• Title/Summary/Keyword: polymer resist

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Polymer Microlens Fabrication (폴리머 마이크로렌즈 제작)

  • Ryoo, Kunkul;Kim, Younggeun;Jeon, Kwangseok
    • Clean Technology
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    • v.11 no.4
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    • pp.205-211
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    • 2005
  • There have been many technologies and materials proposed for realizing microlens array, and plastic injection is recognized as the most promising one because of several merits such as optical properties, impact resistance, formability, lightening and environmental adaptability. Since PR reflow for injection template fabrication enables the lens shape control easier, and the sample technology more effective for mass production, it lowers the cost, enhances integration, and reduces process steps, which leads to be environmentally benign. However injection of polymers may face the difficulty of formability depending on their properties. In order to overcome the difficulty, fast heating/cooling technology was introduced in this study, and microlenses were fabricated and evaluated. template obtained by PR reflow method was heated and cooled fast during injection to fabricate microlens array. PC and PMMA polymer materials were compared, and it was realized that PMMA showed much better formability due to its lower melting temperature. Injection parameters of pressures and velocities were driven out for injection optimization.

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A Study on the Modification of Asphalt with Light (빛에 의한 아스팔트 개질에 관한 연구)

  • Kang, Hyun-Seung;Hong, Young-Keun
    • Elastomers and Composites
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    • v.44 no.1
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    • pp.63-68
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    • 2009
  • Recently, much attention has focused on the permanent deformation of roads in hot summer and cracks in cold winter, which are detrimental to safe driving. This leads to necessity of modification of asphalt to resist those deformation. In this study, a type of modified asphalt was prepared by addition of a photoinitiator which is activated by ultraviolet lay. The mechanical and rheololgical properties of photoinitiator-modified asphalt were examined using UTM and rheometer. Results showed that the modified asphalt was effected by ultraviolet and thus tensile strength and storage modulus increased, due to molecular attraction, with initiator content and irradiation dose. Thermal analysis showed less weight loss upon photoinitiator-modification and this indicated that the molecular attraction is the result of cross linking reaction between asphalt molecules induced by photoinitiator. According to long term ultraviolet curing test, properties of the photoinitiator-modified asphalt did not decrease or even increase for 20 years. This indicates that useful life of the asphalt could be extended by addition of photoinitiator.

A Study on Chloride Threshold Level of Polymer Inhibitive Coating Containing Calcium Hydroxide (수산화칼슘을 혼입한 폴리머 방청 코팅의 부식 임계치 향상에 대한 연구)

  • Song, Ha-Won;Lee, Chang-Hong;Lee, Kewn-Chu;Ann, Ki-Yong
    • Journal of the Korea Concrete Institute
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    • v.20 no.6
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    • pp.713-719
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    • 2008
  • Various types of coatings have been developed for use as reinforcement in concrete and to resist chloride environment. The most commonly used coatings are inhibited and sealed cement slurry coating, cement polymer compositing coating and epoxy coating. Cement slurry offers passive protection, epoxy coating offers barrier protection whereas polymer coating offers both passive protection and barrier protection. Moreover, damage during handling of the steel may result in disbondment of the epoxy coating, which would increase the risk of localized corrosion. In the present study, inhibiting technique was used to increase the calcium hydroxide content at the interface up to 20%. Calcium hydroxide provides a high buffering capacity that resists a local fall in pH and thus maintains the alkaline environment necessary to prevent chloride corrosion. This study examines the use of a calcium hydroxide coating on the steel surface to enhance the pH buffering capacity of steel-concrete interface. Finally, the chloride threshold level (CTL) of polymer inhibitive coating calcium hydroxide is evaluated.

Experimental Study on GFRP Reinforcing Bars with Hollow Section (중공형 GFRP 보강근의 인장성능 실험연구)

  • You, Young-Jun;Park, Ki-Tae;Seo, Dong-Woo;Hwang, Ji-Hyun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.1
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    • pp.45-52
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    • 2015
  • Fiber-reinforced polymer (FRP) has been generally accepted by civil engineers as an alternative for steel reinforcing bars (rebar) due to its advantageous specific tensile strength and non-corrosiveness. Even though some glass fiber reinforced polymer (GFRP) rebars are available on a market, GFRP is still somewhat uncompetitive over steel rebar due to their high cost and relatively low elastic modulus, and brittle failure characteristic. If the price of component materials of GFRP rebar is not reduced, it would be another solution to increase the performance of each material to the highest degree. The tensile strength generally decreases with increasing diameter of FRP rebar. One of the reasons is that only fibers except for fibers in center resist the external force due to the lack of force transfer and the deformation of only outer fibers by gripping system. Eliminating fibers in the center, which do not play an aimed role fully, are helpful to reduce the price and finally FRP rebar would be optimized over the price. In this study, the effect of the hollow section in a cross-section of a GFRP rebar was investigated. A GFRP rebar with 19 mm diameter was selected and an analysis was performed for the tensile test results. Parameter was the ratio of hollow section over solid cross-section. Four kinds of hollow sections were planned. A total of 27 specimens, six specimens for each hollow section and three specimens with a solid cross-section were manufactured and tested. The change by the ratio of hollow section over solid cross-section was analyzed and an optimized cross-section design was proposed.

Research about Chemical-Biological Protection Capability of Selectively Permeable Membrane Materials Based on Polyvinyl Alcohol (폴리비닐알코올 기반 선택투과막 재료의 화생방호성능 연구)

  • Kang, Jae-Sung;Seo, Hyeon-Kwan;Kwon, Tae-Geun;Park, Hyen-Bae;Lee, Hae-Wan
    • Membrane Journal
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    • v.23 no.3
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    • pp.237-244
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    • 2013
  • We fabricated several composite membranes with selectively permeable performance designed to facilitate water vapor transport and resist DMMP vapor permeation. Materials for selective permeable membrane were based on polyvinyl alcohol and functional polymer containing basic functional group. With these materials, we characterized selectively permeable performance to identify next-generation material with chemical-biological protective capability. Results showed that polyvinyl alcohol (PVA)/polyethyleneimine (PEI) materials possessed performance with superior water vapor permeation ($2,200{\sim}2,900g/m^2/day$) and protective capability against DMMP vapor ($47g/m^2/day$).

Direct Patterning of Self Assembled Nano-Structures of Block Copolymers via Electron Beam Lithography

  • Yoon Bo Kyung;Hwang Wonseok;Park Youn Jung;Hwang Jiyoung;Park Cheolmin;Chang Joonyeon
    • Macromolecular Research
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    • v.13 no.5
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    • pp.435-440
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    • 2005
  • This study describes a method where the match of two different length scales, i.e., the patterns from self-assembled block copolymer (<50 nm) and electron beam writing (>50 nm), allow the nanometer scale pattern mask. The method is based on using block copolymers containing a poly(methyl methacrylate) (PMMA) block, which is subject to be decomposed under an electron beam, as a pattern resist for electron beam lithography. Electron beam on self assembled block copolymer thin film selectively etches PMMA microdomains, giving rise to a polymeric nano-pattern mask on which subsequent evaporation of chromium produces the arrays of Cr nanoparticles followed by lifting off the mask. Furthermore, electron beam lithography was performed on the micropatterned block copolymer film fabricated by micro-imprinting, leading to a hierarchical self assembled pattern where a broad range of length scales was effectively assembled, ranging from several tens of nanometers, through submicrons, to a few microns.

SF6 and O2 Effects on PR Ashing in N2 Atmospheric Dielectric Barrier Discharge

  • Jeong, Soo-Yeon;Kim, Ji-Hun;Hwang, Yong-Seuk;Kim, Gon-Ho
    • Transactions on Electrical and Electronic Materials
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    • v.7 no.4
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    • pp.204-209
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    • 2006
  • Photo Resist (PR) ashing process was carried out with the atmospheric pressure- dielectric barrier discharge (ADBD) using $SF_6/N_2/O_2$. Ashing rate (AR) was sensitive to the mixing ratio of the oxygen and nitrogen of the blower type of ADBD asher. The maximum AR of 5000 A/min was achieved at 2% of oxygen in the $N_2$ plasma. With increasing the oxygen concentration to more than 2% in the $N_2$ plasma, the discharge becomes weak due to the high electron affinity of oxygen, resulting in the decrease of AR. When adding 0.5% of SF6 to $O_2/N_2$ mixed plasma, the PR AR increased drastically to 9000 A/min and the ashed surface of PR was smoother compared to the processed surface without $SF_6$. Carbon Fluorinated polymer may passivate the PR surface. It was also observed that the glass surface was not damaged by the fluorine.

Repeated impact response of bio-inspired sandwich beam with arched and honeycomb bilayer core

  • Ahmad B.H. Kueh;Juin-Hwee Tan;Shukur Abu Hassan;Mat Uzir Wahit
    • Structural Engineering and Mechanics
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    • v.85 no.6
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    • pp.755-764
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    • 2023
  • The article examines the impact response of the sandwich beam furnished by a novel bilayer core as inspired by the woodpecker's head architecture under different repeatedly exerted low-velocity impact loadings by employing the finite element package, ABAQUS. The sandwich beam forms four essential parts comprising bottom and top carbon fiber reinforced polymer laminates encasing bilayer core made of laterally arched solid hot melt adhesive material and aluminum honeycomb. Impact loadings are implemented repeatedly with a steel hemisphere impactor for various impact energies, 7.28 J, 9.74 J, and 12.63 J. Essentially, the commonly concentrated stresses at the impact region are regulated away by the arched core in all considered cases thus reducing the threat of failure. The sandwich beam can resist up to 5 continual impacts at 7.28 J and 9.74 J but only up to 3 times repeated loads at 12.63 J before visible failure is noticed. In the examination of several key impact performance indicators under numerous loading cases, the proposed beam demonstrates favorably up to 1.3-11.2 higher impact resistance efficacies compared to existing designs, therefore displaying an improvement in repeated impact resistance of the new design.

Structural Design and Installation of Tracking-type Floating PV Generation System (추적식 수상 태양광발전 시스템의 설계 및 시공)

  • Kim, Sun-Hee;Lee, Young-Guen;Seo, Su-Hong;Joo, Hyung-Joong;Yoon, Soon-Jong
    • Composites Research
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    • v.27 no.2
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    • pp.59-65
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    • 2014
  • Most of energy are obtained from oil, coal, and natural gas, most likely, fossil fuel which is limited throughout the world. Recently, high crude oil price, climate change, oil depletion, etc. are main reason to get attention to non-fossil energy including renewable energy in the world. In this study, we studied analysis and design of structure system composed of pultruded fiber reinforced polymer composite (PFRP) which has many advantages such as high specific strength and stiffness, high corrosion resistance and chemical resistance. For the design and construction of floating-type structure, PFRP structural members may be the first choice. Design of tracking-type floating PV generation structure was performed by using the results of the finite element analysis. The structure is fabricated and installed on the water surface. Before the installation of the structure, safety related problems associated with installation and operation are investigated using the finite element simulation and it was found that the structure is safe enough to resist externally applied loads.

Influence Evaluation of Fiber on the Bond Behavior of GFRP Bars Embedded in Fiber Reinforced Concrete (섬유보강 콘크리트에 묻힌 GFRP 보강근의 부착거동에 대한 섬유영향 평가)

  • Kang, Ji-Eun;Kim, Byoung-Ill;Park, Ji-Sun;Lee, Jung-Yoon
    • Journal of the Korea Concrete Institute
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    • v.24 no.1
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    • pp.79-86
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    • 2012
  • Though steel reinforcing bars are the most widely used tensile reinforcement, corrosion problems are encountered due to the exposure to aggressive environments. As an alternative material to steel, the fiber reinforced polymers have been used as reinforcement in concrete structures. However, bond strength of FRP rebar is relatively low compared to steel rebar. It has been reported that fibers in matrix can resist crack growth, propagation and finally result in an increase of toughness. In this study, high-strength concrete reinforced with structural fibers was produced to enhance interfacial bond behavior between FRP rebar and concrete matrix. The interfacial bond-behaviors were investigated from a direct pullout test. The test variables were surface conditions of GFRP bars and fiber types. Total of 54 pullout specimens with three different types of bars were cast for bond strength tests. The bond strength-slip responses and resistance of the bond failure were evaluated. The test results showed that the bond strength and toughness increased according to the increased fiber volume.