• Title/Summary/Keyword: polymer foundation

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The Formation of Metal Nanoparticles in pH-responsive Block Copolymers and Hydrogels

  • Anastasiadis, S.H.;Vamvakaki, M.;Palioura, D.;Spyros, A.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.85-85
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    • 2006
  • The micellization behavior and the metal-nanoparticle formation in PDEAEMA-b-PHEGMA double hydrophilic block copolymers are investigated. The hydrophobic PDEAEMA block is pH-sensitive: at low pH it can be protonated and it becomes hydrophilic, leading to molecular solubility, whereas at higher pH micelles are formed; the behavior is studied by DLS, NMR and AFM. In these micellar nanoreactors, metal nanorystals nucleate and grow upon reduction with sizes in the range of a few nm's as observed by TEM and XRD. Similarly, metal nanocrystals can be formed within pH-sensitive microgels (${\sim}250nm$ in diameter), synthesized by emulsion copolymerization of DEAEMA, which also exhibit reversible swelling properties in water by adjusting the pH.

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Wave propagation of FG polymer composite nanoplates reinforced with GNPs

  • She, Gui-Lin
    • Steel and Composite Structures
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    • v.37 no.1
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    • pp.27-35
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    • 2020
  • This study examines the wave propagation of the functionally graded polymer composite (FG-PC) nanoplates reinforced with graphene nanoplatelets (GNPs) resting on elastic foundations in the framework of the nonlocal strain gradient theory incorporating both stiffness hardening and softening mechanisms of nanostructures. To this end, the material properties are based on the Halpin-Tsai model, and the expressions for the classical and higher-order stresses and strains are consistently derived employing the second-order shear deformation theory. The equations of motion are then consistently derived using Hamilton's principle of variation. These governing equations are solved with the help of Trial function method. Extensive numerical discussions are conducted for wave propagation of the nanoplates and the influences of different parameters, such as the nonlocal parameter, strain gradient parameter, weight fraction of GNPs, uniform and non-uniform distributions of GNPs, elastic foundation parameters as well as wave number.

Novel technique for preventing make up deterioration using performance materials

  • Miyazawa, Masakazu;Nishikata, Kazuhiro;Mohri, Kunihiko
    • Proceedings of the SCSK Conference
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    • 2003.09b
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    • pp.370-378
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    • 2003
  • MFD (Make up Film Deterioration) is a gradual deterioration of applied make up and is a common problem experienced by most foundation users. Our investigation revealed that for 64% of all make up users MFD is their greatest consern is using foundations. Known that the primary cause of MFD is sebum secretion. We observed that the length of time prior to onset of MFD in people who produce high level of sebum varies significantly from person to person. This suggests that other factors besides quantity of sebum production can affect MFD. Control over this factor would, we believe, be key to developing longer-lasting makeups. We studied the relationship between MFD and skin surface conditions. Our study revealed that furrows on the skin surface affect MFD significantly. Sebum reaches the skin surface from sebaceous glands and flows along furrow on the skin. If there are many deep furrows, it takes longer for sebum to overflow. But if the furrows are few or shallow, sebum quickly overflows and spreads over the skin surface where it can degrade the make up film. Therefore even when the volume of sebum produced is the same, the rate of MFD will be different depending on the number and shape of the furrows. A longer-lasting foundation could be produced by matching personal skin condition, but this would be very difficult because individual variations in texture are very large. Therefore we approached the problem by attempting to impose sebum resistance in under make up and foundation. We have developed two new materials and make up products based on our theory. A new fluoroalkyl acrylate-methacrylates copolymer designed for incorporation in under make up is extremely sebum resistant and sweat proof. Another new acrylate polymer designed for inclusion in foundation absorbs sebum and changes to a solid. Usage tests confirm it is possible to reduce MFD by using under make up and foundation which incorporate our new materials to cover where skin furrows are few or shallow

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Development of Modeling and control Methods for Multi-DOF dielectric polymer actuator

  • Jung, M.Y.;Jung, K.M.;Koo, J.C.;Choi, H.R.;Nam, J.D.;Lee, Y.K.
    • 제어로봇시스템학회:학술대회논문집
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    • 2004.08a
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    • pp.1225-1228
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    • 2004
  • Principles and mechanism of energy transduction of dielectric polymer materials are well known from the various smart material related publications. However their introduction to industrial actuator applications is limited mainly due to difficulties guarantee controllability and reliability. Most of the previous publications have elaborates energy transduction physics of chunk of polymer while development of construction methods for feasible actuators made of the material is rarely proposed. In the present article, a conceptual design of multi-DOF linear polymer actuator construction that is to be controllable with moderate level of control work os introduced. In addition, numerical models that are developed with a unified energy based approach are presented not only for basic working mechanism analysis of the polymetric soft actuator but for providing analytical foundation to expend the concept toward design of multi-DOF actuator controls.

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Buckling of concrete columns retrofitted with Nano-Fiber Reinforced Polymer (NFRP)

  • Bilouei, Babak Safari;Kolahchi, Reza;Bidgoli, Mahmood Rabani
    • Computers and Concrete
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    • v.18 no.5
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    • pp.1053-1063
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    • 2016
  • As concrete is most usable material in construction industry it's been required to improve its quality. Nowadays, nanotechnology offers the possibility of great advances in construction. For the first time, the nonlinear buckling of straight concrete columns armed with single-walled carbon nanotubes (SWCNTs) resting on foundation is investigated in the present study. The column is modelled with Euler-Bernoulli beam theory. The characteristics of the equivalent composite being determined using the Mori-Tanaka model. The foundation around the column is simulated with spring and shear layer. Employing nonlinear strains-displacements, energy methods and Hamilton's principal, the governing equations are derived. Differential quadrature method (DQM) is used in order to obtain the buckling load of structure. The influences of volume percent of SWCNTs, geometrical parameters, elastic foundation and boundary conditions on the buckling of column are investigated. Numerical results indicate that reinforcing the concrete column with SWCNTs, the structure becomes stiffer and the buckling load increases with respect to concrete column armed with steel.

Study for Applicability of Polymer and Polymer Coated Metal Materials within PBF System (PBF 시스템에서 고분자 및 금속 소재 적용성 연구)

  • Kim, Dong Soo;Bae, Sungwoo
    • Journal of the Korean Society for Precision Engineering
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    • v.32 no.9
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    • pp.765-771
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    • 2015
  • In an Additive Manufacturing (AM) system emplying the Powder Bed Fusion (PBF) system, polyamide-12 powder is currently recognized as the general material used. The Polyamide-12 powder's properties include an average particle size of 58 $58{\mu}m$, a density of 0.59 g/cm3, and melting point of $184^{\circ}C$, and can also be to used coat materials for metal powder. For this reason, the sintering process is similar to the polymer powder and polymer coated metal powder process, except during the post-process. The polyamide-12 powder has some disadvantages such as its high cost and the fact that it can only be used for the provided equipment from the maker. Therefore, this study aims to perform the applicability of new material, polymer and polymer coated metal, to the PBF system.

The Properties of Polymer Concrete Recycling Plastic Waste (폐플라스틱을 재활용한 폴리머 콘크리트 특성)

  • 조병완;문린곤;박승국;임상헌
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.441-444
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    • 2003
  • Polymer concrete has more useful than cement concrete in the strength and durability. So, it is widely utilizing as panel for wall, manhole for communication, foundation and underground connection box, etc. But polymer concrete is a defect that is disadvantageous in economical aspect because cost of resin is expensive. Polymer concrete (PC) using unsaturated polyester resins based on recycled polyethylene terephthalate(PET) plastic waste were used in our study for grasping its mechanical properties such as compressive strength, tensile strength, flexural strength and chemical resistance was tested by dealing with 20% HCl, 30% NaOH. As a result of it, compressive, tensile and flexural strength of PC indicated 752kgf/$\textrm{cm}^2$, 80kgf/$\textrm{cm}^2$ and 243kgf/$\textrm{cm}^2$ kind of satisfaction successively. Also, properties of chemical resistance are superior to those of cement concrete.

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Composite Foams for Sandwich Structures

  • Nutt, Steven R.;Shen, B.;Vaikhanski, Lev
    • Journal of the Korean Ceramic Society
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    • v.40 no.7
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    • pp.625-631
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    • 2003
  • Recent work at USC has focused on strategies to enhance the toughness and overall mechanical performance of polymer foams for use in lightweight sandwich structures. Both mechanical and chemical approaches have been employed with reasonable success. Fiber reinforcement, though difficult from a processing perspective, can lead to substantial enhancements in toughness and strength, while reducing friability. Chemical modifications are also challenging from a processing perspective, but can produce similar enhancements in performance. Efforts to enhance performance of phenolic foam and PVC foam through fiber reinforcement and chemical modification are described, along with the resulting enhancements in performance.

Deflection and stress behaviour of multi-walled carbon nanotube reinforced laminated composite beams

  • Lal, Achchhe;Markad, Kanif
    • Computers and Concrete
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    • v.22 no.6
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    • pp.501-514
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    • 2018
  • The paper presents the thermo-mechanically induced non-linear response of multiwall carbon nanotube reinforced laminated composite beam (MWCNTRCB) supported by elastic foundation using higher order shear deformation theory and von-Karman non-linear kinematics. The elastic properties of MWCNT reinforced composites are evaluated using Halpin-Tsai model by considering MWCNT reinforced polymer matrix as new matrix by dispersing in it and then reinforced with E-glass fiber in an orthotropic manner. The laminated beam is supported by Pasternak elastic foundation with Winkler cubic nonlinearity. A generalized static analysis is formulated using finite element method (FEM) through principle of minimum potential energy approach.