• 제목/요약/키워드: polymer walls

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Pixel-Isolation Walls of Liquid Crystal Display Formed by Anisotropic Photoreaction of the Prepolymers Containing Cinnamate Moiety

  • Jung, Eun-Ae;Sung, Shi-Joon;Cho, Kuk-Young;Kim, Dae-Hwan;Son, Dae-Ho;Kang, Jin-Kyu
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.879-882
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    • 2009
  • A pixel isolation wall of liquid crystal display is fabricated by the anisotropic photoreaction of a cinnamate based prepolymer. The various oligomers containing a cinnamate moiety were synthesized and used for the formation of the pixel isolation wall. The anisotropic photoreaction of cinnamate moiety was closely related with the liquid crystal orientation at the polymer wall boundary.

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조적채움벽의 면외보강에 관한 연구 (A study on out-of-plane strengthening of masonry-infilled wall)

  • 장혜숙;은희창
    • 산업기술연구
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    • 제41권1호
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    • pp.7-13
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    • 2021
  • Fiber-reinforced polymer reinforcement or polyurea reinforcement techniques are applied to strengthen unreinforced masonry walls (UMWs). The out-of-plane reinforcing effect of sprayed glass fiber-reinforced polyurea (GFRPU), which is a composite elastomer made of polyurea and milled glass fibers on UMW, is experimentally verified. The out-of-plane strengths and ductile behaviors based on various coating shapes are compared in this study. An empirical formula to describe the degree of reinforcement on the out-of-plane strength of the UMW is derived based on the experimental results. It is reported that the peak load-carrying capacity, ductility, and energy absorption capacity gradually improve with an increase in the strengthening degree or area. Compared with the existing masonry wall reinforcement method, the GFRPU technique is a construction method that can help improve the safety performance along with ease of construction and economic efficiency.

Seismic and vibration tests for assessing the effectiveness of GFRP for retrofitting masonry structures

  • Michelis, Paul;Papadimitriou, Costas;Karaiskos, Grigoris K.;Papadioti, Dimitra-Christina;Fuggini, Clemente
    • Smart Structures and Systems
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    • 제9권3호
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    • pp.207-230
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    • 2012
  • Full-scale shake table seismic experiments and low-amplitude vibration tests on a masonry building are carried out to assess its seismic performance as well as study the effectiveness of a new multifunctional textile material for retrofitting masonry structures against earthquakes. The un-reinforced and the retrofitted with glass fiber reinforced polymer (GFRP) strips masonry building was subjected to a series of earthquake excitations of increasing magnitude in order to progressively induce various small, moderate and severe levels of damage to the masonry walls. The performance of the original and retrofitted building states is evaluated. Changes in the dynamic characteristics (lowest four modal frequencies and damping ratios) of the building are used to assess and quantify the damage states of the masonry walls. For this, the dynamic modal characteristics of the structure states after each earthquake event were estimated by performing low-amplitude impulse hammer and sine-sweep forced vibration tests. Comparisons between the modal results calculated using traditional accelerometers and those using Fiber Bragg Grating (FBG) sensors embedded in the reinforcing textile were carried on to investigate the reliability and accuracy of FBG sensors in tracking the dynamic behaviour of the building. The retrofitting actions restored the stiffness characteristics of the reinforced masonry structure to the levels of the original undamaged un-reinforced structure. The results show that despite a similar dynamic behavior identified, corresponding to reduction of the modal frequencies, the un-reinforced masonry building was severely damaged, while the reinforced masonry building was able to withstand, without visual damage, the induced strong seismic excitations. The applied GFRP reinforcement architecture for one storey buildings was experimentally proven reliable for the most severe earthquake accelerations. It was easily placed in a short time and it is a cost effective solution (covering only 20% of the external wall surfaces) when compared to the cost for full wall coverage by GFRPs.

Paeonia lactiflora Inhibits Cell Wall Synthesis and Triggers Membrane Depolarization in Candida albicans

  • Lee, Heung-Shick;Kim, Younhee
    • Journal of Microbiology and Biotechnology
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    • 제27권2호
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    • pp.395-404
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    • 2017
  • Fungal cell walls and cell membranes are the main targets of antifungals. In this study, we report on the antifungal activity of an ethanol extract from Paeonia lactiflora against Candida albicans, showing that the antifungal activity is associated with the synergistic actions of preventing cell wall synthesis, enabling membrane depolarization, and compromising permeability. First, it was shown that the ethanol extract from P. lactiflora was involved in damaging the integrity of cell walls in C. albicans. In isotonic media, cell bursts of C. albicans by the P. lactiflora ethanol extract could be restored, and the minimum inhibitory concentration (MIC) of the P. lactiflora ethanol extract against C. albicans cells increased 4-fold. In addition, synthesis of $(1,3)-{\beta}-{\small{D}}-glucan$ polymer was inhibited by 87% and 83% following treatment of C. albicans microsomes with the P. lactiflora ethanol extract at their $1{\times}MIC$ and $2{\times}MIC$, respectively. Second, the ethanol extract from P. lactiflora influenced the function of C. albicans cell membranes. C. albicans cells treated with the P. lactiflora ethanol extract formed red aggregates by staining with a membrane-impermeable dye, propidium iodide. Membrane depolarization manifested as increased fluorescence intensity by staining P. lactiflora-treated C. albicans cells with a membrane-potential marker, $DiBAC_4(3)$ ((bis-1,3-dibutylbarbituric acid) trimethine oxonol). Membrane permeability was assessed by crystal violet assay, and C. albicans cells treated with the P. lactiflora ethanol extract exhibited significant uptake of crystal violet in a concentration-dependent manner. The findings suggest that P. lactiflora ethanol extract is a viable and effective candidate for the development of new antifungal agents to treat Candida-associated diseases.

폭발하중을 받는 콘크리트 벽체 구조물의 보강 성능에 대한 해석적 분석 (Analytical Evaluations of the Retrofit Performances of Concrete Wall Structures Subjected to Blast Load)

  • 김호진;남진원;김성배;김장호;변근주
    • 콘크리트학회논문집
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    • 제19권2호
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    • pp.241-250
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    • 2007
  • 폭발하중을 받는 콘크리트 구조물을 섬유 복합재 등의 보강 재료를 사용하여 보강하는 경우에는 강성 증가와 함께 적절한 연성을 확보할 수 있어야 한다. 그러나, 폭발하중을 받는 구조물의 설계 및 해석에 일반적으로 사용되는 기존의 근사적이며 단순화 모델은 보강 재료에 대한 효과를 정확히 반영할 수 없을 뿐 아니라 해석 결과의 정확성 및 신뢰성에 문제가 제기되어왔다. 또한, 동적 하중에 대한 콘크리트와 철근의 응답은 정적 하중에 대한 응답과 상이하기 때문에 기존의 정적, 준정적하에서 정의된 재료물성값들을 폭발하중에 대한 응답 계산에 사용하는 것은 부적절하다. 따라서, 본 연구에서는 명시적(explicit) 해석 프로그램인 LS-DYNA를 사용하여 매우 빠른 재하속도를 갖는 폭발하중에 대하여 강도 증진 및 변형률 속도 효과가 반영된 재료 모델을 포함하고 있는 정밀 HFPB(high fidelity physics based) 유한요소해석 기법을 제시하였다. 제시된 해석적 기법을 통하여 탄소섬유 복합재와 유리섬유 복합재를 사용하여 보강된 콘크리트 벽체의 폭발하중에 대한 거동을 해석하였으며, 이를 보강하지 않은 벽체의 해석 결과와 비교함으로써 보강 성능 분석을 실시하였다. 해석 결과 보강에 따른 최대 처짐이 약 $26{\sim}28%$ 감소하는 보강 성능을 확인하였으며, 제안된 해석 기법이 보강 재료와 보강 기법의 유효성을 평가하는데 효과적으로 적용할 수 있을 것으로 판단된다.

"솔보포빅"한 고분자 마이크로 캡슐을 이용한 효소 안정화에 관한 연구 (Stabilization of Enzyme in "Solvophobically" Controlled Polymer Microcapsules)

  • 김용진;김진웅;김준오;김진우;장이섭
    • 대한화장품학회지
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    • 제32권1호
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    • pp.29-33
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    • 2006
  • 본 연구는 효소의 활성을 저해하는 주위 환경, 특히 열로부터 효소의 활성을 장기간 유지할 수 있는 효소 안정화 시스템에 대한 것으로, 이 시스템은 poly(${\epsilon}-caprolactone$) (PCL) 마이크로 캡슐로, 파파인 효소를 모델 효소로 하여, poly(propylene glycol) (PPG) 층이 코어 효소층을 둘러싸고 있는 형태로 설계되어 있다. 공촛점 현미경 및 장기 열 안정도 결과를 분석해본 결과, 파파인 효소가 소수성 PPG로 둘러쌓여 있고, 배타적 볼륨 효과(exclusive volume effect)에 의해 안정화되어 있음을 밝힐 수 있었다. 이와 같이 향상된 효소의 열 안정도는 소수성 사슬이 긴 PPG를 사용할수록 증가됨을 알 수 있었으며, 이것은 효소와 PPG 계면 사이에서 PPG 층이 파파인 효소를 효과적인 형태 고정(conformational anchoring)을 통해 안정화한 것임을 알 수 있었다.

Origin of Proteinuria as Observed from Qualitative and Quantitative Analysis of Serum and Urinary Proteins

  • Takahashi, Shori
    • Childhood Kidney Diseases
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    • 제19권2호
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    • pp.65-70
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    • 2015
  • It is well known that proteins present in the primary urine are reabsorbed in the renal proximal tubules, and that this reabsorption is mediated via the megalin-cubilin complex and the neonatal $Fc{\gamma}$ receptor. However, the reabsorption is also thought to be influenced by an electrostatic interaction between protein molecules and the microvilli of the renal proximal tubules. By analyzing the charge diversity of urinary IgG, we showed that this reabsorption process occurs in a cationic charge-preferential manner. The charge-selective molecular sieving function of the glomerular capillary walls has long been a target of research since Brenner et al. demonstrated the existence of this function by a differential clearance study by using the anionic dextran sulfate polymer. However, conclusive evidence was not obtained when the study was performed using differential clearance of serum proteins. We noted that immunoglobulin (Ig) A and IgG have similar molecular sizes but distinct molecular isoelectric points. Therefore, we studied the differential clearance of these serum proteins (clearance IgA/clearance IgG) in podocyte diseases and glomerulonephritis. In addition, we studied this differential clearance in patients with Dent disease rather than in normal subjects because the glomerular sieving function is considered to be normal in subjects with Dent disease. Our results clearly showed that the charge-selective barrier is operational in Dent disease, impaired in podocyte disease, and lacking in glomerulonephritis.

Modeling of hollow formation and its dynamics in liquid gas assisted injection molding process

  • Kim, Dong-Hak;Ahn, Kyung-Hyun
    • Korea-Australia Rheology Journal
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    • 제16권1호
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    • pp.27-33
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    • 2004
  • Application of gas assisted injection molding has been expanded during last two decades because of many advantages such as design flexibility, dimensional stability, reduction of machine tonnages, and so on. However, the surface defects including hesitation mark and gloss difference are observed for thick parts. Difficulties in lay-out of the gas channel and processing condition are another disadvantages. Liquid gas assisted injection molding(LGAIM), in which a liquid with a boiling point lower than the temperature of the polymer melt is injected into the melt stream, and travels with the melt into the mold where it vaporizes and pushes the melt downstream and against the cavity walls to create hollow channels within the part, is a good alternative of the conventional gas assisted injection molding especially in manufacturing simple and very thick parts. Though this is a new frontier of the innovation in the injection molding industry, there is no guideline for the design and processing conditions. In this paper, theoretical analysis has been made to describe the hollow formation dynamics in LGAIM. This model provides an insight into LGAIM process: explains why LGAIM has advantages over conventional gas assisted injection molding, and gives a guideline for the design and processing conditions.

Washing Effects on Generation of Pretilt Angle in NLC, 5CB, on a Polyimide Surface with Trifluoromethyl Moieties

  • Lee, Sang-Keuk;Han, Jeong-Min;Hwang, Jeoung-Yeon;Seo, Dae-Shik
    • Transactions on Electrical and Electronic Materials
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    • 제4권1호
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    • pp.21-23
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    • 2003
  • The washing effects on pretilt angle generation in a nematic liquid crystal (NLC), 4-n-pentyl-4'-cyanobiphenyl (5CB) on a rubbed polyimide (PI) surface with trifluoromethyl moiety have been successfully studied. The pretilt angle of 5CB is increased by the washing process on the rubbed PI surface. The surface tension on the rubbed PI surface increases with the rubbing strength RS and then saturated above RS: 150 mm. The pretilt angle of 5CB for all washing processes on the rubbed PI surface decreases with the surface tension. We have found that the pretilt angle of 5CB on the rubbed PI surface may be attributed van der walls (VDW) dispersion interaction between the LC molecules and the polymer surfaces having trifluoromethyl moieties.

An instability criterion for viscoelastic flow past a confined cylinder

  • Dou, Hua-Shu;Phan-Thien, Nhan
    • Korea-Australia Rheology Journal
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    • 제20권1호
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    • pp.15-26
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    • 2008
  • It has been known that there is a viscoelastic instability in the channel flow past a cylinder at high Deborah (De) number. Some of our numerical simulations and a boundary layer analysis indicated that this instability is related to the shear flow in the gap between the cylinder and the channel walls in our previous work. The critical condition for instability initiation may be related to an inflection velocity profile generated by the normal stress near the cylinder surface. At high De, the elastic normal stress coupling with the streamline curvature is responsible for the shear instability, which has been recognized by the community. In this study, an instability criterion for the flow problem is proposed based on the analysis on the pressure gradient and some supporting numerical simulations. The critical De number for various model fluids is given. It increases with the geometrical aspect ratio h/R (half channel width/cylinder radius) and depends on a viscosity ratio ${\beta}$(polymer viscosity/total viscosity) of the model. A shear thinning first normal stress coefficient will delay the instability. An excellent agreement between the predicted critical Deborah number and reported experiments is obtained.