• Title/Summary/Keyword: pore analysis

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Preparation and Characterization of Metal-containing Activated Carbon Derived from Phenolic Resin

  • Oh, Won-Chun
    • Carbon letters
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    • v.4 no.2
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    • pp.86-92
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    • 2003
  • A series of micro- and mesoporous activated carbons were prepared from two kinds of phenolic resin using a metal treated chemical activation methodology. $N_2$-adsorption data were used to characterize the surface properties of the produced activated carbons. Results of the surface properties and pore distribution analysis showed that phenolic resin can be successfully converted to micro- and mesoporous activated carbons with specific surface areas higher than 973 $m^2/g$. Activated carbons with porous structure were produced by controlling the amount of metal chlorides ($CuCl_2$). Pore evolvement depends on the amount of additional metal chloride and precursors used. From the SEM and EDX data, copper contents were shown to be most effected by the incremental addition of metal chloride.

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Migration of calcium hydroxide compounds in construction waste soil

  • Shin, Eunchul;Kang, Jeongku
    • Advances in environmental research
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    • v.4 no.3
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    • pp.183-196
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    • 2015
  • Migration of leachate generated through embankment of construction waste soil (CWS) in low-lying areas was studied through physical and chemical analysis. A leachate solution containing soluble cations from CWS was found to have a pH above 9.0. To determine the distribution coefficients in the alkali solution, column and migration tests were conducted in the laboratory. The physical and chemical properties of CWS satisfied environmental soil criteria; however, the pH was high. The effective diffusion coefficients for CWS ions fell within the range of $0.725-3.3{\times}10^{-6}cm^2/s$. Properties of pore water and the amount of undissolved gas in pore water influenced advection-diffusion behavior. Contaminants migrating from CWS exhibited time-dependent concentration profiles and an advective component of transport. Thus, the transport equations for CWS contaminant concentrations satisfied the differential equations in accordance with Fick's 2nd law. Therefore, the migration of the contaminant plume when the landfilling CWS reaches water table can be predicted based on pH using the effective diffusion coefficient determined in a laboratory test.

Further observations on the genetics and morphometrics of Coolia santacroce (Dinophyceae)

  • Karafas, Sarah J.;Tomas, Carmelo R.
    • ALGAE
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    • v.30 no.4
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    • pp.275-280
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    • 2015
  • Coolia santacroce is a newly described epibenthic dinoflagellate species collected from the U.S. Virgin Islands. The original description indicates this species is unique from others in the Coolia monotis complex due to the relative size of the apical pore complex, broad range of pore sizes, and ribosomal DNA. The original description was done based on the isolation and cultivation of one isolate of the organism. In this study, we report three more isolates of Coolia santacroce collected from the Bahamas. Morphological observations were made using scanning electron microscopy that do not correspond to those from the original description, indicating the variability of the morphological features. However, analysis of the D1 / D2 regions of the large subunit rDNA places the three strains in a strongly supported monophyletic clade with the type specimen.

Modeling of sulfate ionic diffusion in porous cement based composites: effect of capillary size change

  • Gospodinov, Peter N.
    • Computers and Concrete
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    • v.4 no.2
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    • pp.157-166
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    • 2007
  • The paper considers a theoretical model to study sulfate ion diffusion in saturated porous media - cement based mineral composites, accounting for simultaneous effects, such as filling micro-capillaries (pores) with ions and chemical products and liquid push out of them. Pore volume change and its effect on the distribution of ion concentration within the specimen are investigated. Relations for the distribution of the capillary relative radius and volume within the composite under consideration are found. The numerical algorithm used is further completed to consider capillary size change and the effects accompanying sulfate ion diffusion. Ion distribution within the cross section and volume of specimens fabricated from mineral composites is numerically studied, accounting for the change of material capillary size and volume. Characteristic cases of 2D and 3D diffusion are analyzed. The results found can be used to both assess the sulfate corrosion in saturated systems and predict changes occurring in the pore structure of the composite as a result of sulfate ion diffusion.

An Analysis on Remediation of Soil Contaminted with Cobalt by Solvent Flushing

  • Kim, Gyenam;Kyungsuk Suh;Huijun Won;Joonbo Shim;Wonzin Oh
    • Nuclear Engineering and Technology
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    • v.32 no.4
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    • pp.342-349
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    • 2000
  • A soil whose texture is silt loam was collected for the study from an area around a nuclear facility in Korea. The equilibrium sorption coefficient between Co$^{2+}$in water and the soil was 1.51/kg, on the other hand, that between Co$^{2+}$ in EDTA and the soil was 0.21/kg. The values calculated by the developed nonequilibrium sorption code corresponded to the experimental values better than those calculated by the existing equilibrium sorption code. When an EDTA solution was used as a solvent to decontaminate Co$^{2+}$ in the soil column, the relative Co$^{2+}$ concentrations of the effluent were higher at 2~10 pore volumes than those of the case using water. The soil in the column was decontaminated by 95.5% of the total amount of Co$^{2+}$ after being flushed with EDTA solution of 20 pore volumes.e volumes.

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An Analysis on the Deformation of Clayey Foundation Using Elasto-Viscoplastic Model (${\cdot}$粘塑性構成式을 使用한 粘性土地盤의 變形解析)

  • Lee, Moon-Soo
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.34 no.2
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    • pp.60-72
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    • 1992
  • This study aims at predicting the behavior of saturated soft clayey foundation subjected to earth structure loads such as tidal dike, embankment etc. by using Biot's consolidation equation coupled with elasto-viscoplastic constitutive model. To validate the computer program developed b author, a case study was performed for the site of Kwang-yang steel works improved by sand drain, where since the beginning of the works, field measurements(settlement, lateral displacement and excess pore water pressure) had been accurately achieved. Comparisons between numerical results and observation values were carried out. The main results obtained are summarized as follows : 1. Settlement and lateral displacement between numerical and observation values show satisfactory accordance. 2. As for the exess pre water pressure, numerical results appear to be larger than observation values, which may be due to the existence of sand seams which were not found during soil investigation. 3. Useful data available for failure prediction of soft foundation can be secured by examining lateral displacement, settlement, exess pore water pressure and stress paths.

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Development of Seepage Monitoring and Analysis Method with the Hydraulic Head Loss Rate in Sea Dike (수두손실률에 의한 방조제 침투류 감시 및 해석 기법 개발)

  • Eam, Sung Hoon;Heo, Gun
    • Journal of The Korean Society of Agricultural Engineers
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    • v.56 no.6
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    • pp.1-9
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    • 2014
  • In this study the pore water pressures were measured in sea dike constructed with the sand dredged in the sea, and they were analyzed with the hydraulic head loss rate to estimate quantitatively the state of blocking seepage in the sea dike embankment. Blocking state was expressed as the number between 0 and 1. the number of 1 means the state of perfectly blocking seepage and the number of 0 means the state of sea water being passing free. The deeper the installed position was the lower the hydraulic head loss rate was and the longer the seepage path length was the higher the hydraulic head loss rate was. The estimated R-squareds were close to 1, which means that the embankment was steady state without movement of soil particles.

Preparation of Cu2(btc)3-AAO Hybrid Membrane by Layer-by-layer Technique (Layer-by-layer 기법을 통한 Cu2(btc)3-AAO 하이브리드 분리막의 제조)

  • Yoo, Hyeonseok;Choi, Jinsub
    • Journal of Surface Science and Engineering
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    • v.51 no.1
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    • pp.21-26
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    • 2018
  • The $Cu_2(btc)_3$ metal-organic frameworks (MOF) coated anodic aluminum oxide (AAO) membrane was successfully prepared by layer-by-layer technique using hand spray method. It was confirmed that the $Cu_2(btc)_3$ layer, which has the pore sized in 2-3 nm, on surface of AAO exhibited the polycrystalline thin film structure by XRD analysis. More than 100 repetitive spray cycles were required to obtain more robust and thick MOFs on AAO and it was possible to uniformly coat both the top and bottom surfaces of the AAO. It should be noted that the MOFs also could be coated on surface of pores resulting in reduce the size of pore from 52 nm to 32 nm.

Analysis of static and dynamic characteristics of strain gradient shell structures made of porous nano-crystalline materials

  • Hamad, Luay Badr;Khalaf, Basima Salman;Faleh, Nadhim M.
    • Advances in materials Research
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    • v.8 no.3
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    • pp.179-196
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    • 2019
  • This paper researches static and dynamic bending behaviors of a crystalline nano-size shell having pores and grains in the framework of strain gradient elasticity. Thus, the nanoshell is made of a multi-phase porous material for which all material properties on dependent on the size of grains. Also, in order to take into account small size effects much accurately, the surface energies related to grains and pores have been considered. In order to take into account all aforementioned factors, a micro-mechanical procedure has been applied for describing material properties of the nanoshell. A numerical trend is implemented to solve the governing equations and derive static and dynamic deflections. It will be proved that the static and dynamic deflections of the crystalline nanoshell rely on pore size, grain size, pore percentage, load location and strain gradient coefficient.

Effects of pore structures on electrochemical behaviors of polyacrylonitrile-based activated carbon nanofibers by carbon dioxide activation

  • Lee, Hye-Min;Kim, Hong-Gun;An, Kay-Hyeok;Kim, Byung-Joo
    • Carbon letters
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    • v.15 no.1
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    • pp.71-76
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    • 2014
  • Activated carbon nanofibers (ACNF) were prepared from polyacrylonitrile (PAN)-based nanofibers using $CO_2$ activation methods with varying activation process times. The surface and structural characteristics of the ACNF were observed by scanning electron microscopy and X-ray diffraction, respectively. $N_2$ adsorption isotherm characteristics at 77 K were confirmed by Brunauer-Emmett-Teller and Dubinin-Radushkevich equations. As experimental results, many holes or cavernous structures were found on the fiber surfaces after the $CO_2$ activation as confirmed by scanning electron microscopy analysis. Specific surface areas and pore volumes of the prepared ACNFs were enhanced within a range of 10 to 30 min of activation times. Performance of the porous PAN-based nanofibers as an electrode for electrical double layer capacitors was evaluated in terms of the activation conditions.