• Title/Summary/Keyword: pore analysis

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An Experimental Study on the Microstructure Characteristics of Cementitious Composites by MIP (MIP를 통한 혼합 시멘트계 재료의 미세구조 특성에 관한 실험적 연구)

  • Kim, Tae-Sang;Jung, Sang-Hwa;Chae, Seong-Tae;Lee, Bong-Chun;Woo, Young-Je;Song, Ha-Won
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.533-536
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    • 2008
  • Recently, in Korea, there has been an increasing number of research papers published which are to improve durability of concrete, particularly by analyzing correlation between diffusivity of chloride and porosity/pore size distribution. In these studies, such test methods as mercury intrusion porosimetry(MIP), gas adsorption or image analysis method are used to analyze the microstructure of materials while MIP is most widely used for concrete. This study analyzes the results of porosity and pore size distribution of paste and concrete adding fly ash or blast furnace slag by using MIP equipment which is widely used for determining micro-porosity structure of cementitious materials. A variation in porosity and pore size distribution at the curing day 3, 7 and 28 has been observed by using MIP equipment for cement paste 35%, 40%, 45%, 50%, 55%, 60% of W/C when using $300kg/m^3$ of cement, 35%, 45%, 55% of W/C when replaced 60% with blast-furnace slag, and 35%, 45%, 55% of W/C when replaced 30% with fly ash. For long-term water cured normal OPC concrete and mixed concrete replaced 60% with blast-furnace slag powder, micro-structure of the sample has been analyzed by using MIP equipment when W/C indicated 40%, 45%, 50% respectively and the binder varied $300kg/m^3$, $350kg/m^3$, $400kg/m^3$, and $450kg/m^3$.

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A study on the structure of Si-O-C thin films with films size pore by ICPCVD (ICPCVD방법에 의한 나노기공을 갖는 Si-O-C 박막의 형성에 관한 연구)

  • Oh, Teresa
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2002.11a
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    • pp.477-480
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    • 2002
  • Si-O-C(-H) thin film with a tow dielectric constant were deposited on a P-type Si(100) substrate by an inductively coupled plasma chemical vapor deposition (ICPCVD). Bis-trimethylsilymethane (BTMSM, H$_{9}$C$_3$-Si-CH$_2$-Si-C$_3$H$_{9}$) and oxygen gas were used as Precursor. Hybrid type Si-O-C(-H) thin films with organic material have been generated many voids after annealing. Consequently, the Si-O-C(-H) films can be made a low dielectric material by the effect of void. The surface characterization of Si-O-C(-H) thin films were performed by SEM(scanning electron microscope). The characteristic analysis of Si-O-C(-H) thin films were performed by X-ray photoelectron spectroscopy (XPS).

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A Study on Experimental Prediction of Landslide in Korea Granite Weathered Soil using Scaled-down Model Test (축소모형 실험을 통한 국내 화강암 풍화토의 산사태 예측 실험 연구)

  • Son, In-Hwan;Oh, Yong-Thak;Lee, Su-Gon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.6
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    • pp.439-447
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    • 2019
  • In this study, experiments were conducted to establish appropriate measures for slopes with high risk of collapse and to obtain results for minimizing slope collapse damage by detecting the micro-displacement of soil in advance by installing a laser sensor and a vibration sensor in the landslide reduction model experiment. Also, the behavior characteristics of the soil layer due to rainfall and moisture ratio changes such as pore water pressure and moisture were analyzed through a landslide reduction model experiment. The artificial slope was created using granite weathering soil, and the resulting water ratio(water pressure, water) changes were measured at different rainfall conditions of 200mm/hr and 400mm/hr. Laser sensors and vibration sensors were applied to analyze the surface displacement, and the displacement time were compared with each other by video analysis. Experiments have shown that higher rainfall intensity takes shorter time to reach the limit, and increase in the pore water pressure takes shorter time as well. Although the landslide model test does not fully reflect the site conditions, measurements of the time of detection of displacement generation using vibration sensors show that the timing of collapse is faster than the method using laser sensors. If ground displacement measurements using sensors are continuously carried out in preparation for landslides, it is considered highly likely to be utilized as basic data for predicting slope collapse, reducing damage, and activating the measurement industry.

An Analysis of the Settlement Behavior of Soft Clayey Ground Considering the Effect of Creep during the Primary Consolidation (1차압밀과정중의 크리프의 영향을 고려한 연약 점성토지반의 침하거동 해석)

  • Baek, Won-Jin;Matsuda, Hiroshi;Choi, Woo-Jung;Kim, Chan-Kee;Song, Byung-Gwan
    • Journal of the Korean Geotechnical Society
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    • v.24 no.5
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    • pp.107-115
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    • 2008
  • This paper is performed to examine the effect of creep during the primary consolidation and the applicability of the Yin's EVP (Elasto-Visco-Plastic) model. In ordinary consolidation theories using the elastic model, the primary consolidation process can be expressed but the secondary consolidation process cannot. It is due to the viscosity, which can express the secondary consolidation, and is sometimes related to the scale effect (difference of the thickness of clay layer between laboratory sample and field condition) such as hypotheses Type A and Type B shown by Ladd et al. (1977). Usually, the existence of the creep during the primary consolidation has been conformed and the Type B is well acceped. On the other hand, from the large-scaled consolidation tests the intermediate characteristic between Type A and Type B was proposed as Type C by Aboshi (1973). In this study, to clarify the effect of creep on the settlement-time relation during the primary consolidation in detail, Type B consolidation tests were performed using the separate-type consolidation test apparatus for a peat and clay. Then the test results were analyzed by using Yin's EVP Model (Yin and Graham, 1994). In conclusion, followings were obtained. At the end of primary consolidation, the compression for the subspecimens should not be the same because of the difference of the excess pore water pressure dissipation rate. And the average settlement measured by the separate-type consolidometer coincides with the analyzed one using the Yin's EVP model. As for the dissipation of the excess pore water pressure, however, the measured excess pore water pressure dissipates faster compared with the Yin's model.

Surface analysis of rayon-based carbon nanofibers and activated carbon fibers (레이온을 이용한 카본나노섬유와 활성카본섬유의 표면 특성분석)

  • Kim, Youn Jung;Ryu, Sang Hoon;Lim, Woo Taik;Choi, Sik Young
    • Analytical Science and Technology
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    • v.20 no.4
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    • pp.296-301
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    • 2007
  • Carbon nanofibers (CNFs) are non-microporous materials with a high surface area ($100{\sim}200m^2/g$) and high purity. Therefore, the material has a high potential for use as catalyst support. Activated carbon fibers (ACFs) are of increasing concern with regard to the levels of toxic air pollutants emitted from high-technology industry. Rayon-based CNFs and ACFs was subjected to thermal oxidation under a wide variety of temperature and air conditions to modify the surface properties. Rayon-based CNFs and ACFs were prepared by using thermal chemistry. CNFs were synthesized at temperatures above $600^{\circ}C$ in an air atmosphere and grew with increased temperature and air conditions. After heating at $800^{\circ}C$ for 72 hr, carbonized rayon with ACFs had $2,662m^2/g$ (BET) of surface area and $1.41cm^3/g$ of pore volume. The resulting ACFs had a 99% surface area in which pore size was 10 nm or less, and a 60 % surface area in which pore size was 2 nm or less.

Correlatin between the Microstructure and the Electrical Conductivity of SOFC anode, Ni-YSZ : I. Microstructure Analysis (SOFC 음극용 Ni-YSZ 복합체의 미세구조와 전기적 물성간의 상관관계 : I. 미세구조 분석)

  • Moon, Hwan;Lee, Hae-Weon;Lee, Jong-Ho;Yoon, Ki-Hyun
    • Journal of the Korean Ceramic Society
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    • v.37 no.5
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    • pp.479-490
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    • 2000
  • The microstructure of Ni-YSZ composite as an anode of SOFC was investigated as a function of Ni content(10-70 vol%) in order to examine the correlation between microstructural-and electrical property. Image analysis based on quantitative microscopy theory was performed to quantify the microstructural property. We could get the informations about the size and distribution, contiguity and interfacial area of each phase or between the phases from the image analysis. According to the image analysis, contiguity between the same phae was mainly dependent on the amount of the phase while the contiguity between different phases was additionally influenced by the microstructural changes, especailly by the coarsening of the Ni phase. The whole length of pores perimeter was increased as Ni content increased, which indicated the overall microstructural evolution was mostly related with the coarsening of Ni phase. Ni-Ni interfacial area was also gradually increased as Ni content increased but controlled by pore phase at low Ni content region and by YSZ phase at intermediate Ni content region. These quantified microstructural properties were used to characterize the electrical properties of Ni-YSZ composite.

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An Analysis on the Failure Mechanism of Slope behind a Plant Complex of Gimhae due to Typhoon Rusa (태풍 루사에 의한 김해 OO단지 사면붕괴 발생원인 분석)

  • Kang, In-Kyu;Ryu, Jeong-Soo;Kim, Hong-Taek;Baek, Seung-Cheol
    • 한국방재학회:학술대회논문집
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    • 2007.02a
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    • pp.263-266
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    • 2007
  • In this paper, analysis results on the failure of slope behind a Plant Complex of Gimhae due to typhoon Rusa in 2002 are introduced. The left side of the slope was reinforced by soil nails and the right side of the slope was going to construct slope reinforcement works. In the slope failure, the damage area is about $34,000m^2$, the lower width of slope failure is about 230m, the upper width of slope failure is about 50m, and the height of slope failure is about 120m. The elevation of a bedrock in the right side of the slope was lower than the left side of the slope. Due to the depth of weathered soils and weathered rocks in right side of the slope was thick, it will be expected that the effects of pore-water pressure during the rainfalls are large. For the analysis of the failure mechanism, 3-dimensional numerical analysis was carried out by FLAC-3D.

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A study on ground surface settlement due to groundwater drawdown during tunnelling (터널 굴착시 지하수 저하로 인한 지반침하에 관한 연구)

  • Yoo, Chung-Sik;Kim, Sun-Bin
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.9 no.4
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    • pp.361-375
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    • 2007
  • This paper presents the results of investigation on tunnelling-induced ground surface settlement characteristics in water bearing ground using finite element (FE) stress-pore pressure coupled analysis. Fundamental interaction mechanism of ground and groundwater lowering was first examined and a number of influencing factors on the results of the coupled FE analysis were identified. A parametric study was then conducted on the influencing factors such as rock type, thickness of soil layer, permeability of shotcrete lining, among others. The results indicate that the tunneling-induced groundwater drawdown results in a deeper and wider settlement trough than without groundwater drawdown, and that the Error function approach does not yield satisfactory result in predicting a settlement profile. The results of analysis are summarized so that the relationship between the settlement and the influencing factors can be identified.

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A Study on Hydration kinetics and Mechanical Properties of Cement Paste Incoporating Limestone Filler (석회석 미분말을 혼입한 시멘트 페이스트의 수화반응 및 역학적 특성 분석에 관한 연구)

  • Shin, Ki-Su;Bang, Mi-Jin;Park, Ki-Bong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.230-231
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    • 2017
  • The addition of a limestone filler(LF) to fill into the voids between cement and aggregate particles can reduce the cementitious paste volume. This paper aim to evaluate the influence of LF contents on the hydration kinetics and compressive strength. Hydration kinetics were evaluate using heat of hydration, ignition loss and thermal analysis. The heat of hydration was measured using Isothermal Calorimetry. The degree of hydration was measured using ignition loss. Hydration product analysis was carried out by Thermal Gravimetric and Differential Thermal Analysis. The results show that the addition of LF reduces not only the initial setting time and heat of hydration peak, also degree of hydration and rate of strength development at early age increase with the addition of LF. It can be concluded the LF fills the pore between cement particles due to formation of carboaluminate, which may accelerate the setting of cement pastes.

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Analysis of the Negative Skin Friction Acting on a Model Pile (모형말뚝에 작용하는 부마찰력 거동 해석)

  • Lee, Song;Lee, Kyu-Hwan;Yi, Chang-Tok
    • Journal of the Korean Geotechnical Society
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    • v.15 no.2
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    • pp.81-93
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    • 1999
  • This paper investigated the negative skin friction acting on the model piles driven in the cylindrical chamber filled with remolded marine clay. In model tests, three load cells were installed on the model piles consisting of three parts to measure the negative skin friction forces independently. Pore pressures and ground movements were monitored throughout the period of investigation. Finite element analysis was used to simulate the behavior of a model pile. This paper describes the comparison of the behavior of negative skin friction on the single model pile with a numerical analysis by CRISP.

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