• Advanced Composite Materials
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• v.16 no.2
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• pp.151-166
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• 2007

High-cycle fatigue characteristics of quasi-isotropic carbon fiber reinforced plastic (CFRP) laminates [-45/0/45/90]s up to $10^8$ cycles were investigated. To assess the fatigue behavior in the high-cycle region, fatigue tests were conducted at a frequency of 100 Hz, since it is difficult to investigate the fatigue characteristics in high-cycle at 5 Hz. Then, the damage behavior of the specimen was observed with a microscope, soft X-ray photography and a 3D ultrasonic inspection system. In this study, to evaluate quantitative characteristics of both transverse crack propagation and delamination growth in the high-cycle region, the energy release rate associated with damage growth in the width direction was calculated. Transverse crack propagation and delamination growth in the width direction were evaluated based on a modified Paris law approach. The results revealed that transverse crack propagation delayed under the test conditions of less than ${\sigma}_{max}/{\sigma}_b$ = 0.3 of the applied stress level.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2000.11a
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• pp.265-270
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• 2000

Injection molding is a very important industrial process for the manufacturing of plastics objects. During an injection molding process of composites, the fiber-matrix separation and fiber orientation are caused by the flow of molten polymer/fiber mixture. As a result, the product tends to be nonhomogeneous and anisotropic. Hence, it is very important to clarify the relations between separation· orientation and injection molding conditions. So far, there is no research on the measurement of fiber orientation using image processing. In this study, the effects of fiber content ratio and molding condition on the fiber orientation-angle distributions are studied experimentally. Using the image processing method, the fiber orientation distribution of weld-line parts in injection-molded products is assessed. And the effects of fiber content and injection molding conditions on the fiber orientation functions are also discussed

• Journal of Surface Science and Engineering
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• v.50 no.6
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• pp.523-530
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• 2017

In this study, we developed the h-BN interphase for ceramic matrix composites (CMCs) through a wet chemical coating method, which has excellent price competitiveness and is a simple process as a departure from the existing high cost chemical vapor deposition method. The optimum condition for nitriding an h-BN interphase using boric acid and urea as precursors were derived, and the h-BN interphase coating through a wet method on a carbon preform of 2.5 D was conducted to apply the optimum conditions to the CMCs. In order to control the coating property via the wet coating method, four parameters were investigated such as dipping time of the specimen in the precursor solution, the ratio of boric acid and urea in the precursor, the concentration of solution where the precursor was dissolved, and the cycle of dipping and dry process. The CMCs was fabricated through polymer impregnation and pyrolysis (PIP) processes and a three-point flexural strength test was conducted to verify the role of the coated h-BN interphase.

• Steel and Composite Structures
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• v.24 no.6
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• pp.727-740
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• 2017

The present paper studies the stability analysis of the continuously graded CNT-Reinforced Composite (CNTRC) panel stiffened by rings and stringers. The Stiffened Panel (SP) subjected to axial and lateral loads is reinforced by agglomerated CNTs smoothly graded through the thickness. A two-parameter Eshelby-Mori-Tanaka (EMT) model is adopted to derive the effective material moduli of the CNTRC. The stability equations of the CNRTC SP are obtained by means of the adjacent equilibrium criterion. Notwithstanding most available literature in which the stiffener effects were smeared out over the respective stiffener spacing, in the present work, the stiffeners are modeled as Euler-Bernoulli beams. The Generalized Differential Quadrature Method (GDQM) is employed to discretize the stability equations. A numerical study is performed to investigate the influences of different types of parameters involved on the critical buckling of the SP reinforced by agglomerated CNTs. The results achieved reveal that continuously distributing of CNTs adjacent to the inner and outer panel's surface results in improving the stiffness of the SP and, as a consequence, inclining the critical buckling load. Furthermore, it has been concluded that the decline rate of buckling load intensity factor owing to the increase of the panel angle is significantly more sensible for the smaller values of panel angle.

• Composites Research
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• v.34 no.2
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• pp.123-128
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• 2021

This paper dealt with multi-scale natural frequency characteristics of wavy CNT (carbon nanotube) reinforced composites by applying the Mori-Tanaka method, rule of mixture, and Halpin-Tsai equation. By compelling benefit of an ad-hoc Eshelby tensor, the load-transfer characteristics of CNT with a waviness implanted in the polymer matrix was determined. The numerical results obtained are in good agreement with those reported by other investigators. Furthermore, the new results reported in this paper show the interactions between CNT weight, waviness ratios and layup sequences of laminated composites. Key observation points are discussed and significant considerations are given in practical designing of CNT reinforced composites.

• Elastomers and Composites
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• v.54 no.1
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• pp.22-29
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• 2019

Chitosan-polyvinyl alcohol (PVA) -bamboo charcoal/silica (CS-PVA-BC/SI) hybrid fillers with compatibilized styrene-butadiene rubber (SBR) composites were fabricated by the interpenetrating polymer network (IPN) method. The structure and composition of the composite samples were characterized by scanning electron microscope (SEM) and Fourier transform infrared spectroscopy (FT-IR). The viscoelastic behaviors of the rubber composites and their vulcanizates were explored using a rubber processing analyzer (RPA) in the rheometer, strain sweep and temperature sweep modes. The storage and loss moduli of SBR increased significantly with the incorporation of different hybrid fillers, which was attributed to the formation of an interphase between the hybrid fillers and rubber matrix, and the effective dispersion of the hybrid fillers. The mechanical properties (hardness, tensile strength, oxygen transmission rate, and swelling rate) of the composite samples were characterized in detail. From the results of the mechanical test, it was found that BC-CS-PVA0SBR had the best mechanical properties. Therefore, the BC-CS-PVA hybrid filler provided the best reinforcement effects for the SBR latex in this research.

• Membrane Journal
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• v.31 no.1
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• pp.61-66
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• 2021

This study was a study on an facilitated transport membrane to replace the cryogenic separation method currently used in olefin/paraffin separation. Cost reduction is also a very important factor to commercialize facilitated transport membranes. However, AgBF4, which has been studied a lot, is a relatively expensive silver salt. To replace this, a PEBAX-2533/ AgCF3SO3/Al(NO3)3 composite film was prepared using relatively inexpensive AgCF3SO3. It was analyzed through SEM, FT-IR, and RAMAN. Through this study, it was confirmed that the polymer matrix affects the long-term stability.

• Elastomers and Composites
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• v.55 no.4
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• pp.347-353
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• 2020

Stearic acid (SA), polyethylene glycol (PEG), and malic acid (MA) have been used to modify the surface of waste gypsum to develop corresponding poly (butylene adipate-co-terephthalate) (PBAT) composites. According to the mechanical properties, MA-treated gypsum (MA-gypsum) showed the best performance, whereas SA-gypsum showed the worst performance. In contrast to SA and PEG (having -COOH and -OH as polar functional groups, respectively), the presence of both -OH and -COOH in MA is responsible for the superior surface treatment of gypsum and its better dispersion in the polymer matrix (as revealed by FE-SEM analyses). The presence of long aliphatic chain in SA is supposed to inhibit the dispersion of SA-gypsum. Further, the performance of MA-gypsum/PBAT was enhanced by adding polylactic acid (PLA). The maximum optimized contents of MA-gypsum and PLA are 20 and 7.5 wt% for developing a high-performance PBAT composite.

• Computers and Concrete
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• v.32 no.2
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• pp.207-215
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• 2023

This paper investigates wave propagation in functionally graded carbon nano-reinforced composite (FG-CNTRC) plates under the influence of temperature based on Reddy' plate model. The material properties of Carbon Nanotubes (CNTs) are size-dependent, and the volume fraction of CNTs varies only along the thickness direction of the plate for different CNTs reinforcement modes. In addition, the material properties of CNTs can vary for different temperature parameters. By solving the eigenvalue problem, analytical dispersion relations can be derived for CNTRC plates. The partial differential equations for the system are derived from Lagrange's principle and higher order shear deformation theory is used to obtain the wave equations for the CNTRC plate. Numerical analyses show that the wave propagation properties in the CNTRC plate are related to the volume fraction parameters of the CNTRC plate and the distribution pattern of the CNTs in the polymer matrix. The effects of different volume fractions of CNTs and the distribution pattern of carbon nanotubes along the cross section (UD-O-X plate) are discussed in detail.

• Journal of the Korean Ceramic Society
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• v.35 no.9
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• pp.939-944
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• 1998

The formation microstructure and properties of novel ceramic composite materials by active filler con-trolled polymer pyrolysis were investigated. Polymethlsiloxane filled with W is of particular interested be-cause of the formation of ceramic bonded hard materials (WC-$W_{2}C$-$S_{1}OC$) for wear resistant applications. Highly metal-filled polymer suspensions were prepared and their conversion to ceramic composites by an-nealing in $N_{2}C$ atmosphere at 1000-$1600^{\circ}C$ were studied. Dimensional change porosity and phase distribution (filler network) were analyzed and correlated to the resulting material properties. Microcrystalline com-posites with the filler reaction products embedded to the resulting material properties. Microcrystalline com-posites with the filler reaction products embedded in a silicon oxycarbide glass matrix were produced. De-pending on the pyrolysis conditions ceramic composites with a density up to 95 TD% a hardness of 7-8.8GPa Yong's modulus of 220-230 GPa a fracture toughness of 6-6.8$MPam^{1/2}$ and a flexual strength of 380-470 MPa were obtained.