng, Susanto
    • International Journal of Concrete Structures and Materials
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    • v.8 no.2
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    • pp.157-164
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    • 2014
  • Ground granulated blast-furnace slag (GGBS) is a green construction material used to produce durable concrete. The secondary pozzolanic reactions can result in reduced pore connectivity; therefore, replacing partial amount of Portland cement (PC) with GGBS can significantly reduce the risk of sulfate attack, alkali-silica reactions and chloride penetration. However, it may also reduce the concrete resistance against carbonation. Due to the time consuming process of concrete carbonation, many researchers have used accelerated carbonation test to shorten the experimental time. However, there are always some uncertainties in the accelerated carbonation test results. Most importantly, the moisture content and moisture profile of the concrete before the carbonation test can significantly affect the test results. In this work, more than 200 samples with various water-cementitious material ratios and various replacement percentages of GGBS were cast. The compressive strength, electrical resistivity, chloride permeability and carbonation tests were conducted. The moisture loss and microstructure of concrete were studied. The partial replacement of PC with GGBS produced considerable improvement on various properties of concrete.

Processing of Al2O3 Ceramics with a Porous Cellular Structure (셀 다공구조를 갖는 Al2O3세라믹스의 제조)

  • Lim, Byong-Gu;Lee, Lak-Hyoung;Ha, Jung-Soo
    • Journal of the Korean Ceramic Society
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    • v.44 no.10
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    • pp.574-579
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    • 2007
  • Porous $Al_2O_3$ ceramics were prepared by the gelcasting foams method (a slurry foaming process) with acrylamide monomer. The foaming and gelation behavior was investigated with the parameters such as the type and concentration of surfactant, solid loading of slurry, and the concentrations of initiator and catalyst. Density, porosity, microstructure, and strength of the green and sintered samples were characterized. Of the four kinds of surfactants tested, Triton X-114 showed the highest foaming ability for the solid loading of 55-30 vol%. The gelation condition giving the idle time off min was found to set the foamed structure without significant bubble enlargement and liquid lamella thinning. The green samples were fairly strong and machinable and showed maximum strength of 2.4 MPa in diametral compression. The sintered samples showed densities of 10-36% theoretical (i.e. porosity 90-64%) with a highly interconnected network of spherical pores with sizes ranging from 30 to $600{\mu}m$. The pore size and connectivity increased but the cell strut thickness decreased with decreasing the solid loading. Flexural strength of 37.8-1.7 MPa was obtained for the sintered samples.

Enhanced Densification in Tl-1223/Ag Tapes Prepared Using Pretreated Precursors

  • Jeong, D.Y;Baek, S.M.;Kim, B.J.;Kim, Y.C.;Park, K.G.
    • Progress in Superconductivity
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    • v.3 no.2
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    • pp.198-212
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    • 2002
  • The effects of reacted precursors on phase evolution, microstructure, $J_{c}$ and junctional characteristic of the inter-granular contacts were investigated in Ag-sheathed T1-1223 tapes prepared using three kinds of reacted precursors, and compared to those in the tape prepared using an unreacted precursor The precursors were prepared by heat-treating a mixture of Sr-Ba-Ca-Cu-O, $Tl_2$$O_3$, PbO and $Bi_2$$O_3$ powders at $805^{\circ}C$ (precursor I ), $840^{\circ}C$ (precursor II ) and $905^{\circ}C$(precursor III) for 20 min. Tl-1223 phase content, grain size and J\ulcorner in the tapes appeared to increase in an order of precursors I, II and III Compared to tapes prepared using an unreacted precursor, the tapes prewar ed using precursors II and III revealed reduced pore and impurity densities and an enhanced texture. Also characteristic of inter -granular contacts and fraction of strong-links were improved. The improved properties are attributed to enhanced densification resulting from using the reacted precursors.s.

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Maximum shear modulus of rigid-soft mixtures subjected to overconsolidation stress history

  • Boyoung Yoon;Hyunwook Choo
    • Geomechanics and Engineering
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    • v.37 no.5
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    • pp.443-452
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    • 2024
  • The use of sand-tire chip mixtures in construction industry is a sustainable and environmentally friendly approach that addresses both waste tire disposal and soil improvement needs. However, the addition of tire chip particles to natural soils decreases maximum shear modulus (Gmax), but increases compressibility, which can be potential drawbacks. This study examines the effect of overconsolidation stress history on the maximum shear modulus (Gmax) of rigid-soft mixtures with varying size ratios (SR) and tire chip contents (TC) by measuring the wave velocity through a 1-D compression test during loading and unloading. The results demonstrate that the Gmax of tested mixtures in the normally consolidated state increased with increasing SR and decreasing TC. However, the tested mixtures with a smaller SR exhibited a greater increase in Gmax during unloading because of the active pore-filling behavior of the smaller rubber particles and the consequent increased connectivity between sand particles. The SR-dependent impact of the overconsolidation stress history on Gmax was verified using the ratio between the swelling and compression indices. Most importantly, this study reveals that the excessive settlement and lower Gmax of rigid-soft mixtures can be overcome by introducing an overconsolidated state in sand-tire chip mixtures with low TC.

Characteristics of Drainage Pervious Block Considering Urban Rainfall (도심지 강우 특성을 고려한 투수성 보도블록의 배수 특성)

  • Seo, Da-Wa;Yun, Tae-Sup;Youm, Kwang-Soo;Jeong, Sang-Seom;Mun, Sung-Ho
    • Journal of the Korean Geotechnical Society
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    • v.31 no.1
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    • pp.53-64
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    • 2015
  • This study presents the experimental results of pervious blocks subjected to a series of unique inflow conditions in urban area. The measured properties include the strength, permeability, drainage capacity and runoff, and evaporation for blocks made of two different size of aggregates. Results revealed that the strength satisfies the Korean Standard regardless of aggregate size whereas the immediate runoff occurred for the block with small size aggregate. On the other hand, the block with large aggregates allowed the drainage upon the initial inflow condition, which became hampered to induce the runoff by subsequent inflow. It was attributed to the fact that the capillary water often served as the hydraulic barrier in partially saturated condition. The salient observation indicated that the runoff highly depended on the evaporation and pre-wetting condition as well as the porosity and pore connectivity. The bilinear evaporate rate that makes the degree of saturation vary also had great influence on deterining the time-dependent runoff.

Effect of subsurface flow and soil depth on shallow landslide prediction

  • Kim, Minseok;Jung, Kwansue;Son, Minwoo;Jeong, Anchul
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.281-281
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    • 2015
  • Shallow landslide often occurs in areas of this topography where subsurface soil water flow paths give rise to excess pore-water pressures downslope. Recent hillslope hydrology studies have shown that subsurface topography has a strong impact in controlling the connectivity of saturated areas at the soil-bedrock interface. In this study, the physically based SHALSTAB model was used to evaluate the effects of three soil thicknesses (i.e. average soil layer, soil thickness to weathered soil and soil thickness to bedrock soil layer) and subsurface flow reflecting three soil thicknesses on shallow landslide prediction accuracy. Three digital elevation models (DEMs; i.e. ground surface, weathered surface and bedrock surface) and three soil thicknesses (average soil thickness, soil thickness to weathered rock and soil thickness to bedrock) at a small hillslope site in Jinbu, Kangwon Prefecture, eastern part of the Korean Peninsula, were considered. Each prediction result simulated with the SHALSTAB model was evaluated by receiver operating characteristic (ROC) analysis for modelling accuracy. The results of the ROC analysis for shallow landslide prediction using the ground surface DEM (GSTO), the weathered surface DEM and the bedrock surface DEM (BSTO) indicated that the prediction accuracy was higher using flow accumulation by the BSTO and weathered soil thickness compared to results. These results imply that 1) the effect of subsurface flow by BSTO on shallow landslide prediction especially could be larger than the effects of topography by GSTO, and 2) the effect of weathered soil thickness could be larger than the effects of average soil thickness and bedrock soil thickness on shallow landslide prediction. Therefore, we suggest that using BSTO dem and weathered soil layer can improve the accuracy of shallow landslide prediction, which should contribute to more accurately predicting shallow landslides.

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