• Current Applied Physics
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• v.18 no.11
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• pp.1235-1239
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• 2018

We present a novel process to fabricate three-dimensional (3D) metallic patterns from 3D printed polymeric structures utilizing different hygroscopic swelling behavior of two different polymeric materials. 3D patterns are printed with two different polymers as cube shape. The surface of the 3D printed polymeric structures is plated with nickel by an electroless plating method. The nickel patterns on the surface of the 3D printed cube shape structure are formed by removing sacrificial layers using the difference in the rate of hygroscopic swelling between two printing polymer materials. The hygroscopic behavior on the interfaced structure was modeled with COMSOL Multiphysics. The surface and electrical properties of the fabricated three-dimensional patterns were analyzed and characterized.

• Corrosion Science and Technology
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• v.20 no.6
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• pp.347-360
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• 2021

Currently, the demand for eco-friendly energy sources is high, which has prompted research on polymer electrolyte membrane fuel cells. Both aluminum alloys and nickel alloys, which are commonly considered as materials of bipolar plates in fuel cells, oxide layers formed on the metal surface have excellent corrosion resistance. In this research, the electrochemical characteristics of 6061-T6 aluminum alloy and Inconel 600 were investigated with chloride concentrations in an acid environment that simulated the cathode condition of the PEMFC. After potentiodynamic polarization experiments, Tafel analysis and surface analysis were performed. Inconel 600 presented remarkably good corrosion resistance under all test conditions. The corrosion current density of 6061-T6 aluminum alloy was significantly higher than that of Inconel 600 under all test conditions. Also, 6061-T6 aluminum alloy and Inconel 600 presented uniform corrosion and intergranular corrosion, respectively. The Ni, Cr, and Fe, which are the main chemical compositions of Inconel 600, are higher than Al in the electromotive force series. And a double oxide film of NiO-Cr₂O₃, which is more stable than Al₂O₃, is formed. Thus, the corrosion resistance of Inconel 600 is better.

• Structural Engineering and Mechanics
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• v.85 no.3
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• pp.315-335
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• 2023

Limited studies are available on the mathematical estimates of the compressive strength (CS) of glass fiber-embedded polymer (glass-FRP) compressive elements. The present study has endeavored to estimate the CS of glass-FRP normal strength concrete (NSTC) compression elements (glass-FRP-NSTC) employing two various methodologies; mathematical modeling and artificial neural networks (ANNs). The dataset of 288 glass-FRP-NSTC compression elements was constructed from the various testing investigations available in the literature. Diverse equations for CS of glass-FRP-NSTC compression elements suggested in the previous research studies were evaluated employing the constructed dataset to examine their correctness. A new mathematical equation for the CS of glass-FRP-NSTC compression elements was put forwarded employing the procedures of curve-fitting and general regression in MATLAB. The newly suggested ANN equation was calibrated for various hidden layers and neurons to secure the optimized estimates. The suggested equations reported a good correlation among themselves and presented precise estimates compared with the estimates of the equations available in the literature with R²= 0.769, and R² =0.9702 for the mathematical and ANN equations, respectively. The statistical comparison of diverse factors for the estimates of the projected equations also authenticated their high correctness for apprehending the CS of glass-FRP-NSTC compression elements. A broad parametric examination employing the projected ANN equation was also performed to examine the effect of diverse factors of the glass-FRP-NSTC compression elements.

• Journal of the Korean Society for Heat Treatment
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• v.35 no.5
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• pp.262-269
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• 2022

In order to process materials such as engineering plastics, which are difficult to mold due to their high strength compared to conventional polymer materials, it is necessary to improve the hardness and strength of parts such as screws and barrels of injection equipment in extrusion system. High-velocity oxygen fuel (HVOF) process is well known for its contribution on enhancement of surface properties. Thus in this study, using the HVOF process, WC coating layers of different thicknesses were bonded to the surface of S30C substrate by controlling the movement speed of the spray nozzle and each property was evaluated to decide the optimization condition. Through the results, the thickness of WC coating layer increased from 0 to 200 ㎛ maximum, along with the decrement of nozzle movement speed and the surface hardness get increased. Especially, the coated layer with the thickness over 180 ㎛ under the nozzle speed 500 mm/s had high hardness than thinner layer. In addition, the amount of wear consumed per unit time was also significantly reduced due to the formation of the coating layer.

• Prospectives of Industrial Chemistry
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• v.24 no.3
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• pp.14-27
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• 2021

수소 에너지는 환경 문제를 최소화하고 고갈되는 화석연료를 대체할 수 있는 에너지원으로 각광을 받고 있다. 수소연료전지는 이러한 수소를 에너지원으로 사용하고 수소를 전기에너지로 전환하여 그 부산물로 물을 만드는 대표적인 친환경 전기화학 장치이다. 고분자 전해질막 연료전지는 수소이온교환 특성을 갖는 고분자막을 전해질로 사용하는 연료전지로 막전극집합체의 전극층은 촉매가 포함된 고분자 전해질막 연료전지의 주요 요소 중의 하나이다. 소재개발 측면에서 고분자 전해질막 연료전지 전극층 핵심 소재의 물성 발현 원리 등을 이해하고 최적화된 소재 설계를 위해서는 원자레벨에서의 소재 설계 접근법이 필요하다. 따라서 실험적인 연구가 어려운 부분과 원자단위에서의 물질 현상에 대한 이해 그리고 연구 개발의 효율성 증진을 위해 전산재료과학(computational materials science) 기술이 광범위하게 활용될 수 있다. 본 기고문에서는 고분자 전해질막 연료전지에서의 전극층 소재에 대한 분자동역학 기반의 전산모사 활용과 연구동향에 대하여 소개하고자 한다.

• Journal of Electrochemical Science and Technology
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• v.14 no.3
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• pp.283-292
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• 2023

Currently, spray coating has attracted interest in the mass production of anode catalyst layers for proton exchange membrane water electrolysis (PEMWE). The solvent in the spray ink is a critical factor for the catalyst dispersion in ink, the microstructure of the catalyst layer, and the PEMWE performance. Herein, various pure organic solvents were examined as a substitute for conventional isopropanol-deionized water (IPA-DIW) mixture for ink solvent. Among the polar solvents that exhibited better IrO₂ dispersion over nonpolar solvents, 2-butanol (2-BuOH) was selected as a suitable candidate. The PEMWE single cells were fabricated using 2-BuOH at various ionomer contents, spray nozzle types, and drying temperatures, and their performance was compared to the cells fabricated using a conventional IPA-DIW mixture. The PEMWE single cells with 2-BuOH solvent showed good performances comparable to the conventional IPA-DIW mixture case and highly durable performances under accelerated degradation tests.

• Journal of Korean Association for Spatial Structures
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• v.23 no.2
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• pp.79-90
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• 2023

Existing reinforced concrete (RC) frame buildings have seismic vulnerabilities because of seismically deficient details. In particular, since cumulative damage caused by successive earthquakes causes serious damage, repair/retrofit rehabilitation studies for successive earthquakes are needed. This study investigates the repair effect of fiber-reinforced polymer jacketing system for the seismically-vulnerable building structures under successive earthquakes. The repair modeling method developed and validated from the previous study was implemented to the building models. Additionally, the main parameters of the FRP jacketing system were selected as the number of FRP layers associated with the confinement effects and the installation location. To define the repair effects of the FRP jacketing system with the main parameters, this study conducted nonlinear time-history analyses for the building structural models with the various repairing scenarios. Based on this investigation, the repair effects of the damaged building structures were significantly affected by the damage levels induced from the mainshocks regardless of the retrofit scenarios.

• Earthquakes and Structures
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• v.24 no.2
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• pp.97-109
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• 2023

This experimental study investigates the effectiveness of applying carbon fiber reinforced polymer (CFRP) jackets for the retrofit of short reinforced concrete (RC) columns with inadequate transverse reinforcement and stirrup spacing to longitudinal rebar diameter equal to 12. RC columns scaled at 1/3, with round and square section, were subjected to axial compression up to failure. A damage scale is introduced for the assessment of the damage severity, which focusses on the extent of buckling of the longitudinal rebars. The damaged specimens were subsequently repaired with unidirectional CFRP jackets without any treatment of the buckled reinforcing bars and were finally re-tested to failure. Test results indicate that CFRP jackets may be effectively applied to rehabilitate RC columns (a) with inadequate transverse reinforcement constructed according to older practices so as to meet modern code requirements, and (b) with moderately buckled bars without the need of previously repairing the reinforcement bars, an application technique which may considerably facilitate the retrofit of earthquake damaged RC columns. Factors for the estimation of the reduced mechanical properties of the repaired specimens compared to the respective values for intact CFRP-jacketed specimens, in relation to the level of damage prior to retrofit, are proposed both for the compressive strength and the average modulus of elasticity. It was determined that the compressive strength of the retrofitted CFRP-jacketed columns is reduced by 90% to 65%, while the average modulus of elasticity is lower by 60% to 25% in respect to similar undamaged columns jacketed with the same layers of CFRP.

• Journal of Sensor Science and Technology
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• v.32 no.5
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• pp.295-299
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• 2023

Herein, we propose a simple fabrication method for MXene-coated V-groove sensors for applications. To enhance the sensitivity of this sensor, we applied MXene particles, instead of conventional metal layers, as a sensing material on the sensor's surface. This allows for an easier fabrication, as well as higher sensitivity of the sensor compared to those of our previously demonstrated metal-based V-groove sensor. Additionally, polyurethane-acrylate, a UV-curable liquid polymer, can be easily applied using micro-electromechanical systems-based surface-texture micromachining. The sensor sensitivity is approximately 0.08 /mm, and it can be improved by increasing the number of V-grooves. We believe that the proposed MXene-based wearable sensor offers a great potential in detecting various types of motions characteristic of human activities.

• Journal of the Korean Applied Science and Technology
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• v.40 no.4
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• pp.913-923
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• 2023

In this study, a triboelectric nanogenerator was fabricated using the composite of teflon-based polymer and graphene flower, which are stable in air and have relatively high electronegativity. The composite was used to fabricate an electronegative layer of a nanogenerator using a spin-coating method. For the electropositive layer, a zinc oxide film was prepared using a sol-gel method. The fabricated triboelectric nanogenerator produced a maximum power of about 44 ㎼. In conclusion, since all the active layers of the triboelectric nanogenerator was made by the solution process, it is scalable to a large area.