• Title/Summary/Keyword: polymer column

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Temperature Controllable HPLC Column for Preparative Fractionation of Polymers

  • Im, Kyu-Hyun;Park, Hae-Woong;Kim, Young-Tak;Chang, Tai-Hyun
    • Macromolecular Research
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    • v.16 no.6
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    • pp.544-548
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    • 2008
  • An HPLC column with a self-contained temperature control device was constructed for preparative temperature programmed interaction chromatography. Two Peltier plates were attached to a large bore column ($120{\times}22\;mm$ i.d.) and the column temperature was controlled by PID mode feed back control. At a flow rate of 1.5 mL/min, the column temperature could be increased and decreased at a rate as high as $50^{\circ}C/min$ and $10^{\circ}C/min$, respectively, which is much faster than using a column jacket and bath/circulator. The rapid heating and cooling rates allows a high repetition rate of chromatographic fractionation. The performance of the temperature controllable column was demonstrated successfully by the fractionation of homo-polymer precursors from diblock copolymers.

Energy dissipation of steel-polymer composite beam-column connector

  • Wang, Yun-Che;Ko, Chih-Chin
    • Steel and Composite Structures
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    • v.18 no.5
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    • pp.1161-1176
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    • 2015
  • The connection between a column and a beam is of particular importance to ensure the safety of civil engineering structures, such as high-rise buildings and bridges. While the connector must bear sufficient force for load transmission, increase of its ductility, toughness and damping may greatly enhance the overall safety of the structures. In this work, a composite beam-column connector is proposed and analyzed with the finite element method, including effects of elasticity, linear viscoelasticity, plasticity, as well as geometric nonlinearity. The composite connector consists of three parts: (1) soft steel; (2) polymer; and (3) conventional steel to be connected to beam and column. It is found that even in the linear range, the energy dissipation capacity of the composite connector is largely enhanced by the polymer material. Since the soft steel exhibits low yield stress and high ductility, hence under large deformation the soft steel has the plastic deformation to give rise to unique energy dissipation. With suitable geometric design, the connector may be tuned to exhibit different strengths and energy dissipation capabilities for real-world applications.

A Comparison of Design Strength Equations between Steel and Fiber Reinforced Polymer Composites Columns (철골 및 섬유보강 폴리머(FRP) 복합 기둥의 설계강도식에 관한 비교 연구)

  • Choi, Yeol;Pyeon, Hae-Wan
    • Journal of Korean Association for Spatial Structures
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    • v.3 no.3 s.9
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    • pp.85-93
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    • 2003
  • Steel, concrete and their combination materials are the most 6commonly used materials for civil engineering structural systems such as buildings, bridge structures and other structures. Recently, however, fiber reinforced polymer (FRP) composites, a relatively new composite material made of fibers and polymer resins, have been gradually used in structural systems as an alternative structural material. This paper describes a comparison of design strength equations for steel column and FRP composite column based on design philosophies. The safety factors used in allowable stress design (ASD) are relatively higher in FRP structural design than steel structural design. Column critical stress equations of FRP composites column from an experimental study can be represented by Euler elastic buckling equation at the long-range of slenderness, and an exponential form at the short-range of slenderness as defined in Load and Resistance Factor Design (LRFD) of steel column. The column strength of steel and FRP composite columns in large slenderness is independent of material strength, this result verified the elastic buckling equation as derived by Eq. (15) and Eq. (5).

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Behavior of polymer columns in soft clayey soil: A preliminary study

  • Arasan, Seracettin;Akbulut, Rahim Kagan;Isik, Fatih;Bagherinia, Majid;Zaimoglu, Ahmet Sahin
    • Geomechanics and Engineering
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    • v.10 no.1
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    • pp.95-107
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    • 2016
  • Deep soil mixing with cement and cement-lime mixtures has been widely used for decades to improve the strength of soils. In this study, small-scale laboratory model tests of polymer columns in soft clayey soil were conducted to evaluate the feasibility of using various polymeric compounds as binders in deep soil mixing. Floating and end bearing polymer columns were used to examine the load-settlement relationship of improved soft clayey soils for various area replacement ratios. The results indicate that polymer columns show good promise for use in deep mixing applications.

On the Pyrolysis of Polymers II. Identification of the Products from Polymer Pyrolysis by Gas Chromatography (高分子物質의 熱分解에 關한 硏究 (第2報) Gas Chromatography 에 依한 熱分解生成物의 檢索)

  • Chwa-Kyung Sung
    • Journal of the Korean Chemical Society
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    • v.7 no.2
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    • pp.106-114
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    • 1963
  • The products from polymer pyrolysis at $450^{\circ}$ are cooled with ice, then liquid and gaseous portions are analysed by gas chromatography. Di-2-ethyl hexyl sebacate column, silicone oil column, silica gel column and tetraethyleneglycol dimethylether column, which was most effective for the separation of hydrocarbon gases, are used. Identification of isomers could be secured more effectively by gas chromatography than mass spectrometry. Elucidation of the mechanism for thermal decomposition of polymers could be done through the identification of pyrolysis products. Although more extensive work is needed, some patterns of polymer pyrolysis are discussed.

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Numerical Column Model for Damaged Non-ductile Reinforced Concrete Frame Repaired Using FRP Jacketing System (초기 손상을 입은 비연성 철근콘크리트 골조의 FRP재킷으로 보수된 기둥의 수치해석모델)

  • Shin, Jiuk;Jeon, Jong-Su;Kim, JunHee
    • Journal of the Earthquake Engineering Society of Korea
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    • v.22 no.5
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    • pp.291-298
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    • 2018
  • Existing reinforced concrete building structures have seismic vulnerabilities under successive earthquakes (or mainshock-aftershock sequences) due to their inadequate column detailing, which leads to shear failure in the columns. To improve the shear capacity and ductility of the shear-critical columns, a fiber-reinforced polymer jacketing system has been widely used for seismic retrofit and repair. This study proposed a numerical modeling technique for damaged reinforced concrete columns repaired using the fiber-reinforced polymer jacketing system and validated the numerical responses with past experimental results. The column model well captured the experimental results in terms of lateral forces, stiffness, energy dissipation and failure modes. The proposed column modeling method enables to predict post-repair effects on structures initially damaged by mainshock.

Forced Vibration Testing of Full-scale Non-seismic Reinforced Concrete Frame Structure Retrofitted Using FRP Jacketing System (FRP자켓 시스템이 보강된 비내진 철근콘크리트 골조의 실물 크기 강제 진동 실험)

  • Shin, Jiuk
    • Journal of the Earthquake Engineering Society of Korea
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    • v.22 no.5
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    • pp.281-289
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    • 2018
  • Existing reinforced concrete building structures have seismic vulnerabilities due to their seismically-deficient details resulting in non-ductile behavior. The seismic vulnerabilities can be mitigated by retrofitting the buildings using a fiber-reinforced polymer column jacketing system, which can provide additional confining pressures to existing columns to improve their lateral resisting capacities. This study presents dynamic responses of a full-scale non-ductile reinforced concrete frame retrofitted using a fiber-reinforced polymer column jacketing system. A series of forced-vibration testing was performed to measure the dynamic responses (e.g. natural frequencies, story drifts and column/beam rotations). Additionally, the dynamic responses of the retrofitted frame were compared to those of the non-retrofitted frame to investigate effectiveness of the retrofit system. The experimental results demonstrate that the retrofit system installed on the first story columns contributed to reducing story drifts and column rotations. Additionally, the retrofit scheme helped mitigate damage concentration on the first story columns as compared to the non-retrofitted frame.

Numerical Model of FRP Jacketed RC Column Under Blast Loading Scenario (폭발 하중에 대한 FRP 재킷 시스템이 보강된 철근콘크리트 기둥 해석 모델 개발)

  • Shin, Jiuk
    • Journal of Korean Association for Spatial Structures
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    • v.21 no.2
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    • pp.67-79
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    • 2021
  • This paper aims to develop numerical models for seismically-deficient reinforced concrete columns retrofitted using a fiber-reinforced polymer jacketing system under blast loading scenarios. To accomplish the research goal, a coupling model reproducing blast loads was developed and implemented to the column model. The column model was validated with a past experimental study, and the blast responses were compared to the numerical responses produced by past researchers. The validated modeling method was implemented to the non-retrofitted and retrofitted column models to estimate the effectiveness of the retrofit system. Based on the numerical responses, the retrofit system can significantly reduce the peak dynamic responses under a given blast loading scenario.

Seismic response of concrete columns with nanofiber reinforced polymer layer

  • Motezaker, Mohsen;Kolahchi, Reza
    • Computers and Concrete
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    • v.20 no.3
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    • pp.361-368
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    • 2017
  • Seismic response of the concrete column covered by nanofiber reinforced polymer (NFRP) layer is investigated. The concrete column is studied in this paper. The column is modeled using sinusoidal shear deformation beam theory (SSDT). Mori-Tanaka model is used for obtaining the effective material properties of the NFRP layer considering agglomeration effects. Using the nonlinear strain-displacement relations, stress-strain relations and Hamilton's principle, the motion equations are derived. Harmonic differential quadrature method (HDQM) along with Newmark method is utilized to obtain the dynamic response of the structure. The effects of different parameters such as NFRP layer, geometrical parameters of column, volume fraction and agglomeration of nanofibers and boundary conditions on the dynamic response of the structure are shown. The results indicated that applied NFRP layer decreases the maximum dynamic displacement of the structure. In addition, using nanofibersas reinforcement leads a reduction in the maximum dynamic displacement of the structure.

Performance of headed FRP bar reinforced concrete Beam-Column Joint

  • Md. Muslim Ansari;Ajay Chourasia
    • Structural Engineering and Mechanics
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    • v.90 no.1
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    • pp.71-81
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    • 2024
  • Fiber Reinforced Polymer (FRP) bars have now been widely adopted as an alternative to traditional steel reinforcements in infrastructure and civil industries worldwide due variety of merits. This paper presents a numerical methodology to investigate FRP bar-reinforced beam-column joint behavior under quasi-static loading. The proposed numerical model is validated with test results considering load-deflection behavior, damage pattern at beam-column joint, and strain variation in reinforcements, wherein the results are in agreement. The numerical model is subsequently employed for parametric investigation to enhance the end-span beam-column joint performance using different joint reinforcement systems. To reduce the manufacturing issue of bend in the FRP bar, the headed FRP bar is employed in a beam-column joint, and performance was investigated at different column axial loads. Headed bar-reinforced beam-column joints show better performance as compared to beam-column joints having an L-bar in terms of concrete damage, load-carrying capacity, and joint shear strength. The applicability and efficiency of FRP bars at different story heights have also been investigated with varying column axial loads.