• Title/Summary/Keyword: pore analysis

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Corrosion Behaviors of Dental Implant Alloy after Micro-sized Surface Modification in Electrolytes Containing Mn Ion

  • Kang, Jung-In;Son, Mee-Kyoung;Choe, Han-Cheol
    • Journal of Korean Dental Science
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    • v.11 no.2
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    • pp.71-81
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    • 2018
  • Purpose: The purpose of this study was to investigate the corrosion behaviors of dental implant alloy after microsized surface modification in electrolytes containing Mn ion. Materials and Methods: $Mn-TiO_2$ coatings were prepared on the Ti-6Al-4V alloy for dental implants using a plasma electrolytic oxidation (PEO) method carried out in electrolytes containing different concentrations of Mn, namely, 0%, 5%, and 20%. Potentiodynamic method was employed to examine the corrosion behaviors, and the alternatingcurrent (AC) impedance behaviors were examined in 0.9% NaCl solution at $36.5^{\circ}C{\pm}1.0^{\circ}C$ using a potentiostat and an electrochemical impedance spectroscope. The potentiodynamic test was performed with a scanning rate of $1.667mV\;s^{-1}$ from -1,500 to 2,000 mV. A frequency range of $10^{-1}$ to $10^5Hz$ was used for the electrochemical impedance spectroscopy (EIS) measurements. The amplitude of the AC signal was 10 mV, and 5 points per decade were used. The morphology and structure of the samples were examined using field-emission scanning electron microscopy and thin-film X-ray diffraction. The elemental analysis was performed using energy-dispersive X-ray spectroscopy. Result: The PEO-treated surface exhibited an irregular pore shape, and the pore size and number of the pores increased with an increase in the Mn concentration. For the PEO-treated surface, a higher corrosion current density ($I_{corr}$) and a lower corrosion potential ($E_{corr}$) was obtained as compared to that of the bulk surface. However, the current density in the passive regions ($I_{pass}$) was found to be more stable for the PEO-treated surface than that of the bulk surface. As the Mn concentration increased, the capacitance values of the outer porous layer and the barrier layer decreased, and the polarization resistance of the barrier layers increased. In the case of the Mn/Ca-P coatings, the corroded surface was found to be covered with corrosion products. Conclusion: It is confirmed that corrosion resistance and polarization resistance of PEO-treated alloy increased as Mn content increased, and PEO-treated surface showed lower current density in the passive region.

Comparison of Two Methods for Analyzing Stress-Strain Behavior of Soil Beam (지반보의 응력-변형률 거동에 대한 해석법 비교)

  • Lee, Seung-Hyun;Han, Jin-Tae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.12
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    • pp.294-302
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    • 2018
  • To analyze the behavior of a soil beam under pore water pressure, the results of analytical solutions and finite element analysis (FEM) were compared quantitatively. In contrast to the results of the analytical solution, the horizontal stress obtained from the FEM did not show a symmetrical distribution. On the other hand, the horizontal stress became closer to symmetrical distribution as the number of elements of the soil beam were increased. A comparison of the horizontal stresses from the analytic solution with those obtained from Gaussian points of FEM showed that the magnitude of the tensile stress from the FEM using 3 elements was 6% of the maximum value of the analytical solution and the compressive stress from the FEM using the same elements was 37% of the maximum value of the analytical solution. The magnitude of the tensile stress from the FEM using 6 elements was 61% of the maximum value of the analytical solution and the magnitude of the compressive stress from the FEM using the elements was 83% of the maximum value of the analytical solution. Vertical stresses, which were obtained from the analytical solution, showed a continuous distribution with the depth of the soil beam, whereas the vertical stresses from the FEM showed a discrete distribution corresponding to each element. The results also showed that the average value of the vertical stresses of each element was close to that of the pore water pressure. A comparison of the vertical displacements computed at the near vertical center line of the soil beam from the FEM with those of the analytical solution showed that the magnitude of the vertical displacement from FEM using 3 elements was 35% of the value of the analytical solution and the magnitude of the vertical displacement from FEM using 6 elements was 57% of the value of the analytical solution.

Characterization of Charcoals prepared by Korean Traditional Kiln (우리나라 전통 숯가마로부터 생산된 숯의 특성분석)

  • An, Ki Sun;Kwak, Lee Ku;Kim, Hong Gun;Ryu, Seung Kon
    • Korean Chemical Engineering Research
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    • v.60 no.2
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    • pp.208-216
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    • 2022
  • Surface morphology and adsorption characteristics of black and white charcoals prepared from Korean traditional kiln were quantitatively analyzed. TGA and elemental analysis of charcoals were different from produced kiln, and thermal degradation temperature and carbon content of white charcoals were apparently higher than those of black charcoals. Surface morphology shows the activation progressed through the longitudinal direction of woods and new micropores were developed to radial direction on the surface of macropores as the furthermore activation resulting in the pore connection. BET adsorption isotherms show that there are low-pressure hysteresis due to the no desorption of adsorbates, which resulted in unique Type of charcoals overlapping Type I and Type IV. Such a low-pressure hysteresis is occurred from expansion of adsorbates, which were embedded in the micropore entrances and did not get out during the desorption run. The characteristics of charcoals such as specific surface area and pore size distribution did not show correct values depending on not only produced company but also sampling sites of one piece of charcoal. Therefore, it is not easy to suggest the quantitative characteristics of charcoals prepared from Korean traditional kiln. On the other hand, preparation the quality standard of charcoal is necessary for their special uses such as adsorbent.

Uplift Pressure Removal System in Underground Structure by Utilizing Geocomposite System (지오컴포지트를 이용한 양압력 제거공법)

  • Shin, Eun-Chul;Kim, Jong-In;Park, Jeong-Jun
    • Journal of the Korean Geotechnical Society
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    • v.22 no.9
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    • pp.61-68
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    • 2006
  • Recently the large scale civil engineering projects are being implemented by reclaiming the sea or utilizing seashore and river embankment areas. The reclaimed land and utilized seashore are mostly soft ground that doesn't have sufficient bearing capacity. This soft ground consists of fine-grained soil such as clayey and silty soils or large void soil like peat or loose sand. It has high ground water table and it may cause the failure and crock of building foundation by uplift pressure and ground water leakage. In this study, the permittivity and the transmissivity were evaluated with the applied normal pressure in the laboratory. The laboratory model tests were conducted by utilizing geocomposite drainage system for draining the water out to release the uplift pressure. The soil used in the laboratory drainage test was dredged soil from the reclaimed land where uplift pressure problems can arise in soil condition. Geocomposite drainage system was installed at the bottom of apparatus and dredged soil was layered with compaction. Subsequently the water pressure was supplied from the top of specimen and the quantities of drainage and the pore water pressure were measured at each step water pressure. The results of laboratory measurements were compared with theoretical values. For the evaluation of propriety of laboratory drainage test, 2-D finite elements analysis that can analyze the distribution and the transferring of pore water pressure was conducted and compared with laboratory test results.

Analysis of contamination characteristics of filter cloth in filter press by repeated dehydration of organic sludge and evaluation of ultrasonic cleaning application (유기성 슬러지 반복 탈수에 의한 필터프레스 여과포 오염 특성 분석 및 초음파 세척 적용 평가)

  • Eunju Kim;Cheol-Jin Jeong;Kyung Woo Kim;Tae Gyu Song;Seong Kuk Han
    • Journal of the Korea Organic Resources Recycling Association
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    • v.32 no.2
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    • pp.15-25
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    • 2024
  • In this study, the regeneration effect of pressurized water and ultrasonic cleaning was investigated for contaminated filter cloth from the sewage sludge filter press process. For this purpose, contaminated filter cloth was collected from a 3-ton sewage sludge hydrothermal carbon treatment filter press. First, the contamination characteristics were analyzed. According to the location of the filter cloth, air permeability and unit mass were measured, and compared with the values of a new filter cloth. Next, the results were mapped over the entire area to evaluate the contamination characteristics. Finally, pressure cleaning at 3 bar and ultrasound at frequencies of 34, 76, 120, and 168 kHz were performed on the contaminated filter cloth. In addition, the cleaning efficiency was evaluated by 3 levels of contamination degree. As a result, pore contamination occurred mainly at the bottom and both sides of the filter cloth, where the filter material was continuously injected and compressed. Surface contamination appeared evenly over the entire area. As a result of washing, air permeability increased by 1.3-3.1%p and contaminant removal was by 2.7-4.4% under pressure. In ultrasonic cleaning, air permeability increased by 12.5-61.5%p and contaminants were removed by 2.7-29.2%. In ultrasonic cleaning the lower the frequency, the higher air permeability and contaminant removal rate. Also, The higher pore contamination level, the better the air permeability improvement and contaminant removal.

A Study on Change in Cement Mortar Characteristics under Carbonation Based on Tests for Hydration and Porosity (수화물 및 공극률 관측 실험을 통한 시멘트모르타르의 탄산화 특성 변화에 대한 연구)

  • Kwon, Seung-Jun;Song, Ha-Won;Park, Sang-Soon
    • Journal of the Korea Concrete Institute
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    • v.19 no.5
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    • pp.613-621
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    • 2007
  • Due to the increasing significance of durability, much researches on carbonation, one of the major deterioration phenomena are carried out. However, conventional researches based on fully hardened concrete are focused on prediction of carbonation depth and they sometimes cause errors. In contrast with steel members, behaviors in early-aged concrete such as porosity and hydrates (calcium hydroxide) are very important and may be changed under carbonation process. Because transportation of deteriorating factors is mainly dependent on porosity and saturation, it is desirable to consider these changes in behaviors in early-aged concrete under carbonation for reasonable analysis of durability in long term exposure or combined deterioration. As for porosity, unless the decrease in $CO_2$ diffusion due to change in porosity is considered, the results from the prediction is overestimated. The carbonation depth and characteristics of pore water are mainly determined by amount of calcium hydroxide, and bound chloride content in carbonated concrete is also affected. So Analysis based on test for hydration and porosity is recently carried out for evaluation of carbonation characteristics. In this study, changes in porosity and hydrate $(Ca(OH)_2)$ under carbonation process are performed through the tests. Mercury Intrusion Porosimetry (MIP) for changed porosity, Thermogravimetric Analysis (TGA) for amount of $(Ca(OH)_2)$ are carried out respectively and analysis technique for porosity and hydrates under carbonation is developed utilizing modeling for behavior in early-aged concrete such as multi component hydration heat model (MCHHM) and micro pore structure formation model (MPSFM). The results from developed technique is in reasonable agreement with experimental data, respectively and they are evaluated to be used for analysis of chloride behavior in carbonated concrete.

Field Loss Analysis and Cooling Analysis of HTS Synchronous Motor (고온초전도 동기모터의 계자손실 해석 및 냉각 해석)

  • Kim, Ki-Chan;Lee, Dae-Dong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.3
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    • pp.69-74
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    • 2018
  • Large industrial motors require a large area because of the high risk of shutdown accidents and large industrial accidents due to the lowering of the dielectric strength of the armature windings and overheating problems. Therefore, there is a demand for a large-capacity motor that has small size, light weight, and excellent dielectric strength compared with conventional motors. Superconducting motors have advantages of high efficiency and output power, low size, low weight, and improved stability. This results from greatly increasing the magnetic field generation by using superconductive field coils in rotating machines such as generators and motors. It is very important to design and analyze the cooling system to lower the critical temperature of the wires to achieve superconducting performance. In this study, a field loss analysis and low-temperature heat transfer analysis of the cooling system were performed through the conceptual design of a 100-HP high-temperature superconducting synchronous motor. The field loss analysis shows that a uniform pore magnetic flux density appears when high-temperature superconducting wire is used. The low-temperature heat transfer analysis for gaseous neon and liquid neon showed that a flow rate of 1 kg/min of liquid neon is suitable for maintaining low-temperature stability of the high-temperature superconducting wire.

A Role for Leu247 Residue within Transmembrane Domain 2 in Ginsenoside-Mediated α7 Nicotinic Acetylcholine Receptor Regulation

  • Lee, Byung-Hwan;Choi, Sun-Hye;Pyo, Mi Kyung;Shin, Tae-Joon;Hwang, Sung-Hee;Kim, Bo-Ra;Lee, Sang-MoK;Lee, Jun-Ho;Lee, Joon-Hee;Lee, Hui Sun;Choe, Han;Han, Kyou-Hoon;Kim, Hyoung-Chun;Rhim, Hyewhon;Yong, Joon-Hwan;Nah, Seung-Yeol
    • Molecules and Cells
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    • v.27 no.5
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    • pp.591-599
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    • 2009
  • Nicotinic acetylcholine receptors (nAChRs) play important roles in nervous system functions and are involved in a variety of diseases. We previously demonstrated that ginsenosides, the active ingredients of Panax ginseng, inhibit subsets of nAChR channel currents, but not ${\alpha}7$, expressed in Xenopus laevis oocytes. Mutation of the highly conserved Leu247 to Thr247 in the transmembrane domain 2 (TM2) channel pore region of ${\alpha}7$ nAChR induces alterations in channel gating properties and converts ${\alpha}7$ nAChR antagonists into agonists. In the present study, we assessed how point mutations in the Leu247 residue leading to various amino acids affect 20(S)-ginsenoside $Rg_3$ ($Rg_3$) activity against the ${\alpha}7$ nAChR. Mutation of L247 to L247A, L247D, L247E, L247I, L247S, and L247T, but not L247K, rendered mutant receptors sensitive to $Rg_3$. We further characterized $Rg_3$ regulation of L247T receptors. We found that $Rg_3$ inhibition of mutant ${\alpha}7$ nAChR channel currents was reversible and concentration-dependent. $Rg_3$ inhibition was strongly voltage-dependent and noncompetitive manner. These results indicate that the interaction between $Rg_3$ and mutant receptors might differ from its interaction with the wild-type receptor. To identify differences in $Rg_3$ interactions between wild-type and L247T receptors, we utilized docked modeling. This modeling revealed that $Rg_3$ forms hydrogen bonds with amino acids, such as Ser240 of subunit I and Thr244 of subunit II and V at the channel pore, whereas $Rg_3$ localizes at the interface of the two wild-type receptor subunits. These results indicate that mutation of Leu247 to Thr247 induces conformational changes in the wild-type receptor and provides a binding pocket for $Rg_3$ at the channel pore.

Finite Element Analysis for the Effects on the Stiffness of the Embankment and Sandmat on the Deformation Property and the Safety of Road Embankment (성토체 및 모래매트의 강성이 하부지반의 변형과 성토체의 안전에 미치는 영향에 대한 유한요소해석)

  • Bae, Woo-Seok;Kim, Jong-Woo;Kwon, Young-Cheul
    • Journal of the Korean Society of Safety
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    • v.22 no.4
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    • pp.57-65
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    • 2007
  • Effects on the stiffness of the embankment and sandmat on the construction safety of road embankment was investigated in this study by the numerical experiments using FEM. Two points was mainly focused in this study especially. First the deformation characteristics by the change of the stiffness of sand mat and embankment was investigated by the analyzing the consolidation settlement at the center of the embankment and the lateral displacement at the toe of the embankment. And, the effect of the stiffness on the stress distribution characteristics was also investigated in this study. Furthermore, slope stability analysis was carried out to gain the safe factor by change the stiffness of the sandmat and the embankment. The objective of the study is supplying the result of the numerical experiments for the geotechnical engineers who use the FEM for the safety design of the soil structures. As a result, the stiffness of the superstructures greatly affects on the deformation characteristics both in consolidation settlement and lateral displacement. However, it can be aware that it is not dominants to the stress distribution in the aspect that the no changes in the residual excess pore water pressure. Therefore, the decision of the stiffness has to be carried out deliberately considering not only the consolidation the magnitude of the settlement and the lateral displacement, but the slope stability.

Sequence analysis of partial LSU rDNA of three Alexandrium species (Dinophyceae) hitherto unreported

  • Kim, Keun-Yong;Makoto Yoshida;Kim, Chang-Hoon
    • Proceedings of the Korean Aquaculture Society Conference
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    • 2003.10a
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    • pp.35-35
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    • 2003
  • We, for the first time, reported molecular sequences of large subunit ribosomal DNA Dl-D3 region of A. hiranoi, A. leei and A. satoanum hitherto unreported. In addition, this study presented the full-length sequences of A. affine, A. fraterculus, A. catenella and A. tamarense occurring in Korean coastal waters. In total, 17 Alexandrium morphospecies were subjected to the phylogenetic analysis using the Maximum-likelihood (ML) method. The alignment result of sequences of A. hiranoi and A. pseudogonyaulax showed that there were only two substitutions without length heterogeneity implying their genetic affiliation. In ML tree, A. leei formed a deeply diverging branch probably because of the accelerated evolutionary rate, and its phylogenetic position was so ambiguous to resolve the phylogenetic relationship to the residual taxa. An A. satoanum culture showing morphological variation in the sulcal plate formed an independent divergent branch with consistent sister relationship to A. hiranoi/A. pseudogonyaulax clade supported by the high posterior probability (PP) value. Blast search in GenBank showed the sequence data of A. affine, A. fraterculus, A. catenella and A. tamarense corresponded to their morphological species designation. In ML tree, Alexandrium species were commonly split into four main clades. The inter-clade relationships were not clear and usually supported by the week PP values. In general, the sulcal plate of Alexandrium species seemed to reflect the true phylogeny at the main clade level, and the connection between the 1 and the apical pore complex seemed to reflect the phylogeny at the subclade level.

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