• 제목/요약/키워드: polymer synthesis and characterization

검색결과 305건 처리시간 0.034초

Synthesis and Characterization of Crosslinkable Hole-Injection Transport Material for Polymer Light Emitting Diodes

  • Thi, Mai Nguyen;Kim, Jin-Woo;Vu, Quang Hung;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.810-813
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    • 2009
  • Fluorene derivatives are well-known in the polymer OLEDs due to their good charge carrying property. In this work, we synthesized a series of conjugated copolymers based fluorene derivative and phenylamine units by using Buchwald-Hartwig reaction in order to investigate their photoreactivities and use as the HIL/HTL layers of OLEDs using solution processes.

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Synthesis of Host Polymers and Guests for Electrophosphorescence

  • Watkins Scott E.;Chan, Khai Leok;Cho, Sung-Yong;Evans Nicholas R.;Grimsdale Andrew C.;Holmes Andrew B.;Mak Chris S.K.;Sandee Albertus J.;Williams Charlotte K.
    • Macromolecular Research
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    • 제15권2호
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    • pp.129-133
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    • 2007
  • Significant progress has been realized in the design and synthesis of light emitting polymers that emit over the entire visible spectrum. However, up to seventy-five percent of charge recombination events can lead to triplet states that decay non-radiatively. Following the pioneering work in the field of small molecule organic light emitting devices, it has been found that solution processible iridium polymer complexes can be used to harness the wasted triplet energy. In this paper, new results with respect to the electrophosphorescence of solution processible tethered iridium polymer derivatives are presented. Furthermore, our approaches to the design of new high triplet energy conjugated polymer hosts are also reported.

Synthesis and characterization of Reactive Banana-Shaped Mesogens

  • Choi, Min-Ho;Choi, E-Joon;Kim, Young-Chul;Park, Sang-Hyon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.854-857
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    • 2006
  • The synthesis of ester type, banana-shaped, photo - crosslinkable mesogens is described. The reactive mesogens, derivatives of 1,3-phenylene bis{4-[4'- (alken-1-yloxy)-biphenyl-4-carboxylate]benzoate}s, were synthesized varying the length of alkyl end groups. The obtained monomers and polymers were characterized by FT/IR, NMR spectroscopy, DSC, polarized optical microscopy, and X-ray diffractometry.

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Synthesis and Characterization of Poly(alkyl $\alpha$, L-glutamate-co-ethylene oxide)

  • Kim, Gunwoo;Kim, Jin-Yeol;Daewon Sohn;Lee, Youngil
    • Macromolecular Research
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    • 제10권1호
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    • pp.49-52
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    • 2002
  • Rod-coil amphiphilic block copolymers, PALG-PEOs, poly(alkyl $\alpha$, L-glutamate-co-ethylene oxide)s, were successfully synthesized in three steps: 1) esterification of L-glutamic acid, 2) synthesis of ${\gamma}$-alkyl L-gultamate N-carboxyanhydride, and 3) polymerization of NCA monomers. These molecules form polymeric micelles with the hydrophobic core and hydrophilic corona in aqueous solution, which were characterized by light scattering and static fluorescence measurement.

Synthesis of Star like Random Copolymers from Resorcinarene-based Alkoxyamine Initiator via Nitroxide Mediated Free Radical Polymerization

  • Abraham, Sinoj;Choi, Jae-Ho;Ha, Chang-Sik;Kim, Il
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.337-337
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    • 2006
  • The synthesis of an octafunctional resorcinarene based initiator for nitroxide mediated polymerization and its ability to yield random star copolymers of styrene and methyl methacrylate is studied. The effect of the initiator conformations towards its activity and the conditions that permit the formation of well-defined star block copolymers is also investigated in detail. The characterization of the initiator and the polymers were carried out by various spectro-analytical techniques. Well-defined random copolymers were obtained with controlled molecular weight and low PDI depending on the monomer feed.

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Synthesis and Characterization of a Tetrathiafulvalene-Based Polymer

  • Lee, Se-Hyun;Wang, Lei;Hwang, Seok-Ho;Lee, Myong-Hoon;Jeong, Kwang-Un
    • Bulletin of the Korean Chemical Society
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    • 제33권5호
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    • pp.1451-1456
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    • 2012
  • A novel tetrathiafulvalene (TTF)-based main-chain polymer (6TTF-polymer) was successfully synthesized via a condensation polymerization between a newly synthesized dihydroxy TTF derivative and a malonyl chloride, and its chemical structure was characterized by spectroscopic techniques. Molecular weight of the 6TTF-polymer (9,030 g/mol by gel permeation chromatography) was large enough to form the ductile film. The electrochemical and optical properties of the 6TTF-polymer were further estimated by cyclic voltammetry, ultraviolet and photoluminescence spectroscopes. The highest occupied molecular orbital level ($E_{HOMO}$=-4.79 eV) and band-gap energy ($E_g$=1.91 eV) of the 6TTF-polymer suggested that TTF-based polymer could act as a good electron donating material for the optoelectronic applications.