• Corrosion Science and Technology
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• v.3 no.6
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• pp.245-250
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• 2004

A series of classical G109 type concrete specimens was exposed to cyclic wet and dry ponding with 15 w/o NaCl solution for approximately five years. Mix design variables included 1) three cement alkalinities (EqA of 0.97, 0.52, and 0.36) and 2) three water-cement ratios (0.50, 0.41, and 0.37). To determine the corrosion initiation time, corrosion potential and macro-cell current between top and bottom bars were monitored. Subsequent to corrosion initiation, specimens were autopsied and visually inspected. Concrete powder samples were collected from top rebar trace and chloride concentration was measured. Also, time-to-corrosion, $T_i$, for specimens of the individual mix designs was represented using Weibull analysis. Time-to-corrosion was a distributed parameter; and because of this, corrosion initiation of four identical specimens for each mix varied, often over a relatively wide range. Specimens fabricated using the lowest water cement ratio and the highest alkalinity cement exhibited the longest time-to-corrosion initiation and the highest chloride threshold levels. Time-to-corrosion did not increase monotonically with cement alkalinity, however, presumably as a consequence of relatively high $Cl^-$ binding in the lower pore water pH range. The chloride threshold level, $Cl_{th}$, increased with increasing $T_i$ and, consequently, was greatest for the highest cement alkalinity specimens.

• Computers and Concrete
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• v.7 no.3
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• pp.239-247
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• 2010

A proposed topology method is introduced to measure the air content of fresh cement paste and hardened concrete. The method takes advantage of chromatographic analysis in void areas that are highlighted using different color schemes and later calculated using built-in computer software. The air content measured by the topology method is compared with results obtained from the conventional ASTM methods. It is concluded that the proposed method is reliable, and costs less and is easier to operate compared with the ASTM methods. In addition, 3 dimensional pore models can be created using image post-processing techniques. The proposed method helps researchers in understanding the formation and existence of concrete pores. This paper reports a detailed test program demonstrating the standard operating procedure used for the proposed method and presents a comparison of results between the proposed method and conventional ASTM Specifications. It is also concluded that the air content increases with increasing size of pores and increasing percentage of coarse aggregates.

• Bulletin of the Korean Chemical Society
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• v.30 no.1
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• pp.193-196
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• 2009

Mesoporous $TiO_2$ material was synthesized from diblock copolymers with ethylene oxide chains via a sol-gel process in aqueous solution. The properties of these materials were characterized with several analytical techniques including field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), wide angle X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) analysis, and Barrett-Joyner-Halenda (BJH) analysis. The mesoporous $TiO_2$ materials calcined at 400${^{\circ}C}$ were found to have specific surface areas 212 $m^2g^-1$, average pore sizes 6.2 nm, and their average crystal sizes were found to be 8.2 nm. The photocatalytic activity of mesoporous $TiO_2$ was characterized with UV-Vis spectroscopy, and it was found to be 5.8 times higher than that of Degussa P25 $TiO_2$ (P25). For deactivation of Escherichia coli, mesoporous $TiO_2$ also has high photocatalytic inactivity than that of P25. Such a high photocatalytic activity is explained with large surface area and small crystal size with wormhole-like mesoporous structure.

• Structural Engineering and Mechanics
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• v.33 no.4
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• pp.429-446
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• 2009

Three-scale homogenization procedure is proposed in this paper to provide estimates of the effective thermal conductivities of porous carbon-carbon textile composites. On each scale - the level of fiber tow (micro-scale), the level of yarns (meso-scale) and the level of laminate (macro-scale) - a two step homogenization procedure based on the Mori-Tanaka averaging scheme is adopted. This involves evaluation of the effective properties first in the absence of pores. In the next step, an ellipsoidal pore is introduced into a new, generally orthotropic, matrix to make provision for the presence of crimp voids and transverse and delamination cracks resulting from the thermal transformation of a polymeric precursor into the carbon matrix. Other sources of imperfections also attributed to the manufacturing processes, including non-uniform texture of the reinforcements, are taken into consideration through the histograms of inclination angles measured along the fiber tow path together with a particular shape of the equivalent ellipsoidal inclusion proposed already in Sko ek (1998). The analysis shows that a reasonable agreement of the numerical predictions with experimental measurements can be achieved.

• Proceedings of the Korean Geotechical Society Conference
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• 1998.04a
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• pp.37-46
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• 1998

Several researchers have developed a number of theoretical time factors to determine the coefficient of consolidation by biezocone excess pore water dissipation test in soft clay deposits. However, depending on the assumptions and analytical techniques, the estimated coefficient of consolidation could be in a considerably wide range even for a specific degree of consolidation. These solutions are obtained from an initial excess porewater pressure distribution which can be determined from. either the cavity expansion theory or the strain path method. The 야ssipation of the initial excess porelvater pressure has been usally simulated by means of linear-uncoupled consolidation analysis and then the dissipation curve is normalized by the initial excess porewater pressure for easy use. However. since there is no guidelines or rules on which method gives the best solution for obtaining the coefficient of consolidation from the dissipation curve, the final selection was only based on engineer's extrience and Judgements. Thus, such an arbitrary selection might be inappropriate for a specific site to characterize the consolidation behavior. In this paper, we reviewed various theoretical time factors and, based on this consideration, we mentioned needs for researches in selecting a specific solution that is compatible for Korean clays. Also we listed some source of errors that can be encountered in the procedure of dissipation analysis.

• Geotechnical Engineering
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• v.13 no.1
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• pp.47-58
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• 1997

The predicted consolidation behavior of in-situ soft clay is quite different from the meas ureal one mainly due to the approximate numerical modelling techniques as well as the uncertainties involved in soil properties and geological configurations. In order to improve the prediction, this paper takes the following pinto consideration : an optimization technique should be adopted for characterizing the in-situ properties from measurements and also an equivalent and efficient model be considered to incorporate the actual 3-D effects. The soil parameters used be the modified Camflay model, which have an effect on the process of consolidation, were back-analyzed by BFGS scheme on the basis of settlements and pore pressures measured in real sites. The optimization technique was implemented in a general consolidation analysis program SPINED. By using the program, one may be able to appropriately analyze the timetependent consolidation behavior of soft deposits.

• Journal of the Korean Applied Science and Technology
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• v.31 no.3
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• pp.394-401
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• 2014

In order to minimize a building energy consumption with ventilation, a development of smart ventilation system is very important. In this study, a dry adsorbent that is main element of smart ventilation system was developed for removing indoor $CO_2$, and evaluate the adsorption performance. Specific surface area, pore characteristic and crystal structure of the modified sorbent was measured to analyze physical properties. From this analysis, it was found that the developed absorbent has a low specific surface area, due to mesopores of substrate was filled with metal contained raw material. Additionally, through analysis of the adsorption properties, the developed adsorbent was shown a adsorption form of mesopore (type IV), which means adsorption amount was rapidly increased at the part of high-pressure. Order to applying for the field, chamber test was performed. Continuous column tests (2,500 ppm) and batch chamber tests ($4m^3$, 5,000 ppm) showed $CO_2$ removal efficiency of 95% and 88% within 1 hour, respectively.

• Geomechanics and Engineering
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• v.21 no.3
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• pp.279-288
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• 2020

The permeation grouting is a commonly used technique to improve the engineering geology condition of the soft ground. It is of great significance to predict the permeation range of the grout so as to ensure the effects of grouting. This paper conducts a theoretical analysis of jet-grouting effects in ground improvement and rotary grouting pile installation by utilizing deformation-permeation coupled poroelastic solutions based on Biot's theory and Laplace-Fourier integral transform technique. The exponential function and the intermittent trigonometric function are chosen to represent time-dependent grouting pressure usually encountered in ground improvement and rotary grouting pile installation process, respectively. The results, including the radial displacement, the hoop stress, the excess pore fluid pressure, the radial discharge, and the permeation radius of grout, are presented for different grouting time, radial positions and grouting lengths. Parametric study is conducted to explore the effects of variation of the exponent in the exponential grouting pressure-time relationship on grouting-induced responses. It is expected that the proposed solutions can be used to estimate the permeation range of grouting in ground improvement and rotary grouting pile installation.

• Bulletin of the Korean Chemical Society
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• v.19 no.11
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• pp.1185-1188
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• 1998

Layered nanocomposite, SiO2/TiO2 sol pillared clay, has been prepared by the ion exchange reaction of Na' ion in montmorillonite with positively charged mixed SiO2/TiO2 sol. The nanosized sol particles were synthesized by mixing SiO2 sol solution with TiO2 one, which is obtained by acidic hydrolysis of TEOS and TiCl4, respectively. From powder XRD, the basal spacing (d001) of the sample calcined at 400 ℃ was found to be ca. 60 Å, due to the multistacking of nanosized SiO2 and TiO2 sol particles, which was confirmed by the pore size analysis from 129Xe NMR and micropore analysis calculated from nitrogen adsorption. The BET specific surface area shows the value of 684 m2g-1 (Langmuir 1115 m2g-1), which is the highest among various pillared clays ever reported previously, and the total porosity is found to be 0.51 mlg-1, and the pores are mainly composed of micropore with a size of ca. 11.8 Å. This result agrees with the adsorption capacity obtained from water adsorption. According to diffuse reflectance ultraviolet-visible spectroscopy, it is found that the TiO2 particles stabilized in the interlayer space of montmorillonite are quantum-sized of ca. 20 Å.

• Advances in nano research
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• v.7 no.2
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• pp.109-123
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• 2019

In this article, the free vibration analysis of annular sandwich plates with various functionally graded (FG) porous cores and carbon nanotubes reinforced composite (CNTRC) facesheets is investigated based on modified couple stress theory (MCST) and first order shear deformation theories (FSDT). The annular sandwich plate is composed of two face layers and a functionally graded porous core layer which contains different porosity distributions. Various approaches such as extended mixture rule (EMR), Eshelby-Mori-Tanaka (E-M-T), and Halpin-Tsai (H-T) are used to determine the effective material properties of microcomposite circular sandwich plate. The governing equations of motion are extracted by using Hamilton's principle and FSDT. A Ritz method has been utilized to calculate the natural frequency of an annular sandwich plate. The effects of material length scale parameters, boundary conditions, aspect and inner-outer radius ratios, FG porous distributions, pore compressibility and volume fractions of CNTs are considered. The results are obtained by Ritz solutions that can be served as benchmark data to validate their numerical and analytical methods in the future work and also in solid-state physics, materials science, and micro-electro-mechanical devices.