• Title/Summary/Keyword: polymer plate

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Development of Polymer Coating Method for Stable Stent Coating Using Chemical Bond Between Metal Surface and Polymer (안정된 스텐트 코팅막을 형성하기 위해 금속표면과 고분자 사이의 화학적 결합을 이용한 고분자 코팅법 개발)

  • Nam, Dae-Sik;Lee, Woo-Kyoung
    • Journal of Pharmaceutical Investigation
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    • v.37 no.1
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    • pp.7-13
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    • 2007
  • To produce stable polymer coating layer using the interaction between metal stent and polymer layer, Ahx-HSAB was synthesized by coupling 6-aminoheanoic acid (Ahx) with N-Hydroxy succinimidyl 4-azidobenzonate (HSAB) containing photo reactive group. Then, Ahx-HSAB was applied to self·assembled monolayer (SAM) on $TiO_2$-coated surface, since one end of Ahx-HSAB was carboxyl acid which was known to be able to interact with $TiO_2$ surface. That SAM layer was incubated in 1% polycaprolacton (PCL) solution and photoreacted by ultraviolet light (254 nm) to produce the chemical bond between SAM and polymer layer, followed by PCL polymer coating ({\sim}5\;{\mu}m$) by the method of spray coating. The surface change was investigated by measuring of contact angle of the surface. The contact angle values of stainless steel (SS) surface, $TiO_2$-coated surface, SAM layer by Ahx-HSAB, photoreacted surface with PCL and PCL layer by spray coating were 70.48${\pm}$1.89, 38.57${\pm}$3.31, 60.14${\pm}$2.21, 54.91${\pm}$2.70 and 56.47${\pm}$2.12, respectively. The stability of polymer layers was tested by incubation of PCL-coated plates in 0.1M PBS buffer (pH 7.4, 0.05%, Tween 80) with vigorous shaking (200 rpm). While the poiymer layer prepared by these processes showed the intact surface morphology over 3 days, the polymer layers prepared by spray coating of PCL onto SS plate (control 1) and $TiO_2$-coated SS plate (control 2) were Peeled off in 3 days. Thus, the polymer coating method using SAM and photoreaction seems to be a effective method to obtain the stable polymer layer onto SS surface.

THE THREE DIMENSIONAL FINITE ELEMENT ANALYSIS OF STRESS DISTRIBUTION AND DISPLACEMENT IN MANDIBLE ACCORDING TO TREATMENT MODALITIES OF MANDIBULAR ANGLE FRACTURES (하악각 골절의 치료 방법에 따른 하악골의 응력 분포 및 변위에 관한 삼차원 유한요소법적 연구)

  • Ku, Je-Hoon;Kim, Il-Kyu;Chang, Jae-Won;Yang, Jung-Eun;Sasikala, Balaraman;Wang, Boon
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.32 no.3
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    • pp.207-217
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    • 2010
  • The purpose of this study was to evaluate the effects of the stress distribution and displacement in mandible according to treatment modalities of mandibular angle fractures, using a three dimensional finite element analysis. A mechanical model of an edentulous mandible was generated from 3D scan. A 100-N axial load and four masticatory muscular supporting system were applied to this model. According to the number, location and materials of titanium and biodegradable polymer plates, the experimental groups were divided into five types. Type I had a single titanium plate in the superior border of mandibular angle, type II had two titanium plates in the superior tension border and in the inferior compression border of mandibular angle, type III had a single titanium plate in the ventral area of mandibular angle, type IV had a single biodegradable polymer plate in the superior border of mandibular angle, type V had a single biodegradable polymer plate in the ventral area of mandibular angle. The results obtained from this study were follows: 1. Stress was concentrated on the condylar neck of the fractured side except Type III. 2. The values of von-Mises stress of the screws were the highest in the just-posterior screw of the fracture line, and in the just-anterior screw of Type III. 3. The displacement of mandible in Type III was 0.04 mm, and in Type I, II, IV, and V were 0.10 mm. 4. The plates were the most stable in the ventral area of mandibular angle (Type III, V). In conclusion, the ventral area of mandibular angle is the most stable location in the fixation of mandibular angle fractures, and the just- posterior and/or the just-anterior screws of the fracture line must be longer than the other, and surgeons have to fix accurately these screws, and the biodegradable polymer plate also was suitable for the treatment of mandible angle fracture.

Development of high durable metallic bipolar plate for Polymer Electrolyte Membrane Fuel Cells (고분자 전해질 연료전지 금속분리판 코팅 내구성 평가)

  • Kim, Minsung;Seo, Hakyu;Han, In-Su;Jung, Jeehoon;Shin, Hyungil;Hur, Taeuk;Cho, Sungbaek
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.87.1-87.1
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    • 2010
  • Metallic bipolar plate is the one of the promising candidate material for PEMFC because of mechanical strength, low gas permeability, electrical and thermal conductivity. However, the corrosion is the main obstacle of metallic bipolar plate, and many investigations, especially coating on base metal, have been carried out to avoid corrosion. Gold is considered as the one of the best coating material because of its corrosion resistance and electrical conductivity. In this study, gold coated metallic bipolar plate was developed and evaluated. Due to our coating process, gold can be well-adhere to the base material, and hydrophobic material on its gold surface was coated by dipping method for better water management. To verify coating reliability, a single fuel cell(50cm2) was evaluated, and its durability over 4000hrs was demonstrated.

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Vibration of axially moving 3-phase CNTFPC plate resting on orthotropic foundation

  • Arani, Ali Ghorbanpour;Haghparast, Elham;Zarei, Hassan Baba Akbar
    • Structural Engineering and Mechanics
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    • v.57 no.1
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    • pp.105-126
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    • 2016
  • In the present study, modelling and vibration control of axially moving laminated Carbon nanotubes/fiber/polymer composite (CNTFPC) plate under initial tension are investigated. Orthotropic visco-Pasternak foundation is developed to consider the influences of orthotropy angle, damping coefficient, normal and shear modulus. The governing equations of the laminated CNTFPC plates are derived based on new form of first-order shear deformation plate theory (FSDT) which is simpler than the conventional one due to reducing the number of unknowns and governing equations, and significantly, it does not require a shear correction factor. Halpin-Tsai model is utilized to evaluate the material properties of two-phase composite consist of uniformly distributed and randomly oriented CNTs through the epoxy resin matrix. Afterwards, the structural properties of CNT reinforced polymer matrix which is assumed as a new matrix and then reinforced with E-Glass fiber are calculated by fiber micromechanics approach. Employing Hamilton's principle, the equations of motion are obtained and solved by Hybrid analytical numerical method. Results indicate that the critical speed of moving laminated CNTFPC plate can be improved by adding appropriate values of CNTs. These findings can be used in design and manufacturing of marine vessels and aircrafts.

Study on Graphite/Polypropylene/Liquid Crystalline Polymer Composite for a Bipolar Plate of Polymer Electrolyte Membrane Fuel Cell (고분자 전해질막 수소 연료 전지 분리판 용 흑연/폴리프로필렌/액정고분자 복합 재료의 특성에 관한 연구)

  • Dhungana, Biraj;Son, Younggon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.5
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    • pp.3627-3632
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    • 2015
  • We investigated mechanical, rheological and electrical properties of graphite/PP/LCP composites for a bipolar plate of the polymer electrolyte membrane fuel cell. The composites containing very low molecular weighted PP showed much higher electrical conductivity compared with other thermoplastics. This was attributed to the enhanced dispersion of graphite particles due to the low viscosity of the PP. The conductivity of the composites was increased in a great extent by incorporation of small amount of carbon nano tube (CNT). However, the acid treated CNT which contains oxygen atoms did not increase the conductivity of the composite. From this result, it is concluded that the CNT has higher affinity with non polar polymer. The composite with low molecular weighted PP provided good processability so that the composites can be processed by an injection molding while the mechanical strength is deficient compared to other polymers. In order to reinforce the low mechanical property, LCP/PP was used as a binder and the graphite/PP/LCP composite showed the higher conductivity and moderate mechanical strength maintaining suitable processability.

Develop Evaluation Method of Effective Bond Length Between Concrete and Fiber Reinforcement Polymer (FRP로 보강된 콘크리트 부재의 유효부착길이 평가방법 제안)

  • Yi Waon Ho;Woo Hyun Su;Choi Ki Sun;Kang Dae Eon;Yang Won Jik;You Young Chan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.125-128
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    • 2005
  • Recently new materials, such as fiber reinforced polymer(FRP) and other composite materials are being applied in reinforcing plate or plate or prestressing cables of concrete structures. Although these new materials themselves show the excellent durability and high strength, the bond behaviour between concrete surface and FRP is not well recognized. Therefore, this paper propose a evaluation method for effective bond length between fiber reinforced polymer(FRP) and concrete. To develop the evaluation method, this paper presents a review of current evaluation methods for effective bond length. These methods are compared by single face test, expose merits and demerits. And based on them, new evaluation method was developed. Finally, the new method was compared with existing methods to verify a adequateness for evaluation of effective bond length.

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A study on Linear Pattern Fabrication of Plate-type Polymer by Using Thermal Nano Imprint Lithography Process (열간나노임프린트공정을 이용한 평판형 폴리머 소재의 선형 패턴 제작에 관한 연구)

  • Joung, Y.N.;Lee, C.S.;Youn, S.W.;Kang, C.G.
    • Transactions of Materials Processing
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    • v.18 no.8
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    • pp.616-624
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    • 2009
  • In this work we demonstrate the hot-embossing process under different forming conditions such as forming temperature, load, and holding time in pressing, in order to determine the suitable conditions required for linear patterning on polymer plates (PC). Results showed that the replicated pattern depth increased in proportion to an increase in the forming temperature, load, and time. The reduction of the workpiece thickness increased according to the holding time in the pressing process. In the process of time, the reduction ratio of the workpiece thickness decreased due to the surface area increment of the workpiece, while the pressure on the workpiece declined. In order to reduce the bulging ratio we introduced a temperature difference between the upper and the lower punch.

Effect of Surface Modification of Donor Plate on the Fabrication of OLED Devices by LITI Process

  • Bae, Heung-Kwon;Kim, Jin-Hoo;Kwon, Hyeok-Yong;Lee, Yoon-Soo;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.784-786
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    • 2009
  • Thermal transfer of emitting layer from the donor film to the substrates depends on the physical interaction between the donor film, the emitting layer, and the hole-transport layer (HTL). The interfacial adhesion between the donor film and the EML, the cohesive force of the EML, and the interfacial adhesion between the EML and the HIL have to be optimized to achieve good LITI pattern quality. It was found that surface pretreatment of the donor plate was important on the laser induced thermal transfer of the emitting layer onto the HIL layer of the OLED devices.

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Evaluation of Shear Strength for Reinforced Flat Plates Embedded with GFRP Plates (매립형 GFRP 판으로 보강된 플랫 플레이트의 전단강도 평가)

  • Hwang, Seung Yeon;Kim, Min Sook;Lee, Young Hak;Kim, Heecheul
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.27 no.2
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    • pp.121-128
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    • 2014
  • In this study, The purpose of this study is to experimentally investigate the shear behavior of reinforced flat plate embedded with GFRP(glass fiber reinforced polymer) plate with openings. The GFRP shear reinforcement is manufactured into a plate shape with several openings to ensure perfect integration with concrete. The test was performed on 7 specimens. the parameters include the type of reinforcement and amount of the shear reinforcement., From the test, we analysed the crack, failure mode, Strain, load-displacement graph. a calculation of the shear strength of reinforced flat plate with GFRP plate based on the ACI 318-11 was compared with the test results. The results of the experiment indicate that GFRP plate is successfully applied as a shear reinforcement in the flat plate under punching shear.

Experimental Investigation on the Drag Reduction for an Axi-symmetric Body by Micro-bubble and Polymer Solution

  • Yoon, Hyun-Se;Park, Young-Ha;Van, Suak-Ho;Kim, Hyung-Tae;Kim, Wu-Joan
    • Journal of Ship and Ocean Technology
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    • v.8 no.1
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    • pp.1-9
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    • 2004
  • Experiments on friction drag reduction by injecting polymer (Polyethylene oxide) solution or micro-bubbles were carried out in the cavitation tunnel of KRISO. Two different drag reduction mechanisms were applied to a slender axi-symmetric body to measure the total drag reduction. And then the amount of friction drag reduction was estimated under the assumption that the reduction mechanisms were effective only to the friction drag component. As the result of the tests, polymer solution drag reduction up to 23% of the total drag was observed and it corresponds to about 35% of the estimated friction drag of the axi-symmetric body. This result matched reasonably well to that of the flat plate test "(Kim et al, 2003)". The normalization of the controlling parameters was tried at the end of this paper. Micro-bubble drag reduction was within 1% of its total drag. This unexpected result was quite different from that of the flat plate case "(Kim et at, 2003)" The possible reasons were discussed in this paper.