• Microbiology and Biotechnology Letters
• /
• v.25 no.1
• /
• pp.82-88
• /
• 1997

To produce biopolymer, Metarrhizium anisopliae (Metschn.) Sorok was cultured in a medium containing glucose 1.0%, sucrose 2.0% , soluble starch 1.0%, yeast extract 0.5%, polypeptone 0.05%, K$_{2}$HPO$_{4}$ 0.1% MgSO$_{4}$ $\CDOT $ 7H$_{2}$O 0.02%. The culture broth was centrifuged and the polymer was harvested by adding methanol to the culture supermatant. When three times of methanol was added, the polymer was coagulated and precipitated. Then it was further purified through successive SK-1B, SA-20P, HP-20 column chromatographies. This polymer was designated as Biopolymer YU-122.C:H ratio of this Biopolmer YU-122 was 1:2 and small amount of N is detected by CHN analyzer. Glucose and glactose are main components of this polymer. Average molecular weight of this biopolymer was 1.7%$\times $10$^{6}$ by Sepharose 4B gel permeation chromatography. Optimal condition for biopolymer production was investigated. When 5% of mannitol was used as a carbon source, and polypepton as a N source, highest productivity of biopolymer was achieved. C/N ratio as nutrient was also a major factor in polymer production and its optimal ratio was 3.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 1999.11a
• /
• pp.143-148
• /
• 1999

In this paper we present the results of an analytical investigation on the existing concrete structures which are reinforced with carbon fiber grid. The carbon fiber grid and polymer mortar are utilized in the reinforcement of concrete column, beam, and tunnel lining. The physical and mechanical properties of the carbon fiber grid and polymer mortar were obtained experimentally and then used in the analytical investigation. In the analysis concrete structures are modeled with 3-D solid finite elements and the carbon fiber grid is modeled with space frame elements. Through the investigation reinforcing effect of carbon fiber grid on the existing concrete structures is confirmed.

• KSBB Journal
• /
• v.18 no.1
• /
• pp.65-69
• /
• 2003

Two molecular imprinted polymers (MIPs) were prepared by using pentoxifylline and a mixture of caffeine-theophylline (2:1, mole ratio) as the templates, MAA as the monomer, and EDMA as the crosslinker The obtained polymer particles (particle size 25-35 $\mu\textrm{m}$) were packed into a HPLC column (150$\times$3.9mm). The selectivity and chromatographic characterization of the imprinted polymers were studied using pentoxifylline, caffeine, theophylline, theobromine as samples and acetonitrile as the mobile phase, Both imprinted polymers showed increased affinity for structural analogues. By using a mixture of caffeine-theophylline templates MIPs, good separations of caffeine, theobromine and theophylline were obtained, and pentoxifylline and caffeine were partly separated.

• Journal of the Korea Institute of Building Construction
• /
• v.1 no.1
• /
• pp.143-150
• /
• 2001

Permanent-Form is one of system forms for reducing human labor, work costs, oscillation, noise, construction wastes and so on. Permanent-Form is made from precast method in facilities, and carried in construction site to assemble with no demolding. The biggest expense to produce permanent-Form is about manufacturing mold. This papers about structural efficiency evaluation, construction efficiency test. The result of this study is below. (1) In the compressive strength test of column. Fly ash specimen and polymer specimen's strength developed as each 8%, 14% to comparison with standard specimen. The reason of this result from form section area increase and form's reinforcing bar (2) The Degree of column crack in permanent form is lower than another one's The glass fiber's fiber reinforcement effect brings like this. (3) In the flexural load test of beam, the early crack load and maximum load of permanent form use specimen showed 20% higher than standard specimen's. (4) In field application experiment, an constructional error is satisfied with the allowable margin of error, $\pm$5mm (5) When the concrete is placed into the form inside, The transformation degree of permanent form is lower than plywood form's. (6) The concrete packing ability of permanent form is satisfactory. (7) The bonding strength of permanent form shows enough strength - 6kgf/$\textrm{cm}^2$.

• Applied Chemistry for Engineering
• /
• v.25 no.2
• /
• pp.147-151
• /
• 2014

In many polymer processing operations, the diffusion of small molecules in polymeric materials plays an important role. The fundamental physical property required to design and optimize processing operations is the mutual diffusion coefficient. To investigate the transport properties of polymer/solvent systems at infinite dilution, capillary column inverse gas chromatography (CCIGC) is often employed. In this study, diffusion and partition coefficients of cyclic solvents in styrene/butadiene/styrene (SBS) block copolymer were measured over a wide temperature range using the CCIGC technique.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2006.11a
• /
• pp.137-140
• /
• 2006

In this study, a seismic performance of reinforced concrete columns strengthened by a sprayed fiber reinforced polymer (SFRP) is investigated. For this purpose, six column specimens approximately scaled into 2/3, are designed and tested under a constant axial load, 10% of the nominal axial strength of column, and pseudo-static reversed cyclic lateral loading system. Four specimens are strengthened by Sprayed FRP using different combinations of short fibers (carbon or glass fiber) and resins (epoxy or vinyl esther). For comparison, the test investigated in this study also includes a specimen strengthened using carbon fiber reinforced polymer (CFRP), and also a control specimen without strengthening. The results revealed that specimens strengthened using SFRP showed a improved structure behavior, compared to control specimen, in terms of strength, ductility, lateral drift capacity, and energy-absorbtion capacity. In addition, compared to the specimen strengthened using CFRP, Sprayed FRP-strengthened specimens reasonably showed a equivalent seismic performance.

• Steel and Composite Structures
• /
• v.41 no.5
• /
• pp.649-661
• /
• 2021

This paper presents experimental and analytical studies to understand the behavior of crumb rubber concrete (CRC)-filled fiber reinforced polymer (FRP) and steel tube double skin column (DSC) and beam (DSB) members under cyclic loading. The main test variable was the percentage of rubber which ranged from 0 to 40%. For column members, different heights corresponding to different aspect ratios were examined to understand the to understand the effect of DSCs' slenderness on the cyclic response of the columns. the. The behavior of the specimens in terms of failure mode, strain development, energy dissipation, load-displacement response were presented and compared. The ability of the current provisions of the Australian codes to predict the capacity of such double skin members was also evaluated based on the test results. This study concluded that the reduction in the concrete strength was more severe at the material level compared to structural level. Also, as the load changed from axial compression in columns to pure moment in beams the negative effect of rubber percentage on the strength became less significant.

• International Journal of Concrete Structures and Materials
• /
• v.8 no.2
• /
• pp.141-155
• /
• 2014

The use of fiber reinforced polymer (FRP) composites in strengthening reinforced concrete beam-column subassemblies has been scrutinised both experimentally and numerically in recent years. While a multitude of numerical models are available, and many match the experimental results reasonably well, there are not many studies that have looked at the efficiency of different finite elements in a comparative way in order to clearly identify the best practice when it comes to modelling FRP for strengthening. The present study aims at investigating this within the context of FRP retrofitted reinforced concrete beam-column subassemblies. Two programs are used side by side; ANSYS and VecTor2. Results of the finite element modeling using these two programs are compared with a recent experimental study. Different failure and yield criteria along with different element types are implemented and a useful technique, which can reduce the number of elements considerably, is successfully employed for modeling planar structures subjected to in-plane loading in ANSYS. Comparison of the results shows that there is good agreement between ANSYS and VecTor2 results in monotonic loading. However, unlike VecTor2 program, implicit version of ANSYS program is not able to properly model the cyclic behavior of the modeled subassemblies. The paper will be useful to those who wish to study FRP strengthening applications numerically as it provides an insight into the choice of the elements and the methods of modeling to achieve desired accuracy and numerical stability, a matter not so clearly explored in the past in any of the published literature.

• Macromolecular Research
• /
• v.13 no.1
• /
• pp.39-44
• /
• 2005

Ion-exchange polymeric stationary phases presenting amino acid and amino groups were prepared by the surface grafting of glycidyl methacrylate onto a silica gel surface and subsequent amination. Three kinds of amino acids-L-arginine (Arg), D-lysine (Lys), and D-histine (His)-were used in this study. An ion-exchange polymeric stationary phase presenting ethylene diamine (EDA) was also prepared by surface graft polymerization. Separation of the model proteins bovine serum albumin (BSA), chick egg albumin (CEA), and hemoglobin (Hb) was performed using the amino acid- and amine-derived columns. In separating the CEA/BSA mixture, the resolution time of BSA was longer than that of CEA when using the EDA column, whereas the resolution time of BSA was shorter than that of CEA when using the Arg, Lys, and His columns. In the separation of the Hb/BSA mixture, the resolution time of BSA was longer than that of Hb in the EDA column, whereas the resolution time of BSA was shorter than that of Hb in the amino acid columns (D-Lys, L-Arg, and D-His).

• Structural Engineering and Mechanics
• /
• v.61 no.1
• /
• pp.1-13
• /
• 2017

The effectiveness of the repair scheme for the damaged captive-columns with CFRPs (Carbon Fiber Reinforced Polymer) was investigated in terms of response quantities such as strength, ductility, dissipated energy and stiffness degradation. Two 1/3 scale, one-story one-bay RC (Reinforced Concrete) frames were designed to represent the substandard RC buildings in Turkish building stock. The first one, which is the reference specimen, is the bare frame without infill wall. Partial infill wall with opening was constructed between the columns of the second frame and this caused captive column defect. Severe damage was observed with the concentration of shear cracks in the second specimen columns. Then, the damaged members were repaired by CFRP wrapping and retested. For the three test series, similar reversed cyclic lateral displacement under combined effect of axial load was applied to the top of the columns. Overall response of the bare frame was dominated by flexural cracks. Brittle type of shear failure in the column top ends was observed in the specimen with partial infill wall. It was observed that former capacity of damaged members of the second frame was recovered by the applied repair scheme. Moreover, ultimate displacement capacity of the damaged frame was improved considerably by CFRP wrapping.