• Title/Summary/Keyword: polyphenylene sulfide (PPS)

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A Study on the Dielectric properties of polyphenylene Sulfide Film (폴리페닐렌 설파이드 필름의 유전특성에 관한 연구)

  • Song, Ho-Geun;Kim, Myoung-Won;Um, Gi-Ho;Kim, Sung-Ho;Jin, Mu-Ung
    • Proceedings of the KIEE Conference
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    • 1992.07b
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    • pp.871-874
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    • 1992
  • The dielectric constant and dissipation factor of polyphenylene sulfide(PPS) film were measured in range of -40$\sim$+125$^{\circ}C$. The result shows that characteristics of PPS films are superier to PP and PET films. It's dielectric constant was stable to the temperature of +125$^{\circ}C$.

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Effect of Compatibilizer Types on the Properties of Linear PPS/PET Blends (상용화제의 종류가 선형 PPS/PET 블렌드의 물성에 미치는 영향)

  • Kim, Sungki;Hong, In-Kwon;Lee, Sangmook
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.500-506
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    • 2013
  • The effect of compatibilizer types on the properties of polyphenylene sulfide (PPS)/polyethylene terephthalate (PET) blends was investigated. The blends were extruded by a single screw extruder attached with a Maddock mixing zone and their molded properties were examined. As a basic blend composition, a linear PPS/PET (40/60) blend was selected based on cost efficiency. Three types of compatibilizer, SEBS, modified SEBS, and modified PS were added to the basic blend to improve the properties. The thermal, rheological, mechanical properties and the morphology of the ternary blends were analyzed. The maximum mechanical properties of blends was found at 1 phr of m-SEBS or m-PS content, whose values were almost the same as the theoretical values of miscible blend system. It seemed to by the case that the partial reaction between compatibilizer and the basic blend caused the enhancement of compatibility between linear PPS and PET phases. These ternary blends would be applicable as economic linear PPS alloys.

A Study on Properties of the Glass Fiber Reinforced PPS Composites for Automotive Headlight Source Module (자동차 전조등 광원 모듈용 유리섬유강화 PPS 복합재료 특성 연구)

  • Heo, Kwang-Yeol;Park, Sung-Min;Lee, Eun-Soo;Kim, Myung-Soon;Sim, Ji-Hyun;Bae, Jin-Seok
    • Composites Research
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    • v.29 no.5
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    • pp.293-298
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    • 2016
  • In this paper, Glass Fiber Reinforced Thermoplastic (GFRTP) for automotive headlight source module was fabricated by compounding and injection molding using PPS (Poly Phenylene Sulfide) resin with glass fiber which has three cross section (round type, cocoon type, flat type). Tensile, flexural, impact properties were investigated on effect of cross section, glass fiber contents. And it was observed flatness, dimensional stability, fluidity depending on glass fiber cross section. As a result, flat glass fiber reinforced thermoplastic's mechanical properties were most excellent. Also, dimensional stability and flatness showed better results when using flat glass fiber.

The Relation Among the Linear Energy Transfer and Changes of Polyphenylene Sulfide Surface by ion Implantation (이온주입에 의한 고분자(Polyphenylene Sulfide)표면 특성 변화와 선에너지전달(Pineal Energy Transfer)과의 관계)

  • Lee, Jae S.;Kim, Bo-Young;Lee, Jae-Hyung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.5
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    • pp.407-413
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    • 2005
  • Ion implantation provides a unique way to modify the mechanical, optical and electrical properties of polymer by depositing the energy of ions in the material on the atomic scale. Implantation of ions into the polymers generally leads to a radiation damage, which, in many cases, modifies the properties of the surface and bulk of the material. These modifications result from the changes of the chemical structure caused in their turn by changing the chemical bonding when the incident ions cut the polymer chains, breaks covalent bonds, promotes cross-linking, and liberates certain volatile species. We studied the relation among the linear energy transfer (LET) and changes of surface microstructure and surface resistivity on PPS material using the high current ion implantation technology The surface resistivity of nitrogen implanted PPS decreased to $10^{7}{\Omega}/cm^{2}$ due to the chain scission, cross linking, ${\pi}$ electron creation and mobility increase. In this case, the surface conductivity depend on the 1-dimensional hopping mechanism.

Performances of Plastic Pulley with High Mechanical Properties and Low Friction

  • Kim, Namil;Lee, Jung-Seok;Hwang, Byung-Kook;Bae, Seokhu;Yoon, Jeong-Hwan;Yun, Juho
    • Elastomers and Composites
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    • v.54 no.2
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    • pp.135-141
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    • 2019
  • Polyphenylene sulfide (PPS) was filled with glass fiber (GF), aramid fiber (AF), and solid lubricants to improve the mechanical properties and wear resistance. The addition of GF effectively enhanced the tensile strength, flexural modulus, and impact strength of PPS, while solid lubricants such as polytetrafluoroethylene (PTFE), molybdenum disulfide ($MoS_2$), and tungsten disulfide ($WS_2$) lowered the friction coefficients of the composites to below 0.3. The ball nut and motor pulley of the electric power steering (EPS) were manufactured using the PPS composites, and feasibility was ascertained thereafter by conducting the durability test. The composites filled with GF and AF showed high mechanical strength, but slip occurred at the interface between the pulley and belt while testing above $50^{\circ}C$. When small amounts of lubricants were added, the slip was no longer detected because of the suppression of friction heat. It is realized that the low friction as well as high mechanical properties is important to ensure the reliability of plastic pulleys.

Fabrication and Applications of Polyphenylene Sulfide (PPS) Composites: A Short Review (폴리페닐렌설파이드(PPS) 복합소재 제조 및 응용)

  • Choi, Minsik;Lee, Jungrok;Ryu, Seongwoo;Ku, Bon-Cheol
    • Composites Research
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    • v.33 no.3
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    • pp.91-100
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    • 2020
  • Polyphenylene sulfide (PPS) is a semi-crystalline engineering thermoplastic resin that has outstanding thermal stability, mechanical strength, inherent flame retardancy, chemical resistance, and electrical properties. Due to these outstanding properties, it is preferred as a matrix for composite materials. Many studies have been conducted to produce composites with carbon fibers and glass fibers to improve mechanical properties and provide functionality of PPS. In this review paper, we report a brief introduction to the fabrication and applications of PPS composites with carbon nanotubes, graphene, carbon fibers, and glass fibers.

The electrical and corrosion properties of polyphenylene sulfide/carbon composite coated stainless steel bipolar plate for PEM fuel cell

  • Lee, Yang-Bok;Kim, Kyung-Min;Park, Yu-Chun;Hwang, Eun-Ji;Lim, Dae-Soon
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.89.2-89.2
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    • 2011
  • Stainless steel bipolar plates have many advantage such as high electrical conductivity and mechanical strength and low fabrication cost. However, they need a passivation layer due to low corrosion resistance under PEM fuel cell operation condition. In this study, polyphenyene sulfide(PPS)/carbon composite coated stainless steel bipolar plates were fabricated by compression molding method after PPS/carbon composite sprayed on the stainless steel plate. PPS and carbon were chosen as the binder and conductive filler of passivation layer, respectively. The interfacial contact resistance and corrosion resistance of PPS/carbon composite coated stainless steel bipolar plates were investigated and compared to the stainless steel. The PPS/carbon composite coated stainless steel compared to stainless steel was improved interfacial contact resistance. The results of the potentiodynamic and potentiostatic measurements also showed that the PPS/carbon composite coated stainless steel did not corroded under PEM fuel cell operating conditions.

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Computational Investigation of the Thermal Performances of Polymer Heat Sinks Passively-Cooled by Seawater for Thermoelectric Waste Heat Recovery (열전폐열회수를 위해 수동적으로 해수냉각되는 폴리머 히트싱크 열성능의 수치적 연구)

  • Kim, Kyoung Joon
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.4
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    • pp.432-436
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    • 2015
  • This study computationally explored the thermal performance of passively-cooled polymer heat sinks utilizing seawater. Polymer heat sinks are proposed as cooling modules of the cold sides of thermoelectric generators for waste heat recovery. 3-D Computational Fluid Dynamics (CFD) modelling was conducted for a detailed numerical study. Polyphenylene sulfide (PPS) and pyrolytic graphite (PG) were selected for the base materials of polymer heat sinks. The computational study evaluated the performance of the PPS and PG heat sinks at various fin numbers and fin thicknesses. Their performances were compared with those of aluminum (Al) and titanium (Ti) heat sinks. The study results showed that the thermal performance of the PG heat sink was 3~4 times better than that of the Ti heat sink. This might be due mainly to the better heat spreading of the PG heat sink than the Ti heat sink. The effect of the number of fins on the performance of the PG heat sink was dissimilar to the cases of the PPS and Ti heat sinks. This result can be explained by the interrelationships among heat spreading, surface area enhancement, and fluidic resistance incorporating with an increase in the number of fins.

Preparation and Properties of Polymer PTC Composites for Process Safety (공정안전용 Polymer PTC 소재의 제조 및 특성)

  • 강영구;조명호
    • Journal of the Korean Society of Safety
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    • v.18 no.3
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    • pp.101-108
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    • 2003
  • Polymeric positive temperature coefficient(PTC) composites have been prepared by incorporating carbon black(CB) into high density polyethylene(HDPE), polyphenylene sulfide(PPS) and polybutylene terephthalate(PBT) matrices. A PTC effect was observed in the composite, caused by the large thermal expansion due to He consecutive melting of HDPE, PPS and PBT crystallites. This theory is based upon the premise that the PTC phenomenon is due to a critical separation distance between carbon particles in the polymer matrix at the higher temperature. The influence of PTC characteristics of the PPS/CB composite can be explained by DSC result. HDPE, one of prepared composition, exhibit the higher performance PTC behavior that decreaseing of negative temperature coefficient(NTC) effect and improved reproducibility by chemically crosslinking. Also, PBT/CB and PPS/CB composites exhibit the higher PTC peack temperature than HDPE/CB PTC composite, individually $200^{\circ}C$ and $230^{\circ}C$. These PTC composite put to good use in a number of safety application, such as self$.$controlled heater, over-current protectors, auto resettable switch, high temperature proctection sensor, etc.

Preparation and Evaluation of Hybrid Porous Membrane for the Application of Alkaline Water Electrolysis (알칼리 수전해 적용을 위한 하이브리드 다공성 격리막 제조 및 특성평가)

  • Han, Seong Min;Im, Kwang Seop;Jeong, Ha Neul;Kim, Do Hyeong;Nam, Sang Yong
    • Membrane Journal
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    • v.31 no.6
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    • pp.443-455
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    • 2021
  • In this study, polyphenylene sulfide (PPS) was used as a support and a separator was manufactured using polysulfone and inorganic additives to manufacture a separator with low membrane resistance for application of an alkali water electrolysis system, and then the effect on the thickness and porosity of the support was analyzed. The PPS felt used as a support was compressed with variables of temperature (100℃, 150℃, 200℃) and pressure (1 ton, 2 tons, 3 tons, 5 tons) to adjust the thickness. A porous separator could be manufactured by preparing a slurry with polysulfone using BaTiO3 and ZrO2 which have high hydrophilicity and excellent alkali resistance as inorganic particles and casting the slurry on a compressed PPS felt. Changes in morphology of the separator according to compression conditions were confirmed through an electron scanning microscope (SEM). After that, the porosity was calculated, and the thickness and porosity tended to decrease as the compression conditions increased. Various characteristics were evaluated to confirm whether it could be used as a separator for water electrolysis. As a result of measuring the mechanical strength, it was confirmed that the tensile strength gradually increased as the compression conditions (temperature and pressure) increased. Finally, it was confirmed that the porous separator manufactured through the alkali resistance test has excellent alkali resistance, and through the IV test, it was confirmed that the membranes compressed at 100℃ and 150℃ had a lower voltage and improved performance than the existing uncompressed membrane.