• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2000년도 가을 학술발표회 논문집(II)
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• pp.1115-1120
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• 2000

The purpose of this study is to investigate toughening of unsaturated polyester resin by addition of liquid rubber. In general, unsaturated polyester liquid has strong brittleness in spite of if high strength Therefore; it is difficult use polyurethane liquid rubber for the place where impact resistance is demanded. In this study, it was evaluated strength, impact resistance and fracture toughness by adding to polyurethane liquid rubber(0~25%). As a result, it was found that a tendency to be increase bearing impact and fracture toughness as polyurethane liquid rubber increased but strength was decreased.

• 공업화학
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• 제18권5호
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• pp.527-530
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• 2007

방염도료로 일액형 염화고무(Chlorinated Rubber) 백색도료가 많이 사용되고 있는데 이는 탄화시 검은 연기가 많이 발생되고 목재에 대한 표면강도와 접착력 등의 미흡한 단점이 있어 이러한 점 등을 고려한 Polyurethane Resin계(Alkyd Resin) 이액형 방염우레탄라카 백색도료를 개발하였다. 본 실험에서 개발한 목재용 Polyurethane Resin계 방염도료 조성의 물성은 기존의 방염백색도료보다 목재와의 친화력이 향상되고 다량의 연기발생은 억제하는 결과를 얻었다.

• Elastomers and Composites
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• 제29권3호
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• pp.226-233
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• 1994

The properties of the mixed prepolymer-urethane in the range of 10-40 phr were observed. LBR and LCR have same functional group but different in structure of molecular. The viscosity of mixture depending on content of rubber, adhesive strength, thermal property and compatibility with a diluted solvent are as follows: 1. The viscosity of the mixture was influenced by solubility of the diluent for urethane resin and liquid rubber. 2. Adhesive strength showed the highest value at 30phr rubber, decreased gradually at above 30phr rubber. And LBR revealed better physical property than that of LCR. 3. The most effective factors affecting adhesive strength are molecular structure of rubber, the type of solvent, and volatility. 4. Urethane resin containing LBR showed better compatibility for solvent and faster drying velocity. 5. LBR showed more favorable compatibility and dispersion state than those of LCR by analyzing the results of SEM.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 봄 학술발표회 논문집
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• pp.371-376
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• 2001

The purpose of this study is to investigate toughening of unsaturated polyester resin by addition of polyuretane liquid rubber. In general, unsaturated polyester resin has strong brittleness in spite of its high strength Therefore; it is difficult to use unsaturated polyester mortar for the place where impact resistance is demanded. In this study, it was evaluated strength and Gf by using to polyurethane liquid rubber. As a result, the toughness of unsaturated polyester mortar was increased by polyuretane liquid rubber.

• Elastomers and Composites
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• 제25권3호
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• pp.195-202
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• 1990

Rubber-modified polyurethane resin which was prepolymer type terminated with NCO, was synthesized by reacting isocyanate groups[NCO] and hydroxyl groups[OH]. Polybutadiene rubbers which had OH groups in the side of rubber chains, were charged at ratio $0%{\sim}40%$ of solid component in reactants. For products, physical properties were investigated experimentally. The results abtained in experiment were as follows. 1. Liquid resin and dried film was good solubility and clearity at less than 25%, 20% of rubber without being related to sort. 2. G-1000 showed better properties than R-45HT in solubility, dring time and adhesive strength. 3. Dring time and adhesive strength were considerably influenced by molecular weigh and structure of rubber. 4. In using 25% of mixed rubber(G-1000/R-45HT=50/50), It represented best properties in dring time(10 minute) and adhesive strength($23Kg/cm^2$).

• Elastomers and Composites
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• 제28권1호
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• pp.13-21
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• 1993

Polyurethane resin was especially mixed with polybutadiene rubbers which had each other different molecular structures and functional groups. Liquid and cure properties were tested experimentally for mixtures. Viscosity of mixtures and drying time were influenced by solubility of thinner and reactivity of rubber. Adhesive strength represented maxium at rubber content $15{\times}22%$ (Wt. % ), and rapidly decreased over 25%. DBTDL(di-n-butyltindilaurate) showed the longest stroage stability.

• 콘크리트학회논문집
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• 제14권3호
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• pp.283-290
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• 2002

일반적으로 불포화 폴리에스테르 모르타르 및 콘크리트는 강도가 우수하고 내약품성이 좋지만, 취성적이어서, 내충격성이 요구되는 용도로는 사용하기 어렵다. 그러므로, 본 연구에서는 재생골재와 불포화 폴리에스테르 액상수지를 사용한 바닥마감재를 개발하기 위해 불포화 폴리에스테르 모르타르의 취성을 개선시켜보고자 하였다. 불포화 폴리에스테르 모르타르의 취성을 개선하기 위한 재료로 폴리우레탄 액상고무를 사용하였으며, 폴리올의 분자량과 폴리우레탄 액상고무의 치환율에 따른 모르타르의 특성을 검토했다. 실험결과, 폴리우레탄 액상고무의 사용에 따라 불포화 폴리에스테르 모르타르의 점도가 증가하였고, 경화수축은 감소하였다. 그리고, 모르타르내에 생성된 고무입자에 의해 압축강도 및 휨강도는 다소 저하하였지만, 내충격성이 향상되고, 휨파괴시험결과에서 파괴하중이후에도 급격한 파괴를 보이지 않는 결과를 얻을 수 있었다. 따라서, 본 연구의 결과는 폴리올의 분자량 2000, 3000인 폴리우레탄 액상고무를 불포화 폴리에스테르 모르타르에 사용하여 취성의 개선효과를 얻을 수 있다는 것을 제시하고 있다.

• 대한화학회지
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• 제7권2호
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• pp.115-121
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• 1963

Aliphatic hydrocarbon gases from rubber pyrolysis have been identified by gas chromatography with tetraethyleneglycol dimethylether column. Rubbers used in this work are polyisoprene, SBR, NBR, polybutadiene, buthyl rubber, polychloroprene and polyurethane rubber. The chromatogram is characteristic for each polymer. Author proposes a method of identification of synthetic rubbers by gas chromatograph of pyrolyzed gas. Sample is pyrolyzed at $450^{\circ}C$ under nitrogen or more effectively helium and gaseous portion, which eliminated liquid condensate, is passed to the column. The appearance of exclusively large peak of isoprene, isobutylene and carbon dioxide shows the presence of polyisoprene, polyisobutylene and polyurethane, respectively. Large peak of butadiene will appear in case of polybutadiene, SBR and NBR, but SBR can be identified through the styrene peak in gas chromatogram of liquid pyrolyzate and NBR can be identified by the evolution of hydrogen cyanide during pyrolysis. Polychloroprene is identified by the evolution of hydrogen chloride. This method could be applied to the identification of copolymer or polymer blend.

• Elastomers and Composites
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• 제31권2호
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• pp.104-110
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• 1996

The polyurethane was synthesized by the reaction of polycaprolactone diol(Mw 2000), 4,4'-diphenylmethane diisocyanate and 1,4-butanediol as the chain extender. Also, the modified polyurethane polymers based on liquid polybutadiene as a part of soft segment and dimethylolpropionic acid as a chain extender, giving polyurethane with various polarity, were synthesized. The thermal, mechanical, adhesion properties and water contact angles of the polyurethanes were examined. From the result of the water contact angle, the polarity of the acid modified PU containing 6% acid content was unchanged but mechanical and adhesion properties were improved. The water contact angles on polybutadiene modified PU films were increased with increasing polybutadiene content. The mechanical properties of the polybutadiene modified PU were higher than that of acid modified PU. However, the mechanical properties were reduced as polybutadiene content increased. The result is presumably due to phase separation between hard segment and soft segment. The peel strength of the polyurethane introduced with 5wt% polybutadiene was improved about 150% than that of unmodified PU. The same as the mechanical properties, the more polybutadiene was introduced, the lower peel strength was obtained.

• Elastomers and Composites
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• 제41권2호
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• pp.108-115
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• 2006

비페닐기를 함유하는 새로운 형태의 액정성 폴리우레탄을 신규로 합성한 4,4'-Bis(9-hydroxynonoxy)biphenyl (BP9)와 2,6-tolylene diisocyanate, 2,5-tolylene diisocyanate, 2,4-tolylene diisocyanate, 1,4-phenylene diisocyanate 및 hexamethylene diisocyanate의 중부가 반응에 의해 합성하였다. 단량체 BP9은 스멕틱상을 형성하였으며 1,4-PDI/BP9을 제외한 나머지 폴리우레탄에서는 모두 액정성을 나타내었다. 합성된 단량체와 중합체들의 구조는 적외선분광분석기 및 핵자기공명분석기를 사용하여 확인하였으며, 그들의 열적 상전이 온도 및 안정성들은 시차주사 열량분석기와 편광현미경으로 조사하였다.