• Title/Summary/Keyword: polymeric coating solution

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Corrosion resistance performance of arc thermal sprayed Al and Al/epoxy dual metal polymeric coating in 3.5 wt.% NaCl-contaminated concrete pore solution (3.5 wt.% NaCl로 오염된 콘크리트 기공 용액에서 아크 용사 Al 및 Al/에폭시 이중 금속 고분자 코팅의 내식성 성능)

  • Singh, Jitendra Kumar;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.119-120
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    • 2023
  • Corrosion of the steel rebar in coastal environment caused huge economical loss of the globe. Therefore, coating on the steel rebar being used to mitigate the corrosion. In the present study, we have applied epoxy coating on arc thermal sprayed Al coating (a dual metal/polymeric coating) vis-à-vis compared with as coated one (Al coating). The corrosion studies were performed in simulated concrete pore solution with 3.5 wt. % NaCl solution. The morphology of the dual epoxy/Al coating is smooth while Al coating shows rankle and defects. Due to defects, Al coating is susceptible to corrosion while dual epoxy/Al coating has performed excellent compared to as coated one at extended period of immersion.

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Synthesis of Phosphoric Polymer Coating Solution with Antimicrobial Activity and Flame Retardant Efficiency (항균성과 난연성을 함유하고 있는 인계고분자 코팅용액의 합성)

  • Kim, Sang-Kyum;Lee, In-Soo;Seo, Sang-Hee;Choi, Seong-Ho
    • Polymer(Korea)
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    • v.35 no.5
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    • pp.431-437
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    • 2011
  • A polymeric coating solution based on poly(acryloyl diphosphoric acid)(poly(ADP)) was prepared via a radical polymerization of acryloyl diphosphoric acid using ammonium persulfate (APS) as an initiator in water at 70 $^{\circ}C$. The prepared polymeric coating solution exhibited significant antibacterial activity against salmonella typhimurium, pseudomonas aeruginosa, escherichia coli, and staphylococcus aureus. It also exhibited good antifungal activity against Asperigillus niger and good antiviral activity against the influenza (H1N1) virus. Additionally, it exhibited good flame retardant efficiency after applying it as a coating to a cotton fabric.

${\gamma}-LiAlO_2$ Coating on Alumina Fibers by the Sol-Gel Method (졸-겔법에 의한 알루미나 화이버의 ${\gamma}-LiAlO_2$ 코팅)

  • 현상훈;홍성안;김완식;신현철
    • Journal of the Korean Ceramic Society
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    • v.31 no.11
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    • pp.1271-1282
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    • 1994
  • The surface of commercial alumina fibers used for reinforcing the MCFC matrix has been coated with ${\gamma}$-LiAlO2 being the same material as the matrix, by the sol-gel method in order to enhance the corrosion resistivity of alumina fibers. Stable LiAlO2 complex polymeric sols for coating was synthesized by mixing aluminum alkoxide polymeric sols with LiNO3 solution. It was found that the LiAlO2 polymeric sol prepared by adding the mixed chelate of acethylacetone and triethanolamine (the mole ratio of AA/TEA = 0.125/0.75) to the 1 mole of the aluminum alkoxide had the excellent stability and coating behavior. The crystalline structure of the dried gel from the ${\gamma}$-LiAlO2 sol was completely transformed into the ${\gamma}$-LiAlO2 at $600^{\circ}C$. The optimum viscosity of the sol for coating the alumina long fibers was 30~40 cP, while it was 12~20 cP in case of the short fiber coating. The ${\gamma}$-LiAlO2 coated alumina fibers without defects fully densified when heat-treated at 120$0^{\circ}C$.

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Heat-resistant Enamel Varinish (내열성 에나멜 바니쉬)

  • Kim, Yang-Kook;Bae, Hun-Jai
    • Applied Chemistry for Engineering
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    • v.4 no.2
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    • pp.264-272
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    • 1993
  • Current research aimed at investigating of heat-resistance of magnet wire to endow miniaturizing electronic equipment with a high efficiency or reliability. Thermal stability of magnet wire has a close relationship with physical properties of polymeric coating that is formed from enamel varnish. Design of heat-resistant enamel varnish and coating technology of varnish solution were briefly described. Some factors which have a thermal effect on wire were discussed through the evaluation method of the wire properties.

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Continuous Nanocomposite Coatings on a Phosphor for the Enhancement of the Long-term Stability

  • Kim, Jong-Woung;Song, Jung-Oh;Kim, Chang-Keun
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.233-233
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    • 2006
  • [ $Y_{2}O_{2}S:Eu$ ], a red phosphor, coated with silica nanoparticles or nanocomposites composed of silica nanoparticles and polymeric materials such as PMMA and PVP was prepared via sol-gel process. Samples were prepared from four different methods coded P1, P2, P3, and P4. P1 includes a conventional sol-gel process and a dip-coating method while P2 has the same procedure with P1 except that nanocomposites containing both silica nanoparticles and polymer prepared by sol-gel process were used as coating materials. In P3 method, phosphors were dispersed in a solution containing silica precursor, i.e., TEOS and then polymerization was performed to coat onto the phosphors surface while P4 followed the same procedure with P3 except that a solution containing both TEOS and organic monomer were used in preparing coating materials. Among various coating methods examined in this study, uniform coating of phosphor could be achieved by using method P4, i.e., phosphor surface coating in a solution containing hydrophobic monomer and TEOS. Furthermore, $Y_{2}O_{2}S:Eu$ red phosphor coated with nanocomposite composed of PMMA matrix and silica nanoparticles exhibited enhanced PL intensity and long-term stability.

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The Biological Functionality of Electro-Galvanized Steels Coated with a Hybrid Composite Containing Pyrethroid

  • Jo, Du-Hwan;Kim, Myung-Soo;Kim, Jong-Sang;Oh, Hyun-Woo
    • Corrosion Science and Technology
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    • v.17 no.2
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    • pp.74-80
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    • 2018
  • The electronic industries require environmentally-friendly and highly functional materials to enhance the quality of human life. Home appliances require insect repellent steels that work to protect household microwave ovens from incurring damage by insects such as fire ants and cockroaches in tropical regions. Thus, POSCO has developed new types of functional steels, coated with an array of organic-inorganic hybrid composites on the steel surface, to cover panels in microwave ovens and refrigerators. The composite solution uses a fine dispersion of hybrid solution with polymeric resin, inorganic and a pyrethroid additive in aqueous media. The hybrid composite solution coats the steel surface, by using a roll coater and is cured using an induction curing furnace on both the continuous galvanizing line and the electro-galvanizing line. The new steels were evaluated for quality performances, salt spray test for corrosion resistance and biological performance for both insect repellent and antimicrobial activity. The new steels with organic-inorganic composite coating exhibit extraordinarily biological functionalities, for both insect repellent and antimicrobial activities for short and long term tests. The composite-coating solution and experimental results are discussed and suggest that the molecular level dispersion of insecticide on the coating layer is key to biological functional performances.

Excellent Seam Weldable Nano-Composite Coated Zn-Ni Plating Steels for Automotive Fuel Tank

  • Jo, Du-Hwan;Yun, Sang-Man;Park, Kee-Cheol;Kim, Myung-Soo;Kim, Jong-Sang
    • Corrosion Science and Technology
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    • v.18 no.1
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    • pp.16-23
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    • 2019
  • Steels for automotive fuel tank require unique properties such as corrosion resistance for fuel, welding for joining, forming for press, and painting for exterior. Recently, automakers have been requiring excellent seam weldable steels to enhance manufacturing productivity of fuel tank. Thus, POSCO developed a new type of functional steels coated with nano-composite thin layer on Zn-Ni plating steels. The nano-composite coating solution was prepared by mechanical fine dispersion of solutions consisting of polymeric resin and nano-composite materials in aqueous media. The composite solution was coated on the plating steel surface by using roll coater and cured through induction furnace. These new developed plating steels were evaluated for quality performances such as seam and spot weldability, press formability, and corrosion resistance. These new functional steels coated with nano-composite layer exhibited excellent seam weldability and press formability. Detailed discussion of coating solution and experimental results suggest that nano-sized composite dispersion as coating layer plays a key role in enhancing the quality performance.

Fabrication of a Polymeric Film with Nanofiber-based Porous Window and Its Application to Co-culture (섬유 기반의 다공성 윈도우를 가지는 박막 제작 및 공배양에의 활용)

  • Jeong, Young Hun;Lee, Jongwan;Jin, Songwan
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.13 no.2
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    • pp.21-27
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    • 2014
  • Recently, various biochip environments have been presented. In this study, a novel transparent film with porous membrane windows, which is an essential component in a co-cultured biochip environment, is fabricated using spin-coating, 3D printing, and electrospinning processes. In detail, a transparent polystyrene film was fabricated by means of the spin-coating process followed bywindow cutting, after which apolycaprolactone-chloroform solution was deposited along the window edge to introduce an adhesion layer between the PS film and the PCL nanofibers. Nanofibers were electrospun into the window region using a direct-write electrospinning method. Consequently, it was demonstrated that the fabricated window film could be used in a co-culture biochip environment.

Characterization and fabrication of one component solution based CNT/epoxy binder conductive films (일액형 탄소나노튜브/에폭시 바인더 코팅액을 이용한 전도성 필름 제조 및 특성 분석)

  • Han, Joong-Tark;Woo, Jong-Seok;Kim, Sun-Young;Lee, Geon-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.455-456
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    • 2007
  • Optically transparent, highly conductive coating have been major theme of thin film science efforts for some years. In this work, t-MWNT(thin Multi-walled Carbon Nanotubes) are acid treated, then the stable dispersion of t-MWNTs in polar solvent such as alcohols, was achieved by sonication. The transparent conducting films are prepared using the one component solution of t-MWNT/epoxy binder via spray coating on glass substrate. The characterization of acid treated t-MWNTs was performed by Raman spectrometer. The opto-electrical properties of conducting films are analyzed by the binder concentration, and the effect of co-solvent on the compatibility and dispersibility of one component t-MWNT/epoxy binder solutions are discussed.

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Improvement of Inverted Hybrid Organic Light-emitting Diodes Properties with Bar-coating Process (바코팅 공정을 이용한 유기 발광 다이오드 특성 향상)

  • Kwak, Sun-Woo;Yu, Jong-Su;Han, Hyun-Suk;Kim, Jung-Su;Lee, Taik-Min;Kim, Inyoung
    • Journal of the Korean Society for Precision Engineering
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    • v.30 no.6
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    • pp.589-595
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    • 2013
  • Solution processed conjugated molecules enable to manufacture various electronic devices by unconventional and cost effective patterning methods as screen or gravure printing. Spin-coating is the most popularly used method to form conjugated polymeric film for various electronic devices. The coating method has certain disadvantages such as a large amount of unwanted wastes, difficulty forming a film with a large area, and impossible to apply roll-to-roll manufacturing. We present here a promising alternative coating method, bar-coating for conjugated polymer film and OLED with the bar coated light emitting layer. In this papers, we show atomic force microscope images of spin- and bar-coated Poly[(9,9-di-n-octylfluorenyl-2,7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,8-diyl)] (F8BT) films on substrate. The bar-coated film showed a slight lower RMS roughness (1.058 [nm]) than spin-coated film (1.767 [nm]). It means the bar-coating is suitable method to form light emitting layers in OLEDs. By using bar-coating process, an OLED obtained with 4.7 [cd/A] in maximum current efficiency.