• Title/Summary/Keyword: polymer plate

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Development of Composite Bipolar Plate for PEMFC (고분자 전해질 연료전지용 복합수지 분리판 개발)

  • Kang, Hyun-Min;Han, In-Su;Lim, Chan
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.5-7
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    • 2007
  • Graphite/polymer composite bipolar plates for PEMFC are successfully developed, and their typical properties are superior to commercially available ones. Thermal property of the developed bipolar plate was evaluated by dynamic mechanical analyzer, and the results were compared to commercial ones. The specimens were immersed into the deionized water bath at $80^{\circ}C$ for 1500hrs to evaluate dimensional stability and durability. Dimension, weight of the specimens as well as extraction conductivity was measured as each 500hrs. Fully molded bipolar plates without any machining or milling were also prepared using a specially developed mold, and they were applied to the fuel cell performance test. Results were compared to the machined commercial bipolar plate.

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Fabrication of Ionic Polymer-Metal Composite Actuator and Application to Moving Mechanism (이온성 고분자-금속 복합물 액추에이터의 제작 및 이동형 액추에이터에의 응용)

  • Lee, Seung-Ki;Lee, Sang-Jo
    • Journal of Sensor Science and Technology
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    • v.12 no.3
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    • pp.112-120
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    • 2003
  • The composite of ionic polymer and metal has been fabricated and used for actuators. Platinum is deposited by electroless plating method onto the both sides of ionic polymer where ac voltage is applied. This results in the bending motion of a beam type actuator. In this paper, the fabrication method of ionic polymer-metal composite has been explained and the moving mechanism has been fabricated and measured using the ionic polymer-metal composite actuator. The moving mechanism is wireless type and the power is supplied through the rail electrodes in base plate. The maximum speed of the moving mechanism was about 24cm/min.

Comparison of Corrosion Behavior of CrN Coated SUS316L with Different Layer Structure for Polymer Electrode Membrane Fuel Cell Bipolar Plate (CrN 코팅구조에 따른 Polymer Electrode Membrane Fuel Cell 금속분리판의 부식특성 비교)

  • Paik, Jung-Ho;Han, Won-Kyu;Kang, Sung-Goon
    • Korean Journal of Materials Research
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    • v.20 no.4
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    • pp.187-193
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    • 2010
  • Chromium nitride (CrN) samples with two different layer structures (multilayer and single layer) were coated on bipolar plates of polymer electrolyte membrane fuel cells (PEMFC) using the reactive sputtering method. The effects with respect to layer structure on corrosion resistance and overall cell performance were investigated. A continuous and thin chromium nitride layer ($Cr_{0.48}\;N_{0.52}$) was formed on the surface of the SUS 316L when the nitrogen flow rate was 10 sccm. The electrochemical stability of the coated layers was examined using the potentiodynamic and potentiostatic methods in the simulated corrosive circumstances of the PEMFC under $80^{\circ}C$. Interfacial contact resistance (ICR) between the CrN coated sample and the gas diffusion layer was measured by using Wang's method. A single cell performance test was also conducted. The test results showed that CrN coated SUS316L with multilayer structure had excellent corrosion resistance compared to single layer structures and single cell performance results with $25\;cm^2$ in effective area also showed the same tendency. The difference of the electrochemical properties between the single and multilayer samples was attributed to the Cr interlayer layer, which improved the corrosion resistance. Because the coating layer was damaged by pinholes, the Cr layer prevented the penetration of corrosive media into the substrate. Therefore, the CrN with a multilayer structure is an effective coating method to increase the corrosion resistance and to decrease the ICR for metallic bipolar plates in PEMFC.

Preparation of Electrode Coated with Activated Carbon for Dust Removal (분진제거를 위한 활성탄 전극판의 제조)

  • Kim, Kwang Soo;Park, Jung O;Jun, Tae Hwan;Kim, Ilho
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.11
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    • pp.815-820
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    • 2013
  • The purpose of this research is to prepare the aluminum electrode coated with activated carbon for removing air pollution dust. The experiments were studied on the selection of optimal polymer for binding aluminum plate with powdered activated carbon, preventing the pore blocking of activated carbon from polymer binder, and the dust treatability for the prepared activated carbon electrode. The optimal adhesive for coating activated carbon on an electric aluminum plate was polyvinyl acetate (PVA) with vinyl functional group. For the opening of the blocked pore with polymer, it was very effective to embed polymer solvent in pore of activated catbon firstly before mixing activated carbon with PVA, and then to devolatilize the embedded solvent of carbon pore at high temperature. The mass of trapped dust on aluminum electrode coated with activated carbon was about double of the trapped one on just aluminum electrode.

Estimation of Rheological Properties of Highly Concentrated Polymer Bonded Explosive Simulant by Microstructure Analysis (미세구조 해석을 통한 고농축 복합화약 시뮬란트의 유변물성 예측)

  • Lee, Sangmook;Hong, In-Kwon;Lee, Jae Wook;Shim, Jung Seob
    • Polymer(Korea)
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    • v.38 no.2
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    • pp.225-231
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    • 2014
  • The rheological properties of highly concentrated polymer bonded explosive simulant were studied by using poly(ethylene-co-vinyl acetate) with 30 and 60% vinyl acetate (VA) content as a binder, respectively. Calcium carbonate and Dechlorane, whose physical properties are similar to resarch department explosive (RDX)'s, were used as fillers. The suspensions were mixed in a batch melt mixer and it was possible to fill 75 v% at maximum. From dynamic mechanical analysis, Dechlorane showed higher interaction with binder resins than that with calcium carbonate fillers. The effects of microstructural change on the rheological properties of the suspensions were investigated by a plate-plate rheometer with constant shear rate and constant shear stress modes, respectively. The theoretical maximum packing fraction of EVA31/Dechlorane suspension obtained from Krieger-Dougherty equation was 70 v% and it was thought that 2000 Pa was proper shear stress condition for this melt processing.

A Study on Oxygen Diffusion Characteristics According to Changes in Flow Field Shape of Polymer Electrolyte Membrane Fuel Cell Metallic Bipolar Plate for Building (건물용 고분자 전해질 연료전지 금속분리판 유동장 형상 변화에 따른 산소 확산 특성에 대한 연구)

  • PARK, DONGHWAN;SOHN, YOUNG-JUN;CHOI, YOON-YOUNG;KIM, MINJIN;HONG, JONGSUP
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.4
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    • pp.245-255
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    • 2021
  • Various studies about metallic bipolar plates have been conducted to improve fuel cell performance through flow field design optimization. These research works have been mainly focused on fuel cells for vehicle, but not fuel cells for building. In order to reduce the price and volume of fuel cell stacks for building, it is necessary to apply a metallic flow field, In this study, for a metallic flow field applied to a fuel cell for building, the effect of a change in the flow field shape on the performance of a polymer electrolyte membrane fuel cell was confirmed using a model and experiments with a down-sizing single cell. As a result, the flow field using a metal foam outperforms the channel type flow field because it has higher internal differential pressure and higher reactants velocity in gas diffusion layer, resulting in higher water removal and higher oxygen concentration in the catalyst layer than the channel type flow field. This study is expected to contribute to providing basic data for selecting the optimal flow field for the full stack of polymer electrolyte membrane fuel cells for buildings.

Computational Justification of Current Distribution Measurement Technique Via Segmenting Bipolar Plate in Fuel Cells (분리판 분할을 통만 연료전지의 전류분포 측정법에 대한 수치적 검증)

  • Choi, Yong-Jun;Lee, Gi-Yong;Kang, Kyung-Mun;Kim, Whan-Gi;Ju, Hyun-Chul
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.1
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    • pp.1-11
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    • 2010
  • Current distribution measurement technique based on a segmented bipolar plate (BP) has been widely adopted to visualize the distribution of current density in a polymer electrolyte membrane. However, a concern is raised how closely the current density of a segmented BP can approach that of a corresponding non-segmented membrane. Therefore, in this paper, the accuracy of the measurement technique is numerically evaluated by applying a three-dimensional, two-phase fuel cell model to a $100\;cm^2$ area fuel cell geometry in which segmented BPs and non-segmented membrane are combined together. The simulation results reveal that the errors between the current densities of the segmented BPs and non-segmented membrane indeed exist, predicting the maximum relative error of 33% near the U-turn regions of the flow-field. The numerical study further illustrates that the erroneous result originates from the BPs segmented non-symmetrically based on the flow channels that allows some currents bypassing flow channels to flow into its neighboring segment. Finally, this paper suggests the optimal way for bipolar plate segmentation that can minimize the deviation of current measured in a segmented BP from that of a corresponding membrane region.

Comparison of Shear Strength Equation for Flat Plates with GFRP Plate (GFRP 판으로 보강된 플랫 플레이트의 전단강도식에 관한 규준의 비교 분석)

  • Kim, Min Sook;Hwang, Seung Yeon;Kim, Heecheul;Lee, Young Hak
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.27 no.4
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    • pp.247-254
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    • 2014
  • In this study, shear test performed to investigate the shear behavior of flat plate that reinforced by embedded GFRP(glass fiber reinforced polymer) plate with openings. Shape of the GFRP shear reinforcement is a plate with several openings to ensure perfect integration with concrete. The test parameters include the distance between the column face and the first line of GFRP plate and number of GFRP plate vertical strip. The result of test showed that when number of GFRP plate vertical strip was increased, shear strength improved. The shear strength for flat plate reinforced GFRP plate in various codes including ACI 318, BS 8110, EUROCODE 2, and KCI were compared to provide more rational approach for reinforced concrete flat plates with GFRP plate.

Ultrasonic Reflection at a Water/Fiber Reinforced Polymer Composite/Water Interface (물/섬유강화 고분자 복합재료/물 경계면에서의 초음파 반사)

  • Lee, J.H.;Lee, S.C.;Jun, J.N.;Oh, S.J.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.13 no.1
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    • pp.15-20
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    • 1993
  • This study describes ultrasonic reflection at a water/fiber reinforced polymer composite/water interface. Theoretical predictions of reflected beam amplitudes are also presented. Four different polymer composite laminates are investigated : T300/5208 graphite/epoxy $[0]_{31T},\;[45/90/-45/0]_{3S},\;[45/-45]_{2S}$, and S-2 glass/epoxy $[0/90]_{4S}$. The analytical leaky plate wave dispersion curves for the unidirectional laminate and other three laminates can be obtained by searching for the minimum magnitude of the reflection coefficient.

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Development of Polymer Micro-actuator using Segmented Polyurethanes and its Application for the Micro-fluidics (세그먼트화 폴리우레탄을 이용한 고분자 마이크로 액츄에이터의 개발 및 마이크로 플루이딕스에의 적용)

  • 정영대;박한수;조남주;정해도
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.285-290
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    • 2004
  • Electro-active polymer, one of smart materials, is a new alternative technology, which can get an ultra precision movements and bio-compatibilty. This paper presents the relationship between elastic modulus and maximum deflection as a key property of maxwell stress effects and also presents the relationship between dielectric constant and maximum deflection as a key property of electro-striction effects in disc-type actuators using segmented PU. To induce equation about distributed load of a disc, we use boundary condition of fully clamped circular plate and to obtain design parameters of a micro-fluidics system, CFD simulation is performed.

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