• Title/Summary/Keyword: polymeric binder

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Characterization and fabrication of one component solution based CNT/epoxy binder conductive films (일액형 탄소나노튜브/에폭시 바인더 코팅액을 이용한 전도성 필름 제조 및 특성 분석)

  • Han, Joong-Tark;Woo, Jong-Seok;Kim, Sun-Young;Lee, Geon-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.455-456
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    • 2007
  • Optically transparent, highly conductive coating have been major theme of thin film science efforts for some years. In this work, t-MWNT(thin Multi-walled Carbon Nanotubes) are acid treated, then the stable dispersion of t-MWNTs in polar solvent such as alcohols, was achieved by sonication. The transparent conducting films are prepared using the one component solution of t-MWNT/epoxy binder via spray coating on glass substrate. The characterization of acid treated t-MWNTs was performed by Raman spectrometer. The opto-electrical properties of conducting films are analyzed by the binder concentration, and the effect of co-solvent on the compatibility and dispersibility of one component t-MWNT/epoxy binder solutions are discussed.

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Early Strength and Properties of EVA Powder Modified High Strength Concrete (EVA Powder 개질 고강도 콘크리트의 초기강도 및 수밀특성)

  • Kim, Young-Ik;Sung, Chan-Yong
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2005.10a
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    • pp.123-127
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    • 2005
  • EVA Powder modified high strength concretes were prepared by varying polymer/binder mass ratio with a constant water/binder mass ratio of 0.3. The effect of EVA powder on the slump, hydration heat, compressive and flexural strength, toughness and water absorption ratio was studied. In hydration heat test, temperature of hydration reaction displayed almost fixed level regardless of containing rate of EVA powder, but peak time of hydration reaction displayed late inclination as containing rate of powder increases. With the same water/binder mass ratio, the compressive strength and water absorption of EVA powder modified concretes decreased slightly when EVA powder was added and the flexural strength of EVA powder modified concretes rised slightly when EVA powder was added. Also, the toughness of the modified concretes can be improved markedly. The interpenetrating structure between the polymeric phase and cement hydrates formed at a $2{\sim}6%$(containing rate of EVA powder). The properties of the polymer modified concretes were influenced by the polymer film, cement hydrates and the combined structure between the organic and inorganic phases.

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The Preparation of Ceramic YBaCuO System Superconducting wire (세라믹 YBaCuO계 초전도 선재의 제조)

  • 박성진;한태희;한병성;김양수
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.40 no.9
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    • pp.908-912
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    • 1991
  • YBaCuO oxide superconductor-shows superconductive at Liquid Nitrogen temperature-must be preparate wire or thin film form for utility. The wiring is possible with heat treatment after appropriate mixture of polymeric binder and YBaCuO oxide superconductor has fabricated. This study, analyzed the characteristics of fabricated superconductor and extruded wire after application to each of a mixed at different rate in the superconductor and compared with an original pure sample. From the result, we knew that the binder component influences superconducting characteristics. The best condition for superconductivity occurred at a criticla temperature of 86.4K (8:2 rate) and at a critical current density of 100.27A/cmy with a binder packing ratio of about 20~25 percent.

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Thermally Crosslinked Polyimide Binders for Si-alloy Anodes in Li-ion Batteries

  • Chang, Hyeong-Seok;Ji, Sang-Gu;Rho, Miso;Lee, Byoung-Min;Kim, Sung-Soo;Choi, Jae-Hak
    • Journal of Electrochemical Science and Technology
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    • v.13 no.3
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    • pp.339-346
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    • 2022
  • Silicon (Si) has attracted considerable attention due to its high theoretical capacity compared to conventional graphite anode materials. However, Si-based anode materials suffer from rapid capacity loss due to mechanical failure caused by large volume change during cycling. To alleviate this phenomenon, crosslinked polymeric binders with strong interactions are highly desirable to ensure the electrode integrity. In this study, thermally crosslinked polyimide binders were used for Si-alloy anodes in Li-ion batteries. The crosslinked polyimide binder was found to have high adhesion strength, resulting in enhanced electrode integrity during cycling. Therefore, the Si-alloy anodes with crosslinked polyimide binder provide enhanced electrochemical performance, such as Coulombic efficiency, capacity retention, and cycle stability.

Effects of Sheet Thickness on the Electromagnetic Wave Absorbing Characterization of Li0.375Ni0.375Zn0.25-Ferrite Composite as a Radiation Absorbent Material

  • Kim, Dong-Young;Yoon, Young-Ho;Jo, Kwan-Jun;Jung, Gil-Bong;An, Chong-Chul
    • Journal of electromagnetic engineering and science
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    • v.16 no.3
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    • pp.150-158
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    • 2016
  • This paper reports on a study of LiNiZn-ferrite composite as a radiation absorbent material (RAM). The electromagnetic (EM) wave absorbers are composed of an EM wave absorbing material and a polymeric binder. The surface morphology, chemical composition, weight percent of the ferrite composite of the toroid sample, magnetic properties, and return loss are investigated using field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), vibrating sample magnetometer (VSM), and network analyzer. For preparing the absorbing sheet, chlorinated polyethylene (CPE) is used as a polymeric binder. The EM wave absorption properties of the prepared samples were studied at 4 - 8 GHz. We can confirm the effects of the thickness of the samples for absorption properties. An absorption bandwidth of more than a 10-dB return loss shifts toward a lower frequency range along with an increase in the thickness of the absorber.

Coagulation of Cationic Rosin Emulsion and its Effect on Ink Receptivity of Coating Layer (양이온성 로진 에멀션의 응결현상이 도공층의 잉크흡수성에 미치는 영향)

  • 박철웅;이학래
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.3
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    • pp.74-83
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    • 1998
  • The phenomenon of decrease in sizing efficiency when the stock temperature is increased is well recognized as summer sizing, and this is believed to be caused by uneven distribution of sizing agents on paper surface most often incurred by coagulation of sizing agents. When unevenly sized paper is used as coating base stock, nonuniform consolidation of the coating layer may result, which, in turn, causes uneven distribution of binder on coating surface. This causes nonuniform ink absorption to produce print mottle. In this study the effects of simple or polymeric electrolytes, storage temperature and time on the coagulation of cationic dispersed rosin size were investigated using a turbidity measurement method which was verified to correlate well with the particle size of rosin emulsion or its coagulates. Handsheets sized with rosin dispersions coagulated under various conditions were prepared and their sizing degree and coated paper properties including gloss and ink density were examined. The relationship between the sizing nonuniformity of coated papers and its ink absorption property was evaluated. Turbidity of rosin emulsion increased as the storage temperature and time were increased. Addition of simple or polymeric electrolytes caused reduction in $zeta$ -potential of the rosin dispersion and accelerated the coagulation tendency substantially. Reversion of the $zeta$ -potential of rosin dispersion, however, did not occur when coagulation was induced with simple electrolytes. On the other hand, addition of an anionic polyelectrolyte reversed the $zeta$ -potential of the flocculated rosin dispersion. This indicated that electrical double layer compaction and bridging flocculation were coagulation mechanisms for simple and polymeric electrolytes, respectively. Sizing degree decreased as coagulation of rosin was increased. Paper gloss, ink gloss and ink density were increased when sizing degree of base stock was increased most probably due to prevention of base paper swelling and increased binder migration to coating surface. This suggested that uneven printing ink density occurred when uneven sizing development was induced by coagulation of rosin particles.

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Effect of Polymeric Binders on Green body Properties of WC-Co Cemented Carbides (초경합금 성형체 특성 변화에 미치는 유기물 결합제의 영향)

  • Lim, Young-Soo;Ahn, Sun-Yong;Lim, Jae-Suk;Paek, Yeong-Kyeun;Chung, Tai-Joo
    • Journal of Powder Materials
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    • v.29 no.4
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    • pp.291-296
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    • 2022
  • The green body of WC-Co cemented carbides containing polymeric binders such as paraffin, polyethylene glycol (PEG), and polyvinyl acetate (PVA) are prepared. The green density of the WC-Co cemented carbides increases with the addition of binders, with the exception of PVA, which is known to be a polar polymeric substance. The green strength of the WC-Co cemented carbides improves with the addition of paraffin and a mixture of PEG400 and PEG4000. In contrast, the green strength of the WC-Co does not increase when PEG400 and PEG4000 is added individually. The compressive strength of the green body increases to 14 MPa, and the machinability of the green body improves when more than 4-6 wt% paraffin and a mixture of PEG400 and PEG4000 is used. Simultaneously, the sintered density of WC-Co is as high as 99% relative density, similar to a low binder addition of 1-2 wt%.

Slip Casting of Mn-Zn Ferrite Powders Prepared by Alcoholic Dehydration Method (알콜탈수법에 의해 제조된 Mn-Zn Ferrite 분체의 주입성형)

  • 이경직;이대희;신효순;이석기;김창현;이병교
    • Journal of the Korean Ceramic Society
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    • v.34 no.4
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    • pp.394-398
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    • 1997
  • Mn-Zn ferrite powders were prepared by alcoholic dehydration, using coprecipitation method. Then the effects of organic dispersant and polymeric binder concentration on stability and casting of slurry were discussed. Citric acid, the organic dispersant and polyvinylacohol(PVA), the non-ionic binder, were selected as additives of slurry. With variation of concentration of water, citric acid and polyvinylalcohol(PVA), optimum forming conditions were determined from viscosity and density. To compare with dry process, density and microstructure of sintered body formed by uniaxial die pressing were observed.

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Powder Injection Molding Technology (분말 사출 성형 기술)

  • 하태권;성환진;안상호;장영원
    • Transactions of Materials Processing
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    • v.12 no.6
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    • pp.521-528
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    • 2003
  • Powder injection molding (PIM) uses the shaping advantage of injection molding but is applicable to metals and ceramics. This process combines a small quantity of polymer with an inorganic powder to form a feedstock that can be molded. After shaping, the polymeric binder is extracted and the powder is sintered, often to near-theoretical densities. According1y, PIM delivers structural materials in a shaping technology previously restricted to polymers. The process overcomes the shape limitations of traditional powder compaction, the costs of machining, the productivity limits of isostatic pressing and slip casting, and the defect and tolerance limitations of conventional casting. Since 1980s when major attention was given to PIM process, it has been widening the application area from small parts with complex shape and tailored properties to structural parts requiring strength and ductility as in automotive, military and medical industries.

Photopolymers for 3D optical recording (3차원 광기록용 포토폴리머)

  • Lee, Hyo-Jin;Kim, Jeong-Hun;Kim, Eun-Gyeong
    • Proceedings of the Optical Society of Korea Conference
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    • 2006.07a
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    • pp.411-412
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    • 2006
  • Photopolymers have been of considerable due to their easy of processing and high sensitivity. Exposure of photopolymers to optical source produce recroding mark where the light initiates a photoreaction that occurs preferentially in regions of high illumination. The photoreaction typically involves polymerization of an acrylic or epoxy monomer dispersed together with a photoinitiators in a polymeric binder. A number of photopolymerizable materials have been developed to apply them in 3D optical recording such as holographic or 3-dimensional data storage. In this presentation, photopolymers derived from sol-gel matrix and transparent polymer binder are summarized. The effect of monomer composition and plasticizers on optical recording will be discussed based on the monomer transport during the photopolymerization.

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