• Korean Chemical Engineering Research
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• v.49 no.6
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• pp.758-763
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• 2011

In this work, polymer composite electrolytes were prepared by a blend of poly(methyl methacrylate) (PMMA) and poly(ethylene oxide) (PEO) as a polymer matrix, propylene carbonate as a plasticizer, $LiClO_4$ as a salt, and by containing a different content of $TiO_2$, by using the solution casting method. The crystallinity and ionic conductivity of the polymer electrolytes was evaluated using X-ray diffraction(XRD) and AC impedance method, respectively. The morphology of composite electrolyte film was analyzed by SEM method. From the experimental results, by increasing the $TiO_2$ content, crystallinity of PEO was reduced, and ionic conductivity was increased. In particular, the ionic conductivity was dependent on the content of $TiO_2$ and showed the highest value 15 wt%. However, when $TiO_2$ content exceeds 15 wt%, the ionic conductivity was decreased. According to the surface morphology, the ionic conductivity was decreased because the polymer composite electrolytes showed a heterogenous morphology of fillers due to immiscibility or aggregation of the filler within the polymer matrix.

• The Korean Journal of Ceramics
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• v.5 no.3
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• pp.278-283
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• 1999

Formaldehyde has widely been used for the cross-linking of polyvinyl alcohol polyvinyl alcohol polymer. The effects of formaldehyde on the water resistance of MDF cement composites were investigated as a function of types of catalyst, base or acid, and the amount of formaldehyde. The acetalization, reaction of OH group of PVA with aldehyde, was ended incompletely under base atmosphere. However, by addition of citric acid, the cross-linking of PVA polymer could be acheved through acetalization of PVA and formaldehyde. The effects of these different patterne according to the types of catalyst on the water resistance of MDF cement were studied by the preparation of PVA films and MDF composites. Thanks to the cross-linking reaction of PVA polymer chains by formaldehyde, the modified PVA films and MDF composites showed a good water-resistant propety. The modified MDF cement composite to which 3 wt% formaldehyde and 1 wt% cirtic acid were added showed 80% of initial flexural strength and good interfacial state between cement grain and polymer matrix. However, 4 wt% formaldehyde deteriorted the processing conditions, microstructures and eventually the flexural strength, causing sharp increase in the viscosity of sample dough during the mixing process. To study the relatins of flexural strength and interface of cement grain and polymer matrix, SEM and MIP measurement were performed.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.548-548
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• 2012

Thermomechanical and surface chemical properties of composite films of poly(D, L-lactic-co-glycolic acid) (PLGA) were significantly improved by the addition of graphene oxide (GO) nanosheets as nanoscale fillers to the PLGA polymer matrix. Enhanced thermomechanical properties of the PLGA/GO (2 wt.%) composite film, including an increase in the crystallization temperature and reduction in the weight loss, were observed. The tensile modulus of a composite film with increased GO fraction was presumably enhanced due to strong chemical bonding between the GO nanosheets and PLGA matrix. Enhanced hydrophilicity of the composite film due to embedded GO nanosheets also improved the biocompatibility of the composite film. Improved thermomechanical properties and biocompatibility of the PLGA composite films embedded with GO nanosheets may be applicable to biomedical applications such as scaffolds.

• Journal of Sensor Science and Technology
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• v.22 no.6
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• pp.400-403
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• 2013

The piezoelectric composite film of ferroelectric PZT ceramic ($PbZr_xTi_{1-x}O_3$) and polymer (PDMS, Polydimethylsiloxane) was prepared to improve the flexibility of piezoelectric material. The bar coating method was applied to fabricate flexible nanocomposite film with large surface area by low cost process. In the case of using metal electrode on the composite film, although there is no problem by bending process, the electrode is usually broken away from the film by stretching process. However, the well-attached, flexible CNT electrode on PZT/PDMS film improved flexibility, especially stretchability. PZT particles was usually settled down into polymer matrix due to gravity of the weighty particle, so to improve the dispersion of PZT powder in polymer matrix, small amount of additives (CNT powder, Carbon nanotube powder) was physically mixed with the matrix. By stretching the film, an output voltage of PZT(70 wt%)/PDMS with CNT (0.5 wt%) was measured.

• Proceedings of the Korean Society For Composite Materials Conference
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• 1999.11a
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• pp.1-4
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• 1999

The attenuation coefficients of SiC particle reinforced low-density polyethylene (LDPE) matrix composites were measured by pulse echo method and dynamic elastic measure method with varying the volume fraction of SiC particle ranged from 0% to 40% and the size of SiC particles ranged from 0.8$\mu$m to 48$\mu$m. The SiCp/LDPE composites were fabricated with the melt injection process and the fabricated composites showed almost full density above 99% up to 40vo1% SiCp reinforcements. The attenuation constant of LDPE measured by dynamic elastic constant had same result with that measured by pulse echo method, but the attenuation constant of SiCp/LDPE measured by dynamic elastic constant did not have same result with that measured by pulse echo method.

• Journal of the Korean Wood Science and Technology
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• v.21 no.2
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• pp.31-37
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• 1993

Composites of styrene polymers with woody fibers were prepared, and the effect of compatibilizers on their mechanical properties was evaluated. To improve the compatibility of wood fibers and the matrix polymers, styrene-maleic anhydride copolymer(SMA) and maleic anhydride-modified polymers were used as compatibilizers. As results, maleic anhydride-modified polystyrene and SMA were proved to improve the tensile strength of the molded composites, and also were evaluated as good compatibilizers for the wood fiber polystyrene composite. Cellulosic fiber (dissolving pulp) provided better reinforcement than lignocellulosic fiber(thermomechanical pulp). On the contrary in the case of the composite of wood fiber and acrylonitrile-butadiene styrene copolymer(ABS), SMA and maleic anhydride-modified acrylonitrile-butadiene-styrene copolymer(MABS) did not act as compatibilizers. However, MABS was evaluated as a good polymer matrix to make wood fiber reinforced composite. The tensile properties of the composites of wood fiber and MABS were superior than those of wood fiber-ABS composites.

• Composites Research
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• v.37 no.3
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• pp.186-189
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• 2024

This study compared and evaluated the mechanical properties of carbon fiber reinforced thermoplastic polymer (CFRTP) mixed with nanofillers. After mixing various nanofillers such as Multi-wall carbon nanotube (MWCNT), Silicon oxide, Core shell rubber, and Aramid nanofiber with Polyamide 6 (PA6) resin, this is used as a matrix to create a carbon fiber reinforced composite material (CFRP) was manufactured and its physical properties were measured. Depending on the type and mixing ratio of nanofiller, tensile strength, inter-laminar shear strength (ILSS), and Izod impact strength were measured. In terms of tensile strength and impact strength, the highest values were obtained when mixing core shell rubber, however the ILSS was optimal when mixing less than 1 wt.% of silicon oxide.

• Carbon letters
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• v.19
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• pp.1-11
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• 2016

In efforts to characterize and understand the properties and processing of phenylethynyl-terminated imide (LaRC PETI-5, simply referred to as PETI-5) oligomers and polymers as a high-temperature sizing material for carbon fiber-reinforced polymer matrix composites, PETI-5 imidization and thermal curing behaviors have been extensively investigated based on the phenylethynyl end-group reaction. These studies are reviewed here. In addition, the use of PETI-5 to enhance interfacial adhesion between carbon fibers and a bismaleimide (BMI) matrix, as well as the dynamic mechanical properties of carbon/BMI composites, are discussed. Reports on the thermal expansion behavior of intercalated graphite flake, and the effects of exfoliated graphite nanoplatelets (xGnP) on the properties of PETI-5 matrix composites are also reviewed. The dynamic mechanical and thermal properties and the electrical resistivity of xGnP/PETI-5 composites are characterized. The effect of liquid rubber amine-terminated poly(butadiene-co-acrylonitrile) (ATBN)-coated xGnP particles incorporated into epoxy resin on the toughness of xGnP/epoxy composites is examined in terms of its impact on Izod strength. This paper provides an extensive overview from fundamental studies on PETI-5 and xGnP, as well as applied studies on relevant composite materials.

• International Journal of Aerospace System Engineering
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• v.7 no.1
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• pp.16-20
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• 2020

The recent trend is increasing towards the usage of polymer matrix composites since they have a wide variety of applications. They have applications in the field of aircraft and space industry, sporting goods, medical devices, marine and automotive applications and also in commercial usage. The most commonly used fibre-reinforced polymer matrix composite is Glass fibre reinforced epoxy (GFRE) composite which is used in aviation, sports and automotive industries. However, the strength of GFRE composites is not adequate for structural applications. Therefore, the current research focuses on increasing the strength of GFRE composites by reinforcing with micro Graphite (Gr) particulates. The Gr used is an ultra-fine powder with particle size 250 ㎛. Gr is known to have good wear resistance, thermal conductivity and can operate at high temperatures. Gr particulates are mixed with the epoxy matrix in various weight ratios. Hand-lay technique is used for fabricating the composites. Mechanical properties such as tensile strength, elongation, compressive strength and flexural strength are obtained experimentally to study the effect of change in Gr content (0-5 wt. %). The tests were done as per ASTM standards.

• Composites Research
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• v.16 no.6
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• pp.33-40
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• 2003

The initial thermal degradation of polymer matrix composite is not observed easily. At the beginning of thermal degradation of polymer matrix composites, phase transformation such as chain scission, oxidation occur, and then micro delamination is produced in matrix and interface between matrix and fiber before blistering. Initial heat damage deteriorate mechanical properties of composites. We presented the detection method of the initial heat damage of composites conveniently using ultrasonic technique. Absorption coefficient and material velocity was measured with thermal degradation and degree of cure. The more thermal degradation was progressed, the more absorption coefficient was increased. When the cure temperature is more high, the absorption coefficient of cured composite is increased and material velocity is decreased. We concluded that cure temperature is more high, the defects such as void is increased and molecular structure cured at high temperature has cross-linking structure which is more absorb the ultrasonic waves.